CA1144695A - Methode de preparation de copolymeres - Google Patents

Methode de preparation de copolymeres

Info

Publication number: CA1144695A
Authority: CA; Canada
Prior art keywords: ethylene; olefin; compound; catalyst; alpha
Prior art date: 1979-12-26
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000367569A

Other languages

English (en)

Inventor

Kazuo Matsuura

Noboru Yamaoka

Katumi Usui

Mituji Miyoshi

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Eneos Corp

Original Assignee

Nippon Oil Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1979-12-26

Filing date

1980-12-24

Publication date

1983-04-12

1980-12-24 Application filed by Nippon Oil Corp filed Critical Nippon Oil Corp

1983-04-12 Application granted granted Critical

1983-04-12 Publication of CA1144695A publication Critical patent/CA1144695A/fr

Status Expired legal-status Critical Current

Links

238000004519 manufacturing process Methods 0.000 title claims description 7
229920001577 copolymer Polymers 0.000 title abstract description 14
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 49
239000005977 Ethylene Substances 0.000 claims abstract description 49
239000003054 catalyst Substances 0.000 claims abstract description 37
239000012808 vapor phase Substances 0.000 claims abstract description 18
238000000034 method Methods 0.000 claims description 36
150000001875 compounds Chemical class 0.000 claims description 34
239000007787 solid Substances 0.000 claims description 31
239000000126 substance Substances 0.000 claims description 29
150000003609 titanium compounds Chemical class 0.000 claims description 19
150000003682 vanadium compounds Chemical class 0.000 claims description 16
NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 claims description 14
239000010936 titanium Substances 0.000 claims description 14
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 13
229910052749 magnesium Inorganic materials 0.000 claims description 13
239000011777 magnesium Substances 0.000 claims description 12
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 11
239000001257 hydrogen Substances 0.000 claims description 11
229910052739 hydrogen Inorganic materials 0.000 claims description 11
229910003480 inorganic solid Inorganic materials 0.000 claims description 10
150000002148 esters Chemical class 0.000 claims description 9
229920000089 Cyclic olefin copolymer Polymers 0.000 claims description 8
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 8
229910052719 titanium Inorganic materials 0.000 claims description 8
238000007334 copolymerization reaction Methods 0.000 claims description 7
PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 claims description 7
239000002253 acid Substances 0.000 claims description 6
150000004820 halides Chemical class 0.000 claims description 6
125000003118 aryl group Chemical group 0.000 claims description 5
229910052720 vanadium Inorganic materials 0.000 claims description 4
229910052799 carbon Inorganic materials 0.000 claims description 3
125000004432 carbon atom Chemical group C* 0.000 claims description 3
125000005843 halogen group Chemical group 0.000 claims description 3
LNUFLCYMSVYYNW-ZPJMAFJPSA-N [(2r,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6r)-6-[(2r,3r,4s,5r,6r)-6-[(2r,3r,4s,5r,6r)-6-[[(3s,5s,8r,9s,10s,13r,14s,17r)-10,13-dimethyl-17-[(2r)-6-methylheptan-2-yl]-2,3,4,5,6,7,8,9,11,12,14,15,16,17-tetradecahydro-1h-cyclopenta[a]phenanthren-3-yl]oxy]-4,5-disulfo Chemical compound O([C@@H]1[C@@H](COS(O)(=O)=O)O[C@@H]([C@@H]([C@H]1OS(O)(=O)=O)OS(O)(=O)=O)O[C@@H]1[C@@H](COS(O)(=O)=O)O[C@@H]([C@@H]([C@H]1OS(O)(=O)=O)OS(O)(=O)=O)O[C@@H]1[C@@H](COS(O)(=O)=O)O[C@H]([C@@H]([C@H]1OS(O)(=O)=O)OS(O)(=O)=O)O[C@@H]1C[C@@H]2CC[C@H]3[C@@H]4CC[C@@H]([C@]4(CC[C@@H]3[C@@]2(C)CC1)C)[C@H](C)CCCC(C)C)[C@H]1O[C@H](COS(O)(=O)=O)[C@@H](OS(O)(=O)=O)[C@H](OS(O)(=O)=O)[C@H]1OS(O)(=O)=O LNUFLCYMSVYYNW-ZPJMAFJPSA-N 0.000 claims 1
