CA1059975A - Corps poreux a teneur de silice a pores de dimension controlee - Google Patents

Corps poreux a teneur de silice a pores de dimension controlee

Info

Publication number: CA1059975A
Authority: CA; Canada
Prior art keywords: solution; silica; silicate; silicate solution; colloidal silica
Prior art date: 1974-02-08
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA206,974A

Other languages

English (en)

Inventor

Robert D. Shoup

Paul E. Blaszyk

William J. Wein

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Corning Glass Works

Original Assignee

Corning Glass Works

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1974-02-08

Filing date

1974-08-14

Publication date

1979-08-07

1974-08-14 Application filed by Corning Glass Works filed Critical Corning Glass Works

1979-08-07 Application granted granted Critical

1979-08-07 Publication of CA1059975A publication Critical patent/CA1059975A/fr

Status Expired legal-status Critical Current

Links

VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 239
239000011148 porous material Substances 0.000 title claims abstract description 90
239000000377 silicon dioxide Substances 0.000 title claims abstract description 85
239000008119 colloidal silica Substances 0.000 claims abstract description 68
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims abstract description 62
239000000463 material Substances 0.000 claims abstract description 18
239000011236 particulate material Substances 0.000 claims abstract description 15
238000002386 leaching Methods 0.000 claims abstract description 12
230000001747 exhibiting effect Effects 0.000 claims abstract description 9
239000000243 solution Substances 0.000 claims description 194
239000004111 Potassium silicate Substances 0.000 claims description 70
229910052913 potassium silicate Inorganic materials 0.000 claims description 70
NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 claims description 68
235000019353 potassium silicate Nutrition 0.000 claims description 68
239000000203 mixture Substances 0.000 claims description 57
239000004115 Sodium Silicate Substances 0.000 claims description 45
229910052911 sodium silicate Inorganic materials 0.000 claims description 45
229940032158 sodium silicate Drugs 0.000 claims description 45
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 44
235000019794 sodium silicate Nutrition 0.000 claims description 44
ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 claims description 42
229910052681 coesite Inorganic materials 0.000 claims description 32
229910052906 cristobalite Inorganic materials 0.000 claims description 32
235000012239 silicon dioxide Nutrition 0.000 claims description 32
229910052682 stishovite Inorganic materials 0.000 claims description 32
229910052905 tridymite Inorganic materials 0.000 claims description 32
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 26
229910052744 lithium Inorganic materials 0.000 claims description 26
125000001453 quaternary ammonium group Chemical group 0.000 claims description 23
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 21
238000000034 method Methods 0.000 claims description 20
XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims description 16
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 14
229910052799 carbon Inorganic materials 0.000 claims description 14
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 10
KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 claims description 10
TZIHFWKZFHZASV-UHFFFAOYSA-N anhydrous methyl formate Natural products COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 claims description 8
150000002894 organic compounds Chemical class 0.000 claims description 8
AIJULSRZWUXGPQ-UHFFFAOYSA-N Methylglyoxal Chemical group CC(=O)C=O AIJULSRZWUXGPQ-UHFFFAOYSA-N 0.000 claims description 7
229930040373 Paraformaldehyde Natural products 0.000 claims description 7
239000002253 acid Substances 0.000 claims description 7
WBJINCZRORDGAQ-UHFFFAOYSA-N formic acid ethyl ester Natural products CCOC=O WBJINCZRORDGAQ-UHFFFAOYSA-N 0.000 claims description 7
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 6
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 6
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 6
238000009835 boiling Methods 0.000 claims description 6
230000001427 coherent effect Effects 0.000 claims description 6
238000007710 freezing Methods 0.000 claims description 6
230000008014 freezing Effects 0.000 claims description 6
WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims description 6
XOJVVFBFDXDTEG-UHFFFAOYSA-N Norphytane Natural products CC(C)CCCC(C)CCCC(C)CCCC(C)C XOJVVFBFDXDTEG-UHFFFAOYSA-N 0.000 claims description 5
229910052581 Si3N4 Inorganic materials 0.000 claims description 5
229910000272 alkali metal oxide Inorganic materials 0.000 claims description 5
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 5
238000010304 firing Methods 0.000 claims description 5
HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 5
229910010271 silicon carbide Inorganic materials 0.000 claims description 5
-1 quaternary ammonium ions Chemical class 0.000 claims description 4
HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 4
229910000314 transition metal oxide Inorganic materials 0.000 claims description 4
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 3
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 3
230000002902 bimodal effect Effects 0.000 claims description 3
229910052804 chromium Inorganic materials 0.000 claims description 3
239000011651 chromium Substances 0.000 claims description 3
229910017052 cobalt Inorganic materials 0.000 claims description 3
239000010941 cobalt Substances 0.000 claims description 3
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 3
229910052802 copper Inorganic materials 0.000 claims description 3
239000010949 copper Substances 0.000 claims description 3
229910052742 iron Inorganic materials 0.000 claims description 3
238000002844 melting Methods 0.000 claims description 3
230000008018 melting Effects 0.000 claims description 3
229910052759 nickel Inorganic materials 0.000 claims description 3
229910052720 vanadium Inorganic materials 0.000 claims description 3
FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 claims description 2
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 2
XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 claims description 2
UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 2
235000013980 iron oxide Nutrition 0.000 claims description 2
VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 claims description 2
229910052748 manganese Inorganic materials 0.000 claims description 2
239000011572 manganese Substances 0.000 claims description 2
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims 1
238000001879 gelation Methods 0.000 abstract description 28
239000003153 chemical reaction reagent Substances 0.000 abstract description 16
229910052910 alkali metal silicate Inorganic materials 0.000 abstract description 7
239000003054 catalyst Substances 0.000 abstract description 3
238000002360 preparation method Methods 0.000 abstract description 3
238000003915 air pollution Methods 0.000 abstract description 2
238000001914 filtration Methods 0.000 abstract description 2
239000007789 gas Substances 0.000 abstract description 2
239000007788 liquid Substances 0.000 abstract description 2
229910001868 water Inorganic materials 0.000 description 29
238000003756 stirring Methods 0.000 description 27
239000004033 plastic Substances 0.000 description 25
239000002245 particle Substances 0.000 description 17
PUAQLLVFLMYYJJ-UHFFFAOYSA-N 2-aminopropiophenone Chemical compound CC(N)C(=O)C1=CC=CC=C1 PUAQLLVFLMYYJJ-UHFFFAOYSA-N 0.000 description 16
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
238000012935 Averaging Methods 0.000 description 12
239000003795 chemical substances by application Substances 0.000 description 12
239000002243 precursor Substances 0.000 description 9
239000003513 alkali Substances 0.000 description 8
239000012895 dilution Substances 0.000 description 8
238000010790 dilution Methods 0.000 description 8
239000006185 dispersion Substances 0.000 description 8
239000012456 homogeneous solution Substances 0.000 description 7
239000011734 sodium Substances 0.000 description 7
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
230000015572 biosynthetic process Effects 0.000 description 6
229910052708 sodium Inorganic materials 0.000 description 6
229920002866 paraformaldehyde Polymers 0.000 description 5
238000007792 addition Methods 0.000 description 4
238000009826 distribution Methods 0.000 description 4
150000002148 esters Chemical class 0.000 description 4
239000000945 filler Substances 0.000 description 4
LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 4
150000002500 ions Chemical class 0.000 description 4
239000000843 powder Substances 0.000 description 4
239000003929 acidic solution Substances 0.000 description 3
230000003247 decreasing effect Effects 0.000 description 3
239000004615 ingredient Substances 0.000 description 3
229910044991 metal oxide Inorganic materials 0.000 description 3
150000004706 metal oxides Chemical class 0.000 description 3
238000002156 mixing Methods 0.000 description 3
238000001556 precipitation Methods 0.000 description 3
239000007787 solid Substances 0.000 description 3
239000004094 surface-active agent Substances 0.000 description 3
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
230000002378 acidificating effect Effects 0.000 description 2
239000007864 aqueous solution Substances 0.000 description 2
QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 2
230000000694 effects Effects 0.000 description 2
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
229940015043 glyoxal Drugs 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
239000008240 homogeneous mixture Substances 0.000 description 2
