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BRPI1104809B1 - refractory inks based on water and alcohol made with the use of bauxite and molten alumina in arc furnaces applied in the melting of carbon steel, high alloy, low alloy and especially manganese and production process - Google Patents

refractory inks based on water and alcohol made with the use of bauxite and molten alumina in arc furnaces applied in the melting of carbon steel, high alloy, low alloy and especially manganese and production process Download PDF

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Publication number
BRPI1104809B1
BRPI1104809B1 BRPI1104809A BRPI1104809A BRPI1104809B1 BR PI1104809 B1 BRPI1104809 B1 BR PI1104809B1 BR PI1104809 A BRPI1104809 A BR PI1104809A BR PI1104809 A BRPI1104809 A BR PI1104809A BR PI1104809 B1 BRPI1104809 B1 BR PI1104809B1
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Prior art keywords
bauxite
alcohol
water
thixotropic agent
fused
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BRPI1104809A
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Portuguese (pt)
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Gonçalves De Souza Fernando
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Fernando Goncalves De Souza
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Application filed by Fernando Goncalves De Souza filed Critical Fernando Goncalves De Souza
Priority to BRPI1104809A priority Critical patent/BRPI1104809B1/en
Priority to PCT/BR2012/000409 priority patent/WO2013059899A1/en
Publication of BRPI1104809B1 publication Critical patent/BRPI1104809B1/en

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/10Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/12Condensation polymers of aldehydes or ketones
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/04Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/10Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/12Condensation polymers of aldehydes or ketones
    • C04B26/122Phenol-formaldehyde condensation polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/43Thickening agents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482Coating or impregnation materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/28Fire resistance, i.e. materials resistant to accidental fires or high temperatures

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Structural Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Ceramic Products (AREA)
  • Paints Or Removers (AREA)

Abstract

tintas refratarias base água e álcool feitas com a utilização de bauxita e alumina fundida em fornos a arco aplicadas na fusão de aços carbono, alta liga, baixa liga e especialmente manganês e processo de produção trata de um processo de produção e produto obtido, particularmente tintas refratárias para aplicação em quaisquer tipos de aço voltada para pintura de machos e moldes de areia de sílica, cromita e zirconita para fusão de aços de carbono, alta liga, baixa liga, manganês e ferros.refractory inks based on water and alcohol made with the use of bauxite and molten alumina in arc furnaces applied in the melting of carbon steel, high alloy, low alloy and especially manganese and the production process deals with a production process and product obtained, particularly paints refractory for application in any type of steel for painting cores and molds of silica, chromite and zirconite sand for melting carbon steel, high alloy, low alloy, manganese and irons.

Description

RELATÓRIO DESCRITIVO DE PATENTE DE INVENÇÃO “TINTAS REFRATARIAS BASE ÁGUA E ÁLCOOL FEITAS COM A UTILIZAÇÃO DE BAUXITA E ALUMINA FUNDIDA EM FORNOS A ARCO APLICADAS NA FUSÃO DE AÇOS CARBONO, ALTA LIGA, BAIXA LIGA E ESPECIALMENTE MANGANÊS E PROCESSO DE PRODUÇÃO” O presente pedido de patente de invenção do titulo em epígrafe e objeto de descrição e reivindicação nesta cártula trata de uma solução inventiva no campo de aplicação da indústria química para a obtenção de tintas refratárias que será aplicada na pintura de machos e moldes de areia de silica, cromita e zirconita para fusão de aços carbono, alta liga, baixa liga, manganês e ferros.DESCRIPTIVE REPORT OF THE PATENT OF INVENTION “REFRACTORY INKS BASED ON WATER AND ALCOHOL MADE WITH THE USE OF BAUXITE AND CAST ALUMINUM APPLIED IN THE FUSION OF CARBON STEELS, HIGH ALLOY, LOW ALLOY AND SPECIAL MANGANIC PROCESS AND MANUFACTURING OF THIS MANGANISH PROCESS invention patent of the title in title and object of description and claim in this carton deals with an inventive solution in the field of application of the chemical industry for obtaining refractory paints that will be applied in the painting of cores and molds of silica, chromite and zirconite for melting carbon steel, high alloy, low alloy, manganese and irons.

