BR112021006019A2 - fungicidal mixtures, pesticidal composition, use of the mixture and method for controlling phytopathogenic pests - Google Patents

Abstract

FUNGICIDAL MIXTURES, COMPOSITION PESTICIDE, USE OF THE MIXTURE AND METHOD TO CONTROL PESTS PHYTOPATOGENIC. The present invention relates to fungicidal mixtures comprising, as active components: (1) fenpropimorph as compound I, and (2) a fungicidal compound II, wherein compound II is a succinate inhibitor dehydrogenase and is selected from the group consisting of: 2-(difluoromethyl)-N-(1,1-dimethyl-3-propyl-indan-4-yl)pyridine-3-carboxamide, 2-(difluoromethyl)-N-[(3R)-1,1-dimethyl-3-propyl-indan-4-yl]pyridine-3-carboxamide, 2-(difluoromethyl)-N-(1,1,3-trimethylindan-4-yl)pyridine-3-carboxamide, 2-(difluoromethyl)-N-[(3R)-1,1,3-trimethylindan-4-yl]pyridine-3-carboxamide, 2-(difluoromethyl)-N-(3-ethyl-1,1-dimethyl-indan-4-yl)pyridine-3-carboxamide, 2-(difluoromethyl)-N-[(3R)-3-ethyl-1,1-dimethyl-indan-4-yl]pyridine-3-carboxamide, 2-(difluoromethyl)-N-(3-isobutyl-1,1-dimethyl-indan-4-yl)pyridine-3-carboxamide, 2-(difluoromethyl)-N-[(3R)-3-isobutyl-1,1-dimethyl-indan-4-yl]pyridine-3-carboxamide, inpirfluxam, bixafem, pidiflumetofem, benzovindiflupyr, fluxapyroxad, fluindapyr, isoflucipram, sedaxane, and (3) a fungicidal compound III, in that compound III is selected from the group consisting of: N'-(2,5-dimethyl-4-phenoxy-phenyl)-N-ethyl-N-methyl-formamidine, N'-[5-bromo-2-methyl-6-(1-methyl-2-propoxy-ethoxy)-3-pyridyl]-N-ethyl-N-methyl-formamidine, N'-[4-[[3-[(4-chlorophenyl)methyl]-1,2,4-thiadiazol-5-yl]oxy]-2,5-dimethyl-phenyl]-N-ethyl-N-methyl -formamidine, copper oxychloride, fluazinam, methiram, dithianone, propineb, chlorothalonil, mancozeb, florylpicoxamide.

Description

“FUNGICIDAL MIXTURES, PESTICIDE COMPOSITION, USE OF MIXTURE AND METHOD TO CONTROL PHYTOPATOGENIC PESTS” DESCRIPTION

[001] The present invention relates to fungicidal mixtures comprising, as active components: (1) phenpropimorph as compound I, and (2) a fungicidal compound II, wherein compound II is a succinate dehydrogenase inhibitor and is selected from the group consisting of: 2-(difluoromethyl)-N-(1,1-dimethyl-3-propyl-indan-4-yl)pyridine-3-carboxamide, 2-(difluoromethyl)-N-[(3R )-1,1-dimethyl-3-propyl-indan-4-yl]pyridine-3-carboxamide, 2-(difluoromethyl)-N-(1,1,3-trimethylindan-4-yl)pyridine-3-carboxamide , 2-(difluoromethyl)-N-[(3R)-1,1,3-trimethylindan-4-yl]pyridine-3-carboxamide, 2-(difluoromethyl)-N-(3-ethyl-1,1-dimethyl -indan-4-yl)pyridine-3-carboxamide, 2-(difluoromethyl)-N-[(3R)-3-ethyl-1,1-dimethyl-indan-4-yl]pyridine-3-carboxamide, 2- (difluoromethyl)-N-(3-isobutyl-1,1-dimethyl-indan-4-yl)pyridine-3-carboxamide, 2-(difluoromethyl)-N-[(3R)-3-isobutyl-1,1- dimethyl-indan-4-yl]pyridine-3-carboxamide, inpirfluxam, bixafem, pidiflumetophem, benzovindiflupyr, fluxapyroxad, fluindapyr, isoflucy pram, sedaxane, and (3) a fungicidal compound III, wherein compound III is selected from the group consisting of: N'-(2,5-dimethyl-4-phenoxy-phenyl)-N-ethyl-N -methyl-formamidine, N'-[5-bromo-2-methyl-6-(1-methyl-2-propoxy-ethoxy)-3-

pyridyl]-N-ethyl-N-methyl-formamidine, N'-[4-[[3-[(4-chlorophenyl)methyl]-1,2,4-thiadiazol-5-yl]oxy]-2,5 -dimethyl-phenyl]-N-ethyl-N-methyl-formamidine, copper oxychloride, fluazinam, methyram, dithianone, propineb, chlorothalonil, mancozeb, florylpicoxamide.

[002] Furthermore, the invention relates to a use of the mixture for controlling harmful phytopathogenic fungi and a method for controlling phytopathogenic pests, wherein the pest, its habitat, breeding grounds (breeding areas) and the location or plants to be are protected from pest attack, the soil or plant propagation material is treated with an effective amount of the mixture.

[003] The expression “plant propagation material” should be understood as all generative parts of the plant, such as seeds and vegetative material, such as cuttings and tubers (e.g. potato), which can be used for the multiplication of the plant. This includes seeds, roots, fruits, tubers, bulbs, rhizomes, shoots, shoots and other plant parts, including seedlings or seedlings and young plants, which are being transplanted after germination, or after emergence from the ground.

These young plants can also be protected before transplanting by total or partial treatment by immersion or pouring. In a particularly preferred example embodiment, the term propagation material denotes seeds.

[004] Compounds I, II and III, as well as their pesticidal actions and methods for their production are generally known (cf.: http://www.alanwood.net/pesticides/); these substances are commercially available. 2-(difluoromethyl)-N-(1,1,3-trimethylindan-4-yl)pyridine-3-carboxamide, 2-(difluoromethyl)-N-[(3R)-1,1,3-trimethylindan-4- yl]pyridine-3-carboxamide, 2-(difluoromethyl)-N-(3-ethyl-1,1-dimethyl-indan-4-yl)pyridine-3-carboxamide, 2-(difluoromethyl)-N-[(3R )-3-ethyl-1,1-dimethyl-indan-4-yl]pyridine-3-carboxamide, 2-

(difluoromethyl)-N-(1,1-dimethyl-3-propyl-indan-4-yl)pyridine-3-carboxamide, 2-(difluoromethyl)-N-[(3R)-1,1-dimethyl-3- propyl-indan-4-yl]pyridine-3-carboxamide, 2-(difluoromethyl)-N-(3-isobutyl-1,1-dimethyl-indan-4-yl)pyridine-3-carboxamide and 2-(difluoromethyl) -N-[(3R)-3-isobutyl-1,1-dimethyl-indan-4-yl]pyridine-3-carboxamide are known from WO 2015/197530.

[005] N'-[5-bromo-2-methyl-6-(1-methyl-2-propoxy-ethoxy)-3-pyridyl]-N-ethyl-N-methyl-formamidine is known from WO2012146125 , WO2017063973 (Syn.: Formamidine: LS 6097809). N'-(2,5-dimethyl-4-phenoxy-phenyl)-N-ethyl-N-methyl-formamidine and N'-[4-[[3-[(4-chlorophenyl)methyl]-1,2, 4-Thiadiazol-5-yl]oxy]-2,5-dimethyl-phenyl]-N-ethyl-N-methyl-formamidine are known from WO2014037314, WO2014037315, WO201512131, EP2865265.

[006] Phenpropimorph ternary mixtures are known from EP-3162208, WO 2018/162999 and IPCOM000244894D.

[007] A typical problem that arises in the field of pest control lies in the need to reduce dosage rates of the active ingredient in order to reduce or avoid unfavorable environmental or toxicological effects, while still allowing effective pest control.

