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BR9912316A - Catalisador de ciclopentadienil/fosfinimina com um e somente um ligando ativável - Google Patents

Catalisador de ciclopentadienil/fosfinimina com um e somente um ligando ativável

Info

Publication number
BR9912316A
BR9912316A BR9912316-9A BR9912316A BR9912316A BR 9912316 A BR9912316 A BR 9912316A BR 9912316 A BR9912316 A BR 9912316A BR 9912316 A BR9912316 A BR 9912316A
Authority
BR
Brazil
Prior art keywords
ligand
activable
cyclopentadienyl
phosphinimine
phosphinimine catalyst
Prior art date
Application number
BR9912316-9A
Other languages
English (en)
Other versions
BR9912316B1 (pt
Inventor
Ruppert Edward Von Hake Spence
Douglas W Stephan
Stephen John Brown
Dusan Jeremic
Qinyan Wang
Original Assignee
Nova Chem Int Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nova Chem Int Sa filed Critical Nova Chem Int Sa
Publication of BR9912316A publication Critical patent/BR9912316A/pt
Publication of BR9912316B1 publication Critical patent/BR9912316B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/535—Organo-phosphoranes
    • C07F9/5355—Phosphoranes containing the structure P=N-
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Molecular Biology (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Catalysts (AREA)

Abstract

"CATALISADOR DE CICLOPENTADIENIL/FOSFINIMINA COM UM E SOMENTE UM LIGANDO ATIVáVEL" Complexos organometálicos de titânio ou zircónio tendo somente 3 ligandos (especificamente, um ligando ciclopentadienil, um ligando fosfinimina e um ligando ativável) são componentes de catalisadores para a polimerização olefínica. Os sistemas de polimerização preferidos são preparados pela combinação dos complexos organometálicos com um ativador iónico e / ou um alumoxano. Os componentes de catalisador preferidos contêm titânio (III) e são utilizados na polimeração de etileno.
BRPI9912316-9A 1998-07-21 1999-06-08 catalisador de ciclopentadienil/fosfinimina com um e somente um ligando ativável. BR9912316B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CA002243726A CA2243726C (en) 1998-07-21 1998-07-21 Cyclopentadienyl/phosphinimine catalyst with one and only one activatable ligand
PCT/CA1999/000526 WO2000005236A1 (en) 1998-07-21 1999-06-08 Cyclopentadienyl /phosphinimine catalyst with one and only one activatable ligand

Publications (2)

Publication Number Publication Date
BR9912316A true BR9912316A (pt) 2001-05-08
BR9912316B1 BR9912316B1 (pt) 2010-06-01

Family

ID=4162677

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI9912316-9A BR9912316B1 (pt) 1998-07-21 1999-06-08 catalisador de ciclopentadienil/fosfinimina com um e somente um ligando ativável.

Country Status (12)

Country Link
US (1) US6355744B1 (pt)
EP (1) EP1112276B1 (pt)
JP (1) JP4377061B2 (pt)
KR (1) KR100533925B1 (pt)
CN (1) CN1161364C (pt)
AT (1) ATE228141T1 (pt)
AU (1) AU4126399A (pt)
BR (1) BR9912316B1 (pt)
CA (1) CA2243726C (pt)
DE (1) DE69904061T2 (pt)
ES (1) ES2187161T3 (pt)
WO (1) WO2000005236A1 (pt)

Families Citing this family (35)