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims 1
238000006116 polymerization reaction Methods 0.000 description 41
229920000642 polymer Polymers 0.000 description 37
239000002002 slurry Substances 0.000 description 13
239000002904 solvent Substances 0.000 description 9
239000000203 mixture Substances 0.000 description 8
-1 polyethylenè Polymers 0.000 description 8
229910010066 TiC14 Inorganic materials 0.000 description 6
238000010528 free radical solution polymerization reaction Methods 0.000 description 6
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 6
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 6
229920001971 elastomer Polymers 0.000 description 5
239000000806 elastomer Substances 0.000 description 5
150000002902 organometallic compounds Chemical class 0.000 description 5
230000037048 polymerization activity Effects 0.000 description 5
239000000243 solution Substances 0.000 description 5
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 4
229910052782 aluminium Inorganic materials 0.000 description 4
239000000460 chlorine Substances 0.000 description 4
230000000694 effects Effects 0.000 description 4
229910052751 metal Inorganic materials 0.000 description 4
239000002184 metal Substances 0.000 description 4
239000001301 oxygen Substances 0.000 description 4
229910052760 oxygen Inorganic materials 0.000 description 4
239000012071 phase Substances 0.000 description 4
229920003023 plastic Polymers 0.000 description 4
239000004033 plastic Substances 0.000 description 4
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
150000001336 alkenes Chemical class 0.000 description 3
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 3
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
238000006243 chemical reaction Methods 0.000 description 3
230000000052 comparative effect Effects 0.000 description 3
238000005336 cracking Methods 0.000 description 3
YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 3
239000007789 gas Substances 0.000 description 3
239000002245 particle Substances 0.000 description 3
229920005672 polyolefin resin Polymers 0.000 description 3
238000002203 pretreatment Methods 0.000 description 3
229910052717 sulfur Inorganic materials 0.000 description 3
239000011593 sulfur Substances 0.000 description 3
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 3
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 3
ZEYHEAKUIGZSGI-UHFFFAOYSA-N 4-methoxybenzoic acid Chemical compound COC1=CC=C(C(O)=O)C=C1 ZEYHEAKUIGZSGI-UHFFFAOYSA-N 0.000 description 2
WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
239000004698 Polyethylene Substances 0.000 description 2
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
238000005054 agglomeration Methods 0.000 description 2
230000002776 aggregation Effects 0.000 description 2
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
238000000498 ball milling Methods 0.000 description 2
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
239000007795 chemical reaction product Substances 0.000 description 2
229920001038 ethylene copolymer Polymers 0.000 description 2
229910052736 halogen Inorganic materials 0.000 description 2
150000002367 halogens Chemical class 0.000 description 2
229930195733 hydrocarbon Natural products 0.000 description 2
150000002430 hydrocarbons Chemical class 0.000 description 2
229920001684 low density polyethylene Polymers 0.000 description 2
ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 2
239000001095 magnesium carbonate Substances 0.000 description 2
229910000021 magnesium carbonate Inorganic materials 0.000 description 2
235000014380 magnesium carbonate Nutrition 0.000 description 2
VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 2
239000000347 magnesium hydroxide Substances 0.000 description 2
229910001862 magnesium hydroxide Inorganic materials 0.000 description 2