[008] With respect to the present invention, the term pest encompasses animal pests and harmful fungi.

[009] Another problem encountered concerns the need to have pest control agents available that are effective against a broad spectrum of harmful animal pests and harmful fungi.

[010] There is also a need for pest control agents that combine immediate action (knock-down) activity with prolonged control, that is, fast action with long-lasting action.

[011] Another difficulty with the use of pesticides is that the repeated and exclusive application of an individual pesticidal compound leads, in many cases, to rapid selection of pests, which means that harmful animal pests and fungi have developed naturally or adapted by acquiring resistance against the active compound in question. There is, therefore, a need for pest control agents that help to prevent pests or prevent them from acquiring resistance.

[012] Controlling fungal diseases especially in soybeans is a challenge and currently more than one active ingredient is needed to obtain sufficient activity. It is expected that in the future all products will consist of at least three active ingredients (ternary mixtures).

[013] Phenpropimorph has been known for many years. However, the compound has only recently been introduced into the soybean fungicide market. It was surprisingly found that novel ternary mixtures of phenpropimorph with other selected compounds are synergistically highly active. Because of this and the limited number of highly active compounds, phenpropimorph is expected to become a key partner of other active ingredients in ternary blends.

[014] Therefore, it was an object of the present invention to provide pesticide mixtures that solve the problems of dose rate reduction and/or that increase the spectrum of activity and/or combine knock-down activity with prolonged control and/or manage plant resistance and/or health promotion.

[015] We conclude that this objective is achieved, in part or in full, by the fungicidal mixtures as defined above.

[016] It has especially been found that the mixtures defined above show remarkably improved action against pests compared to the control rates that are possible with the individual compounds and/or are suitable for improving plant health when applied to plants, parts of plants, seeds, or the place where they grow. Especially high activity was shown in soybeans.

[017] It was found that the action of the mixtures of the invention, comprising compound I, compound II and compound III, goes far beyond the fungicidal action and/or plant health improvement of the active compounds present in the mixture when used alone ( synergistic action).

[018] In addition, we found that the simultaneous application, whether jointly or separately, of compound I, compound II and compound III; or the successive application of compound I, compound II and compound III, allows better control of harmful fungi, compared to the control rates that are possible with individual compounds (synergistic mixtures).

[019] In addition, we have found that the simultaneous application, either jointly or separately, of compound I, compound II and compound III, or the successive application of compound I, compound II and compound III, provides improved effects for the health of plants in compared to the effects on plant health that are possible with the compounds when applied individually.

[020] The weight ratio of compound I and compound II in ternary mixtures is from 500:1 to 1:500, preferably from 100:1 to 1:100 more preferably from 50:1 to 1:50, most preferably from 20:1 to 1:20, also including ratios of 10:1 to 1:10, 1:5 to 5:1, or 1:1. The weight ratio of compound I and compound III in ternary mixtures is from 500:1 to 1:500, preferably from 100:1 to 1:100 more preferably from 50:1 to 1:50, most preferably from 20: 1 to 1:20, also including ratios of 10:1 to 1:10, 1:5 to 5:1, or 1:1.

[021] All blends referred to above are also referred to below as “blends of the invention”.

[022] The present invention relates to synergistic three-way mixtures presented in the Table below, which comprise three components, as appropriate:

Mixture Compound I Compound II Compound III Culture 1 fenpropimorph inpirfluxam oxychloride copper soya 2 fenpropimorph inpirfluxam fluazinam soybeans 3 fenpropimorph inpirfluxam metiram soybean 4 fenpropimorph inpirfluxam dithianon soybeans 5 fenpropimorph inpirfluxam propineb soybean 6 fenpropimorph bixafem oxychloride copper soybean 7 fenpropimorph bixafem fluazinam soybean 8 fenpropimorph bixafem metiram soy 9 fenpropimorph bixafem dithianon soybean 10 fenpropimorph bixafem propineb soybean 11 fenpropimorph pidiflumetofem oxychloride copper soybean 12 fenpropimorph pidiflumetofem fluazinam soybean 13 fenpropimorph pidiflumetofem metiram soybean 14 fenpropimorph pidiflumetofem dithianon soybean 15 fenpropimorph pidiflumetofem propineb soybean 16 fenpropimorph benzovindiflupir oxychloride copper soybean 17 fenpropimorph benzovindiflupir fluazinam soy 18 phenpropimorph benzovindyflupyr methyram soy 19 phenpropimorph benzovindyflupyr dithianone soy 20 phenpropimorph benzovindiflupyr propineb soy 21 phenpropimorph fluxapyr oxade oxychloride copper soybean 22 fenpropimorph fluxapyroxad fluazinam soybean 23 fenpropimorph fluxapyroxad metiram soybean 24 fenpropimorph fluxapyroxad dithianon soybean 25 fenpropimorph fluxapyroxad propineb soybean 26 fenpropimorph fluindapir chlorothalonil soybean 27 fenpropimorph fluindapir mancozeb Soybean 28 fenpropimorph fluindapir oxychloride copper soybean 29 fenpropimorph fluindapir fluazinam Soybean 30 fenpropimorph fluindapir metiram soybean 31 fenpropimorph fluindapir dithianon soybean 32 fenpropimorph fluindapir propineb soybean 33 fenpropimorph isoflucipram chlorothalonil soybean 34 fenpropimorph isoflucipram mancozeb soybean 35 fenpropimorph isoflucipram soybean copper oxychloride 36 fenpropimorph isoflucipram soybean fluazinam 37 fenpropimorph isoflucipram metiram soybean 38 fenpropimorph isoflucipram dithianon soybean 39 fenpropimorph isoflucipram propineb soybean 40 fenpropimorph sedaxane chlorothalonil soy

Mixture Compound I Compound II Compound III Culture 41 fenpropimorph sedaxane mancozeb soy 42 fenpropimorph sedaxane copper oxychloride soy 43 fenpropimorph sedaxane fluazinam soy 44 phenpropimorph sedaxane methram soy 45 phenpropimorph sedaxane dithianone soy 46 phenpropimorph sedaxane propineb soy 47 phenpropimorph sedaxane propineb soy 47 phenpropimorph sedaxane soy 47 phenpropimorph 2-difluoromethyl) (1,1,3-chlorothalonyl soya trimethylindan-4-yl)pyridine-3-carboxamide 48 fenpropimorph 2-(difluoromethyl)–N-(1,1,3-mancozeb soya trimethylindan-4-yl)pyridine-3-carboxamide 49 phenpropimorph 2-(difluoromethyl)-N-(1,1,3-copper oxychloride soy trimethylindan-4-yl)pyridine-3-carboxamide 50 fenpropimorph 2-(difluoromethyl)-N-(1,1,3-fluazinam trimethylindan-4-yl)pyridine-3-carboxamide 51 fenpropimorph 2-(difluoromethyl)-N–(1,1,3-methyram trimethylindan-4-yl)pyridine-3-carboxamide 52 fenpropimorph 2-(difluoromethyl)- N-(1,1,3-dithianone soy trimethylindan-4-yl)pyridine-3-carboxamide 53 fenpropimorph 2-(difluoromethyl)-N-(1,1,3-propineb soy trime tilindan-4-yl)pyridine-3-carboxamide 54 fenpropimorph 2-(difluoromethyl)-N-[(3R)-chlorothalonyl soy 1,1,3-trimethylindan-4-yl]pyridine-3-carboxamide 55 fenpropimorph 2-( difluoromethyl)-N-[(3R)-mancozeb soy 1,1,3-trimethylindan-4-yl]pyridine-3-carboxamide 56 fenpropimorph 2-(difluoromethyl)-N-[(3R)-copper oxychloride soy 1, 1,3-trimethylindan-4-yl]pyridine-3-carboxamide 57 fenpropimorph 2-(difluoromethyl)-N-[(3R)-fluazinam soy 1,1,3-trimethylindan-4-yl]pyridine-3-carboxamide 58 fenpropimorph 2-(difluoromethyl)-N-[(3R)-methylram soy 1,1,3-trimethylindan-4-yl]pyridine-3-carboxamide 59 fenpropimorph 2-(difluoromethyl)-N-[(3R)-dithianone soy 1,1,3-trimethylindan-4-yl]pyridine-3-carboxamide 60 fenpropimorph 2-(difluoromethyl)-N-[(3R)-propineb soy 1,1,3-trimethylindan-4-yl]pyridine-3- carboxamide