230000036571 hydration Effects 0.000 description 2
238000006703 hydration reaction Methods 0.000 description 2
238000007654 immersion Methods 0.000 description 2
239000011159 matrix material Substances 0.000 description 2
238000005259 measurement Methods 0.000 description 2
238000006116 polymerization reaction Methods 0.000 description 2
229910052700 potassium Inorganic materials 0.000 description 2
239000011591 potassium Substances 0.000 description 2
239000002002 slurry Substances 0.000 description 2
229910000144 sodium(I) superoxide Inorganic materials 0.000 description 2
RLQWHDODQVOVKU-UHFFFAOYSA-N tetrapotassium;silicate Chemical compound [K+].[K+].[K+].[K+].[O-][Si]([O-])([O-])[O-] RLQWHDODQVOVKU-UHFFFAOYSA-N 0.000 description 2
239000004408 titanium dioxide Substances 0.000 description 2
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 2
BHMLFPOTZYRDKA-IRXDYDNUSA-N (2s)-2-[(s)-(2-iodophenoxy)-phenylmethyl]morpholine Chemical compound IC1=CC=CC=C1O[C@@H](C=1C=CC=CC=1)[C@H]1OCCNC1 BHMLFPOTZYRDKA-IRXDYDNUSA-N 0.000 description 1
PLFFHJWXOGYWPR-HEDMGYOXSA-N (4r)-4-[(3r,3as,5ar,5br,7as,11as,11br,13ar,13bs)-5a,5b,8,8,11a,13b-hexamethyl-1,2,3,3a,4,5,6,7,7a,9,10,11,11b,12,13,13a-hexadecahydrocyclopenta[a]chrysen-3-yl]pentan-1-ol Chemical compound C([C@]1(C)[C@H]2CC[C@H]34)CCC(C)(C)[C@@H]1CC[C@@]2(C)[C@]4(C)CC[C@@H]1[C@]3(C)CC[C@@H]1[C@@H](CCCO)C PLFFHJWXOGYWPR-HEDMGYOXSA-N 0.000 description 1
WPFUFWIHMYZXSF-UHFFFAOYSA-N 4-[2-(difluoromethyl)benzimidazol-1-yl]-n-[2-methyl-1-[2-(1-methylpiperidin-4-yl)phenyl]propan-2-yl]-6-morpholin-4-yl-1,3,5-triazin-2-amine Chemical compound C1CN(C)CCC1C1=CC=CC=C1CC(C)(C)NC1=NC(N2CCOCC2)=NC(N2C3=CC=CC=C3N=C2C(F)F)=N1 WPFUFWIHMYZXSF-UHFFFAOYSA-N 0.000 description 1
SYQQWGGBOQFINV-FBWHQHKGSA-N 4-[2-[(2s,8s,9s,10r,13r,14s,17r)-10,13-dimethyl-17-[(2r)-6-methylheptan-2-yl]-3-oxo-1,2,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-2-yl]ethoxy]-4-oxobutanoic acid Chemical compound C1CC2=CC(=O)[C@H](CCOC(=O)CCC(O)=O)C[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 SYQQWGGBOQFINV-FBWHQHKGSA-N 0.000 description 1
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
AXISYYRBXTVTFY-UHFFFAOYSA-N Isopropyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OC(C)C AXISYYRBXTVTFY-UHFFFAOYSA-N 0.000 description 1
241001091433 Itea Species 0.000 description 1
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
241000282941 Rangifer tarandus Species 0.000 description 1
241000212342 Sium Species 0.000 description 1
WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
239000000654 additive Substances 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
238000005054 agglomeration Methods 0.000 description 1
230000002776 aggregation Effects 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
239000002585 base Substances 0.000 description 1
SMDHCQAYESWHAE-UHFFFAOYSA-N benfluralin Chemical compound CCCCN(CC)C1=C([N+]([O-])=O)C=C(C(F)(F)F)C=C1[N+]([O-])=O SMDHCQAYESWHAE-UHFFFAOYSA-N 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
229910000423 chromium oxide Inorganic materials 0.000 description 1
239000002131 composite material Substances 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
238000007596 consolidation process Methods 0.000 description 1
230000002596 correlated effect Effects 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
MCWXGJITAZMZEV-UHFFFAOYSA-N dimethoate Chemical compound CNC(=O)CSP(=S)(OC)OC MCWXGJITAZMZEV-UHFFFAOYSA-N 0.000 description 1
230000003467 diminishing effect Effects 0.000 description 1
239000008098 formaldehyde solution Substances 0.000 description 1
238000007429 general method Methods 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
238000011068 loading method Methods 0.000 description 1
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
229910052753 mercury Inorganic materials 0.000 description 1
229910017604 nitric acid Inorganic materials 0.000 description 1
238000012856 packing Methods 0.000 description 1
239000012254 powdered material Substances 0.000 description 1
239000000376 reactant Substances 0.000 description 1
230000003014 reinforcing effect Effects 0.000 description 1
229910052814 silicon oxide Inorganic materials 0.000 description 1
239000007858 starting material Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
239000008399 tap water Substances 0.000 description 1
235000020679 tap water Nutrition 0.000 description 1
238000009827 uniform distribution Methods 0.000 description 1
238000009736 wetting Methods 0.000 description 1
NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/24—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/08—Silica
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/06—Washing
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Materials Engineering (AREA)
Organic Chemistry (AREA)
Ceramic Engineering (AREA)
Inorganic Chemistry (AREA)
Structural Engineering (AREA)
Silicon Compounds (AREA)
Catalysts (AREA)
Silicates, Zeolites, And Molecular Sieves (AREA)

