BRPI0507923A - process for the carbonylation of a conjugated diene - Google Patents
process for the carbonylation of a conjugated dieneInfo
- Publication number
- BRPI0507923A BRPI0507923A BRPI0507923-3A BRPI0507923A BRPI0507923A BR PI0507923 A BRPI0507923 A BR PI0507923A BR PI0507923 A BRPI0507923 A BR PI0507923A BR PI0507923 A BRPI0507923 A BR PI0507923A
- Authority
- BR
- Brazil
- Prior art keywords
- conjugated diene
- atoms
- carbonylation
- group
- bonded
- Prior art date
Links
- 150000001993 dienes Chemical class 0.000 title abstract 4
- 230000006315 carbonylation Effects 0.000 title abstract 3
- 238000005810 carbonylation reaction Methods 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- 125000004437 phosphorous atom Chemical group 0.000 abstract 4
- 125000004432 carbon atom Chemical group C* 0.000 abstract 3
- 229910052698 phosphorus Inorganic materials 0.000 abstract 3
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract 2
- 125000004429 atom Chemical group 0.000 abstract 2
- VURFVHCLMJOLKN-UHFFFAOYSA-N diphosphane Chemical compound PP VURFVHCLMJOLKN-UHFFFAOYSA-N 0.000 abstract 2
- 125000000962 organic group Chemical group 0.000 abstract 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 1
- 150000001450 anions Chemical class 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 229910052763 palladium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
- C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
PROCESSO PARA A CARBONILAçãO DE UM DIENO CONJUGADO Um processo para a carbonilação de um dieno conjugado, que compreende reagir o dieno conjugado com monóxido de carbono e um coreagente tendo um átomo de hidrogênio ativo na presença de um sistema de catalisador que inclui: (a) uma fonte de paládio e (b) um ligando de difosfina bidentado da fórmula (II): R¬1¬ > P¬1¬ - R - P¬2¬ < R¬2¬R¬3¬ em que P¬1¬e P¬2¬ representam átomos de fósforo; R¬1¬ representa um grupo orgânico divalente opcionalmente substituído ligado ao átomo de fósforo por dois átomos de carbono terciários e R¬2¬ e R¬3¬ independentemente representam grupos univalentes de 1 a 20 átomos contendo um átomo de carbono terciário através do qual cada grupo é ligado ao átomo de fósforo ou R¬2¬ e R¬3¬ juntamente formam um grupo orgânico divalente opcionalmente substituído contendo pelo menos 2 átomos de carbono terciários através do qual o grupo é ligado ao átomo de fósforo e R representa um grupo de ligação em ponte que compreende 3 átomos através dos quais P¬1¬ e linearmente conectado a P¬2¬ e (c) uma fonte de um ânion.A process for the carbonylation of a conjugated diene A process for the carbonylation of a conjugated diene comprising reacting the conjugated diene with carbon monoxide and a coreagent having an active hydrogen atom in the presence of a catalyst system which includes: (a) a palladium source and (b) a bidentate diphosphine ligand of the formula (II): where P¬1¬ - R - P¬2¬ <R¬2¬R¬3¬ where P¬1¬ and P¬2¬ represent phosphorus atoms; R¬1¬ represents an optionally substituted divalent organic group bonded to the phosphorus atom by two tertiary carbon atoms and R¬2¬ and R¬3¬ independently represent univalent groups of 1 to 20 atoms containing a tertiary carbon atom through which each group is bonded to the phosphorus atom or R¬2¬ and R¬3¬ together form an optionally substituted divalent organic group containing at least 2 tertiary carbon atoms through which the group is bonded to the phosphorus atom and R represents a group A bridging moiety comprising 3 atoms through which P¬1¬ is linearly connected to P¬2¬ and (c) a source of an anion.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP04251064 | 2004-02-26 | ||
| PCT/EP2005/050790 WO2005082829A1 (en) | 2004-02-26 | 2005-02-24 | Process for the carbonylation of a conjugated diene |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BRPI0507923A true BRPI0507923A (en) | 2007-07-17 |
Family
ID=34896130
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0507923-3A BRPI0507923A (en) | 2004-02-26 | 2005-02-24 | process for the carbonylation of a conjugated diene |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP1730096A1 (en) |
| JP (1) | JP2007524697A (en) |
| KR (1) | KR20070003945A (en) |
| CN (1) | CN1926090A (en) |
| BR (1) | BRPI0507923A (en) |
| CA (1) | CA2557360A1 (en) |
| TW (1) | TW200531962A (en) |
| WO (1) | WO2005082829A1 (en) |
| ZA (1) | ZA200606272B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0908980D0 (en) * | 2009-05-26 | 2009-07-01 | Johnson Matthey Plc | Process for preparing a complex |
| EP3527576B1 (en) * | 2018-02-14 | 2020-11-18 | Evonik Operations GmbH | Propyl-bridged diphosphine ligands for alkoxycarbonylation |
| CN109187831B (en) * | 2018-09-29 | 2021-08-03 | 云南中烟工业有限责任公司 | Simultaneous and rapid determination of nine alcohol compounds in alcohol by GC-MS |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW524801B (en) * | 1999-03-22 | 2003-03-21 | Shell Int Research | Process for the carbonylation of conjugated dienes |