Mixture Compound I Compound II Compound III Culture 61 fenpropimorph 2-(difluoromethyl)-N-(3-ethyl-1,1-chlorothalonyl soy dimethyl-indan-4-yl)pyridine-3-carboxamide 62 fenpropimorph 2-(difluoromethyl)- N-(3-ethyl-1,1-mancozeb soy dimethyl-indan-4-yl)pyridine-3-carboxamide 63 fenpropimorph 2-(difluoromethyl)-N-(3-ethyl-1,1-copper oxychloride soy dimethyl -indan-4-yl)pyridine-3-carboxamide 64 fenpropimorph 2-(difluoromethyl)-N-(3-ethyl-1,1-fluazinam soy dimethyl-indan-4-yl)pyridine-3-carboxamide 65 fenpropimorph 2- (difluoromethyl)-N-(3-ethyl-1,1-methyram soy dimethyl-indan-4-yl)pyridine-3-carboxamide 66 fenpropimorph 2-(difluoromethyl)-N-(3-ethyl-1,1-dithianone soy dimethyl-indan-4-yl)pyridine-3-carboxamide 67 fenpropimorph 2-(difluoromethyl)-N-(3-ethyl-1,1-propineb soy dimethyl-indan-4-yl)pyridine-3-carboxamide 68 fenpropimorph 2-(difluoromethyl)-N-[(3R)-3-chlorothalonyl soy ethyl-1,1-dimethyl-indan-4-yl]pyridine-3-carboxamide 69 fenpropimorph 2-(difluoromethyl)-N-[(3R) -3- mancozeb soy ethyl -1,1-dimethyl-indan-4-yl]pyridine-3-carboxamide 70 fenpropimorph 2-(difluoromethyl)-N-[(3R)-3-copper oxychloride soy ethyl-1,1-dimethyl-indan-4 -yl]pyridine-3-carboxamide 71 fenpropimorph 2-(difluoromethyl)-N-[(3R)-3-fluazinam soy ethyl-1,1-dimethyl-indan-4-yl]pyridine-3-carboxamide 72 fenpropimorph 2- (difluoromethyl)-N-[(3R)-3-methyram soy ethyl-1,1-dimethyl-indan-4-yl]pyridine-3-carboxamide 73 fenpropimorph 2-(difluoromethyl)-N-[(3R)-3 - dithianone soya ethyl-1,1-dimethyl-indan-4-yl]pyridine-3-carboxamide 74 fenpropimorph 2-(difluoromethyl)-N-[(3R)-3-propineb soya ethyl-1,1-dimethyl-indan -4-yl]pyridine-3-carboxamide 75 fenpropimorph 2-(difluoromethyl)-N-(1,1-chlorothalonyl soy dimethyl-3-propyl-indan-4-yl)pyridine-3-carboxamide 76 fenpropimorph 2-(difluoromethyl )-N-(1,1-mancozeb soy dimethyl-3-propyl-indan-4-yl)pyridine-3-carboxamide

Mixture Compound I Compound II Compound III Culture 77 fenpropimorph 2-(difluoromethyl)-N-(1,1-copper oxychloride soy dimethyl-3-propyl-indan-4-yl)pyridine-3-carboxamide 78 fenpropimorph 2-(difluoromethyl )-N-(1,1-fluazinam soya dimethyl-3-propyl-indan-4-yl)pyridine-3-carboxamide 79 fenpropimorph 2-(difluoromethyl)-N-(1,1-methyram soya dimethyl-3-propyl -indan-4-yl)pyridine-3-carboxamide 80 fenpropimorph 2-(difluoromethyl)-N-(1,1-dithianone soy dimethyl-3-propyl-indan-4-yl)pyridine-3-carboxamide 81 fenpropimorph 2- (difluoromethyl)-N-(1,1-propineb soy dimethyl-3-propyl-indan-4-yl)pyridine-3-carboxamide 82 fenpropimorph 2-(difluoromethyl)-N-[(3R)-1,1-chlorothalonyl soy dimethyl-3-propyl-indan-4-yl]pyridine-3-carboxamide 83 fenpropimorph 2-(difluoromethyl)-N-[(3R)-1,1-mancozeb soy dimethyl-3-propyl-indan-4-yl ]pyridine-3-carboxamide 84 fenpropimorph 2-(difluoromethyl)-N-[(3R)-1,1-copper oxychloride soy dimethyl-3-propyl-indan-4-yl]pyridine-3-carboxamide 85 fenpropimorph 2- (difluoromethyl 1)-N-[(3R)-1,1-fluazinam soy dimethyl-3-propyl-indan-4-yl]pyridine-3-carboxamide 86 fenpropimorph 2-(difluoromethyl)-N-[(3R)-1, 1-methyram soya dimethyl-3-propyl-indan-4-yl]pyridine-3-carboxamide 87 fenpropimorph 2-(difluoromethyl)-N-[(3R)-1,1-dithianone soya dimethyl-3-propyl-indan- 4-yl]pyridine-3-carboxamide 88 fenpropimorph 2-(difluoromethyl)-N-[(3R)-1,1-propineb soy dimethyl-3-propyl-indan-4-yl]pyridine-3-carboxamide 89 fenpropimorph 2 -(difluoromethyl)-N-(3-chlorothalonyl soya isobutyl-1,1-dimethyl-indan-4-yl)pyridine-3-carboxamide 90 fenpropimorph 2-(difluoromethyl)-N-(3-mancozeb soya isobutyl-1, 1-dimethyl-indan-4-yl)pyridine-3-carboxamide 91 fenpropimorph 2-(difluoromethyl)-N-(3-copper oxychloride soy isobutyl-1,1-dimethyl-indan-4-yl)pyridine-3- carboxamide 92 fenpropimorph 2-(difluoromethyl)-N-(3-fluazinam soy isobutyl-1,1-dimethyl-indan-4-yl)pyridine-3-carboxamide

