CA1172899A - Process for the production of a frozen chopped egg product - Google Patents
Process for the production of a frozen chopped egg productInfo
- Publication number
- CA1172899A CA1172899A CA000382076A CA382076A CA1172899A CA 1172899 A CA1172899 A CA 1172899A CA 000382076 A CA000382076 A CA 000382076A CA 382076 A CA382076 A CA 382076A CA 1172899 A CA1172899 A CA 1172899A
- Authority
- CA
- Canada
- Prior art keywords
- whites
- yolks
- egg
- temperature
- frozen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims abstract description 38
- 238000004519 manufacturing process Methods 0.000 title abstract description 6
- 210000002969 egg yolk Anatomy 0.000 claims abstract description 129
- 235000013601 eggs Nutrition 0.000 claims abstract description 52
- 238000010438 heat treatment Methods 0.000 claims abstract description 31
- 235000014103 egg white Nutrition 0.000 claims abstract description 28
- 210000000969 egg white Anatomy 0.000 claims abstract description 28
- 235000013345 egg yolk Nutrition 0.000 claims abstract description 19
- 239000000203 mixture Substances 0.000 claims abstract description 18
- 230000008014 freezing Effects 0.000 claims abstract description 16
- 238000007710 freezing Methods 0.000 claims abstract description 16
- 239000000047 product Substances 0.000 claims abstract 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- 238000010257 thawing Methods 0.000 claims description 8
- 239000011230 binding agent Substances 0.000 claims 6
- 102000002322 Egg Proteins Human genes 0.000 abstract description 12
- 108010000912 Egg Proteins Proteins 0.000 abstract description 12
- 239000002245 particle Substances 0.000 abstract description 10
- QCVGEOXPDFCNHA-UHFFFAOYSA-N 5,5-dimethyl-2,4-dioxo-1,3-oxazolidine-3-carboxamide Chemical compound CC1(C)OC(=O)N(C(N)=O)C1=O QCVGEOXPDFCNHA-UHFFFAOYSA-N 0.000 abstract description 9
- 235000013409 condiments Nutrition 0.000 abstract description 5
- 230000003068 static effect Effects 0.000 description 10
- 238000010411 cooking Methods 0.000 description 9
- 229920002472 Starch Polymers 0.000 description 8
- 235000019698 starch Nutrition 0.000 description 7
- 239000000463 material Substances 0.000 description 6
- 239000008107 starch Substances 0.000 description 6
- 240000008415 Lactuca sativa Species 0.000 description 4
- 238000002845 discoloration Methods 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 235000012045 salad Nutrition 0.000 description 4
- 230000002411 adverse Effects 0.000 description 3
- 230000015271 coagulation Effects 0.000 description 3
- 238000005345 coagulation Methods 0.000 description 3
- 238000005520 cutting process Methods 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 235000013305 food Nutrition 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 2
- 235000014633 carbohydrates Nutrition 0.000 description 2
- 150000001720 carbohydrates Chemical class 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000004676 glycans Chemical class 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 229920001282 polysaccharide Polymers 0.000 description 2
- 239000005017 polysaccharide Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000004278 EU approved seasoning Substances 0.000 description 1
- 240000003183 Manihot esculenta Species 0.000 description 1
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 102000035195 Peptidases Human genes 0.000 description 1
- 108091005804 Peptidases Proteins 0.000 description 1
- 241000592503 Speea Species 0.000 description 1
- 206010041662 Splinter Diseases 0.000 description 1
- 238000010793 Steam injection (oil industry) Methods 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920001525 carrageenan Polymers 0.000 description 1
- 235000010418 carrageenan Nutrition 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 230000002844 continuous effect Effects 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 235000011194 food seasoning agent Nutrition 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 229920001592 potato starch Polymers 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 229940024999 proteolytic enzymes for treatment of wounds and ulcers Drugs 0.000 description 1
- BALXUFOVQVENIU-KXNXZCPBSA-N pseudoephedrine hydrochloride Chemical compound [H+].[Cl-].CN[C@@H](C)[C@@H](O)C1=CC=CC=C1 BALXUFOVQVENIU-KXNXZCPBSA-N 0.000 description 1
- 235000008001 rakum palm Nutrition 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVATION OF FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES; CHEMICAL RIPENING OF FRUIT OR VEGETABLES
- A23B5/00—Preservation of eggs or egg products
- A23B5/04—Freezing; Subsequent thawing; Cooling
- A23B5/041—Freezing or cooling without shell
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L15/00—Egg products; Preparation or treatment thereof
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Health & Medical Sciences (AREA)
- Nutrition Science (AREA)
- Meat, Egg Or Seafood Products (AREA)
Abstract
A PROCESS FOR THE PRODUCTION OF
A FROZEN CHOPPED EGG PRODUCT
Abstract of the Disclosure A cooked and frozen chopped egg product is dis-closed which is suitable as a condiment for foodstuffs.
The chopped egg product is produced by a process comprising;
dynamically or continuously preheating egg yolks to a pro-duct temperature which does not exceed about 183°F. and dynamically or continuously preheating egg whites to a product temperature which does not exceed about 167°F.
Preheating of the yolks and whites is followed by stati-cally heating the egg yolks and whites at a temperature and time effective to coagulate the yolks and whites to a substantially firm texture followed by freezing of the coagulated yolks and whites. The frozen whites and yolks are chopped at a temperature of 22 - 30°F. to provide a chopped egg mixture having desirable color and texture, without significant smearing of the yolks on the particles of egg white.
A FROZEN CHOPPED EGG PRODUCT
Abstract of the Disclosure A cooked and frozen chopped egg product is dis-closed which is suitable as a condiment for foodstuffs.
The chopped egg product is produced by a process comprising;
dynamically or continuously preheating egg yolks to a pro-duct temperature which does not exceed about 183°F. and dynamically or continuously preheating egg whites to a product temperature which does not exceed about 167°F.
