BRPI0411635A - processos para produção de polìmero, polìmero, composição de revestimento, processos para produção de um copolìmero de enxerto e de mistura de polìmero e sistemas de polimerização - Google Patents
processos para produção de polìmero, polìmero, composição de revestimento, processos para produção de um copolìmero de enxerto e de mistura de polìmero e sistemas de polimerizaçãoInfo
- Publication number
- BRPI0411635A BRPI0411635A BRPI0411635-6A BRPI0411635A BRPI0411635A BR PI0411635 A BRPI0411635 A BR PI0411635A BR PI0411635 A BRPI0411635 A BR PI0411635A BR PI0411635 A BRPI0411635 A BR PI0411635A
- Authority
- BR
- Brazil
- Prior art keywords
- polymer
- hybrid
- polymerization
- processes
- reactors
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
- C08G18/6283—Polymers of nitrogen containing compounds having carbon-to-carbon double bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0006—Controlling or regulating processes
- B01J19/0013—Controlling the temperature of the process
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/18—Stationary reactors having moving elements inside
- B01J19/1862—Stationary reactors having moving elements inside placed in series
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/08—Homopolymers or copolymers of acrylic acid esters
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00002—Chemical plants
- B01J2219/00027—Process aspects
- B01J2219/00029—Batch processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00002—Chemical plants
- B01J2219/00027—Process aspects
- B01J2219/0004—Processes in series
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00054—Controlling or regulating the heat exchange system
- B01J2219/00056—Controlling or regulating the heat exchange system involving measured parameters
- B01J2219/00058—Temperature measurement
- B01J2219/00063—Temperature measurement of the reactants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00054—Controlling or regulating the heat exchange system
- B01J2219/00056—Controlling or regulating the heat exchange system involving measured parameters
- B01J2219/00065—Pressure measurement
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
- B01J2219/00094—Jackets
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00121—Controlling the temperature by direct heating or cooling
- B01J2219/00123—Controlling the temperature by direct heating or cooling adding a temperature modifying medium to the reactants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00121—Controlling the temperature by direct heating or cooling
- B01J2219/0013—Controlling the temperature by direct heating or cooling by condensation of reactants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00162—Controlling or regulating processes controlling the pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00182—Controlling or regulating processes controlling the level of reactants in the reactor vessel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/02—Apparatus characterised by their chemically-resistant properties
- B01J2219/025—Apparatus characterised by their chemically-resistant properties characterised by the construction materials of the reactor vessel proper
- B01J2219/0277—Metal based
- B01J2219/0286—Steel
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
- Polymerisation Methods In General (AREA)
- Polyethers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Graft Or Block Polymers (AREA)
Abstract
"PROCESSOS PARA PRODUçãO DE POLìMERO, POLìMERO, COMPOSIçãO DE REVESTIMENTO, PROCESSOS PARA PRODUçãO DE UM COPOLìMERO DE ENXERTO E DE MISTURA DE POLìMERO E SISTEMAS DE POLIMERIZAçãO". A presente invenção refere-se a um novo processo de polimerização em alta temperatura que opera a altas pressões para a produção de um polímero. O processo inclui o transporte das misturas de reator híbrido, as quais incluem um ou mais monómeros de reator híbrido e um ou mais iniciadores de reator híbrido a um ou mais reatores híbridos. Os reatores híbridos são mantidos a temperaturas de polimerização híbridas e pressões padrão de polimerização de sub-refluxo eficazes para