CA206,974A 1974-02-08 1974-08-14 Corps poreux a teneur de silice a pores de dimension controlee Expired CA1059975A (fr)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US44069374A	1974-02-08	1974-02-08

Publications (1)

Publication Number	Publication Date
CA1059975A true CA1059975A (fr)	1979-08-07

Family

ID=23749795

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA206,974A Expired CA1059975A (fr)	1974-02-08	1974-08-14	Corps poreux a teneur de silice a pores de dimension controlee

Country Status (6)

Country	Link
JP (1)	JPS50115191A (fr)
CA (1)	CA1059975A (fr)
DE (1)	DE2503332C2 (fr)
FR (1)	FR2260547B1 (fr)
GB (1)	GB1501445A (fr)
NL (1)	NL7501483A (fr)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4090887A (en) *	1975-11-25	1978-05-23	E. I. Du Pont De Nemours And Company	Pigmented microporous silica microspheres produced by a water in oil emulsion
US4230679A (en)	1978-12-22	1980-10-28	E. I. Du Pont De Nemours And Company	Poly(silicic acid)
DE3837614A1 (de) *	1988-11-05	1990-05-10	Merck Patent Gmbh	Adsorptionsmittel fuer die chromatographie
DE4142898A1 (de) *	1991-12-23	1993-06-24	Sued Chemie Ag	Formlinge auf der basis von pyrogener kieselsaeure
DE4142902A1 (de) *	1991-12-23	1993-06-24	Sued Chemie Ag	Formlinge auf der basis von pyrogener kieselsaeure
US7135429B2 (en) *	2002-05-24	2006-11-14	Ppg Industries Ohio, Inc.	Attrition resistant carrier product
EP1629887B1 (fr) *	2004-07-29	2007-04-11	Qiagen GmbH	Corps formé monolithique pour la purification et la séparation de biopolymères
DE102009046257A1 (de) *	2009-10-30	2011-05-12	Carcoustics Techconsult Gmbh	Plattenförmige Isolationslage für eine Wand, Verfahren zu deren Herstellung sowie plattenförmiges Wandelement

