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BR9909136A - Polìmero modificado e membranas poliméricas modificadas - Google Patents

Polìmero modificado e membranas poliméricas modificadas

Info

Publication number
BR9909136A
BR9909136A BR9909136-4A BR9909136A BR9909136A BR 9909136 A BR9909136 A BR 9909136A BR 9909136 A BR9909136 A BR 9909136A BR 9909136 A BR9909136 A BR 9909136A
Authority
BR
Brazil
Prior art keywords
polymers
sulfonated
aryl
nitrated
optionally
Prior art date
Application number
BR9909136-4A
Other languages
English (en)
Other versions
BRPI9909136B1 (pt
Inventor
Jochen Kerres
Original Assignee
Univ Stuttgart Inst Fuer Chemi
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univ Stuttgart Inst Fuer Chemi filed Critical Univ Stuttgart Inst Fuer Chemi
Publication of BR9909136A publication Critical patent/BR9909136A/pt
Publication of BRPI9909136B1 publication Critical patent/BRPI9909136B1/pt

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1041—Polymer electrolyte composites, mixtures or blends
    • H01M8/1044—Mixtures of polymers, of which at least one is ionically conductive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/52—Polyethers
    • B01D71/522—Aromatic polyethers
    • B01D71/5223—Polyphenylene oxide, phenyl ether polymers or polyphenylethers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/66—Polymers having sulfur in the main chain, with or without nitrogen, oxygen or carbon only
    • B01D71/68—Polysulfones; Polyethersulfones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
    • C08G65/48—Polymers modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/02—Polythioethers
    • C08G75/0204—Polyarylenethioethers
    • C08G75/0286—Chemical after-treatment
    • C08G75/0295—Modification with inorganic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/20—Polysulfones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/20—Polysulfones
    • C08G75/23—Polyethersulfones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218—Synthetic macromolecular compounds
    • C08J5/2256—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions other than those involving carbon-to-carbon bonds, e.g. obtained by polycondensation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
    • C08L81/02—Polythioethers; Polythioether-ethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
    • C08L81/06—Polysulfones; Polyethersulfones
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1023—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1025—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon and oxygen, e.g. polyethers, sulfonated polyetheretherketones [S-PEEK], sulfonated polysaccharides, sulfonated celluloses or sulfonated polyesters
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1027—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having carbon, oxygen and other atoms, e.g. sulfonated polyethersulfones [S-PES]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1032—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having sulfur, e.g. sulfonated-polyethersulfones [S-PES]
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2381/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen, or carbon only; Polysulfones; Derivatives of such polymers
    • C08J2381/02—Polythioethers; Polythioether-ethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2381/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen, or carbon only; Polysulfones; Derivatives of such polymers
    • C08J2381/06—Polysulfones; Polyethersulfones
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Sustainable Development (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Energy (AREA)
  • Electrochemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Composite Materials (AREA)
  • Materials Engineering (AREA)
  • Polyethers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)

Abstract

Patente de Invenção: <B>"POLìMERO MODIFICADO E MEMBRANAS POLIMéRICAS MODIFICADAS"<D>. A invenção refere-se a um método para a produção de polímeros de cadeia principal arila nitratados e, opcionalmente, sulfonados e aminados e, opcionalmente, sulfonados, além de polímeros de cadeia principal arila assim modificados. Polímeros de cadeia principal arila (por exemplo (1)) são nitratados por dissolução em solventes caros, tóxicos e ambientalmente perigosos. Polímeros de cadeia principal arila que fossem seletiva e simultaneamente nitratados e sulfonados não eram anteriormente conhecidos na literatura. O método da invenção torna possível produzir polímeros de cadeia principal arila nitratados (e opcionalmente sulfonados (2)) ou aminados após a redução (e opcionalmente sulfonados) de baixo custo, sem nenhum solvente orgânico. A nitratação (e opcionalmente sulfonação adicional) dos polímeros de cadeia principal arila ocorre por dissolução em ácido sulfúrico concentrado e por adição de quantidades desejadas de ácido nítrico a diferentes temperaturas e com diferentes tempos de agitação. A reação pode ser realizada (a) como um processo em duas etapas: nitratação seguida por isolamento do polímero, então, sulfonação opcional, e (b) como um processo em etapa única: nitratação e sulfonação simultâneas (2). Os polímeros nitratados (ou adicionalmente sulfonados) podem ser, então, reduzidos para formar polímeros aminado (ou adicionalmente sulfonado). Os polímeros podem ser reagidos com outros polímeros para formar misturas de polímeros. Os polímeros e as misturas de polímeros podem ser usados como membranas de condução de íons em processos de eletromembrana.
BRPI9909136A 1998-03-27 1999-03-26 processo para preparação de um polímero nitrado e sulfonado apresentando esqueletos arílicos, membrana polimérica compreendendo tal polímero e processo para a preparação de tal membrana BRPI9909136B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19813613A DE19813613A1 (de) 1998-03-27 1998-03-27 Modifiziertes Polymer und modifizierte Polymermembran
PCT/DE1999/000929 WO1999048932A2 (de) 1998-03-27 1999-03-26 Modifiziertes polymer und modifizierte polymermembran