Mixture Compound I Compound II Compound III Culture 93 fenpropimorph 2-(difluoromethyl)-N-(3-methyl) soy isobutyl-1,1-dimethyl-indan-4-yl)pyridine-3-carboxamide 94 fenpropimorph 2-(difluoromethyl)- N-(3-dithianone soya isobutyl-1,1-dimethyl-indan-4-yl)pyridine-3-carboxamide 95 fenpropimorph 2-(difluoromethyl)-N-(3-propineb soya isobutyl-1,1-dimethyl-indan -4-yl)pyridine-3-carboxamide 96 fenpropimorph 2-(difluoromethyl)-N-[(3R)-3-chlorothalonyl soya isobutyl-1,1-dimethyl-indan-4-yl]pyridine-3-carboxamide 97 fenpropimorph 2-(difluoromethyl)-N-[(3R)-3-mancozeb soy isobutyl-1,1-dimethyl-indan-4-yl]pyridine-3-carboxamide 98 fenpropimorph 2-(difluoromethyl)-N-[(3R) -3- copper oxychloride soya isobutyl-1,1-dimethyl-indan-4-yl]pyridine-3-carboxamide 99 fenpropimorph 2-(difluoromethyl)-N-[(3R)-3-fluazinam soya isobutyl-1,1 -dimethyl-indan-4-yl]pyridine-3-carboxamide 100 fenpropimorph 2-(difluoromethyl)-N-[(3R)-3-methyl-soya isobutyl-1,1-dimethyl-indan-4-yl]pyridine-3 -carboxamide 101 fenpropimorph 2-(difluoromethyl)-N-[(3R)-3-dithianone soy isobutyl-1,1-dimethyl-indan-4-yl]pyridine-3-carboxamide 102 fenpropimorph 2-(difluoromethyl)-N-[(3R) -3- propineb soy isobutyl-1,1-dimethyl-indan-4-yl]pyridine-3-carboxamide 103 fenpropimorph inpirfluxam florylpicoxamide soy 104 fenpropimorph inpirfluxam N'-[5-bromo-2-methyl-6-(1-soy) methyl-2-propoxy-ethoxy)-3-pyridyl]-N-ethyl-N-methyl-formamidine 105 fenpropimorph inpirfluxam N'-(2,5-dimethyl-4-phenoxy-soyphenyl)-N-ethyl-N- methylformamidine 106 fenpropimorph inpirfluxam N'-[4-[[3-[(4-soy chlorophenyl)methyl]-1,2,4-thiadiazol-5-yl]oxy]-2,5-dimethyl-phenyl]- N-ethyl-N-methyl-formamidine 107 fenpropimorph bixaphem florylpicoxamide soy 108 fenpropimorph bixaphem N'-[5-bromo-2-methyl-6-(1-soy methyl-2-propoxy-ethoxy)-3-pyridyl]-N -ethyl-N-methyl-formamidine

Mixture Compound I Compound II Compound III Culture 109 fenpropimorph bixaphen N'-(2,5-dimethyl-4-phenoxy-soy phenyl)-N-ethyl-N-methyl-formamidine 110 fenpropimorph bixafen N'-[4-[[3 -[(4-soy chlorophenyl)methyl]-1,2,4-thiadiazol-5-yl]oxy]-2,5-dimethyl-phenyl]-N-ethyl-N-methyl-formamidine 111 fenpropimorph pidiflumetophem florylpicoxamide soy 112 fenpropimorph pidiflumetophem N'-[5-bromo-2-methyl-6-(1-soya methyl-2-propoxy-ethoxy)-3-pyridyl]-N-ethyl-N-methyl-formamidine 113 fenpropimorph pidiflumetophem N'-( 2,5-dimethyl-4-phenoxy-soyphenyl)-N-ethyl-N-methyl-formamidine 114 fenpropimorph pidiflumetophem N'-[4-[[3-[(4-soy chlorophenyl)methyl]-1,2, 4-thiadiazol-5-yl]oxy]-2,5-dimethyl-phenyl]-N-ethyl-N-methyl-formamidine 115 fenpropimorph benzovindiflupyr florylpicoxamide soy 116 fenpropimorph benzovindiflupyr N'-[5-bromo-2-methyl-6 -(1-soy methyl-2-propoxy-ethoxy)-3-pyridyl]-N-ethyl-N-methyl-formamidine 117 fenpropimorph benzovindiflupyr N'-(2,5-dimethyl-4-phenoxy-soy phenyl)-N -ethyl-N-methyl-formamidine 118 fenpropimorph benzovindiflupyr N'-[4-[[3-[(4-soy chlorophenyl)methyl]-1,2,4-thiadiazol-5-yl]oxy]-2,5-dimethyl-phenyl]-N-ethyl- N-methyl-formamidine 119 fenpropimorph fluxapyroxade florylpicoxamide soy 120 fenpropimorph fluxapyroxad N'-[5-bromo-2-methyl-6-(1-soy methyl-2-propoxy-ethoxy)-3-pyridyl]-N-ethyl-N -methyl-formamidine 121 fenpropimorph fluxapyroxade N'-(2,5-dimethyl-4-phenoxy-soy phenyl)-N-ethyl-N-methyl-formamidine 122 fenpropimorph fluxapyroxade N'-[4-[[3-[(4) - soya chlorophenyl)methyl]-1,2,4-thiadiazol-5-yl]oxy]-2,5-dimethyl-phenyl]-N-ethyl-N-methyl-formamidine 123 fenpropimorph fluindapyr florylpicoxamide soya 124 fenpropimorph fluindapyr N' -[5-bromo-2-methyl-6-(1-soy methyl-2-propoxy-ethoxy)-3-pyridyl]-N-ethyl-N-methyl-formamidine

Mixture Compound I Compound II Compound III Culture 125 fenpropimorph fluindapyr N'-(2,5-dimethyl-4-phenoxy-soy phenyl)-N-ethyl-N-methyl-formamidine 126 fenpropimorph fluindapyr N'-[4-[[3] -[(4-soy chlorophenyl)methyl]-1,2,4-thiadiazol-5-yl]oxy]-2,5-dimethyl-phenyl]-N-ethyl-N-methyl-formamidine 127 fenpropimorph isoflucipram florylpicoxamide soy 128 fenpropimorph isoflucipram N'-[5-bromo-2-methyl-6-(1-soy methyl-2-propoxy-ethoxy)-3-pyridyl]-N-ethyl-N-methyl-formamidine 129 fenpropimorph isoflucipram N'-( 2,5-dimethyl-4-phenoxy-soyphenyl)-N-ethyl-N-methyl-formamidine 130 fenpropimorph isoflucipram N'-[4-[[3-[(4-soy chlorophenyl)methyl]-1,2, 4-thiadiazol-5-yl]oxy]-2,5-dimethyl-phenyl]-N-ethyl-N-methyl-formamidine 131 fenpropimorph sedaxane florylpicoxamide soy 132 fenpropimorph sedaxane N'-[5-bromo-2-methyl-6 -(1-soy methyl-2-propoxy-ethoxy)-3-pyridyl]-N-ethyl-N-methyl-formamidine 133 fenpropimorph sedaxane N'-(2,5-dimethyl-4-phenoxy-soy phenyl)-N -ethyl-N-methyl-formamidine 134 fenpropimorph sedaxane N' -[4-[[3-[(4-soy chlorophenyl)methyl]-1,2,4-thiadiazol-5-yl]oxy]-2,5-dimethyl-phenyl]-N-ethyl-N-methyl- Formamidine 135 fenpropimorph 2-(difluoromethyl)-N-(1,1,3-florylpicoxamide soy trimethylindan-4-yl)pyridine-3-carboxamide 136 fenpropimorph 2-(difluoromethyl)-N-(1,1,3-N' -[5-bromo-2-methyl-6-(1-soy trimethylindan-4-yl)pyridin-3-methyl-2-propoxy-ethoxy)-3-carboxamide pyridyl]-N-ethyl-N-methyl-formamidine 137 phenpropimorph 2-(difluoromethyl)-N-(1,1,3-N'-(2,5-dimethyl-4-phenoxy-soy trimethylindan-4-yl)pyridin-3-phenyl)-N-ethyl-N -methyl-carboxamide formamidine 138 fenpropimorph 2-(difluoromethyl)-N-(1,1,3-N'-[4-[[3-[(4-soy trimethylindan-4-yl)pyridine-3-chlorophenyl)methyl ]-1,2,4-carboxamide thiadiazol-5-yl]oxy]-2,5-dimethyl-phenyl]-N-ethyl-N-methyl-formamidine 139 fenpropimorph 2-(difluoromethyl)-N-[(3R) - florylpicoxamide soy 1,1,3-trimethylindan-4-yl]pyridine-3-carboxamide