A solução proposta é provida de requisito de novidade com atividade inventiva, dado que não decorre de maneira óbvia de nenhum processo de produção, nem de tintas refratárias conhecidas no estado da técnica, sendo provido ainda de aplicabilidade industrial, atendendo aos requisitos de patenteabilidade, notadamente como patente de invenção, conforme disposto no artigo 8o da Lei 9.279.The proposed solution is provided with a novelty requirement with inventive step, given that it does not result obviously from any production process, nor from refractory inks known in the state of the art, and is also provided with industrial applicability, meeting patentability requirements, notably as patent as Article 8 of Law 9.279.

FUNDAMENTOS DA TÉCNICA: a fim de propiciar veracidade ao contexto explicitado no quadro introdutório, será apresentada uma breve explanação sobre o estado da técnica onde será possível a um técnico que milita no assunto reconhecer seus aspectos limitantes, para em momento posterior discorrer sobre as vantagens agregadas com a introdução deste inédito processo e produto obtido reivindicado.TECHNICAL FUNDAMENTALS: in order to provide veracity to the context explained in the introductory table, a brief explanation of the state of the art will be presented where it will be possible for a technician who fights on the subject to recognize its limiting aspects, to later discuss the aggregated advantages with the introduction of this unprecedented process and product claimed.

2/72/7

No atual estado da técnica para tintas refratárias são comumente utilizados minerais, tais como: zirconita, olivina, magnesita, silicato de alumínio, grafite, feldspatos, etc.. Estes materiais são usados na aplicação em aços puros ou combinados em 2 ou mais minerais na mesma mistura.In the current state of the art for refractory paints, minerals are commonly used, such as: zirconite, olivine, magnesite, aluminum silicate, graphite, feldspars, etc. These materials are used in the application in pure steels or combined in 2 or more minerals in same mixture.

Em sua produção são feitas em álcool como solvente na proporção de 10 - 30%; agentes de tixotropia 2 - 15%; fixadores 0,5 - 10% e minerais 35 - 80% para serem aplicadas por meio de spray, pincel, lavagem ou imersão.In their production they are made in alcohol as solvent in the proportion of 10 - 30%; thixotropy agents 2 - 15%; fixers 0.5 - 10% and minerals 35 - 80% to be applied by spray, brush, washing or immersion.

Estas tintas apresentam bons resultados técnicos, porem pelo fato de terem muito oxido de silica livre podem reagir em alguns casos com aços manganês gerando assim defeitos em peças fundidas.These paints present good technical results, but due to the fact that they have a lot of free silica oxide they can react in some cases with manganese steels, thus generating defects in castings.

Com isso para solucionar estes problemas atualmente são usados tintas feitas com zirconita, silicatos puros ou mixados para se fundir aços carbono, baixa liga, alta liga e inox e no caso de aços manganês usa-se tintas feitas com olivina e magnesita.In order to solve these problems, paints made with zirconite, pure or mixed silicates are currently used to melt carbon, low alloy, high alloy and stainless steel and in the case of manganese steel, paints made with olivine and magnesite are used.

Em caso de tintas base água 10 - 35%, agentes de tixotropia 3 - 15%; fixadores 1 - 15% e minerais 35 - 80%, a sua aplicação pode ser feita com sucesso no caso de tintas base zirconita e silicatos de alumínio puros ou mixados para fusão de aços carbono, alta liga, baixa liga e inox.In case of water-based paints 10 - 35%, thixotropic agents 3 - 15%; fasteners 1 - 15% and minerals 35 - 80%, can be applied successfully in the case of zirconite based paints and pure or mixed aluminum silicates for melting carbon, high alloy, low alloy and stainless steel.

Para aços manganês que devem ser feitos com magnesita o grande problema é o fato da magnesita reagir com água causando o endurecimento da tinta.For manganese steels that must be made with magnesite the big problem is the fact that the magnesite reacts with water causing the paint to harden.

Na literatura patentária a PI0802952-0 de 09/07/2008 trata de um composto para retirada de tinta presente em peças plásticas e processo de aplicação deste como um composto paraIn patent literature PI0802952-0 of 09/07/2008 deals with a compound for removing paint present in plastic parts and the process of applying this as a compound for

3/7 retirada de tinta presente em peças plásticas e processo de aplicação deste que, de acordo com as suas características, propicia a partir da utilização de um composto a base de oxido de alumínio e bauxita sintetizada na forma de grãos esféricos ou grãos angulares e de um processo de aplicação específico de retirada da tinta presente em peças plásticas em geral. Esta solução trata de um composto para retirada de tinta e não de uma tinta refratária.3/7 removal of paint present in plastic parts and application process, which, according to its characteristics, allows the use of a compound based on aluminum oxide and bauxite synthesized in the form of spherical grains or angular grains and of a specific application process of removing the paint present in plastic parts in general. This solution deals with an ink removal compound and not a refractory ink.

