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CA1143024A - Hermetic electrical feedthrough assembly - Google Patents

Hermetic electrical feedthrough assembly

Info

Publication number
CA1143024A
CA1143024A CA000344568A CA344568A CA1143024A CA 1143024 A CA1143024 A CA 1143024A CA 000344568 A CA000344568 A CA 000344568A CA 344568 A CA344568 A CA 344568A CA 1143024 A CA1143024 A CA 1143024A
Authority
CA
Canada
Prior art keywords
feedthrough
gold
niobium
insulator
sapphire
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA000344568A
Other languages
French (fr)
Inventor
Robert E. Kraska
Joseph F. Lessar
Frank J. Wilary
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Medtronic Inc
Original Assignee
Medtronic Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Medtronic Inc filed Critical Medtronic Inc
Application granted granted Critical
Publication of CA1143024A publication Critical patent/CA1143024A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C27/00Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
    • C03C27/04Joining glass to metal by means of an interlayer
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61NELECTROTHERAPY; MAGNETOTHERAPY; RADIATION THERAPY; ULTRASOUND THERAPY
    • A61N1/00Electrotherapy; Circuits therefor
    • A61N1/18Applying electric currents by contact electrodes
    • A61N1/32Applying electric currents by contact electrodes alternating or intermittent currents
    • A61N1/36Applying electric currents by contact electrodes alternating or intermittent currents for stimulation
    • A61N1/372Arrangements in connection with the implantation of stimulators
    • A61N1/375Constructional arrangements, e.g. casings
    • A61N1/3752Details of casing-lead connections
    • A61N1/3754Feedthroughs
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B17/00Insulators or insulating bodies characterised by their form
    • H01B17/26Lead-in insulators; Lead-through insulators
    • H01B17/30Sealing
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings; Jackets or wrappings
    • H01M50/183Sealing members
    • H01M50/186Sealing members characterised by the disposition of the sealing members
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings; Jackets or wrappings
    • H01M50/183Sealing members
    • H01M50/19Sealing members characterised by the material
    • H01M50/191Inorganic material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Electrochemistry (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Radiology & Medical Imaging (AREA)
  • Inorganic Chemistry (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Ceramic Engineering (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Products (AREA)
  • Materials For Medical Uses (AREA)
  • Mechanical Coupling Of Light Guides (AREA)

Abstract

ABSTRACT OF THE DISCLOSURE
Disclosed is a hermetic electrical feedthrough consisting of a niobium electrical lead-in wire surrounded by a sapphire insulator which is carried by a niobium ferrule or the like. The lead-wire is brazed to the insulator and the insulator to the ferrule. The braze composition is se-lected from the group consisting of substantially pure gold and an alloy of gold, vanadium, yttrium and/or scandium. The optical transparency of the sapphire allows visual inspection of the sapphire-to-niobium bond for the presence of defects. The feedthrough is particularly adapted for use in encapsulated electrical devices for human implant.

Description

This inven1ion relates to a hel~etic electrical feedthrough assembly which makes use of niobium and sapphire. The optical transparency of sapphire allows visual inspection of the sapphire-to-niobium bond for the presence of defects. I{ermetic seals in electrical feedthroughs consisting of the specific comblnations of materials disclosed herein and prepared according to this invention have been found to be more likely to resist delamination between the insulator and metal members of the feedthrough, ie., they are more resistant to stress induced cracking during fabrication or testing.
Sapphire is an alumimlm oxide which is grown with a single crystal lattice structure and can be easily cut and polished to optical clarity without creating cracks or defects. If cracks or defects do result during preparation of a sapphire insulator for a feedthrough or during fabrication oX the feedthrough assembly, they can be easily seen at low magnification.
The ease of visual inspection consequently allows for 100% final product in-spection. The specific combination of materials ie., sapphire and niobium, are resistant to defect formation during manufacture. Hence, greater yields are provided. Off-the-shelf watch jewels of sapphire are readily available for use in accordance with this invention.
It is a purpose of this invention to provide high yield electrical feedthroughs which can be optically inspected.
Additionally~ and more importantly, it is a purpose of this invent-ion to provide improved hermetic electrical feedthroughs which are particular-ly adapted for use in encapsulated electrical devices, such as electro-chemical cells, heartpacers and the like for human implant. Such devices require high assurety against the presence of defects and loss of hermeticity in the feedthroughs.
The improved feedthrough of the invention consists of a niobium ,~F