Mixture Compound I Compound II Compound III Culture 140 fenpropimorph 2-(difluoromethyl)-N-[(3R)-N'-[5-bromo-2-methyl-6-(1-soy 1,1,3-trimethylindan-4 - methyl-2-propoxy-ethoxy)-3-yl]pyridine-3-carboxamide pyridyl]-N-ethyl-N-methyl-formamidine 141 fenpropimorph 2-(difluoromethyl)-N-[(3R)-N'-( 2,5-dimethyl-4-phenoxy-soybean 1,1,3-trimethylindan-4-phenyl)-N-ethyl-N-methyl-yl]pyridine-3-carboxamide formamidine 142 fenpropimorph 2-(difluoromethyl)-N- [(3R)-N'-[4-[[3-[(4-soy 1,1,3-trimethylindan-4-chlorophenyl)methyl]-1,2,4-yl]pyridine-3-carboxamide thiadiazol- 5-yl]oxy]-2,5-dimethyl-phenyl]-N-ethyl-N-methyl-formamidine 143 fenpropimorph 2-(difluoromethyl)-N-(3-ethyl-1,1-florylpicoxamide soy dimethyl-indan- 4-yl)pyridine-3-carboxamide 144 fenpropimorph 2-(difluoromethyl)-N-(3-ethyl-1,1-N'-[5-bromo-2-methyl-6-(1-soy dimethyl-indan- 4-yl)pyridin-3-methyl-2-propoxy-ethoxy)-3-carboxamide pyridyl]-N-ethyl-N-methyl-formamidine 145 fenpropimorph 2-(difluoromethyl)-N-(3-ethyl-1,1 - N'-(2,5-dimethyl-4-phenoxy-soy dimethyl -indan-4-yl)pyridin-3-phenyl)-N-ethyl-N-methyl-carboxamide formamidine 146 fenpropimorph 2-(difluoromethyl)-N-(3-ethyl-1,1-N'-[4-[ [3-[(4-soy dimethyl-indan-4-yl)pyridin-3-chlorophenyl)methyl]-1,2,4-carboxamide thiadiazol-5-yl]oxy]-2,5-dimethyl-phenyl]- N-ethyl-N-methyl-formamidine 147 fenpropimorph 2-(difluoromethyl)-N-[(3R)-3-florylpicoxamide soya ethyl-1,1-dimethyl-indan-4-yl]pyridine-3-carboxamide 148 fenpropimorph 2 -(difluoromethyl)-N-[(3R)-3-N'-[5-bromo-2-methyl-6-(1-soy ethyl-1,1-dimethyl-indan-4-methyl-2-propoxy- ethoxy)-3-yl]pyridine-3-carboxamide pyridyl]-N-ethyl-N-methyl-formamidine 149 fenpropimorph 2-(difluoromethyl)-N-[(3R)-3-N'-(2,5-dimethyl -4-phenoxy-soy ethyl-1,1-dimethyl-indan-4-phenyl)-N-ethyl-N-methyl-yl]pyridine-3-carboxamide formamidine 150 fenpropimorph 2-(difluoromethyl)-N-[(3R )-3-N'-[4-[[3-[(4-soy ethyl-1,1-dimethyl-indan-4-chlorophenyl)methyl]-1,2,4-yl]pyridine-3-carboxamide thiadiazole -5-yl]oxy]-2,5-dimethyl-phenyl]-N-ethyl-N-methyl-formamidine 151 fenpropimorph 2-(difluorome til)-N-(1,1-florylpicoxamide soy dimethyl-3-propyl-indan-4-yl)pyridine-3-carboxamide 152 fenpropimorph 2-(difluoromethyl)-N-(1,1-N'-[5- bromo-2-methyl-6-(1-soy dimethyl-3-propyl-indan-4-methyl-2-propoxy-ethoxy)-3-yl)pyridine-3-carboxamide pyridyl]-N-ethyl-N-methyl - Formamidine 153 fenpropimorph 2-(difluoromethyl)-N-(1,1-N'-(2,5-dimethyl-4-phenoxy-soy dimethyl-3-propyl-indan-4-phenyl)-N-ethyl-N -methyl-yl)pyridine-3-carboxamide formamidine

Mixture Compound I Compound II Compound III Culture 154 fenpropimorph 2-(difluoromethyl)-N-(1,1-N'-[4-[[3-[(4-soy dimethyl-3-propyl-indan-4-chlorophenyl)) methyl]-1,2,4-yl)pyridine-3-carboxamide thiadiazol-5-yl]oxy]-2,5-dimethyl-phenyl]-N-ethyl-N-methyl-formamidine 155 fenpropimorph 2-(difluoromethyl) -N-[(3R)-1,1-florylpicoxamide soy dimethyl-3-propyl-indan-4-yl]pyridine-3-carboxamide 156 fenpropimorph 2-(difluoromethyl)-N-[(3R)-1,1- N'-[5-bromo-2-methyl-6-(1-soy dimethyl-3-propyl-indan-4-methyl-2-propoxy-ethoxy)-3-yl]pyridine-3-carboxamide pyridyl]-N -ethyl-N-methyl-formamidine 157 fenpropimorph 2-(difluoromethyl)-N-[(3R)-1,1-N'-(2,5-dimethyl-4-phenoxy-soy dimethyl-3-propyl-indan- 4-phenyl)-N-ethyl-N-methyl-yl]pyridine-3-carboxamide formamidine 158 fenpropimorph 2-(difluoromethyl)-N-[(3R)-1,1-N'-[4-[[3- [(4-soy dimethyl-3-propyl-indan-4-chlorophenyl)methyl]-1,2,4-yl]pyridine-3-carboxamide thiadiazol-5-yl]oxy]-2,5-dimethyl-phenyl] -N-ethyl-N-methyl-formamidine 159 fenpropimorph 2-(difluoromethyl)-N-(3 - florylpicoxamide soy isobutyl-1,1-dimethyl-indan-4-yl)pyridine-3-carboxamide 160 fenpropimorph 2-(difluoromethyl)-N-(3-N'-[5-bromo-2-methyl-6-( 1-soy isobutyl-1,1-dimethyl-indan-4-methyl-2-propoxy-ethoxy)-3-yl)pyridine-3-carboxamide pyridyl]-N-ethyl-N-methyl-formamidine 161 fenpropimorph 2-( difluoromethyl)-N-(3-N'-(2,5-dimethyl-4-phenoxy-soy isobutyl-1,1-dimethyl-indan-4-phenyl)-N-ethyl-N-methyl-yl)pyridine- 3-carboxamide formamidine 162 fenpropimorph 2-(difluoromethyl)-N-(3-N'-[4-[[3-[(4-soy isobutyl-1,1-dimethyl-indan-4-chlorophenyl)methyl]-1 ,2,4-yl)pyridine-3-carboxamide thiadiazol-5-yl]oxy]-2,5-dimethyl-phenyl]-N-ethyl-N-methyl-formamidine 163 fenpropimorph 2-(difluoromethyl)-N-[ (3R)-3-florylpicoxamide soy isobutyl-1,1-dimethyl-indan-4-yl]pyridine-3-carboxamide 164 fenpropimorph 2-(difluoromethyl)-N-[(3R)-3-N'-[5- bromo-2-methyl-6-(1-soy isobutyl-1,1-dimethyl-indan-4-methyl-2-propoxy-ethoxy)-3-yl]pyridine-3-carboxamide pyridyl]-N-ethyl-N -methyl-formamidine 165 fenpropimorph 2-(difluorome ethyl)-N-[(3R)-3-N'-(2,5-dimethyl-4-phenoxy-soy isobutyl-1,1-dimethyl-indan-4-phenyl)-N-ethyl-N-methyl- yl]pyridine-3-carboxamide formamidine 166 fenpropimorph 2-(difluoromethyl)-N-[(3R)-3-N'-[4-[[3-[(4-soy isobutyl-1,1-dimethyl-indan- 4-chlorophenyl)methyl]-1,2,4-yl]pyridine-3-carboxamide thiadiazol-5-yl]oxy]-2,5-dimethyl-phenyl]-N-ethyl-N-methyl-formamidine

[023] The mixtures of the invention can be converted into customary/common types of agrochemical compositions, for example, solutions, suspensions, dusts, powders, pastes, granules, capsules, tablets, and mixtures thereof. Examples for types of composition are suspensions (eg SC, OD, FS), emulsifiable concentrates (eg EC), emulsions (eg EW, EO, ES, ME), capsules (eg CS, ZC) , pastes, tablets, wettable powder or dust (e.g. WP, SP, WS, DP, DS), pressed (e.g. BR, TB, DT), granules (e.g. WG, SG, GR, FG, GG , MG), insecticidal articles (eg LN) as well as gel formulations for the treatment of plant propagation materials such as seeds (eg GF). These and other types of compositions are defined in the “Catalogue of pesticide formulation types and international coding system”, Technical Monograph No. 2, 6th Ed.; May 2008, CropLife International.