235000012254 magnesium hydroxide Nutrition 0.000 description 2
239000000395 magnesium oxide Substances 0.000 description 2
235000012245 magnesium oxide Nutrition 0.000 description 2
238000002156 mixing Methods 0.000 description 2
YNPNZTXNASCQKK-UHFFFAOYSA-N phenanthrene Chemical compound C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 description 2
229920000573 polyethylene Polymers 0.000 description 2
239000000047 product Substances 0.000 description 2
239000007858 starting material Substances 0.000 description 2
150000003623 transition metal compounds Chemical class 0.000 description 2
MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 1
OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 description 1
WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
KPZGRMZPZLOPBS-UHFFFAOYSA-N 1,3-dichloro-2,2-bis(chloromethyl)propane Chemical compound ClCC(CCl)(CCl)CCl KPZGRMZPZLOPBS-UHFFFAOYSA-N 0.000 description 1
PRBHEGAFLDMLAL-UHFFFAOYSA-N 1,5-Hexadiene Natural products CC=CCC=C PRBHEGAFLDMLAL-UHFFFAOYSA-N 0.000 description 1
HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
CMAOLVNGLTWICC-UHFFFAOYSA-N 2-fluoro-5-methylbenzonitrile Chemical compound CC1=CC=C(F)C(C#N)=C1 CMAOLVNGLTWICC-UHFFFAOYSA-N 0.000 description 1
INYHZQLKOKTDAI-UHFFFAOYSA-N 5-ethenylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(C=C)CC1C=C2 INYHZQLKOKTDAI-UHFFFAOYSA-N 0.000 description 1
239000005711 Benzoic acid Substances 0.000 description 1
NTWOIGOPFDMZAE-UHFFFAOYSA-M CCO[Ti](Cl)(OCC)OCC Chemical compound CCO[Ti](Cl)(OCC)OCC NTWOIGOPFDMZAE-UHFFFAOYSA-M 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
UOACKFBJUYNSLK-XRKIENNPSA-N Estradiol Cypionate Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H](C4=CC=C(O)C=C4CC3)CC[C@@]21C)C(=O)CCC1CCCC1 UOACKFBJUYNSLK-XRKIENNPSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
101100536883 Legionella pneumophila subsp. pneumophila (strain Philadelphia 1 / ATCC 33152 / DSM 7513) thi5 gene Proteins 0.000 description 1
239000004743 Polypropylene Substances 0.000 description 1
101100240664 Schizosaccharomyces pombe (strain 972 / ATCC 24843) nmt1 gene Proteins 0.000 description 1
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
MGSCVPSSIVOYMY-UHFFFAOYSA-N [V+3].CC[O-].CC[O-].CC[O-] Chemical compound [V+3].CC[O-].CC[O-].CC[O-] MGSCVPSSIVOYMY-UHFFFAOYSA-N 0.000 description 1
238000013019 agitation Methods 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
150000001299 aldehydes Chemical class 0.000 description 1
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
150000004703 alkoxides Chemical class 0.000 description 1
125000005907 alkyl ester group Chemical group 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
229910052786 argon Inorganic materials 0.000 description 1
125000003710 aryl alkyl group Chemical group 0.000 description 1
235000010233 benzoic acid Nutrition 0.000 description 1
238000000071 blow moulding Methods 0.000 description 1
239000011575 calcium Substances 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
150000004649 carbonic acid derivatives Chemical class 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
150000001805 chlorine compounds Chemical class 0.000 description 1
239000011362 coarse particle Substances 0.000 description 1
229920001887 crystalline plastic Polymers 0.000 description 1
229920006038 crystalline resin Polymers 0.000 description 1
230000006866 deterioration Effects 0.000 description 1
150000001993 dienes Chemical class 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
230000006353 environmental stress Effects 0.000 description 1
UHSDHNXHBQDMMH-UHFFFAOYSA-L ethanolate;titanium(4+);dichloride Chemical compound CCO[Ti](Cl)(Cl)OCC UHSDHNXHBQDMMH-UHFFFAOYSA-L 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
239000005038 ethylene vinyl acetate Substances 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