~ ~3~

lead wire extendi.ng through a sapphire insulator, preferably a disc-like insulator. The sapphire insulator is carried by a niobium ferrule or the like. The assembly is hrazed together by means of either a gold braze or a gold-vanadium-yttrium alloy braze. Some compositional variations are allow-ed in this alloy~as is discussed below. ~Vhen the gold braze is used, the surfaces of the sapphire in the brazed areas are first metallized with a discrete layer of titanium and a layer of gold, the gold overlaying the titanium.
Thus, in accordance with a broad aspect of tile invention, there is provided an electrical feedthrough comprising an electrical lead-wire con-sisting essentially of niobium; an insulator around a portion of the lead-wire, the insulator consisting essentially of sapphire; a ferrule consisting essentially of niobium positioned around at least a peripheral portion of the insulator, and brazes joining the lead-wire to the insulator and the insula-tor to the ferrule, the braze composition being selected from the group con-sisting of substantially pure gold and an alloy of gold, vanadium, yttrium and/or scandium and optionally including an amount of niobium.
The invention will now be further described in conjunction with the accompanying drawings, in which:
Figure 1 is the schematic cross-section of a first embodiment of a feedthrough according to the invention.
Figure 2 is a schematic cross-section of another embodiment of a feedthrough according to the invention.
Figure 3 is yet another schematic cross-section showing a third embodiment of a feedthrough according to the invention.
Figure 4 is a schematic cross-section of a fourth embodiment of the invention .
The electrical feedthroughs shown in Figures 1-4 represent several ~3~

variations of the invention. Ilowever, all of the embodiments include a more or less centrally positioned niobium lead-in wire or pin 10 extending through a sapphire lnsulator body 12. Body 12 is preferably generally disc shaped. Even more preferably, the sapphire body will be formed with a cup-like surface 12~a) as shown in Figures 1 and 2. The feedthrough assembly also includes a niobium ferrule or the like 14 which more or less peripherally contacts sapphire body 12 as is well known in the case of metal ferrule and glass insu]ator arrangements already known in this art. Ferrule 14 is utilized for mounting the feedthrough. For example, in a preferred use, this feedthrough will be mo~mted in a titanium encapsulating structure (not shown) which contains an electrical device for human implant. Normally, the ferrule will be welded to the titanium container.
The niobium used for the lead-wire and ferrule herein may also be a niobium alloy so long as its thermal expansion coefficient remains about + 10% of that of commercially pure niobium. An example of such an alloy is 99Nb-l~r (Wt.%). Herein, when these components are described as consisting essentially of niobium, such alloys are intended to be included along with pure niobium.
The members of the feedthrough are assembled together by brazing.
As is well known in the art, brazing of the feedthrough assembly may be accomplished by placing rings of the brazing material at the joints to be brazed and heating the assembly to the appropriate melting temperature of the braze material. Ilowever, in the instance of this invention, only two brazing materials are acceptable. The first and most preferred of these are alloys of gold, vanadium and yttrium and/or scandium and optionally including niobium. Assemblies using this alloy brazing material are shown in Figures 1, 2 and 3.
Brazing alloys of the foregoing type which may be utilized with ~3~2'~