[024] The compositions are prepared in a known manner, as described by Mollet and Grubemann, Formulation technology, Wiley VCH, Weinheim, 2001; or Knowles, New developments in crop protection product formulation, Agrow Reports DS243, T&F Informa, London, 2005.

[025] Suitable auxiliaries are solvents, liquid vehicles, solid vehicles or fillers, surfactants, dispersants, emulsifiers, wetting agents, adjuvants, solubilizers, penetration enhancers, protective colloids, adhesion agents, thickeners, wetting agents, repellents, baits/attractors (attractants), food stimulants, compatibilizers, bactericides, anti-freezing agents, anti-foaming agents, dyes, tackifiers and binders/binders.

[026] Suitable solvents and liquid vehicles are water and organic solvents, such as mineral oil fractions of medium to high boiling point, eg kerosene, diesel oil; oils of vegetable or animal origin; aliphatic, cyclic and aromatic hydrocarbons, e.g. toluene,

paraffin, tetrahydronaphthalene, alkylated naphthalenes; alcohols, for example ethanol, propanol, butanol, benzyl alcohol, cyclohexanol; glycols; DMSO; ketones, for example cyclohexanone; esters, e.g. esters of lactates, carbonates, fatty acids, gamma-butyrolactone; fatty acids; phosphonates; amines; amides, for example N-methylpyrrolidone, fatty acid dimethylamides; and mixtures thereof.

[027] Suitable solid fillers or carriers are earth minerals, for example silicates, silica gels, talc, kaolin, limestone, lime, chalk, clays, dolomite, earth diatoms, bentonite, calcium sulfate, magnesium sulfate, oxide of magnesium; polysaccharides, for example cellulose, starch; fertilizers, eg ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas; products of plant origin, for example, cereal flour, tree bark, wood flour, nutshell flour, and mixtures thereof.

[028] Suitable surfactants are composed of surfactants such as anionic, cationic, nonionic and amphoteric surfactants, block polymers, polyelectrolytes, and mixtures thereof. Such surface-active agents can be used as an emulsifier, dispersant, solubilizer, wetting agent, penetration enhancer, protective colloid or adjuvant. Examples of surfactants are listed in McCutcheon, Vol.1: Emulsifiers & Detergents, McCutcheon's Directories, Glen Rock, USA, 2008 (International Edition or North American Edition).

[029] Suitable anionic surfactants are alkaline, alkaline-earth or ammonium salts of sulfonates, sulfates, phosphates, carboxylates, and mixtures thereof. Examples of sulfonates are alkylarylsulfonates, diphenylsulfonates, alpha-olefin sulfonates, lignin sulfonates, fatty acid and oil sulfonates, ethoxylated alkylphenol sulfonates, alkoxylated arylphenol sulfonates, condensed naphthalene sulfonates, dodecyl- and tridecylbenzene sulfonates, sulfonates of naphthalenes and alkylnaphthalenes, sulfosuccinates or sulfosuccinamates. Examples of sulfates are sulfates of fatty acids and oils, of ethoxylated alkylphenols, of alcohols, of ethoxylated alcohols, or of esters of fatty acids. Examples of phosphates are phosphate esters. Examples of carboxylates are alkyl carboxylates, carboxylated alcohol or alkylphenol ethoxylates.

[030] Suitable nonionic surfactants are alkoxylated, N-substituted fatty acid amides, amine oxides, esters, sugar-based surfactants, polymeric surfactants and mixtures thereof.

Examples of alkoxylates are compounds such as alcohols, alkylphenols, amines, amides, arylphenols, fatty acids or fatty acid esters that have been alkoxylated with 1 to 50 equivalents. Ethylene oxide and/or propylene oxide may be used for the alkoxylation, preferably ethylene oxide. Examples of N-substituted fatty acid amides are fatty acid glucamides or fatty acid alkanolamides. Examples of esters are fatty acid esters, glycerol esters or monoglycerides. Examples of sugar-based surfactants are sorbitans, ethoxylated sorbitans, esters of sucrose and glucose or alkylpolyglycosides. Examples of polymeric surfactants are homo- or copolymers of vinylpyrrolidone, vinyl alcohols, or vinyl acetate.

[031] Suitable cationic surfactants are quaternary surfactants, for example quaternary ammonium compounds with one or two hydrophobic groups, or salts of long-chain primary amines.

Suitable amphoteric surfactants are alkylbetaines and imidazolines. Suitable block polymers are block polymers of type A-B or A-B-A, comprising blocks of polyethylene oxide and polypropylene oxide, or of type A-B-C comprising alkanol, polyethylene oxide and polypropylene oxide. Suitable polyelectrolytes are polyacids or polybases.

Examples of polyacids are alkaline salts of polyacrylic acid or comb polymers of polyacids. Examples of polybases or polyvinylamines are polyethyleneamines.

[032] Suitable adjuvants are compounds that have a negligible or even absent pesticidal activity of their own, and that improve the biological performance of the mixtures of the invention on the target.

Examples are surfactants, mineral or vegetable oils, and other auxiliaries. Additional examples are listed in Knowles, Adjuvants and additives, Agrow Adjuvants and additives, Agrow Reports DS256, T&F Informa - UK, 2006, chapter 5.

[033] Suitable thickeners are polysaccharides (eg, xanthan gum, carboxymethyl cellulose), inorganic clays (organically modified or unmodified), polycarboxylates, and silicates.

[034] Suitable bactericides are bronopol and isothiazolinone derivatives such as alkylisothiazolinone and benzisothiazolinone.

[035] Suitable antifreeze agents are ethylene glycol, propylene glycol, glycerin and urea.

[036] Suitable antifoaming (or antifoaming) agents are silicones, long-chain alcohols, and fatty acid salts.

[037] Suitable dyes (eg in red, blue or green) are low water soluble pigments and water soluble dyes. Examples are inorganic dyes (e.g. iron oxide, titanium oxide, iron hexacyanoferrate) and organic dyes (e.g. alizarin, azocyanine and phthalocyanine dyes).

[038] Suitable tackifiers or binding agents are polyvinylpyrrolidones, polyvinylacetates, polyvinyl alcohols, polyacrylates, biological or synthetic waxes, and cellulose ethers.

[039] Examples for the types of composition and their preparation are:

i) Water-soluble concentrates (SL, LS):

10-60% by weight of a mixture of the invention and 5 to 15% by weight of wetting agent (e.g. alkoxylated alcohol) are dissolved in water and/or a water-soluble solvent (e.g. alcohols) added until

100% by weight.

The active substance dissolves after dilution with water;

ii) Dispersible concentrates (DC):

5-25% by weight of a mixture of the invention and 1-10% by weight of dispersant (eg polyvinylpyrrolidone) are dissolved in organic solvent (eg cyclohexanone) added to 100% by weight.

Dilution with water forms a dispersion;

iii) Emulsifiable concentrates (EC):

15-70% by weight of a mixture of the invention and 5-10% by weight of emulsifiers (e.g. calcium dodecylbenzenesulfonate and ethoxylated castor oil) are dissolved in water-insoluble organic solvent (e.g. aromatic hydrocarbons) up to 100 % by weight.