150000008282 halocarbons Chemical class 0.000 description 1
239000001307 helium Substances 0.000 description 1
229910052734 helium Inorganic materials 0.000 description 1
SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical compound C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 1
229920001903 high density polyethylene Polymers 0.000 description 1
229920006158 high molecular weight polymer Polymers 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
229910000041 hydrogen chloride Inorganic materials 0.000 description 1
150000004679 hydroxides Chemical class 0.000 description 1
239000012535 impurity Substances 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
239000002932 luster Substances 0.000 description 1
235000001055 magnesium Nutrition 0.000 description 1
229910001629 magnesium chloride Inorganic materials 0.000 description 1
235000011147 magnesium chloride Nutrition 0.000 description 1
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
229920001179 medium density polyethylene Polymers 0.000 description 1
150000002736 metal compounds Chemical class 0.000 description 1
229910001507 metal halide Inorganic materials 0.000 description 1
150000005309 metal halides Chemical class 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
239000003607 modifier Substances 0.000 description 1
125000002950 monocyclic group Chemical group 0.000 description 1
238000000465 moulding Methods 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
239000012299 nitrogen atmosphere Substances 0.000 description 1
ZWLPBLYKEWSWPD-UHFFFAOYSA-N o-toluic acid Chemical compound CC1=CC=CC=C1C(O)=O ZWLPBLYKEWSWPD-UHFFFAOYSA-N 0.000 description 1
125000001741 organic sulfur group Chemical group 0.000 description 1
150000002901 organomagnesium compounds Chemical class 0.000 description 1
150000002926 oxygen Chemical class 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
125000003367 polycyclic group Polymers 0.000 description 1
239000002685 polymerization catalyst Substances 0.000 description 1
229920000098 polyolefin Polymers 0.000 description 1
229920001155 polypropylene Polymers 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
238000011084 recovery Methods 0.000 description 1
229920005989 resin Polymers 0.000 description 1
239000011347 resin Substances 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
238000000926 separation method Methods 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
239000010703 silicon Substances 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
230000035882 stress Effects 0.000 description 1
150000003568 thioethers Chemical class 0.000 description 1
150000003573 thiols Chemical class 0.000 description 1
UBZYKBZMAMTNKW-UHFFFAOYSA-J titanium tetrabromide Chemical compound Br[Ti](Br)(Br)Br UBZYKBZMAMTNKW-UHFFFAOYSA-J 0.000 description 1
NLLZTRMHNHVXJJ-UHFFFAOYSA-J titanium tetraiodide Chemical compound I[Ti](I)(I)I NLLZTRMHNHVXJJ-UHFFFAOYSA-J 0.000 description 1
229910052723 transition metal Inorganic materials 0.000 description 1
150000003624 transition metals Chemical class 0.000 description 1
ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 1
LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
239000011882 ultra-fine particle Substances 0.000 description 1
LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical compound [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 description 1
JBIQAPKSNFTACH-UHFFFAOYSA-K vanadium oxytrichloride Chemical compound Cl[V](Cl)(Cl)=O JBIQAPKSNFTACH-UHFFFAOYSA-K 0.000 description 1
238000012725 vapour phase polymerization Methods 0.000 description 1
239000008096 xylene Substances 0.000 description 1
150000003738 xylenes Chemical class 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/02—Carriers therefor
- C08F4/022—Magnesium halide as support anhydrous or hydrated or complexed by means of a Lewis base for Ziegler-type catalysts