Preheating of the yolks and whites is followed by stati-cally heating the egg yolks and whites at a temperature and time effective to coagulate the yolks and whites to a substantially firm texture followed by freezing of the coagulated yolks and whites. The frozen whites and yolks are chopped at a temperature of 22 - 30°F. to provide a chopped egg mixture having desirable color and texture, without significant smearing of the yolks on the particles of egg white.
Description
~ ~l 172899 ( SP-750A
~C~9~0 ~ 1ol~
The present invention relates to a chopped egg product and a process for producing the same.
Various types of egg products have been produced for consumer use. Raw egg products have been prepared and frozen in order that they may be subsequently thawed and used in the same manner as fresh eggs. More recently, cooked egg products have ~een produced which are suitable for freezing with subsequent thawing and use. These cooked -egg products are very desirable because of the con~enience .
of simply thawing the pxoduct to permit use by the consumer.
These products and processes for their production are generally described in the following U.S. Patents. I
U.S. Patent 3,510,315 describes a cooked egg product in which the yolks are separately cooked.in a mo]d and placed in a larger mold in which the uncooked e~g whites are placed and cooked surround the yolk. I'he mixture is frozen and a starch material is included in the whites to proYide good freeze-thaw stability. A rozen product with an egg yolk core surrounded by cooked egg white is obtained which can easily he thawed and used by the consumer.
Improvements on the abo~e process for the production of cooked frozen egg products are described in U.S. Patent 3,598,612 in which treatment of the yolk with an oxidizing agent prevents discoloration of the interface area between the yolk and white. U.S. Patent 3/598,613 describes a process in which the yolks are preheated in a jet cooker to a solid or semi-solid state, ground and then heated to form a solid yolk product. U.S. Paten~ 3,798,336 and 3,711,304 describe processes and apparatus for centering of the yolk body in the egg whites before or during cooking to form a core o~
~C~9~0 ~ 1ol~
The present invention relates to a chopped egg product and a process for producing the same.
Various types of egg products have been produced for consumer use. Raw egg products have been prepared and frozen in order that they may be subsequently thawed and used in the same manner as fresh eggs. More recently, cooked egg products have ~een produced which are suitable for freezing with subsequent thawing and use. These cooked -egg products are very desirable because of the con~enience .
of simply thawing the pxoduct to permit use by the consumer.
These products and processes for their production are generally described in the following U.S. Patents. I
U.S. Patent 3,510,315 describes a cooked egg product in which the yolks are separately cooked.in a mo]d and placed in a larger mold in which the uncooked e~g whites are placed and cooked surround the yolk. I'he mixture is frozen and a starch material is included in the whites to proYide good freeze-thaw stability. A rozen product with an egg yolk core surrounded by cooked egg white is obtained which can easily he thawed and used by the consumer.
Improvements on the abo~e process for the production of cooked frozen egg products are described in U.S. Patent 3,598,612 in which treatment of the yolk with an oxidizing agent prevents discoloration of the interface area between the yolk and white. U.S. Patent 3/598,613 describes a process in which the yolks are preheated in a jet cooker to a solid or semi-solid state, ground and then heated to form a solid yolk product. U.S. Paten~ 3,798,336 and 3,711,304 describe processes and apparatus for centering of the yolk body in the egg whites before or during cooking to form a core o~
- 2 -( SP-750~
~ 17289~ ( `` ;
egg yolk concentrically surrounded by the cooked whites.
These products can be conveniently thawed and sliced and easily used by the consumer without cooking and peeling of shell eggs.
The above types of cooked, frozen egg products have been extensively used by restaurants because of the ease of preparation. A recent addition to restaurants and institu-tions engaged in mass feeding in this country, has been the sala~ bar in which the customer can prepare his own salad 10- -with ingredients of his own choosing. A popular ingredient at these salad bars is chopped or diced eggs which can be sprinkled on the salad by the customer. Obviously~ the cooking and chopping of eggs requires an extensive amount of preparation, in addition to the fact that chopping usually smears the yolk over the egg white particles resulting in a pasty mess the consumer does not readily associate with chopped eggs. In addition, when whole eggs are cooked, they also suffer from problems with green discolora~ion of the yolk surface which is visible in a chopped egg product since the particles are exposed by ~irtue of being chopped up or diced.
While the cooked, frozen egg products described above avoid many of the discoloration problems associated with whole eggs, nevertheless, these products also present a poor appearance if they were simply thawed and chopped or diced since the yolk readily smears onto the whites. A
need, therefore, exists fox a chopped frozen egg product without significant smearing of the yolks on the whites, which has a smooth texture, and may be readily thawed and used by the consumer as an ingredient in or as a condiment for foods.
SP-750~
289~
Canadian ~pplication ~erial No. 382,077, filed July 20, 1981, discloses a chopped egg produc-t of highly desixable characteristics in which smearing of tha yolk during chopping i~ avoided by carrying out the chopping at a critically defined temperature range. The process disclosed therein involves a single stage heating step in which the yolks and whites are separately heated to coagulate them prior to chopping.
It would be highly desirable to employ a process in which the yolks and whites can be coagulated on a continuous basis. In evaluating means for the continuous or dynamic coagulation of the yolks and whites, it was determined that the shear forces normally encountered in the dynamic heating of fluids adversely effect the texture of the yolks and the whites and if the temperature was increased during dynamic heating to effectively coagula~e the yolks and whites, the yolks and whites would still mai~tain a soft s~ate.
Accordingly, it was determined that dynamic or con-tinuous heatiny could be used only if it was usad for pre-heating of the ~olks and whites and cArried out below acritically defined product temperature. Dynamic preheating of the yo~ks and whites is followed by heating ox maintaining the product at a given temperature under static conditions to effectively coagulate the yolks and whites to a substantially firm texture and provide the reguisite texture needed for subsequent freezing and chopping of the yolks and whites.