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US6242545B1 (en) * 1997-12-08 2001-06-05 Univation Technologies Polymerization catalyst systems comprising substituted hafinocenes
US8497330B2 (en) * 1997-12-08 2013-07-30 Univation Technologies, Llc Methods for polymerization using spray dried and slurried catalyst
US20060293470A1 (en) * 2005-06-28 2006-12-28 Cao Phuong A Polymerization process using spray-dried catalyst
JP4122655B2 (ja) * 1999-10-05 2008-07-23 住友化学株式会社 遷移金属化合物、付加重合用触媒成分、付加重合用触媒およびオレフィン重合体の製造方法
CA2311068C (en) * 2000-06-08 2010-03-09 Nova Chemicals Corporation Process to prepare ethylene propylene elastomer
DE10028432A1 (de) * 2000-06-13 2001-12-20 Basell Polyolefine Gmbh Auf calciniertes Hydrotalcit geträgerter Katalysatorfeststoff zur Olefinpolymerisation
CA2347410C (en) * 2001-05-11 2009-09-08 Nova Chemicals Corporation Solution polymerization process catalyzed by a phosphinimine catalyst
EP1651686B1 (en) * 2003-08-04 2013-10-16 Lanxess Elastomers B.V. Improved method of preparing a hydrocarbylated metal-organic compound
EP1506974A1 (en) 2003-08-04 2005-02-16 DSM IP Assets B.V. Process for the preparation of a metalloorganic compound comprising at least one imine ligand
US7547751B2 (en) 2003-08-04 2009-06-16 Dsm Ip Assets B.V. Process for the preparation of a polyolefin
EP1535936A1 (en) * 2003-11-25 2005-06-01 DSM IP Assets B.V. Improved method of preparing a hydrocarbylated metal-organic compound
EP1651691A2 (en) * 2003-08-04 2006-05-03 DSM IP Assets B.V. Process for the preparation of a polyolefin
US7754830B2 (en) 2004-05-20 2010-07-13 Univation Technologies, Llc Polymerization reaction monitoring with determination of induced condensing agent concentration for preventing discontinuity events
US7683140B2 (en) * 2004-05-20 2010-03-23 Univation Technologies, Llc Method for determining temperature value indicative of resin stickiness from data generated by polymerization reaction monitoring
CN101511882B (zh) * 2006-09-07 2011-09-21 尤尼威蒂恩技术有限责任公司 使用降低熔融起始温度的模型在线测定树脂粘着性程度的方法
CA2662796A1 (en) * 2006-09-07 2008-03-13 Univation Technologies, Llc Methods for determining temperature value indicative of resin stickiness from data generated by polymerization reaction monitoring
WO2008148499A1 (en) * 2007-06-06 2008-12-11 Dsm Ip Assets B.V. Imine catalyst
WO2008151776A1 (en) * 2007-06-12 2008-12-18 Dsm Ip Assets B.V. Imine catalyst
BR112012020718A2 (pt) * 2010-02-19 2016-04-26 Dow Global Technologies Inc complexo de metal-ligante e catalisador
CA2695552C (en) * 2010-03-04 2017-01-03 Nova Chemicals Corporation Process for preparing low molecular weight wax
US9120741B2 (en) 2012-12-21 2015-09-01 Governors Of The University Of Alberta Transition metal catalysts for hydrogenation and hydrosilylation
US9051229B2 (en) 2012-12-21 2015-06-09 Governors Of The University Of Alberta Transition metal catalysts for C—O hydrogenolysis and hydrodeoxygenation
US8901334B2 (en) 2012-12-21 2014-12-02 Governors Of The University Of Alberta Transition metal-phosphoranimide catalysts
US9120984B2 (en) 2012-12-21 2015-09-01 Governors Of The University Of Alberta Transition metal catalysts for hydrodesulfurization
US9458395B2 (en) 2013-05-21 2016-10-04 Governors Of The University Of Alberta Catalysts for hydrodesulfurization
US9000198B2 (en) 2013-05-21 2015-04-07 Governors Of The University Of Alberta Mixed-valent transition metal-phosphoranimide catalysts
CA2820501C (en) * 2013-06-27 2021-01-26 Nova Chemicals Corporation Synthesis of phosphinimide coordination compounds
CN110386956B (zh) * 2018-04-20 2022-01-04 中国石油化工股份有限公司 前过渡金属化合物及其制备方法和中间体以及在烯烃聚合中的应用
CN110386957B (zh) * 2018-04-20 2022-01-04 中国石油化工股份有限公司 异核双金属配合物及其制备方法及在制备双峰分布的烯烃聚合物中的应用
CN110386955B (zh) * 2018-04-20 2022-01-04 中国石油化工股份有限公司 前过渡金属化合物及其制备方法和中间体以及在烯烃聚合中的应用
CA3037503A1 (en) * 2018-04-26 2019-10-26 Nova Chemicals Corporation Phosphinimine amido-ether complexes
JP7558658B2 (ja) 2019-01-25 2024-10-01 三井化学株式会社 オレフィン重合用触媒
CN115734975B (zh) * 2020-06-29 2024-02-27 宝理塑料株式会社 环状烯烃共聚物的制造方法、和降冰片烯单体与乙烯的共聚用的催化剂组合物
CN114933665B (zh) * 2022-06-06 2023-11-21 中国科学院长春应用化学研究所 一种异金属双核催化剂及其制法和组合物及应用
CN115043965B (zh) * 2022-07-27 2023-04-21 中国科学技术大学 含有膦亚胺配体骨架的单茂金属催化剂及其制备方法和应用

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CA2210131C (en) * 1997-07-09 2005-08-02 Douglas W. Stephan Supported phosphinimine-cp catalysts

Also Published As

Publication number Publication date
ATE228141T1 (de) 2002-12-15
ES2187161T3 (es) 2003-05-16
DE69904061T2 (de) 2003-07-17
EP1112276A1 (en) 2001-07-04
US6355744B1 (en) 2002-03-12
JP4377061B2 (ja) 2009-12-02
DE69904061D1 (de) 2003-01-02
KR20010070992A (ko) 2001-07-28
CN1319103A (zh) 2001-10-24
CA2243726C (en) 2006-12-12
AU4126399A (en) 2000-02-14
WO2000005236A1 (en) 2000-02-03
CN1161364C (zh) 2004-08-11
KR100533925B1 (ko) 2005-12-07
BR9912316B1 (pt) 2010-06-01
JP2002521500A (ja) 2002-07-16
CA2243726A1 (en) 2000-01-21
EP1112276B1 (en) 2002-11-20

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TE Change of address
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B09A Decision: intention to grant [chapter 9.1 patent gazette]
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B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

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