A aplicação de bauxita e alumina fundida é conhecida na produção de refratários para fornos e panelas de vazamento, em alguns casos como 100% do refratário e em outros casos mesclados com outros produtos.The application of bauxite and molten alumina is known in the production of refractories for furnaces and pouring pans, in some cases as 100% of the refractory and in other cases mixed with other products.

Pelo fato de apresentar um alto teor de oxido de alumínio e baixos teores de oxido de silica, o alto ponto de fusão (superior a 2000C) e alem de estarem estabilizados quimicamente pela fusão nos possibilitou chegar a conclusão que poderiamos aplicar estes matérias na produção de tintas refratarias para fusão de todos os tipos de aços.Due to its high content of aluminum oxide and low levels of silica oxide, the high melting point (above 2000C) and in addition to being chemically stabilized by fusion allowed us to conclude that we could apply these materials in the production of refractory inks for melting all types of steel.

O requerente conhecedor dos aspectos restritivos das soluções atuais desenvolveu uma tinta refratária cuja nova composição química permite sua utilização em todos os tipos de aços na sua fusão.The applicant with knowledge of the restrictive aspects of current solutions has developed a refractory paint whose new chemical composition allows its use in all types of steel in its melting.

A proposta da presente invenção tem como maior novidade o fato de se ter uma única tinta tanto base álcool como base água que pode ser usadas para fundir todos os tipos de aços, acabando assim com o uso de até três tintas para fundir aços.The proposal of the present invention has as its greatest novelty the fact that it has a single ink, both alcohol-based and water-based, which can be used to melt all types of steels, thus ending the use of up to three paints to melt steels.

4/74/7

Isso elimina os problemas de mistura de produtos gerando contaminações, controle maior do processo de aplicação da tinta por ser um único produto.This eliminates the problems of product mixing generating contamination, greater control of the paint application process as it is a single product.

Os maiores problemas enfrentados atualmente são os controles de qualidade que são demandados nas tintas.The biggest problems faced today are the quality controls that are demanded in paints.

A baixa refratariedade da magnesita usada em aços manganês, o fato da mesma reagir com água causando seu endurecimento.The low refractoriness of magnesite used in manganese steels, the fact that it reacts with water causing it to harden.

No caso de aços carbono, baixa liga, alta liga e inox esta tinta substitui com superioridade os materiais feitos com zirconita pura, silicato de alumínio puro e até mesmo os que são feitos com a mistura dos dois produtos.In the case of carbon steels, low alloys, high alloys and stainless steel, this paint is a superior substitute for materials made with pure zirconite, pure aluminum silicate and even those made with a mixture of the two products.

Com a presente invenção temos a unificação de uma única tinta para fundir todos os tipos de aços e reduzindo os custos em relação as tintas convencionais utilizadas.With the present invention we have the unification of a single paint to melt all types of steels and reducing costs in relation to the conventional paints used.

Para consolidar as “TINTAS REFRATARIAS BASE ÁGUA E ÁLCOOL FEITAS COM A UTILIZAÇÃO DE BAUXITA E ALUMINA FUNDIDA EM FORNOS A ARCO APLICADAS NA FUSÃO DE AÇOS CARBONO, ALTA LIGA, BAIXA LIGA E ESPECIALMENTE MANGANÊS E PROCESSO DE PRODUÇÃO” o requerente revela uma forma de realização do presente invento na descrição detalhada que se segue.In order to consolidate the “WATER AND ALCOHOL-BASED REFRACTORY PAINTS MADE WITH THE USE OF BAUXITE AND CAST ALUMINUM IN ARC OVENS APPLIED IN THE FUSION OF CARBON STEELS, HIGH ALLOY, LOW ALLOY AND ESPECIALLY MANGANESE AND PRODUCTION PROCESS” reveals the applicant's production process of the present invention in the following detailed description.

Para produção e obtenção da tinta refratária, objeto de reivindicação que consiste de um processo que se inicia em uma etapa de mistura em misturadores preferencialmente do tipo sigma e cawles onde ocorre a adição de solvente este sendo álcool ou água seguido da adição de fixadores e agentes de tixotropia por aproximadamente 20 minutos. Após esta etapaFor production and obtaining of refractory paint, object of claim that consists of a process that starts in a mixing stage in mixers preferably of the sigma and cawles type where the addition of solvent occurs, this being alcohol or water followed by the addition of fixatives and agents thixotropy for approximately 20 minutes. After this step

5/7 ocorre a adição de minerais partindo para outra etapa de mistura por aproximadamente 20 minutos de maneira a obter uma homogeneidade total da solução resultante. O processo em si consiste de etapas de misturas rápidas e simples.5/7 there is the addition of minerals, leaving for another mixing stage for approximately 20 minutes in order to obtain a total homogeneity of the resulting solution. The process itself consists of quick and simple mixing steps.