It is, therefore, an object of the present invention to provide a cooked frozen chopped egg product which avoids significant smearing of the yolk on the choppQd egg white particles.
( (~ SP-750~
~ ~ ~2~9 ~ ~
It is also an object o~ the present invention to provide a cooked and frozen chopped egg product which employs a dynamic or continuous cooking process for preheating of the yolks and whites for faster cooking time with greater-energy savings~
It is also an object to provide a cooked and frozen chopped egg product in which the yolk is a bright yellow with an absence of discoloration.
It is also an object to provide a cooked and frozen 1~- ~chopped egg product which has good freeze-thaw stability . ...................... .
without significant deterioration of the yolks and whites during storage.
It is also an object to provide a cooked and frozen chopped egg product which has a smooth but firm texture without significant sticking or clumping,of the particles of yolks and whites.
It is a further object to provide a unique process for the production of a cooked a'nd frozen chopped egg product which meets the above objectives which is reliable and con-venient to practice on a commercial basis.
Summary o~ the Invention These and other ob~ects are achieved in the present invention which pro~ides a unique process for the production of a cooked and frozen chopped egg product.
~ he present process comprises dynamically preheating egg yolks to a product temperature which does not exceed 183F and egg whites to a product temperature which does not exceed 167F followed by static heating of egg yolks and whites at and for a period of time sufficient to coagulate or f ( SP~750A
~ ~289~ `-effectively cook the yolks and,the whites to a substantially firm texture. The separately cooked yolks and whites are then frozen~ A chopped egg mixture is formed by simultaneously or sequentially chopping the rozen whites at a critical temperature range of between about 22 - 30F. to provide a chopped egg mixture in which minimal smearing o the yolk on the whites occurs during chopping and the mixture has a smooth but firm texture. The chopped mixture can then be refrozen and sQld in this fashion for use by restaurants or -institutions as a food condiment. The product represents a . . .
distinct improvement over cooked, chopped, shell eggs in appearance and texture as well as convenience to the user of the product.
A significant factor in the above process which provide the chopped egg product with such desirable appearance and texture is the temperature range at which the simultaneous or sequential chopping of the cooked yolk and white is carried out. For example, if the temperature of the cooked egg during chopping is above this tempexature range, extensive 2a smearing of the yolk and the white occurs resulting in a product with an undesirable appearance. By contrast, at a temperature below this range, the yolk and the white tend to shatter or splinter resulting in an excessive amount of fines which will also detract from the appearance o the mixture.
Likewise, :lt is important relative to the above process that dynamic or continuous preheating be carried out below a specifie~l product t~mperature, since it has been determined i f this temperature is exceeded during dynamic preheating subsequent static heating will not coagulate the yolk and white to a firm texture and it will remain soft.
The combination of dynamic and static heating can improve (: SP 7~0 2 ~ 9 9 the efficiency of the present process by reducing the overall cooking time with yreater energy ~avings.
Descri tion of the Preferred Embodiments P . . ~
In accordance with the present invention, pasteurized liquid egg yolks a~d whites are obtained and placed into separate containers for heating. It is not critical to the present invention that the yolks or whites include additional ingredients although various flavorings, spices, and/or seasonings can be included if desired, It is extremely desirable IQ however, to include a water binding material in the egg whites since the product will be frozen and the addition of the water binding material prevents syneresis during subsequent freezing and thawing of the product. The water binding materials which may be employed in the present invention include polysaccharides or carbohydrates such as colloids, starches, cereals or ~lours capable of absorbing and binding water~ Examples of suitable materials include corn, tapioca, rice and potato starches, 10urs and the like. Polysaccharides such as algins, carrageenans, xanthan gum or various other colloids are also suitable as water binding matexials. Carbohydrates which are particularly pre-~erred are ood starches which have good freeze thaw s~ability or po~sess the abili~y to retain watex in the egg whi~e portion after the product has been frozen and subsequently thawedO The water binding materials ~hould be present in the egg white por-tion in an amount effective to prevent syneresis upon freezing ,and thawing, typically at levels between about 0.5 and 10~
by weight of-the egg whites. A preferred level is between about 2 and 4% by weight of the egg whites.
It is also possible, although not critical, to include proteolytic enzymes or other additives in the egg yolk portion ~ ( c SP~750~
1 172~9~
,i as described in U.S. Patent 3,S10,315, although such an additive can be omitted entirely.
In the present inVentiQn~ a dynamic preheating step is carried ou~ a~ a pxoduct tempexature below about 183F for the egg yolks and 167F for the egg whites. As previously noted, shear conditions, as normally encountered in the dynamic heating of fluids, adversely affect coagulation of the yolks and whites. Accordingly, dynamic heating can only be carried - out in conjunction with a static heating step to effectively Io. coagulate the yolks and whites and must be carried out below certain temperatures in order for the static heating step to effectively coagulate the yolks or whites t~ a substantially firm texture.
Dynamic heating is intended to refer to a continuous process as is normally employed for the heating of fluids and it is not intended to limit the present invention by specific apparatus necessary to carry out the dynamic heating step of the present invention. Typically, various heat exchanger~ in which steam is the primary heating source are suitable, including heat exchangers indirectly heated by the steam or those which utilize dixect steam injection to heat the slurry.
Typical steam pressures are between 0 - 25 psig, more typically lQ - 20 psig. The most critical factor in the use of dynamic preheating for the yolks and whites iB th~ adverse effect of shear on ~exture of the cooked yolks and whitesO To minimize ~his problem it is essential to avoid dynamic preheating at a product temperature above 183F for the yolks and 167F for the whites. Typically, the product temperature range for dynamic preheating should be between about 149-183~F for the yolks and 144-1~7F or the whites. This degree of heat treatment provides ` 11728g9 (: SP-750A
; , sufficient heat to effectively complete ~oagulation of the yolks and white~ to a substantially firm texture during the static heating step. Dynamic heating also increases the overall efficiency of the process by reducing the batch type heating process in which the yolks and whites are coagula~ed in individual containers to result in time and energy savings.