Dilution with water forms an emulsion;

iv) Emulsions (EW, EO, ES):

5-40% by weight of a mixture of the invention and 1-10% by weight of emulsifier (e.g. calcium dodecylbenzenesulfonate and ethoxylated castor oil) are dissolved in 20-40% by weight of water-insoluble organic solvent (e.g. example, aromatic hydrocarbon). This mixture is introduced into water until it reaches 100% by weight through an emulsifying machine and transformed into a homogeneous emulsion.

Dilution with water forms an emulsion;

v) Suspensions (SC, OD, FS): In a ball mill, 20-60% by weight of a composition of the invention is milled with the addition of 2-10% by weight of dispersants and wetting agents (e.g. lignosulfonate sodium and ethoxylated alcohol),

0.1-2% by weight of thickener (eg xanthan gum) and water are added up to 100% by weight to obtain a fine active substance suspension.

Dilution with water forms a stable suspension of the active substance.

For the FS-type composition, up to 40% by weight of binder (eg polyvinyl alcohol) is added;

vi) Water dispersible granules and water soluble granules (WG, SG):

50-80% by weight of a mixture of the invention is finely ground with the addition of dispersing agents and wetting agents (e.g. sodium lignosulfonate and ethoxylated alcohol) to 100% by weight and the mixture is prepared as water-dispersible granules or water-soluble by means of technical apparatus (eg extrusion, spray tower, fluidized bed). Dilution with water forms a stable dispersion or suspension of the active substance;

vii) Water dispersible powders and water soluble powders (WP,

SP, WS):

50-80% by weight of mixtures according to the present invention are ground in a rotor-stator mill with addition of 1-5% by weight of dispersants (e.g. sodium lignosulfonate), 1-3% by weight of agents. wetting agents (e.g. ethoxylated alcohol) and solid carrier (e.g. silica gel) up to 100% by weight.

Dilution with water forms a stable dispersion or suspension of the active substance;

viii) Gel (GW, GF):

In a ball mill, 5-25% of a composition of the invention is milled with the addition of 3-10% by weight of dispersants (e.g. sodium lignosulfonate), 1-5% by weight of thickeners (e.g. carboxymethylcellulose) and water to complete 100% by weight to form a fine suspension of the active substance. Dilution with water forms a stable suspension of the active substance; ix) Microemulsions (ME): 5-20% by weight of a mixture of the invention is added to 5-30% by weight of organic solvent mixture (e.g. fatty acid dimethylamide and cyclohexanone), 10-25% by weight of a mixture of surfactants (e.g. ethoxylated alcohols and ethoxylated arylphenol) and water to 100% by weight. This mixture is stirred for 1 h to spontaneously produce a thermodynamically stable microemulsion; x) Microcapsules (CS): The oil phase comprising 5-50% by weight of a mixture of the invention, 0-40% by weight of water-insoluble organic solvent (e.g. aromatic hydrocarbons), 2-15% by weight of acrylic monomers (eg methyl methacrylate, methacrylic acid and a di- or triacrylate) is dispersed in an aqueous solution of a protective colloid (eg polyvinyl alcohol). Radical polymerization initiated by a radical initiator results in the formation of poly(meth)acrylate microcapsules.

Alternatively, an oil phase comprising 5-50% by weight of the inventive mixture according to the present invention, 0-40% by weight of water-insoluble organic solvent (e.g. aromatic hydrocarbons), and an isocyanate monomer (e.g. (eg, diphenylmethane-4,4'-diisocyanate) is dispersed in an aqueous solution of a protective colloid (eg, polyvinyl alcohol). Addition of a polyamine (eg hexamethylenediamine) results in the formation of polyurea microcapsules. The monomers amount to 1-10% by weight. The % by weight refers to the total CS composition; xi) Dusting powder (DP, DS): 1-10% by weight of a mixture of the invention is finely ground and intimately mixed with a solid carrier (e.g. finely divided kaolin) to 100% by weight; xii) Granules (GR, FG): 0.5-30% by weight of a mixture of the invention are finely ground and intimately mixed with a solid carrier (eg silicate) to 100% by weight. Granulation is achieved by extrusion, spray-drying (spray-drying) or fluidized bed; and xiii) Ultra-low volume (UL) liquids: 1-50% by weight of a mixture of the invention is dissolved in organic solvent (eg aromatic hydrocarbon) added up to 100% by weight.

[040] Compositions of types i) to xiii) may optionally comprise other auxiliaries, such as 0.1-1% by weight of bactericides, 5-15% by weight of antifreeze agents, 0.1-1% by weight weight of anti-foaming agents, and 0.1-1% by weight of dyes.

[041] The resulting agrochemical compositions generally comprise between 0.01 and 95%, preferably between 0.1 and 90%, and in particular between 0.5 and 75% by weight of active substance. The active substances are used in a purity of 90% to 100%, preferably 95% to 100% (according to the NMR spectrum).

[042] Seed treatment solutions (LS), suspoemulsions (SE), fluid concentrates (FS), powder for dry treatment (DS), water dispersible powder for treatment in semi-fluid dispersion (WS), powder soluble in water (SS), emulsions (ES), emulsifiable concentrates (EC) and gels (GF) are commonly used for the treatment of plant propagation materials, especially seeds. The compositions in question provide, after dilution from two to ten times, concentrations of active substance between 0.01 and 60% by weight, preferably between 0.1 and 40%,

in ready-to-use preparations. Application can be carried out before or during sowing. Methods for applying the mixtures of the invention and compositions thereof, respectively, on plant propagation material, especially seeds, include dressing, coating, granulating, dusting, dipping and seeding furrow application of propagation material. . Preferably, the inventive mixtures and compositions, respectively, are applied to plant propagation material by a method such that germination is not induced, for example, by seed coating, pelleting, covering and dusting.

[043] When used in plant protection, the amounts of active substances applied, depending on the type of effect desired, are between 0.001 and 2 kg per ha, preferably from 0.005 to 2 kg per ha and more preferably from 0.01 to 0.01 to 1kg per ha, and in particular from 0.05 to 0.75 kg per ha.

[044] In the treatment of plant propagation materials such as seeds, for example by sprinkling, coating or soaking, amounts of active substances from 0.1 to -10 kg, preferably from 1-1000 g, more preferably from 1-100 g per 100 kg of plant propagation material (preferably seeds).

[045] When used to protect stored materials or products, the amount of active substance applied depends on the type of application area and the desired effect. Values usually applied in the protection of materials are from 0.001 g to 2 kg, preferably 0.005 g to 1 kg, of active substance per cubic meter of treated material.

[046] Various types of oils, humectants, adjuvants, fertilizers, or additional micronutrients and pesticides (e.g. herbicides, insecticides, fungicides, growth regulators, protective agents (or phytoprotectants)) can be added to the active substances, or to compositions comprising such substances or, if appropriate, not until immediately before use (tank mix). These agents can be mixed with the compositions of the invention in a weight ratio (weight ratio) of 1:100 to 100:1, preferably 1:10 to 10:1.

[047] The user applies the composition according to the present invention from a pre-dosing device, a backpack sprayer, a spray tank, a spray plane, or irrigation system. Typically, the agrochemical composition is made with water, buffer, and/or other auxiliary agents to the desired application concentration and the 'ready-to-use' spray solution or agrochemical composition according to the invention is thus obtained. Typically, 20 to 2000 litres, preferably 50 to 400 litres, of the ready-to-use spray solution is applied per hectare of agricultural usable area.

[048] According to an example of embodiment, the individual components of the composition according to the invention, such as parts of a kit, or parts of a binary mixture, can be mixed by the user himself in a spray tank or any type container used for applications (eg seed treatment drums, seed granulation machines, knapsack sprayer) and other auxiliaries can be added if appropriate.

[049] Accordingly, an exemplary embodiment of the invention is a kit for preparing a usable pesticidal composition, which kit comprises; a) a composition comprising component 1), preferably compound i of formula I as defined in the present invention and at least one auxiliary; and b) a composition comprising component 2) as defined in the present invention and at least one auxiliary; and optionally c) a composition comprising at least one auxiliary and,

optionally, an additional active ingredient 3) as defined in the present invention.