this invention is disclosed in United States patent No. 4,180,700, issued Dec. 25, 1979, and assigned to the same assignee as is this application. As indicated therein, the alloys may include scandium and niobium. One exemp-lary alloy is vanadium-5.5%, yttrium-0.2%, balance gold, the percentages being expressed in terms of atomic percentages.
Another braze material which may be used, as mentioned above, is gold ie., commercially pure gold (99.9%). However, when the pure gold braze material is utilized, the sapphire must first be provided with a coating of titanium and a coating of gold over the titanium in the areas where the brazed joint is to be formed. These coatings are preferably formed by sputtering and may be very thin. Preferably the titanium will have a thick-ness on the order of about 10,000 angstroms and the gold will have a thickness on the order of about 2,000 angstroms. Such a metallized version is shown in Figure 4, the titanium and gold layers being schematically indicated at 18, the gold braze at 16 in Figure 4.
The different braze materials may be used in any of the feedthrough configurations disclosed herein. The various configurations differ in geometry, Figure 1 being the simplest. Figures 2 and 3 are self-fixturing due to the notched portions included in either the ferrule body 14, as shown in Figure 2, or in the insulator body 12, as shown in Figure 3.
The sapphire used herein may be the "clear" sapphire or the "doped"
sapphire ie., sapphire containing a few tenths of a percent of a dopant such as chromium, cobalt or nickel and taking on a characteristic color such as ruby, blue or emerald, respectively.
Having described the invention, the exclusive rights and privi-leges thereto are to be defined by the following claims in the light of the foregoing description:

.

Claims (8)

THE EMBODIMENTS OF THE INVENTION IN WHICH AN EXCLUSIVE
PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS:
1. An electrical feedthrough comprising an electrical lead-wire consisting essentially of niobium; an insulator around a portion of the lead-wire, the insulator consisting essentially of sapphire; a ferrule con-sisting essentially of niobium positioned around at least a peripheral portion of the insulator, and brazes joining the lead-wire to the insulator and the insulator to the ferrule, the braze composition being selected from the group consisting of substantially pure gold, an alloy of gold, vanadium and yttrium, an alloy of gold, vanadium and scandium and an alloy of gold, vanadium, yttrium and scandium.
2. The feedthrough of claim 1 in which the surfaces of the sapphire at the brazed areas are metallized.
3. The feedthrough of claim 2 in which the metallization consists of a layer of titanium and a layer of gold.
4. The feedthrough of claim 3 in which the gold layer overlays the titanium layer.
5. The feedthrough of claim 4 in which the titanium layer is about 10,000 angstroms thick and the gold is less thick.
6. The feedthrough of claim 5 in which the gold layer is about 2,000 angstroms thick.
7. The feedthrough of claim 1, 2 or 3 in which the alloy also includes an amount of niobium.
8. The feedthrough of claim 4,5 or 6 in which the alloy also includes an amount of niobium.
CA000344568A 1979-01-29 1980-01-29 Hermetic electrical feedthrough assembly Expired CA1143024A (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US715379A 1979-01-29 1979-01-29
US7,153 1979-01-29
US5198779A 1979-06-25 1979-06-25
US51,987 1979-06-25

Publications (1)

Publication Number Publication Date
CA1143024A true CA1143024A (en) 1983-03-15

Family

ID=26676599

Family Applications (1)

Application Number Title Priority Date Filing Date
CA000344568A Expired CA1143024A (en) 1979-01-29 1980-01-29 Hermetic electrical feedthrough assembly

Country Status (5)