While it is not completely understood why exceeding the above temperature limits during dynamic'heating prevents coagula'~ion of ~he yolks and whites during subsequent static heating, .-; - . .
nevertheless, the heated yolks and whites will not set up or coagulate to a firm texture even with prolonged static heating.
The preheated yolks and whites are placed in separate containers and statical'ly heated to complete coagulation of the yolks and whites. Although the exact type of apparatus or equipment used in the present process is not critical relative to practice of the present invention for the static heating step, a preferred container for heating is to place th0 yolks and whites in flexible containers ox bags for immersion in the cooking baths. This per,mits easy trans~er of the yolks and whites thxough the heatin~ and reezing steps, followed by easy removal o the frozen yolks and whites from the containers pr~or to chopping. Heating of the yolks and whites is carried out in a hot water or steam bath at a temperature of between about 165 - 210F, preferably 170 - 185~F for a period of time suffi-cient to coagulate or effectively cook the egg yolks and whites ,to a substantially firm texture and typically about 10 to 20 minutes. _ The heated or cooked yolks and whites are then removed from the cooking bath and cooled to facilitate rapid freezing _ 9 .
,- SP-750 31~28g9 either by spraying with cool water or dipping the containers into a cool water bath. The heated whites and yolks are then frozen as quickly as possible to a product temperature of 22 - 30F.
After freezing of the product to the above tempera-ture the flexible containers with the frozen yolks and whites are briefly ~armed to permit easy removal of the frozen yolks and whites from the conkainers as an integral mass for choppi~g.
-This ~rief period of warming to permit removal fro~ the con-tainer does not appreciably alter the temperature of the frozenyolks and whites from the desired range of about 22 - 30F.
The separately cooked and frozen yolks and whites at a temperature range of 22 - 30F, preferably 24 - 28F are then chopped by simultaneous or sequential feeding of the frozen yolks and whites to a mechanical chopping or cutting device to quickly subdivide the yolksand whites into small particles~ It is not critical to the practice of the present process at wha~
weight ratio the yolks and whites are combined during chopping and any weight ratio o~ white~ and yolks may be used. A pre-20 ferred weight ratio for the chopped egg product is 30 to 40 partsof yolk to 70 to 60 parts of white. An especially preferred ratio i5 about 30 parts of yolk to 70 parts of white since this weight ratio somewhat approximates the ratio of white to yolk normally found in whole eggsO Chopping may ~e carried out in any type of ~ood cutter or similar device provided the tempera-ture of the product during chopping does not rise above the noted temperature range by exeessive heat generation during chopping.
The chopped, cooked egg product is then rapidly 30 refrozen as a mixture even though only partial thawing on the surfaces of the yolks and whites has taken place ~uring chopping.
f . ( SP-750~ 1 .. . .
~ ~72~99;
The chopped product is b~st frozen while in particulate form before being placed in a container~ A preferred, though n~n-limiting means for quick freezing the chopped yolk and white mix~ure is by using an individual quick frozen sy~tem ~IQF~
of any type for quick freezing of the particulate eggs and whites~
The resultant product, because of separate cooking of the yolks and whites, has no discoloration from contac~
between the two and has a uniform, bright yellow color with .. separate and identifiable pieces of egg white O The particles of chopped white and yolks are xelatively uniform without signi-ficant pasting or smearing of the yolk over the surfaces of the egg white particles. The diced product is highly suitable as a condiment for foodstuffs such as salads and represents a significant improvement over similar con~iments prepared from cooked shell eggs.
The followin~ Examples wil} serve as illustrative but non-limiting embodiments of the present invention Example I
To 30 pounds of pasteuriæed liquid egg whites is added 7O4~ by weight of modified food starch, with the trade-name "Consista" manufactured by A. E. Staley, D~catur, Illinois and mixed.
The egg white, starch mixture and 30 pounds of pasteurized egg yolks are separately preheated ~y pass~ng through a heat exchanger which comprises a 15 ft, 0.209" I.D.
coil which is indirectly heated by steam at a pressure o lO ~ 20 psig in the surrounding chamber for the heat exch~nger coil. The flow rate of yolks and whites through the coil is 2 lb/min. The yolks are preheated to a product ternperature of 180F and the ( ( SP~750 2~
whites preheated to a product temperature of 160F. Following preheating, 2 lb quantities of the egg white-starch mixture and 2 lb quantities of the yolks are metered into flexible, plastic bags. The bags are sealed and placed in a hot water bath held at a temperature of 194F for 10 - 20 minutes. It was observed that the whites and yolks cooked in this manner coagulated satisfactorily and had the characteristically f-irm texture of cooked egg yolks and whites. The bags containing ~ the coagulated yolks and whites are conveyed through a ~ater spray of cool water at 70 - 75F and cooled.
The coagulated yolks and whites are then placed in a blast freezer and frozen to a product temperature of 22 - 30F.
The yolks and whites are removed from the ~lexible bays by brief thawing of the mass of frozen yolks and whites and 70 parts by weight sf the whites and 30 parts by weight of the fxozen yolks are placed in a batch type cutting dev.ice consisting of a rotating bowl and a set o vertically rotating, high speeA cutting blades. The yolks and whites are chopped for a period of 3 minutes.
The chopped egg product is then refrozen before packaging by being passed through individually quick fro~en system (IQF) to quick free~e the particles.
The egg product after chopping and freezing has no significant smearing of the yolks on the particles of egg whites and consisted of relati~ely uniform and distinct pieces of yolks and whites. The chopped product is highly suitable as a condiment ~or foodstuffs.
~ ( SP-750A
~ 17289~ i Example II
To 30 pounds of pasteurized liquid egg whites is added 7.4% by weight of moaified food starch, with the tradename "Consista", manufactured by A. E. Staley, Decatur, Illinois and mixed.