| DE10106348A1 (en) * | 2001-02-09 | 2002-08-14 | Basf Ag | Compound suitable as a catalyst or for producing a catalyst system |
| DE10148712A1 (en) * | 2001-10-02 | 2003-04-17 | Basf Ag | New 2-phosphatricyclodecane diphosphine derivatives useful as components of palladium catalysts for carbonylating conjugated dienes |
| US6794553B2 (en) * | 2001-11-09 | 2004-09-21 | Shell Oil Company | Process for the telomerization of a conjugated diene, catalyst and bidentate ligand useful therein |
-
2005
- 2005-02-24 KR KR1020067019037A patent/KR20070003945A/en not_active Withdrawn
- 2005-02-24 WO PCT/EP2005/050790 patent/WO2005082829A1/en not_active Application Discontinuation
- 2005-02-24 CA CA002557360A patent/CA2557360A1/en not_active Abandoned
- 2005-02-24 BR BRPI0507923-3A patent/BRPI0507923A/en not_active Application Discontinuation
- 2005-02-24 TW TW094105626A patent/TW200531962A/en unknown
- 2005-02-24 CN CNA2005800061112A patent/CN1926090A/en active Pending
- 2005-02-24 JP JP2007500215A patent/JP2007524697A/en not_active Withdrawn
- 2005-02-24 EP EP05716788A patent/EP1730096A1/en not_active Withdrawn
-
2006
- 2006-07-28 ZA ZA200606272A patent/ZA200606272B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CA2557360A1 (en) | 2005-09-09 |
| WO2005082829A1 (en) | 2005-09-09 |
| ZA200606272B (en) | 2008-01-30 |
| EP1730096A1 (en) | 2006-12-13 |
| JP2007524697A (en) | 2007-08-30 |
| KR20070003945A (en) | 2007-01-05 |
| CN1926090A (en) | 2007-03-07 |
| TW200531962A (en) | 2005-10-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| BRPI0410471A (en) | process for the carbonylation of a conjugated diene, bidentate diphosphine binder, catalytic composition, and carbonylation product composition | |
| BR0009187A (en) | Process for the carbonylation of dienosconjugates, process for preparingcaprolactam, nylon 6 or nylon 6,6, catalyst system, and, use of this | |
| ATE388157T1 (en) | NEW PHOSPHITE COMPOUNDS AND THEIR RH COMPLEXES | |
| BR0109242A (en) | Carbonylation process of ethylenically unsaturated compounds | |
| BR9810978A (en) | Processes for preparing mononitrile mixtures and for preparing adiponitrile, and, use of catalysts | |
| BRPI0507918A (en) | process for the carbonylation of unsaturated compounds, catalyst composition, and asymmetric bidentate diphosphine ligand | |
| BR0214038A (en) | Iminoamide catalyst compositions for olefin polymerization | |
| BR0211455A (en) | Suitable catalyst system and processes for the preparation thereof, mixtures of mono-olefinic c5 mononitriles, dinitrile and adipodinitrile | |
| BR0015200A (en) | Phosphite, process to prepare it, use of it, transition metal complex, process to prepare it, use of it, and processes for the addition of cyanidric acid in an olefinic double bond, and, for the isomerization of organic nitriles | |
| BRPI0706486C8 (en) | process for the preparation of compounds, compound, non-symmetric iron complex, catalyst system, use of a catalyst system, and process for the preparation of polyolefins | |
| BR9810432A (en) | Catalyst systems for | |
| BR0309585A (en) | Homogeneous process for the hydrogenation of carboxylic acids and derivatives thereof | |
| BR112012016473A2 (en) | Bidentate ligand, process for the carbonylation of ethylenically unsaturated compounds, complex, and catalyst system | |
| BR9812207A (en) | Catalyst, processes for preparing a catalyst, mixtures of monoolefins c5 mononitriles and adiponitrile, and use of catalysts | |
| ATE258936T1 (en) | BIDENTATE LIGANDS FOR CATALYST SYSTEMS | |
| BRPI0417643A (en) | process for the preparation of glycolaldehyde, catalyst composition and process for the preparation of ethylene glycol | |
| BR9610819A (en) | Hydrocyanation process of organic compounds | |
| BRPI0507923A (en) | process for the carbonylation of a conjugated diene | |
| BR112012014500A2 (en) | method for increasing the exchange number (ton) of a catalyst system | |
| MY127097A (en) | Process for the carbonylation of a conjugated diene | |
| KR900012942A (en) | Preparation of Aminopropyl Alkoxy Silanes | |
| WO2004028689A3 (en) | Process for the hydroformylation of an ethylenically unsaturated compound using a bidentate diphosphine composition with a bridging group comprising sp2 hybridized carbon atoms bound to the phosphorous atoms | |
| FR2596390B1 (en) | CATALYTIC DIMERIZATION PROCESS OF A LOWER ALKYL ACRYLATE AND CATALYTIC COMPOSITION | |
| BR9913404A (en) | Process for preparing cyanovaleric acid or esters, diphosphine compound, and catalyst composition | |
| BRPI0502897A (en) | coloring compounds |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B11A | Dismissal acc. art.33 of ipl - examination not requested within 36 months of filing | ||
| B11Y | Definitive dismissal acc. article 33 of ipl - extension of time limit for request of examination expired |