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US3678144A (en) *	1970-06-12	1972-07-18	Corning Glass Works	Silicate bodies containing coprecipitated oxides

1974
- 1974-08-14 CA CA206,974A patent/CA1059975A/fr not_active Expired
1975
- 1975-01-28 DE DE2503332A patent/DE2503332C2/de not_active Expired
- 1975-02-06 GB GB5068/75A patent/GB1501445A/en not_active Expired
- 1975-02-06 JP JP50015840A patent/JPS50115191A/ja active Pending
- 1975-02-07 FR FR7503875A patent/FR2260547B1/fr not_active Expired
- 1975-02-07 NL NL7501483A patent/NL7501483A/xx not_active Application Discontinuation

Also Published As

Publication number	Publication date
GB1501445A (en)	1978-02-15
FR2260547A1 (fr)	1975-09-05
NL7501483A (nl)	1975-08-12
FR2260547B1 (fr)	1980-03-21
DE2503332C2 (de)	1983-12-01
JPS50115191A (fr)	1975-09-09
DE2503332A1 (de)	1975-08-14

Publication	Publication Date	Title
US4112032A (en)	1978-09-05	Silica-containing porous bodies of controlled pore size
DE68911811T2 (de)	1994-06-09	Poröser keramischer Sinter und Verfahren zu dessen Herstellung.
CA1087593A (fr)	1980-10-14	Microspheroides macroporeux et procede de fabrication
US3920578A (en)	1975-11-18	Colloidal silica-based binder vehicles and gels
US4010242A (en)	1977-03-01	Uniform oxide microspheres and a process for their manufacture
CA1059975A (fr)	1979-08-07	Corps poreux a teneur de silice a pores de dimension controlee
DE2631090C3 (de)	1980-08-07	Bindemittelgenüsch
US3492137A (en)	1970-01-27	Siliceous compositions
US6986819B2 (en)	2006-01-17	Metal-oxide-based energetic materials and synthesis thereof
EP0563310A4 (en)	1993-10-27	Method for preparating high solids bentonite slurries
US3718491A (en)	1973-02-27	Process for silicate-perlite structures
US4221578A (en)	1980-09-09	Method of making controlled-pore silica structures for high temperature insulation
EP0412673B1 (fr)	1994-03-09	Filtre en mousse céramique
JPS62180300A (ja)	1987-08-07	核廃棄物を固形化するガラス形成スラリ−及び固形化法
US3804650A (en)	1974-04-16	Silicate binders
US4125651A (en)	1978-11-14	Method for making chemically durable silicate coatings
US4346177A (en)	1982-08-24	Pulverulent compositions and refractory article obtained with said composition
US3791987A (en)	1974-02-12	Minute capsules having walls of siliceous material-hydroxy-containing material complex and process for their manufacture
US3782982A (en)	1974-01-01	Products prepared from soluble silicate solutions
JPH0615427B2 (ja)	1994-03-02	無機多孔体とその製造方法
DE69210813T2 (de)	1997-01-02	Vibrationsfähige harzgebundene feuerfestzusammensetzung
US4482388A (en)	1984-11-13	Method of reducing the green density of a slip cast article
US5320989A (en)	1994-06-14	Boron nitride-containing bodies and method of making the same
JPH0829952B2 (ja)	1996-03-27	多孔質ガラスの製造法
US3692690A (en)	1972-09-19	Encapsulation process by complex coacervation using polymers and capsule product therefrom