The egg whlte starch mixture and 30 pounds of pasteurized egg yolks are separately preheated by passing through a heat exchanger which comprises a 15 ft. 0.209"
I.D. coil which is indirectly heated by steam at a pressure -of 10 - 20 psig in the surrounding chamber for the heat ....
exchanger coil. The flow rate of the yolks and whites through the coil is 2 pounds/minute. The yolks as preheated to a product temperature of 194~F and the whites preheated to a product temperature of 176F. Following preheating 2 lb.
quantities of the egg white starch mixture and 2 lb. quantities of the yolks are metered into flexible plastlc bags. The bags are sealed and placed in a hot water bath held at a temperature of 194F. for 10 - 20 minutes. The yolks and whites would not set up to form firm coagulated yolks and whites and were judged to be unsuitable for further freezing and processing to form a frozen diced egg product.
Having described the above invention with reference to the above specific embodiments, it is to be understood that numerous variations can be made without departing from the spirit of the invention and it is intended to include such reasonable variations and equivalents within the scope of the present invention.
~ 17289~ ( `` ;
egg yolk concentrically surrounded by the cooked whites.
These products can be conveniently thawed and sliced and easily used by the consumer without cooking and peeling of shell eggs.
The above types of cooked, frozen egg products have been extensively used by restaurants because of the ease of preparation. A recent addition to restaurants and institu-tions engaged in mass feeding in this country, has been the sala~ bar in which the customer can prepare his own salad 10- -with ingredients of his own choosing. A popular ingredient at these salad bars is chopped or diced eggs which can be sprinkled on the salad by the customer. Obviously~ the cooking and chopping of eggs requires an extensive amount of preparation, in addition to the fact that chopping usually smears the yolk over the egg white particles resulting in a pasty mess the consumer does not readily associate with chopped eggs. In addition, when whole eggs are cooked, they also suffer from problems with green discolora~ion of the yolk surface which is visible in a chopped egg product since the particles are exposed by ~irtue of being chopped up or diced.
While the cooked, frozen egg products described above avoid many of the discoloration problems associated with whole eggs, nevertheless, these products also present a poor appearance if they were simply thawed and chopped or diced since the yolk readily smears onto the whites. A
need, therefore, exists fox a chopped frozen egg product without significant smearing of the yolks on the whites, which has a smooth texture, and may be readily thawed and used by the consumer as an ingredient in or as a condiment for foods.
SP-750~
289~
Canadian ~pplication ~erial No. 382,077, filed July 20, 1981, discloses a chopped egg produc-t of highly desixable characteristics in which smearing of tha yolk during chopping i~ avoided by carrying out the chopping at a critically defined temperature range. The process disclosed therein involves a single stage heating step in which the yolks and whites are separately heated to coagulate them prior to chopping.
It would be highly desirable to employ a process in which the yolks and whites can be coagulated on a continuous basis. In evaluating means for the continuous or dynamic coagulation of the yolks and whites, it was determined that the shear forces normally encountered in the dynamic heating of fluids adversely effect the texture of the yolks and the whites and if the temperature was increased during dynamic heating to effectively coagula~e the yolks and whites, the yolks and whites would still mai~tain a soft s~ate.
Accordingly, it was determined that dynamic or con-tinuous heatiny could be used only if it was usad for pre-heating of the ~olks and whites and cArried out below acritically defined product temperature. Dynamic preheating of the yo~ks and whites is followed by heating ox maintaining the product at a given temperature under static conditions to effectively coagulate the yolks and whites to a substantially firm texture and provide the reguisite texture needed for subsequent freezing and chopping of the yolks and whites.
It is, therefore, an object of the present invention to provide a cooked frozen chopped egg product which avoids significant smearing of the yolk on the choppQd egg white particles.
( (~ SP-750~
~ ~ ~2~9 ~ ~
It is also an object o~ the present invention to provide a cooked and frozen chopped egg product which employs a dynamic or continuous cooking process for preheating of the yolks and whites for faster cooking time with greater-energy savings~
It is also an object to provide a cooked and frozen chopped egg product in which the yolk is a bright yellow with an absence of discoloration.
It is also an object to provide a cooked and frozen 1~- ~chopped egg product which has good freeze-thaw stability . ...................... .
without significant deterioration of the yolks and whites during storage.
It is also an object to provide a cooked and frozen chopped egg product which has a smooth but firm texture without significant sticking or clumping,of the particles of yolks and whites.
It is a further object to provide a unique process for the production of a cooked a'nd frozen chopped egg product which meets the above objectives which is reliable and con-venient to practice on a commercial basis.
Summary o~ the Invention These and other ob~ects are achieved in the present invention which pro~ides a unique process for the production of a cooked and frozen chopped egg product.
~ he present process comprises dynamically preheating egg yolks to a product temperature which does not exceed 183F and egg whites to a product temperature which does not exceed 167F followed by static heating of egg yolks and whites at and for a period of time sufficient to coagulate or f ( SP~750A
~ ~289~ `-effectively cook the yolks and,the whites to a substantially firm texture. The separately cooked yolks and whites are then frozen~ A chopped egg mixture is formed by simultaneously or sequentially chopping the rozen whites at a critical temperature range of between about 22 - 30F. to provide a chopped egg mixture in which minimal smearing o the yolk on the whites occurs during chopping and the mixture has a smooth but firm texture. The chopped mixture can then be refrozen and sQld in this fashion for use by restaurants or -institutions as a food condiment. The product represents a . . .
distinct improvement over cooked, chopped, shell eggs in appearance and texture as well as convenience to the user of the product.