A tinta refratária da presente invenção apresenta uma composição química que permite ser aplicada em quaisquer tipos de aços sendo caracterizada por conter os ingredientes nas proporções reveladas onde:The refractory paint of the present invention has a chemical composition that allows it to be applied to any type of steel and is characterized by containing the ingredients in the revealed proportions where:

Exemplo 01 tinta refratária tendo água como solvente Água: 10-40%Example 01 refractory paint with water as solvent Water: 10-40%

Resina pva: 1-8%Pva resin: 1-8%

Agente tixotropia: 2-15%Thixotropic agent: 2-15%

Alumina fundida: 30-85%Fused alumina: 30-85%

Exemplo 02 tinta refratária tendo água como solvente Água: 10-40%Example 02 refractory paint with water as solvent Water: 10-40%

Resina pva: 1-8%Pva resin: 1-8%

Agente tixotropia: 2-15%Thixotropic agent: 2-15%

Bauxita fundida: 30-85%Fused bauxite: 30-85%

Exemplo 03 tinta refratária tendo água como solvente Água: 10-40%Example 03 refractory paint with water as solvent Water: 10-40%

Resina pva: 1-8%Pva resin: 1-8%

Agente tixotropia: 2-15%Thixotropic agent: 2-15%

Alumina fundida: 20-50%Fused alumina: 20-50%

Bauxita fundida: 20-50%Fused bauxite: 20-50%

Exemplo 04 tinta refratária tendo água como solventeExample 04 refractory paint with water as solvent

6/Ί6 / Ί

Água: 10-40%Water: 10-40%

Resina pva: 1-8%Pva resin: 1-8%

Agente tixotropia: 2-15%Thixotropic agent: 2-15%

Alumina fundida: 20-50%Fused alumina: 20-50%

Bauxita fundida: 20-50%Fused bauxite: 20-50%

Zirconita: 10-40%Zirconite: 10-40%

Exemplo 05 tinta refratária tendo álcool como solventeExample 05 refractory ink with alcohol as solvent

Álcool: 10-40%Alcohol: 10-40%

Resina fenólica/pva: 1-8%Phenolic resin / pva: 1-8%

Agente tixotropia: 2-15%Thixotropic agent: 2-15%

Alumina fundida: 30-85%Fused alumina: 30-85%

Exemplo 06 tinta refratária tendo álcool como solventeExample 06 refractory paint having alcohol as a solvent

Álcool: 10-40%Alcohol: 10-40%

Resina fenólica/pva: 1-8%Phenolic resin / pva: 1-8%

Agente tixotropia: 2-15%Thixotropic agent: 2-15%

Alumina fundida: 20-55%Fused alumina: 20-55%

Bauxita fundida: 20-55%Fused bauxite: 20-55%

Exemplo 07 tinta refratária tendo álcool como solventeExample 07 refractory paint having alcohol as a solvent

Álcool: 10-40%Alcohol: 10-40%

Resina fenólica/pva: 1-8%Phenolic resin / pva: 1-8%

Agente tixotropia: 2-15%Thixotropic agent: 2-15%

Bauxita fundida: 20-85%Fused bauxite: 20-85%

Exemplo 08 tinta refratária tendo álcool como solvente Álcool: 10-40%Example 08 refractory paint with alcohol as solvent Alcohol: 10-40%

7/77/7

Resina fenólica/pva: 1-8%Phenolic resin / pva: 1-8%

Agente tixotropia: 2-15%Thixotropic agent: 2-15%

Alumina fundida: 20-55%Fused alumina: 20-55%

Bauxita fundida: 20-55%Fused bauxite: 20-55%

Zirconita: 10-45%Zirconite: 10-45%

Exemplo 09 tinta refratária tendo álcool como solventeExample 09 refractory paint having alcohol as a solvent

Álcool: 10-40%Alcohol: 10-40%

Resina fenólica/pva: 1-8% io Agente tixotropia: 2-15%Phenolic resin / pva: 1-8% io Thixotropic agent: 2-15%