Country Link
EP (1) EP0022863A1 (en)
CA (1) CA1143024A (en)
CH (1) CH649411A5 (en)
DE (1) DE3030687T1 (en)
WO (1) WO1980001620A1 (en)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4678868A (en) * 1979-06-25 1987-07-07 Medtronic, Inc. Hermetic electrical feedthrough assembly
DE3786210T2 (en) * 1986-08-15 1993-09-23 Medtronic Inc HEART PACEMAKER WITH OXYGEN SENSOR.
EP0269007A1 (en) * 1986-11-28 1988-06-01 Siemens Aktiengesellschaft Ceramic-metal feedthrough assembly, in particular for cardiac or neural stimulation, and method of manufacturing it
US5870272A (en) * 1997-05-06 1999-02-09 Medtronic Inc. Capacitive filter feedthrough for implantable medical device
US6198952B1 (en) 1998-10-30 2001-03-06 Medtronic, Inc. Multiple lens oxygen sensor for medical electrical lead
US6134459A (en) * 1998-10-30 2000-10-17 Medtronic, Inc. Light focusing apparatus for medical electrical lead oxygen sensor
US5902326A (en) * 1997-09-03 1999-05-11 Medtronic, Inc. Optical window for implantable medical devices
US6125290A (en) * 1998-10-30 2000-09-26 Medtronic, Inc. Tissue overgrowth detector for implantable medical device
US6125291A (en) * 1998-10-30 2000-09-26 Medtronic, Inc. Light barrier for medical electrical lead oxygen sensor
US6248080B1 (en) 1997-09-03 2001-06-19 Medtronic, Inc. Intracranial monitoring and therapy delivery control device, system and method
US6144866A (en) * 1998-10-30 2000-11-07 Medtronic, Inc. Multiple sensor assembly for medical electric lead
US6163723A (en) * 1998-10-22 2000-12-19 Medtronic, Inc. Circuit and method for implantable dual sensor medical electrical lead
US6830249B2 (en) * 2002-04-22 2004-12-14 General Electric Company Brazeable, multi-lead, low profile sealing fitting and method of installation
HUE039631T2 (en) * 2011-02-18 2019-01-28 Schott Ag Glass, in particular glass solder or fusible glass
US12123497B2 (en) 2016-05-23 2024-10-22 Daniel Hiram DEEKS Method and apparatus for the hermetic sealing of martensitic metals for precompression for cryogenic applications
US11143304B2 (en) * 2016-05-23 2021-10-12 Daniel Hiram DEEKS Methods and apparatus for sealing of metals
DE102021110048A1 (en) 2021-04-21 2022-10-27 Schott Ag Feedthrough through a housing component, especially for harsh, mechanically and thermally stressed environments

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Publication number Priority date Publication date Assignee Title
US3001269A (en) * 1954-09-20 1961-09-26 Gen Electric Composite material, brazing alloys and process of manufacture
US3063144A (en) * 1956-04-16 1962-11-13 American Lava Corp Metal-to-ceramic seals
US3371406A (en) * 1965-11-26 1968-03-05 Philips Corp Hermetic electrical lead-in assembly
US3936320A (en) * 1972-10-18 1976-02-03 Nuclear Battery Corporation Header
FR2217290B1 (en) * 1972-12-01 1975-03-28 Quartex Sa
US3873944A (en) * 1973-03-01 1975-03-25 Varian Associates Bonding of ferrite to metal for high-power microwave applications
US3906311A (en) * 1974-02-27 1975-09-16 Mallory & Co Inc P R Metal-to-glass-to-ceramic seal
US3920888A (en) * 1974-06-04 1975-11-18 Nuclear Battery Corp Electrical feed-through assembly suitable for electronic devices implantable in a human body
US4016527A (en) * 1975-09-25 1977-04-05 North American Philips Corporation Hermetically sealed film resistor
US4078711A (en) * 1977-04-14 1978-03-14 Rockwell International Corporation Metallurgical method for die attaching silicon on sapphire devices to obtain heat resistant bond
US4180700A (en) * 1978-03-13 1979-12-25 Medtronic, Inc. Alloy composition and brazing therewith, particularly for _ceramic-metal seals in electrical feedthroughs

Also Published As

Publication number Publication date
CH649411A5 (en) 1985-05-15
EP0022863A1 (en) 1981-01-28
DE3030687C2 (en) 1991-06-13
DE3030687T1 (en) 1981-02-12
WO1980001620A1 (en) 1980-08-07

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