A significant factor in the above process which provide the chopped egg product with such desirable appearance and texture is the temperature range at which the simultaneous or sequential chopping of the cooked yolk and white is carried out. For example, if the temperature of the cooked egg during chopping is above this tempexature range, extensive 2a smearing of the yolk and the white occurs resulting in a product with an undesirable appearance. By contrast, at a temperature below this range, the yolk and the white tend to shatter or splinter resulting in an excessive amount of fines which will also detract from the appearance o the mixture.
Likewise, :lt is important relative to the above process that dynamic or continuous preheating be carried out below a specifie~l product t~mperature, since it has been determined i f this temperature is exceeded during dynamic preheating subsequent static heating will not coagulate the yolk and white to a firm texture and it will remain soft.
The combination of dynamic and static heating can improve (: SP 7~0 2 ~ 9 9 the efficiency of the present process by reducing the overall cooking time with yreater energy ~avings.
Descri tion of the Preferred Embodiments P . . ~
In accordance with the present invention, pasteurized liquid egg yolks a~d whites are obtained and placed into separate containers for heating. It is not critical to the present invention that the yolks or whites include additional ingredients although various flavorings, spices, and/or seasonings can be included if desired, It is extremely desirable IQ however, to include a water binding material in the egg whites since the product will be frozen and the addition of the water binding material prevents syneresis during subsequent freezing and thawing of the product. The water binding materials which may be employed in the present invention include polysaccharides or carbohydrates such as colloids, starches, cereals or ~lours capable of absorbing and binding water~ Examples of suitable materials include corn, tapioca, rice and potato starches, 10urs and the like. Polysaccharides such as algins, carrageenans, xanthan gum or various other colloids are also suitable as water binding matexials. Carbohydrates which are particularly pre-~erred are ood starches which have good freeze thaw s~ability or po~sess the abili~y to retain watex in the egg whi~e portion after the product has been frozen and subsequently thawedO The water binding materials ~hould be present in the egg white por-tion in an amount effective to prevent syneresis upon freezing ,and thawing, typically at levels between about 0.5 and 10~
by weight of-the egg whites. A preferred level is between about 2 and 4% by weight of the egg whites.
It is also possible, although not critical, to include proteolytic enzymes or other additives in the egg yolk portion ~ ( c SP~750~
1 172~9~
,i as described in U.S. Patent 3,S10,315, although such an additive can be omitted entirely.
In the present inVentiQn~ a dynamic preheating step is carried ou~ a~ a pxoduct tempexature below about 183F for the egg yolks and 167F for the egg whites. As previously noted, shear conditions, as normally encountered in the dynamic heating of fluids, adversely affect coagulation of the yolks and whites. Accordingly, dynamic heating can only be carried - out in conjunction with a static heating step to effectively Io. coagulate the yolks and whites and must be carried out below certain temperatures in order for the static heating step to effectively coagulate the yolks or whites t~ a substantially firm texture.
Dynamic heating is intended to refer to a continuous process as is normally employed for the heating of fluids and it is not intended to limit the present invention by specific apparatus necessary to carry out the dynamic heating step of the present invention. Typically, various heat exchanger~ in which steam is the primary heating source are suitable, including heat exchangers indirectly heated by the steam or those which utilize dixect steam injection to heat the slurry.
Typical steam pressures are between 0 - 25 psig, more typically lQ - 20 psig. The most critical factor in the use of dynamic preheating for the yolks and whites iB th~ adverse effect of shear on ~exture of the cooked yolks and whitesO To minimize ~his problem it is essential to avoid dynamic preheating at a product temperature above 183F for the yolks and 167F for the whites. Typically, the product temperature range for dynamic preheating should be between about 149-183~F for the yolks and 144-1~7F or the whites. This degree of heat treatment provides ` 11728g9 (: SP-750A
; , sufficient heat to effectively complete ~oagulation of the yolks and white~ to a substantially firm texture during the static heating step. Dynamic heating also increases the overall efficiency of the process by reducing the batch type heating process in which the yolks and whites are coagula~ed in individual containers to result in time and energy savings.
While it is not completely understood why exceeding the above temperature limits during dynamic'heating prevents coagula'~ion of ~he yolks and whites during subsequent static heating, .-; - . .
nevertheless, the heated yolks and whites will not set up or coagulate to a firm texture even with prolonged static heating.
The preheated yolks and whites are placed in separate containers and statical'ly heated to complete coagulation of the yolks and whites. Although the exact type of apparatus or equipment used in the present process is not critical relative to practice of the present invention for the static heating step, a preferred container for heating is to place th0 yolks and whites in flexible containers ox bags for immersion in the cooking baths. This per,mits easy trans~er of the yolks and whites thxough the heatin~ and reezing steps, followed by easy removal o the frozen yolks and whites from the containers pr~or to chopping. Heating of the yolks and whites is carried out in a hot water or steam bath at a temperature of between about 165 - 210F, preferably 170 - 185~F for a period of time suffi-cient to coagulate or effectively cook the egg yolks and whites ,to a substantially firm texture and typically about 10 to 20 minutes. _ The heated or cooked yolks and whites are then removed from the cooking bath and cooled to facilitate rapid freezing _ 9 .
,- SP-750 31~28g9 either by spraying with cool water or dipping the containers into a cool water bath. The heated whites and yolks are then frozen as quickly as possible to a product temperature of 22 - 30F.
After freezing of the product to the above tempera-ture the flexible containers with the frozen yolks and whites are briefly ~armed to permit easy removal of the frozen yolks and whites from the conkainers as an integral mass for choppi~g.
-This ~rief period of warming to permit removal fro~ the con-tainer does not appreciably alter the temperature of the frozenyolks and whites from the desired range of about 22 - 30F.