Alumina fundida: 20-55%Fused alumina: 20-55%

Bauxita fundida: 20-55%Fused bauxite: 20-55%

Magnesita: 10-45%Magnesite: 10-45%

Exemplo 10 tinta refratária tendo álcool como solventeExample 10 refractory ink having alcohol as a solvent

Álcool: 10-40%Alcohol: 10-40%

Resina fenólica/pva: 1-8%Phenolic resin / pva: 1-8%

Agente tixotropia: 2-15%Thixotropic agent: 2-15%

Alumina fundida: 20-55%Fused alumina: 20-55%

Bauxita fundida: 20-55%Fused bauxite: 20-55%

Silicato de alumínio: 10-50%Aluminum silicate: 10-50%

Deve-se destacar que a presente invenção não limita sua aplicação aos usos e etapas aqui descritas, podendo atender 25 a outras modalidades e ainda ser produzida segundo outras técnicas ou modos, porém sendo o escopo principal as formulações reveladas, quer sejam a base de água, solvente, ou isento de solvente.It should be noted that the present invention does not limit its application to the uses and steps described here, it can meet 25 other modalities and still be produced according to other techniques or modes, however the main scope being the formulations revealed, whether they are water-based , solvent, or solvent-free.

Claims (2)

REIVINDICAÇÕES 1) “TINTAS REFRATARIAS BASE ÁGUA E ÁLCOOL FEITAS COM A UTILIZAÇÃO DE BAUXITA E ALUMINA FUNDIDA EM FORNOS A ARCO APLICADAS NA FUSÃO DE AÇOS CARBONO, ALTA LIGA, BAIXA LIGA E ESPECIALMENTE MANGANÊS” consiste de uma composição química caracterizada por formulação (A) Água: 10-40%, Resina pva: 1-8%, Agente tixotropia: 2-15%, Alumina fundida: 30-85%; Formulação (B) Água: 10-40%, Resina pva: 1-8%, Agente tixotropia: 2-15%, Bauxita fundida: 30-85%; Formulação (C) Água: 10-40%, Resina pva: 1-8%, Agente tixotropia: 2-15%, Alumina fundida: 20-50%, Bauxita fundida: 20-50%;1) “WATER AND ALCOHOL-BASED REFRACTORY PAINTS MADE WITH THE USE OF BAUXITE AND MELTED ALUMINUM IN ARC OVENS APPLIED IN THE FUSION OF CARBON STEELS, HIGH ALLOY, LOW ALLOY AND ESPECIALLY MANGANESE” consists of a chemical composition characterized by water (formulation) : 10-40%, White resin: 1-8%, Thixotropic agent: 2-15%, Fused alumina: 30-85%; Formulation (B) Water: 10-40%, PVA resin: 1-8%, Thixotropic agent: 2-15%, molten bauxite: 30-85%; Formulation (C) Water: 10-40%, PVA resin: 1-8%, Thixotropic agent: 2-15%, Fused alumina: 20-50%, Fused bauxite: 20-50%; Formulação (D) Água: 10-40%, Resina pva: 1-8%, Agente tixotropia: 2-15%, Alumina fundida: 20-50%, Bauxita fundida: 20-50%,Formulation (D) Water: 10-40%, Resin: 1-8%, Thixotropic agent: 2-15%, Fused alumina: 20-50%, Fused bauxite: 20-50%, Zirconita: 10-40%; Formulação (E) Álcool: 10-40%, Resina fenólica/pva: 1-8%, Agente tixotropia: 2-15%, Alumina fundida: 3085%; Formulação (F) Álcool: 10-40%, Resina fenólica/pva: 1-8%, Agente tixotropia: 2-15%, Alumina fundida: 20-55%, Bauxita fundida: 20-55%; Formulação (G) Álcool: 10-40%, Resina fenólica/pva: 1-8%, Agente tixotropia: 2-15%, Bauxita fundida: 2085%; Formulação (H) Álcool: 10-40%, Resina fenólica/pva: 1-8%, Agente tixotropia: 2-15%, Alumina fundida: 20-55%, Bauxita fundida: 20-55%, Zirconita: 10-45%; Formulação (I) Álcool: 10-40%, Resina fenólica/pva: 1-8%, Agente tixotropia: 2-15%, Alumina fundida: 20-55%, Bauxita fundida: 20-55%, Magnesita: 10-45%; Formulação (J) Álcool: 10-40%, Resina fenólica/pva: 1-8%, Agente tixotropia: 2-15%, Alumina fundida: 20-55%, Bauxita fundida: 2055%, Silicato de alumínio: 10-50%.Zirconite: 10-40%; Formulation (E) Alcohol: 10-40%, Phenolic resin / pva: 1-8%, Thixotropic agent: 2-15%, Fused alumina: 3085%; Formulation (F) Alcohol: 10-40%, Phenolic resin / pva: 1-8%, Thixotropic agent: 2-15%, Fused alumina: 20-55%, Fused bauxite: 20-55%; Formulation (G) Alcohol: 10-40%, Phenolic resin / pva: 1-8%, Thixotropic agent: 2-15%, Molten bauxite: 2085%; Formulation (H) Alcohol: 10-40%, Phenolic resin / pva: 1-8%, Thixotropic agent: 2-15%, Fused alumina: 20-55%, Fused bauxite: 20-55%, Zirconite: 10-45 %; Formulation (I) Alcohol: 10-40%, Phenolic resin / pva: 1-8%, Thixotropic agent: 2-15%, Fused alumina: 20-55%, Fused bauxite: 20-55%, Magnesite: 10-45 %; Formulation (J) Alcohol: 10-40%, Phenolic resin / pva: 1-8%, Thixotropic agent: 2-15%, Fused alumina: 20-55%, Fused bauxite: 2055%, Aluminum silicate: 10-50 %. 2/22/2 2) “PROCESSO DE PRODUÇÃO”, CARACTERIZADO PELO fato de que consiste de um processo que se inicia em uma etapa de mistura em misturadores preferencialmente do tipo sigma e cawles onde ocorre a adição de solvente este sendo álcool ou água 5 seguido da adição de fixadores e agentes de tixotropia por aproximadamente 20 minutos; etapa de adição de minerais partindo para outra etapa de mistura por aproximadamente 20 minutos de maneira a obter uma homogeneidade total da solução resultante.2) “PRODUCTION PROCESS”, CHARACTERIZED BY THE fact that it consists of a process that begins in a mixing stage in mixers preferably of the sigma and cawles type where the addition of solvent occurs, this being alcohol or water 5 followed by the addition of fixatives and thixotropy agents for approximately 20 minutes; step of adding minerals leaving for another mixing step for approximately 20 minutes in order to obtain a total homogeneity of the resulting solution.
BRPI1104809A 2011-10-28 2011-10-28 refractory inks based on water and alcohol made with the use of bauxite and molten alumina in arc furnaces applied in the melting of carbon steel, high alloy, low alloy and especially manganese and production process BRPI1104809B1 (en)

