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BR9907708A - Polietileno produzido pela homopolimerização de etileno ou copolimerização de etileno com alfa-olefinas na presença de um catalisador - Google Patents

Polietileno produzido pela homopolimerização de etileno ou copolimerização de etileno com alfa-olefinas na presença de um catalisador

Info

Publication number
BR9907708A
BR9907708A BR9907708-6A BR9907708A BR9907708A BR 9907708 A BR9907708 A BR 9907708A BR 9907708 A BR9907708 A BR 9907708A BR 9907708 A BR9907708 A BR 9907708A
Authority
BR
Brazil
Prior art keywords
ethylene
olefins
catalyst
homopolymerization
copolymerization
Prior art date
Application number
BR9907708-6A
Other languages
English (en)
Inventor
Arild Follestad
Vidar Almquist
Espen Ommundsen
Tore Dreng
Original Assignee
Borealis As
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Borealis As filed Critical Borealis As
Publication of BR9907708A publication Critical patent/BR9907708A/pt

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/69Chromium, molybdenum, tungsten or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/639Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/639Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63916Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/639Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/63922Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/63925Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Peptides Or Proteins (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

"POLIETILENO PRODUZIDO PELA HOMOPOLIMERIZAçãO DE ETILENO OU COPOLIMERIZAçãO DE ETILENO COM ALFA-OLEFINAS NA PRESENçA DE UM CATALISADOR". Um polietileno produzido pela homopolimerização de etileno ou copolimerização de etileno com <244>-olefinas, na presença de um catalisador, caracterizado pelo fato de que a fração de polímeros de baixo peso molecular tendo PM <5000 g/mol é menor do que 12% em peso do polímero produzido e de que o polietileno produzido tem uma resistência em fusão medida expressa por um valor de desvio (OH) satisfazendo a expressão HO > K~ 1.<sym>0,05~ + K~ 2~, em que K~ 1~ é 9,10^ -5^ e K~ 2~ é 0,4.
BR9907708-6A 1998-02-09 1999-02-09 Polietileno produzido pela homopolimerização de etileno ou copolimerização de etileno com alfa-olefinas na presença de um catalisador BR9907708A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NO980552A NO980552D0 (no) 1998-02-09 1998-02-09 Katalysatorbestandel og katalysator for (ko)polymerisering av etylen, og fremgangsmåte for fremstilling av slik
PCT/NO1999/000044 WO1999040131A1 (en) 1998-02-09 1999-02-09 Polyethylenes obtained by use of dual site catalyst

Publications (1)

Publication Number Publication Date
BR9907708A true BR9907708A (pt) 2000-11-14

Family

ID=19901654

Family Applications (2)

Application Number Title Priority Date Filing Date
BR9907702-7A BR9907702A (pt) 1998-02-09 1999-02-09 Catalisador particulado de óxido de cromo modificado para a polimeração de etileno ou etileno com alfa-olefinas, processo para a preparação do mesmo, e, polietileno
BR9907708-6A BR9907708A (pt) 1998-02-09 1999-02-09 Polietileno produzido pela homopolimerização de etileno ou copolimerização de etileno com alfa-olefinas na presença de um catalisador

Family Applications Before (1)

Application Number Title Priority Date Filing Date
BR9907702-7A BR9907702A (pt) 1998-02-09 1999-02-09 Catalisador particulado de óxido de cromo modificado para a polimeração de etileno ou etileno com alfa-olefinas, processo para a preparação do mesmo, e, polietileno

Country Status (14)

Country Link
US (2) US6541581B1 (pt)
EP (2) EP1053264A1 (pt)
JP (2) JP2002502895A (pt)
KR (1) KR20010040769A (pt)
CN (2) CN1132853C (pt)
AR (1) AR018078A1 (pt)
AT (1) ATE283866T1 (pt)
AU (2) AU738712B2 (pt)
BR (2) BR9907702A (pt)
CA (2) CA2320436C (pt)
DE (1) DE69922340T2 (pt)
ES (1) ES2234237T3 (pt)
NO (1) NO980552D0 (pt)
WO (2) WO1999040131A1 (pt)