The separately cooked and frozen yolks and whites at a temperature range of 22 - 30F, preferably 24 - 28F are then chopped by simultaneous or sequential feeding of the frozen yolks and whites to a mechanical chopping or cutting device to quickly subdivide the yolksand whites into small particles~ It is not critical to the practice of the present process at wha~
weight ratio the yolks and whites are combined during chopping and any weight ratio o~ white~ and yolks may be used. A pre-20 ferred weight ratio for the chopped egg product is 30 to 40 partsof yolk to 70 to 60 parts of white. An especially preferred ratio i5 about 30 parts of yolk to 70 parts of white since this weight ratio somewhat approximates the ratio of white to yolk normally found in whole eggsO Chopping may ~e carried out in any type of ~ood cutter or similar device provided the tempera-ture of the product during chopping does not rise above the noted temperature range by exeessive heat generation during chopping.
The chopped, cooked egg product is then rapidly 30 refrozen as a mixture even though only partial thawing on the surfaces of the yolks and whites has taken place ~uring chopping.
f . ( SP-750~ 1 .. . .
~ ~72~99;
The chopped product is b~st frozen while in particulate form before being placed in a container~ A preferred, though n~n-limiting means for quick freezing the chopped yolk and white mix~ure is by using an individual quick frozen sy~tem ~IQF~
of any type for quick freezing of the particulate eggs and whites~
The resultant product, because of separate cooking of the yolks and whites, has no discoloration from contac~
between the two and has a uniform, bright yellow color with .. separate and identifiable pieces of egg white O The particles of chopped white and yolks are xelatively uniform without signi-ficant pasting or smearing of the yolk over the surfaces of the egg white particles. The diced product is highly suitable as a condiment for foodstuffs such as salads and represents a significant improvement over similar con~iments prepared from cooked shell eggs.
The followin~ Examples wil} serve as illustrative but non-limiting embodiments of the present invention Example I
To 30 pounds of pasteuriæed liquid egg whites is added 7O4~ by weight of modified food starch, with the trade-name "Consista" manufactured by A. E. Staley, D~catur, Illinois and mixed.
The egg white, starch mixture and 30 pounds of pasteurized egg yolks are separately preheated ~y pass~ng through a heat exchanger which comprises a 15 ft, 0.209" I.D.
coil which is indirectly heated by steam at a pressure o lO ~ 20 psig in the surrounding chamber for the heat exch~nger coil. The flow rate of yolks and whites through the coil is 2 lb/min. The yolks are preheated to a product ternperature of 180F and the ( ( SP~750 2~
whites preheated to a product temperature of 160F. Following preheating, 2 lb quantities of the egg white-starch mixture and 2 lb quantities of the yolks are metered into flexible, plastic bags. The bags are sealed and placed in a hot water bath held at a temperature of 194F for 10 - 20 minutes. It was observed that the whites and yolks cooked in this manner coagulated satisfactorily and had the characteristically f-irm texture of cooked egg yolks and whites. The bags containing ~ the coagulated yolks and whites are conveyed through a ~ater spray of cool water at 70 - 75F and cooled.
The coagulated yolks and whites are then placed in a blast freezer and frozen to a product temperature of 22 - 30F.
The yolks and whites are removed from the ~lexible bays by brief thawing of the mass of frozen yolks and whites and 70 parts by weight sf the whites and 30 parts by weight of the fxozen yolks are placed in a batch type cutting dev.ice consisting of a rotating bowl and a set o vertically rotating, high speeA cutting blades. The yolks and whites are chopped for a period of 3 minutes.
The chopped egg product is then refrozen before packaging by being passed through individually quick fro~en system (IQF) to quick free~e the particles.
The egg product after chopping and freezing has no significant smearing of the yolks on the particles of egg whites and consisted of relati~ely uniform and distinct pieces of yolks and whites. The chopped product is highly suitable as a condiment ~or foodstuffs.
~ ( SP-750A
~ 17289~ i Example II
To 30 pounds of pasteurized liquid egg whites is added 7.4% by weight of moaified food starch, with the tradename "Consista", manufactured by A. E. Staley, Decatur, Illinois and mixed.
The egg whlte starch mixture and 30 pounds of pasteurized egg yolks are separately preheated by passing through a heat exchanger which comprises a 15 ft. 0.209"
I.D. coil which is indirectly heated by steam at a pressure -of 10 - 20 psig in the surrounding chamber for the heat ....
exchanger coil. The flow rate of the yolks and whites through the coil is 2 pounds/minute. The yolks as preheated to a product temperature of 194~F and the whites preheated to a product temperature of 176F. Following preheating 2 lb.
quantities of the egg white starch mixture and 2 lb. quantities of the yolks are metered into flexible plastlc bags. The bags are sealed and placed in a hot water bath held at a temperature of 194F. for 10 - 20 minutes. The yolks and whites would not set up to form firm coagulated yolks and whites and were judged to be unsuitable for further freezing and processing to form a frozen diced egg product.
Having described the above invention with reference to the above specific embodiments, it is to be understood that numerous variations can be made without departing from the spirit of the invention and it is intended to include such reasonable variations and equivalents within the scope of the present invention.
Claims (18)
1. A method of forming a chopped egg product comprising.
a. dynamically preheating egg yolks to a pro-duct temperature which does not exceed about 183°F and dynamically preheating egg whites to a product temperature which does not exceed about 167°F followed by statically heating egg yolks and egg whites at a tempera-ture and time effective to coagulate the yolks and whites.
b. freezing said coagulated yolks and whites, c. chopping the frozen whites and yolks at a temperature of between about 22 - 30°F to pro-vide a chopped egg mixture without smearing of the yolks.
a. dynamically preheating egg yolks to a pro-duct temperature which does not exceed about 183°F and dynamically preheating egg whites to a product temperature which does not exceed about 167°F followed by statically heating egg yolks and egg whites at a tempera-ture and time effective to coagulate the yolks and whites.
b. freezing said coagulated yolks and whites, c. chopping the frozen whites and yolks at a temperature of between about 22 - 30°F to pro-vide a chopped egg mixture without smearing of the yolks.
2. A method as set forth in Claim 1 wherein the yolks and whites are statically heated at a temperature of between about 170 to 185°F.