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Polymerisation Methods In General (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

CA000367569A 1979-12-26 1980-12-24 Methode de preparation de copolymeres Expired CA1144695A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
JP168176/1979		1979-12-26
JP54168176A JPS6042806B2 (ja)	1979-12-26	1979-12-26	共重合体の製造方法

Publications (1)

Publication Number	Publication Date
CA1144695A true CA1144695A (fr)	1983-04-12

Family

ID=15863195

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000367569A Expired CA1144695A (fr)	1979-12-26	1980-12-24	Methode de preparation de copolymeres

Country Status (7)

Country	Link
JP (1)	JPS6042806B2 (fr)
AU (1)	AU537527B2 (fr)
CA (1)	CA1144695A (fr)
DE (1)	DE3048437A1 (fr)
FR (1)	FR2472583B1 (fr)
GB (1)	GB2066274B (fr)
IT (1)	IT1209378B (fr)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
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CA1174800A (fr) *	1981-08-24	1984-09-18	Charles Cozewith	Methode de la phase gazeuse pour l'obtention de copolymeres d'ethylene et d'alpha-olefines superieures
JPS5898315A (ja) *	1981-12-07	1983-06-11	Chisso Corp	ポリオレフイン共重合体の粉体流動性改良法
JPS58157839A (ja) *	1982-03-16	1983-09-20	Nippon Oil Co Ltd	耐衝撃性ポリオレフイン樹脂組成物
JPS5936110A (ja) *	1982-08-25	1984-02-28	Asahi Chem Ind Co Ltd	新規なエチレン〜α−オレフイン共重合体
DE3239883A1 (de) *	1982-10-28	1984-05-10	Basf Ag, 6700 Ludwigshafen	Verfahren zum kontinuierlichen herstellen von copolymerisaten des ethylens mit hoeheren (alpha)-monoolefinen
DE3239884A1 (de) *	1982-10-28	1984-05-03	Basf Ag, 6700 Ludwigshafen	Verfahren zum kontinuierlichen herstellen von copolymerisaten des ethylens mit hoeheren (alpha)-monoolefinen
FR2541683B1 (fr) *	1983-02-28	1986-05-09	Ato Chimie	Procede pour la preparation d'un solide hydrocarbone actif utilisable pour polymeriser des olefines, et procede de synthese d'un polymere ou copolymere olefinique faisant appel audit solide hydrocarbone actif comme systeme
IL71357A (en) *	1983-03-29	1987-03-31	Union Carbide Corp	Process for producing low density ethylene copolymers
US4558105A (en) *	1983-12-07	1985-12-10	Chemplex Company	Copolymerization of ethylene
US4976898A (en) *	1985-06-17	1990-12-11	Viskase Corporation	Process for making puncture resistant, heat-shrinkable films containing very low density polyethylene
CA1340037C (fr) *	1985-06-17	1998-09-08	Stanley Lustig	Pellicules thermoretrecissables resistant au percement, a base d'un copolymere de polyethylene de tres faible densite
US5256351A (en) *	1985-06-17	1993-10-26	Viskase Corporation	Process for making biaxially stretched, heat shrinkable VLDPE films
US5059481A (en) *	1985-06-17	1991-10-22	Viskase Corporation	Biaxially stretched, heat shrinkable VLDPE film
JPS6255276A (ja) *	1985-08-20	1987-03-10	Nippon Oil Co Ltd	車両用マツドガ−ド
USRE35285E (en) *	1985-09-30	1996-06-25	W. R. Grace & Co.-Conn.	Thermoplastic multi-layer packaging film and bags made therefrom
NL8702902A (nl) *	1987-04-06	1988-11-01	Stamicarbon	Etheencopolymeer.
JPH0745233B2 (ja) *	1988-02-02	1995-05-17	住友化学工業株式会社	農業用フィルム
KR930001064B1 (ko) *	1988-09-13	1993-02-15	미쓰이 세끼유 가가꾸 고오교오 가부시끼가이샤	올레핀중합용 촉매성분 및 그 제조방법, 올레핀중합용 촉매 및 올레핀의 중합방법
KR920007040B1 (ko) *	1988-09-14	1992-08-24	미쓰이세끼유 가가꾸 고오교오 가부시끼가이샤	올레핀 중합용 촉매와 그 촉매의 성분 및 그 촉매에 의한 올레핀 중합법과 그 폴리올레핀에 의한 필름 및 사출성형품
US5247032A (en) *	1989-12-29	1993-09-21	Mitsui Petrochemical Industries, Ltd.	Solid catalyst components for olefin polymerization and processes for the polymerization of olefin using same
JP2940684B2 (ja) *	1989-12-29	1999-08-25	三井化学株式会社	オレフィン重合用固体状触媒成分およびこの触媒成分を用いたオレフィンの重合方法
FR2800379A1 (fr) *	1999-10-29	2001-05-04	Bp Chemicals Snc	Procede de copolymerisation en phase gazeuse d'au moins deux alpha-olefines ayant de 2 a 12 atomes de carbone