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NO981631L (no) * 1998-04-08 1999-10-11 Borealis As Katalysator for polymerisasjon av etylen, og fremgangsmaate for fremstilling av denne
US6272384B1 (en) 1999-05-27 2001-08-07 Urologix, Inc. Microwave therapy apparatus
GB9919718D0 (en) * 1999-08-19 1999-10-20 Borealis As Process
US6433133B1 (en) 1999-11-16 2002-08-13 Eastman Chemical Company Process for reducing the weight average molecular weight and melt index ratio of polyethylenes and polyethylene products
US6388017B1 (en) * 2000-05-24 2002-05-14 Phillips Petroleum Company Process for producing a polymer composition
KR100893971B1 (ko) 2001-04-30 2009-04-20 더블유.알. 그레이스 앤드 캄파니-콘. 지지된 이중 전이금속 촉매 시스템
US6943224B2 (en) 2001-04-30 2005-09-13 W. R. Grace & Co.-Conn. Process for preparing supported transition metal catalyst systems and catalyst systems prepared thereby
AU2003292377A1 (en) * 2002-12-17 2004-07-09 Bp Chemicals Limited Supported oftien polymerization catalyst
WO2004096867A1 (en) * 2003-03-31 2004-11-11 Exxonmobil Chemical Patents Inc. Utility conduit resin
WO2004096868A1 (en) * 2003-03-31 2004-11-11 Exxonmobil Chemical Patents Inc. Resin for extruded pipe
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US20040192864A1 (en) * 2003-03-31 2004-09-30 Exxonmobil Chemical Company Utility conduit resin
DE102005019395A1 (de) * 2005-04-25 2006-10-26 Basell Polyolefine Gmbh Formmasse aus Polyethylen zur Folienherstellung und Verfahren zum Herstellen der Formmasse in Gegenwart eines Mischkatalysators
DE102005019393A1 (de) 2005-04-25 2006-10-26 Basell Polyolefine Gmbh Polyethylenformmassen für Spritzgussanwendungen
RU2444546C2 (ru) 2006-04-07 2012-03-10 ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи Полиолефиновые композиции, изделия из них и методы их получения
CA2605077C (en) * 2007-10-01 2014-07-08 Nova Chemicals Corporation A co-supported catalyst system
CA2605044C (en) * 2007-10-01 2014-12-02 Nova Chemicals Corporation Polymerization process using a mixed catalyst system
AU2010218444A1 (en) * 2009-02-27 2011-09-08 Chevron Phillips Chemical Company Lp Polyethylene film having improved barrier properties and methods of making same
US7951881B2 (en) 2009-02-27 2011-05-31 Chevron Phillips Chemical Company Lp Polyethylene film having improved barrier properties and methods of making same
US8852748B2 (en) 2009-02-27 2014-10-07 Chevron Phillips Chemical Company Lp Polyethylene film having improved barrier properties and methods of making same
CA2713042C (en) 2010-08-11 2017-10-24 Nova Chemicals Corporation Method of controlling polymer architecture
US8148470B1 (en) 2010-11-19 2012-04-03 Exxonmobil Chemical Patents Inc. Processes for making multimodal molecular weight distribution polyolefins
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US8653208B2 (en) * 2012-05-18 2014-02-18 Union Carbide Chemicals & Plastics Technology Llc Process for preparing catalysts and catalysts made thereby
CA2783494C (en) 2012-07-23 2019-07-30 Nova Chemicals Corporation Adjusting polymer composition
CN104877051B (zh) * 2015-05-06 2018-04-13 无锡耀汇科技有限公司 一种聚烯烃催化剂
CN104877052B (zh) * 2015-05-06 2018-04-13 无锡耀汇科技有限公司 一种聚乙烯树脂
SG11201808889RA (en) 2016-04-20 2018-11-29 Univation Tech Llc Polymer flow index modifier
CN110167975A (zh) 2017-01-11 2019-08-23 Sabic环球技术有限责任公司 用于乙烯聚合的氧化铬催化剂
WO2018130539A1 (en) * 2017-01-11 2018-07-19 Sabic Global Technologies B.V. Chromium oxide catalyst for ethylene polymerization
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Also Published As

Publication number Publication date
CN1132853C (zh) 2003-12-31
ATE283866T1 (de) 2004-12-15
AU2443099A (en) 1999-08-23
US6780809B1 (en) 2004-08-24
AR018078A1 (es) 2001-10-31
US6541581B1 (en) 2003-04-01
WO1999040131A1 (en) 1999-08-12
JP2002502897A (ja) 2002-01-29
CA2320436A1 (en) 1999-08-12
BR9907702A (pt) 2000-11-14
WO1999040126A1 (en) 1999-08-12
CN1136241C (zh) 2004-01-28
ES2234237T3 (es) 2005-06-16
AU2443199A (en) 1999-08-23
EP1045866A1 (en) 2000-10-25
CA2320436C (en) 2007-08-14
AU738712B2 (en) 2001-09-27
AU740974B2 (en) 2001-11-15
JP2002502895A (ja) 2002-01-29
CA2320271A1 (en) 1999-08-12
EP1053264A1 (en) 2000-11-22
CA2320271C (en) 2007-07-17
KR20010040769A (ko) 2001-05-15
CN1290272A (zh) 2001-04-04
EP1045866B1 (en) 2004-12-01
NO980552D0 (no) 1998-02-09
DE69922340D1 (de) 2005-01-05
CN1290274A (zh) 2001-04-04
DE69922340T2 (de) 2005-11-10
WO1999040126A9 (en) 1999-10-21

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