causar a polimerização de uma parte dos monómeros de reator híbrido no polímero. O processo inclui além disso o transporte do conteúdo do reator híbrido dos reatores híbridos a um ou mais reatores de batelada mantidos a temperaturas de polimerização de batelada e a pressões de polimerização de refluxo eficazes para causar a polimerização de uma parte restante dos monómeros de reator híbrido no polímero. Os reatores híbridos são menores em volume do que os reatores de batelada. Ao utilizar a combinação de reator híbrido/de batelada, o processo da presente invenção pode ser executado sob condições de operação seguras. O processo da presente invenção também permite o controle da polidispersão e do peso molecular dos polímeros resultantes. Em conseqüência disto, os polímeros produzidos dessa maneira podem ser usados como aglutinantes em composições, tais como as composições de revestimento usadas em reacabamento automotivo e aplicações de OEM que têm as propriedades de revestimento desejadas. A presente invenção também se refere a um sistema de polimerização usado no processo da presente invenção.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/612,495 US6989421B2 (en) | 2003-07-02 | 2003-07-02 | Two component coating compositions and coatings produced therefrom |
US10/617,270 US7585924B2 (en) | 2002-07-11 | 2003-07-10 | Pressurized high temperature polymerization process and polymerization system used therein |
PCT/US2004/021684 WO2005003185A1 (en) | 2003-07-02 | 2004-07-01 | Pressurized high temperature polymerization process |
Publications (1)
Publication Number | Publication Date |
---|---|
BRPI0411635A true BRPI0411635A (pt) | 2006-08-29 |
Family
ID=33568011
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BRPI0411680-1A BRPI0411680A (pt) | 2003-07-02 | 2004-07-01 | composição de revestimento e processo de produção de revestimento |
BRPI0411635-6A BRPI0411635A (pt) | 2003-07-02 | 2004-07-01 | processos para produção de polìmero, polìmero, composição de revestimento, processos para produção de um copolìmero de enxerto e de mistura de polìmero e sistemas de polimerização |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BRPI0411680-1A BRPI0411680A (pt) | 2003-07-02 | 2004-07-01 | composição de revestimento e processo de produção de revestimento |
Country Status (8)
Country | Link |
---|---|
EP (2) | EP1639048B1 (pt) |
JP (2) | JP2007523962A (pt) |
KR (2) | KR20060027829A (pt) |
AU (2) | AU2004253971A1 (pt) |
BR (2) | BRPI0411680A (pt) |
CA (2) | CA2526696A1 (pt) |
MX (2) | MXPA05013541A (pt) |
WO (2) | WO2005003185A1 (pt) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20070066777A1 (en) * | 2004-09-03 | 2007-03-22 | Bzowej Eugene I | Methods for producing crosslinkable oligomers |
US7989573B2 (en) | 2005-12-16 | 2011-08-02 | 3M Innovative Properties Company | Method of free radically polymerizing vinyl monomers |
US7968661B2 (en) | 2005-12-28 | 2011-06-28 | 3M Innovative Properties Company | Method of free radically polymerizing vinyl monomers |
CN102015935A (zh) * | 2008-03-18 | 2011-04-13 | 纳米X有限公司 | 制备高耐磨性车辆漆的方法、车辆漆及其用途 |
CN103415539B (zh) | 2010-11-25 | 2016-10-12 | 巴斯夫欧洲公司 | 细碎的阳离子性或两性聚合物水分散体、其制备方法、其用途、阳离子性或两性保护胶体及其制备方法 |
BR112014019591A2 (pt) * | 2012-02-10 | 2019-09-24 | List Holding Ag | processo para a execução de processos mecânicos, químicos e/ou térmicos |
US20180222168A1 (en) * | 2015-08-07 | 2018-08-09 | Daikin Industries, Ltd. | Composition, coating film, fluorine-containing coating film and laminate |
CN113544182B (zh) * | 2019-03-19 | 2023-09-19 | 科思创知识产权两合公司 | 基于环醚的含仲氨基的粘料 |
FR3109102B1 (fr) * | 2020-04-14 | 2022-12-02 | Les Laboratoires Osteal Medical | Station de polymérisation pour greffage d’un revêtement bioactif |
FR3122103A1 (fr) * | 2021-04-27 | 2022-10-28 | Ipsomedic | Cascade de réacteur Gaz - Liquide - Solide pour la réalisation de réactions chimiques en flux continu sous haute pression |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5518698B1 (pt) * | 1971-04-03 | 1980-05-21 | ||
US4480078A (en) * | 1981-09-23 | 1984-10-30 | The Goodyear Tire & Rubber Company | Continuous emulsion polymerization process |