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BRPI1104809A BRPI1104809B1 (en) 2011-10-28 2011-10-28 refractory inks based on water and alcohol made with the use of bauxite and molten alumina in arc furnaces applied in the melting of carbon steel, high alloy, low alloy and especially manganese and production process
PCT/BR2012/000409 WO2013059899A1 (en) 2011-10-28 2012-10-18 "water and alcohol based refractory paints made with bauxite and alumina fused in arc furnaces and applied in moulds for the fusion of carbon steels, high alloy, low- alloy steels and especially manganese and production process"

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CN104399872A (en) * 2014-11-08 2015-03-11 芜湖市鸿坤汽车零部件有限公司 Alcohol-based casting paint containing modified coconut shell powder and manufacturing method thereof
JP6416005B2 (en) * 2015-02-06 2018-10-31 株式会社熊谷組 Method for forming fireproof paint layer
CN110560629B (en) * 2019-09-20 2021-11-30 宁波江丰电子材料股份有限公司 Coating for smelting and casting high-purity aluminum and preparation method and application thereof

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GB1532864A (en) * 1977-09-29 1978-11-22 Ciba Geigy Ag Dressings for foundry moulds and cores
RO95389B1 (en) * 1986-07-03 1989-05-31 Institutul De Cercetare Stiintifica Thixotropic refractory paint
EP0420781A3 (en) * 1989-09-08 1992-09-02 Bostlan, S.A. Refractory paint for covering foundry moulds
ATE188458T1 (en) * 1995-03-06 2000-01-15 Shinagawa Refractories Co FIREPROOF SPRAY COMPOSITION
BRPI0603482B1 (en) * 2006-08-16 2017-11-21 Refrata Cerâmica Refratária Ltda REFRACTORY INK COMPOSITION, APPLICATION AND USE PROCESS
BRPI0902048E2 (en) * 2009-01-26 2010-12-14 Profusa Produtos Para Fundicao Ltda machining process of cores and molds
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