3. A method as set forth in Claim 1 wherein said egg whites includes a water binding agent in an amount effec-tive to prevent syneresis during freezing and thawing of said product.
4. A method as set forth in Claim 3 wherein the amount of water binding agent is between about 1.5 and 10%
by weight of the egg whites.
by weight of the egg whites.
5. A method as set forth in Claim 4 wherein the amount of water binding agent is between about 2 and 4% by weight of the egg whites.
6. A method as set forth in Claim 1 wherein the frozen yolks and whites are chopped at a temperature of between about 24 - 28°F.
7. A method as set forth in Claim 1 wherein the yolks are dynamically preheated to a temperature of between about 149 - 183°F.
8. A method as set forth in Claim 1 wherein the whites are dynamically preheated to a temperature of between about 144 - 167°F.
9. A method as set forth in Claim 1 wherein the frozen white and yolks are combined in a weight ratio of 30:40 parts yolk to 70:60 parts whites during chopping.
10. A method as set forth in Claim 9 wherein the frozen whites and yolks are combined in a weight ratio of 30 parts of yolks and 70 parts of whites.
11. A method as set forth in Claim 1 including the step of refreezing the egg mixture after chopping.
12. A method of forming a cooked and frozen, chopped egg product comprising:
a. dynamically preheating egg yolks to a product temperature which does not exceed about 183°F
and dynamically preheating egg whites to a pro-duct temperature which does not exceed about 167°F followed by statically heating egg yolks and whites at a temperature of between about 170 to 185°F for a period of time effective to coagulate the yolks and whites, b. freezing said coagulated yolks and whites, c. chopping the frozen whites and yolks at a temperature of between about 22 - 30°F to provide a chopped egg mixture having a weight ratio of 30:40 parts of yolks to 70:60 parts of whites.
a. dynamically preheating egg yolks to a product temperature which does not exceed about 183°F
and dynamically preheating egg whites to a pro-duct temperature which does not exceed about 167°F followed by statically heating egg yolks and whites at a temperature of between about 170 to 185°F for a period of time effective to coagulate the yolks and whites, b. freezing said coagulated yolks and whites, c. chopping the frozen whites and yolks at a temperature of between about 22 - 30°F to provide a chopped egg mixture having a weight ratio of 30:40 parts of yolks to 70:60 parts of whites.
13. A method as set forth in Claim 12 wherein said egg whites includes a water binding agent in an amount effec-tive to prevent syneresis during freezing and thawing of said product.
14. A method as set forth in Claim 13 wherein the amount of water binding agent is between about 0.5 and 10%
by weight of the egg whites.
by weight of the egg whites.
15. A method as set forth in Claim 14 wherein the amount of water binding agent is between about 2 and 4% by weight of the whites.
16. A method as set forth in Claim 12 wherein the frozen yolks and whites are chopped at a temperature of between about 24 - 28°F.
17. A method as set forth in Claim 12 wherein the frozen whites and yolks are combined in a weight ratio of about 30 parts of yolks and about 70 parts of whites.
18. A method of forming a cooked and frozen chopped egg product comprising:
a. dynamically preheating egg yolks to a product temperature which does not exceed about 183°F
and dynamically preheating egg whites to a pro-duct temperature which does not exceed about 167°F
followed by statically heating egg yolks and whites at a temperature of between about 170 to 185°F for a period of time effective to coagulate the yolks and whites;
b. freezing said coagulated yolks and whites, c. chopping the frozen whites and yolks at a temperature of between about 24 - 28°F to provide a chopped egg mixture having a weight ratio of 30:40 parts of yolks to 70:60 parts of whites; and d. refreezing said chopped egg mixture.
a. dynamically preheating egg yolks to a product temperature which does not exceed about 183°F
and dynamically preheating egg whites to a pro-duct temperature which does not exceed about 167°F
followed by statically heating egg yolks and whites at a temperature of between about 170 to 185°F for a period of time effective to coagulate the yolks and whites;
b. freezing said coagulated yolks and whites, c. chopping the frozen whites and yolks at a temperature of between about 24 - 28°F to provide a chopped egg mixture having a weight ratio of 30:40 parts of yolks to 70:60 parts of whites; and d. refreezing said chopped egg mixture.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US18458480A | 1980-09-05 | 1980-09-05 | |
US184,584 | 1980-09-05 |
Publications (1)
Publication Number | Publication Date |
---|---|
CA1172899A true CA1172899A (en) | 1984-08-21 |
Family
ID=22677505
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA000382076A Expired CA1172899A (en) | 1980-09-05 | 1981-07-20 | Process for the production of a frozen chopped egg product |
Country Status (5)
Country | Link |
---|---|
JP (1) | JPS5774040A (en) |
CA (1) | CA1172899A (en) |
DE (1) | DE3134731A1 (en) |
FR (1) | FR2489663A1 (en) |
NL (1) | NL8104084A (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0145544B1 (en) * | 1983-11-07 | 1987-06-03 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Process and apparatus for making particles of frozen food products |
MX2022005057A (en) * | 2019-12-19 | 2022-05-18 | Michael Foods Inc | Method for producing cooked egg product having controlled curd size and/or shape. |
-
1981
- 1981-07-20 CA CA000382076A patent/CA1172899A/en not_active Expired
- 1981-09-01 FR FR8116644A patent/FR2489663A1/en not_active Withdrawn
- 1981-09-02 DE DE19813134731 patent/DE3134731A1/en not_active Ceased
- 1981-09-03 NL NL8104084A patent/NL8104084A/en not_active Application Discontinuation
- 1981-09-03 JP JP56137879A patent/JPS5774040A/en active Pending
Also Published As
Publication number | Publication date |
---|---|
NL8104084A (en) | 1982-04-01 |
FR2489663A1 (en) | 1982-03-12 |
JPS5774040A (en) | 1982-05-10 |
DE3134731A1 (en) | 1982-04-01 |
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