US4559374A (en) * | 1984-09-19 | 1985-12-17 | The Goodyear Tire & Rubber Company | Continuous emulsion polymerization process for preparation of flame-retardant latex |
JPH0618841B2 (ja) * | 1986-01-28 | 1994-03-16 | 三井東圧化学株式会社 | プロピレンのブロツク共重合体の製造方法 |
JPS63186714A (ja) * | 1987-01-20 | 1988-08-02 | イー・アイ・デュポン・ドゥ・ヌムール・アンド・カンパニー | アクリロウレタン反応生成物 |
US5098956A (en) * | 1988-01-22 | 1992-03-24 | S.C. Johnson & Son, Inc. | Polyol blends of low TG and high TG acrylic copolymers |
JP2677449B2 (ja) * | 1990-10-30 | 1997-11-17 | 積水化学工業株式会社 | 車体へのマーキング方法 |
US5171768A (en) * | 1991-10-21 | 1992-12-15 | The Goodyear Tire & Rubber Company | Process for the production of carboxylated latexes by the selective monomer addition and polymerization |
US5264315A (en) * | 1992-04-20 | 1993-11-23 | Xerox Corporation | Process for the continuous preparation of encapsulated toner |
JP2923125B2 (ja) * | 1992-05-26 | 1999-07-26 | 関西ペイント株式会社 | 塗料組成物 |
US5936026A (en) * | 1994-05-19 | 1999-08-10 | E. I. Du Pont De Nemours And Company | Coatings comprising self-stabilized lattices prepared in a aqueous carrier |
IL116255A (en) * | 1995-01-05 | 2004-02-19 | Du Pont | High-solids coating composition |
US5747590A (en) * | 1996-12-04 | 1998-05-05 | E. I. Du Pont De Nemours And Company | Acrylic-melamine-functionalized oligomer coating composition |
US5955532A (en) * | 1997-07-17 | 1999-09-21 | E. I. Du Pont De Nemours And Company | Aqueous coating composition of a self-stabilized crosslinked latex |
JPH1180654A (ja) * | 1997-09-03 | 1999-03-26 | Kansai Paint Co Ltd | 高固形分塗料組成物及びそれを用いる上塗り塗膜形成方法 |
CA2304529C (en) * | 1997-11-03 | 2010-02-02 | E.I. Du Pont De Nemours And Company | Reactive oligomers for isocyanate coatings |
US6319987B1 (en) * | 1998-08-31 | 2001-11-20 | Ppg Industries Ohio, Inc. | Thermosetting compositions containing hydroxyl-functional polymers prepared using atom transfer radical polymerization |
JP3984488B2 (ja) * | 2001-03-27 | 2007-10-03 | 日本ペイント株式会社 | 硬化性塗料組成物および塗膜形成方法 |
US7585924B2 (en) * | 2002-07-11 | 2009-09-08 | E. I. Du Pont De Nemours And Company | Pressurized high temperature polymerization process and polymerization system used therein |
-
2004
- 2004-07-01 EP EP04756709A patent/EP1639048B1/en not_active Revoked
- 2004-07-01 EP EP04777656A patent/EP1639019A4/en not_active Withdrawn
- 2004-07-01 KR KR1020057025385A patent/KR20060027829A/ko not_active Withdrawn
- 2004-07-01 AU AU2004253971A patent/AU2004253971A1/en not_active Abandoned
- 2004-07-01 BR BRPI0411680-1A patent/BRPI0411680A/pt not_active IP Right Cessation
- 2004-07-01 JP JP2006518858A patent/JP2007523962A/ja active Pending
- 2004-07-01 CA CA002526696A patent/CA2526696A1/en not_active Abandoned
- 2004-07-01 MX MXPA05013541A patent/MXPA05013541A/es unknown
- 2004-07-01 BR BRPI0411635-6A patent/BRPI0411635A/pt not_active Application Discontinuation
- 2004-07-01 CA CA002527084A patent/CA2527084A1/en not_active Abandoned
- 2004-07-01 KR KR1020057025289A patent/KR20060038405A/ko not_active Withdrawn
- 2004-07-01 WO PCT/US2004/021684 patent/WO2005003185A1/en active Application Filing
- 2004-07-01 JP JP2006518857A patent/JP2007527451A/ja active Pending
- 2004-07-01 AU AU2004254267A patent/AU2004254267A1/en not_active Abandoned
- 2004-07-01 WO PCT/US2004/021685 patent/WO2005003243A2/en active Application Filing
- 2004-07-01 MX MXPA05013523A patent/MXPA05013523A/es unknown
Also Published As
Publication number | Publication date |
---|---|
EP1639048A2 (en) | 2006-03-29 |
EP1639048B1 (en) | 2012-11-14 |
EP1639019A1 (en) | 2006-03-29 |
CA2526696A1 (en) | 2005-01-13 |
MXPA05013523A (es) | 2006-03-09 |
WO2005003185A1 (en) | 2005-01-13 |
AU2004253971A1 (en) | 2005-01-13 |
JP2007523962A (ja) | 2007-08-23 |
JP2007527451A (ja) | 2007-09-27 |
MXPA05013541A (es) | 2006-03-09 |
KR20060027829A (ko) | 2006-03-28 |
WO2005003243A2 (en) | 2005-01-13 |
CA2527084A1 (en) | 2005-01-13 |
BRPI0411680A (pt) | 2006-08-08 |
KR20060038405A (ko) | 2006-05-03 |
AU2004254267A1 (en) | 2005-01-13 |
EP1639019A4 (en) | 2008-11-12 |
EP1639048A4 (en) | 2006-07-05 |
WO2005003243A3 (en) | 2005-11-03 |
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