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YU35844B (en) *	1968-11-25	1981-08-31	Montedison Spa	Process for obtaining catalysts for the polymerization of olefines
FR2405961A1 (fr) *	1977-10-12	1979-05-11	Naphtachimie Sa	Procede de copolymerisation d'olefines en phase gazeuse en presence d'un lit fluidise de copolymere et d'un catalyseur contenant du titane et du magnesium
US4302565A (en) *	1978-03-31	1981-11-24	Union Carbide Corporation	Impregnated polymerization catalyst, process for preparing, and use for ethylene copolymerization
ZA791363B (en) *	1978-03-31	1980-03-26	Union Carbide Corp	Preparation of ethylene copolymers in fluid bed reactor
JPS5554308A (en) *	1978-10-17	1980-04-21	Nippon Oil Co Ltd	Preparation of copolymer
JPS5556110A (en) *	1978-10-20	1980-04-24	Nippon Oil Co Ltd	Preparation of copolymer
JPS5556111A (en) *	1978-10-20	1980-04-24	Nippon Oil Co Ltd	Preparation of copolymer
JPS5558210A (en) *	1978-10-26	1980-04-30	Nippon Oil Co Ltd	Production of copolymer
JPS5573712A (en) *	1978-11-29	1980-06-03	Nippon Oil Co Ltd	Preparation of copolymer
JPS6024805B2 (ja) *	1979-09-05	1985-06-14	日石三菱株式会社	共重合体の製法

1979
- 1979-12-26 JP JP54168176A patent/JPS6042806B2/ja not_active Expired
1980
- 1980-12-18 AU AU65532/80A patent/AU537527B2/en not_active Ceased
- 1980-12-22 DE DE19803048437 patent/DE3048437A1/de active Granted
- 1980-12-22 IT IT8026857A patent/IT1209378B/it active
- 1980-12-23 GB GB8041313A patent/GB2066274B/en not_active Expired
- 1980-12-24 CA CA000367569A patent/CA1144695A/fr not_active Expired
- 1980-12-24 FR FR8027553A patent/FR2472583B1/fr not_active Expired

Also Published As

Publication number	Publication date
DE3048437C2 (fr)	1991-01-10
AU537527B2 (en)	1984-06-28
FR2472583B1 (fr)	1985-09-27
AU6553280A (en)	1981-07-02
GB2066274A (en)	1981-07-08
JPS6042806B2 (ja)	1985-09-25
JPS5692902A (en)	1981-07-28
DE3048437A1 (de)	1982-04-08
IT1209378B (it)	1989-07-16
IT8026857A0 (it)	1980-12-22
FR2472583A1 (fr)	1981-07-03
GB2066274B (en)	1984-06-20

Publication	Publication Date	Title
CA1144695A (fr)	1983-04-12	Methode de preparation de copolymeres
CA1142678A (fr)	1983-03-08	Compositions de polymere
US4330639A (en)	1982-05-18	Polymer blend composition for forming polyethylene film
US4495334A (en)	1985-01-22	Ethylene polymer blend compositions
EP0480376B1 (fr)	1997-03-05	Catalyseur et procédé de préparation de polyoléfines bimodales
US4322514A (en)	1982-03-30	Process for preparing a copolymer
CA1124948A (fr)	1982-06-01	Methode de preparation d'un copolymere
EP0597461B1 (fr)	1997-05-28	Procédé de copolymérisation de propylène et d'éthylène en phase gazeuse et films fabriqués à partir de ces copolymères
US4511704A (en)	1985-04-16	Process for producing polyolefin
GB2034336A (en)	1980-06-04	Preparation of ethylene-butene copolymers
CA1126900A (fr)	1982-06-29	Methode de preparation d'un copolymere
GB2034337A (en)	1980-06-04	Preparation of ethylene-propylene
GB2036764A (en)	1980-07-02	Process for preparing a copolymer
CA1118946A (fr)	1982-02-23	Methode de preparation des polyolefines
CA1127799A (fr)	1982-07-13	Methode de preparation d'un copolymere
JPS6357457B2 (fr)	1988-11-11
EP0126515B1 (fr)	1991-07-24	Procédé de (co)polymeérisation de l'éthylène
EP0338843B1 (fr)	1994-06-29	Composition de polyéthylène
EP0305122B1 (fr)	1992-04-01	Copolymères fluorés de l'éthylène et d'alpha-oléfines
US6713572B2 (en)	2004-03-30	Ethylene copolymerization process

Legal Events

Date	Code	Title	Description
2000-04-12	MKEX	Expiry