Publications (2)

Publication Number Publication Date
BR9909136A true BR9909136A (pt) 2000-12-05
BRPI9909136B1 BRPI9909136B1 (pt) 2016-04-12

Family

ID=7862588

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI9909136A BRPI9909136B1 (pt) 1998-03-27 1999-03-26 processo para preparação de um polímero nitrado e sulfonado apresentando esqueletos arílicos, membrana polimérica compreendendo tal polímero e processo para a preparação de tal membrana

Country Status (8)

Country Link
US (1) US6509441B1 (pt)
EP (1) EP1076674B1 (pt)
JP (1) JP2002507636A (pt)
AT (1) ATE469936T1 (pt)
BR (1) BRPI9909136B1 (pt)
CA (1) CA2337818C (pt)
DE (2) DE19813613A1 (pt)
WO (1) WO1999048932A2 (pt)

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DE19919708A1 (de) * 1999-04-30 2001-03-01 Univ Stuttgart Stufenweise Alkylierung von polymeren Aminen
DE19959289A1 (de) * 1999-12-09 2001-06-13 Axiva Gmbh Verfahren zur Herstellung von sulfonierten aromatischen Polymeren und Verwendung der Verfahrensprodukte zur Herstellung von Membranen
DE10010001A1 (de) * 2000-03-02 2001-09-06 Celanese Ventures Gmbh Neue Blendpolymermembranen zum Einsatz in Brennstoffzellen
DE10010002A1 (de) 2000-03-02 2001-09-06 Celanese Ventures Gmbh Verfahren zur Nitrierung und Aminierung von Arylpolymer
NL1017412C2 (nl) * 2001-02-21 2002-08-22 Tno Werkwijze voor het tegen biologische aangroei beschermen van oppervlakken.
DE10149035A1 (de) * 2001-10-05 2003-04-24 Fraunhofer Ges Forschung Verfahren zur Sulfonierung von aromatischen Polymeren, Polyelektrolyte sowie deren Verwendung
JP2006506472A (ja) * 2002-05-13 2006-02-23 ポリフューエル・インコーポレイテッド スルホン化コポリマー
JP2006512428A (ja) * 2002-05-13 2006-04-13 ポリフューエル・インコーポレイテッド イオン伝導性ブロックコポリマー
US7354679B2 (en) * 2002-05-13 2008-04-08 Polyfuel, Inc. Ion conductive random copolymers
US6630265B1 (en) 2002-08-13 2003-10-07 Hoku Scientific, Inc. Composite electrolyte for fuel cells
WO2005020362A1 (en) * 2002-12-05 2005-03-03 Hoku Scientific, Inc. Composite polymer electrolytes for proton exchange membrane fuel cells
US20040259446A1 (en) * 2003-06-20 2004-12-23 Jain Mukesh K. Chemical protective articles of apparel and enclosures
US20050014432A1 (en) * 2003-06-20 2005-01-20 Jain Mukesh K. Waterproof and high moisture vapor permeable fabric laminate
US6962959B2 (en) 2003-08-28 2005-11-08 Hoku Scientific, Inc. Composite electrolyte with crosslinking agents
WO2007135689A2 (en) 2006-05-24 2007-11-29 Ben Gurion University Of The Negev R&D Authority Membranes, coatings and films and methods for their preparation
CN102405094A (zh) * 2009-02-19 2012-04-04 内盖夫研究与发展部本-古里安大学 耐化学性膜、涂层和膜层及它们的制备方法
US9457318B2 (en) 2010-12-12 2016-10-04 Ben-Gurion University Of The Negev Research And Development Authority Anion exchange membranes, methods of preparation and uses
CA2923657C (en) * 2013-11-01 2022-05-31 Virginia Tech Intellectual Properties, Inc. Crosslinked polymer compositions for gas separation membranes
CN108359089B (zh) * 2018-01-11 2019-12-10 大连九信精细化工有限公司 一种抗菌性聚芳醚酮材料及其制备方法
CN109821426B (zh) * 2019-01-22 2021-08-03 天津理工大学 一种含有联萘结构聚酰亚胺薄膜的制备方法及用途

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Also Published As

Publication number Publication date
WO1999048932A2 (de) 1999-09-30
CA2337818C (en) 2011-05-31
BRPI9909136B1 (pt) 2016-04-12
CA2337818A1 (en) 1999-09-30
EP1076674A2 (de) 2001-02-21
DE19813613A1 (de) 1999-09-30
JP2002507636A (ja) 2002-03-12
ATE469936T1 (de) 2010-06-15
EP1076674B1 (de) 2010-06-02
US6509441B1 (en) 2003-01-21
WO1999048932A3 (de) 1999-12-02
DE59915171D1 (de) 2010-07-15

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