[050] As stated above, the present invention comprises the use of the mixture to control harmful phytopathogenic fungi and a method of controlling phytopathogenic pests, wherein the pest, its habitat, breeding grounds (breeding grounds), the site or plants to be are protected from pest attack, the soil or plant propagation material is treated with an effective amount of the mixture.

[051] Advantageously, the mixtures of the invention are suitable for controlling the following fungal diseases in plants: Albugo spp. (white rust) on ornamental plants, vegetables (eg A. candida) and sunflowers (eg A. tragopogonis); Alternaria spp. (Alternaria leaf spot) on vegetables (e.g. A. dauci or A. porri), canola oil (A. brassicicola or brassicae), beetroot (A. tenuis), fruit (e.g. A. grandis ), rice, soybeans, potatoes and tomatoes (e.g. A. solani, A. grandis or A. alternata), tomatoes (e.g. A. solani or A. alternata) and wheat (e.g. A. triticina); Aphanomyces spp. in beets, vegetables and greens; Ascochyta spp. in cereals and legumes, such as A. tritici (anthracnose) in wheat and A. hordei in barley; Aureobasidium zeae (syn. Kapatiella zeae) in maize; Bipolaris and Drechslera spp. (teleomorph: Cochliobolus spp.), such as southern leaf spot (D. maydis) or northern leaf spot (B. zeicola) on maize, such as spot blister (B.

sorokiniana) in cereals and, for example, B. oryzae in rice and grass; Blumeria (formerly Erysiphe) graminis (powder mildew) on cereals (eg on wheat or barley); Botrytis cinerea (teleomorph: Botryotinia fuckeliana: gray mold) on fruits and berries (eg strawberries), vegetables (eg lettuce, carrots, celery and cabbage); B. squamosa or B. allii in the onion family), canola, ornamental plants (eg B. elliptica), grapes,

forest plants and wheat; Bremia lactucae (downy mildew) on lettuce; Ceratocystis (syn. Ophiostoma) spp. (rot or wilt) on broadleaf trees and perennials such as C. ulmi (Dutch elm disease) on elms; Cercospora spp. (Cercospora leaf spots) on maize (eg, gray leaf spots: C. zeae-maydis), rice, sugar beet (eg C. beticola), sugar cane, legumes, vegetables, coffee and soybeans (eg for example, C. sojina or C. kikuchii) and rice; Cladobotryum (syn. Dactylium) spp (eg, C. mycophilum (formerly, Dactylium dendroides, teleomorph: Nectria albertinii, Nectria rosella sin. Hypomyces rosellus) on mushrooms; Cladosporium spp. on tomatoes (eg, C. fulvum: leaf mold ) and cereals such as C. herbarum (black ear) on wheat; Claviceps purpurea (ergot) on cereals; Cochliobolus (anamorph: Helminthosporium de Bipolaris) spp. (leaf spots) on maize (C. carbonum), cereals (for e.g. C. sativus, anamorph: B. sorokiniana) and rice (e.g. C.

miyabeanus, anamorph: H. oryzae); Colletotrichum (teleomorph: Glomerella) spp. (anthracnose) on cotton (eg C. gossypii), maize (eg C. graminicola: Anthracnose stem rot), soft fruits, potatoes (eg C. coccodes: black spots), beans (eg , Ç.

lindemuthianum), soybeans (eg, C. truncatum or C. gloeosporioides), vegetables (eg, C. lagenarium or C. capsici), fruits (eg, C. acutatum), coffee (eg, C. coffeanum or C. kahawae) and C.

gloeosporioides in different seasons; Corticium spp., eg C. sasakii (sheath rust) on rice; Corynespora cassiicola (leaf spots) on soybean and ornamental plants; Cycloconium spp., such as C. oleaginum on olive trees; Cylindrocarpon spp. (eg, canker of fruit trees or decline of young grapes, teleomorph: Nectria or Neonectria spp.) on fruit trees, grapes (eg, C. liriodendri, teleomorph: Neonectria liriodendri: black foot disease) and ornamental plants; Dematophora (teleomorph: Rosellinia) necatrix

(stem and root rot) in soybean; Diaporthe spp., such as D. phaseolorum (damp-off) on soybean; Drechslera (syn. Helminthosporium, teleomorph: Pyrenophora) spp. in maize, cereals such as barley (e.g. D. teres, reticular leaf spot) and wheat (e.g. D. tritici-repentis: brown leaf spot), rice and grass; Esca (decline, apoplexy) in grapes, caused by Formitiporia (syn. Phellinus) punctata, F. mediterranea, Phaeomoniella chlamydospora (formerly Phaeoacremonium chlamydosporum), Phaeoacremonium aleophilum and/or Botryosphaeria obtusa; Elsinoe spp. in pome fruit (E.

pyri), soft fruits (E. veneta: anthracnose) and grapes (E. ampelina: anthracnose); Entyloma oryzae (leaf soot) on rice; Epicoccum spp. (black mold) on wheat; Erysiphe spp. (powder mildew) on beets (E. betae), vegetables (e.g. E. pisi), such as pumpkins (e.g. E.

cichoracearum), cabbage, canola (eg, E. cruciferarum); Eutypa lata (cancer or Eutypa decline, anamorph: Cytosporina lata, sin. Libertella blepharis) on fruit, grapes and ornamental wood; Exserohilum (syn.

Helminthosporium) spp. in maize (eg E. turcicum); Fusarium (teleomorph: Gibberella) spp. (withering, stem or root rot) in various plants, such as F. graminearum or F. culmorum (root rot, head blight or scab) in cereals (e.g. wheat or barley), F.

oxysporum on tomatoes, F. solani (F. sp. glycines, now syn. F. virguliforme), F.

tucumaniae and F. brasiliense, each causing sudden death syndrome in soybean, and F. verticillioides in corn; Gaeumannomyces graminis (foot sickness) in cereals (eg wheat or barley) and maize; Gibberella spp. in cereals (eg G. zeae) and rice (eg G. fujikuroi: Bakanae disease); Glomerella cingulata on grapes, apples and other plants and G. gossypii on cotton; grain coloring complex in rice; Guignardia bidwellii (black rot) on grapes; Gymnosporangium spp. in rosaceous and juniper plants, such as G. sabinae (rust) in pears; Helminthosporium spp.

(syn. Drechslera, teleomorph: Cochliobolus) in maize, cereals, potatoes and rice; Hemileia spp., such as H. vastatrix (coffee leaf rust) in coffee; Isariopsis clavispora (syn. Cladosporium vitis) on grapes; Macrophomina phaseolina (sin. phaseoli) (root and stem rot) in soybean and cotton; Microdochium (syn. Fusarium) nivale (pink snow mold) in cereals (eg wheat or barley); Microsphaera diffusa (powder mildew) in soybean; Monilinia spp., such as M. laxa, M. fructicola and M. fructigena (syn. Monilia spp.: twig and flower blight, brown rot) on drupes and other rosaceous plants; Mycosphaerella spp. on cereals, bananas, soft fruits and peanuts, such as M. graminicola (anamorph: Zymoseptoria tritici, formerly Septoria tritici: Septoria rust) on wheat or M. fijiensis (syn.

Pseudocercospora fijiensis: black Sigatoka disease) and M. musicola on bananas, M. arachidicola (syn. M. arachidis or Cercospora arachidis), M.

berkeleyi on peanuts, M. pisi on peas and M. brassiciola on Brassica; Peronospora spp. (downy mildew) on cabbage (e.g. P. brassicae), canola (e.g. P. parasitica), onions (e.g. P. destructor), tobacco (P. tabacina) and soybeans (e.g. P. manshurica ); Phakopsora pachyrhizi and P. meibomiae (soybean rust) on soybean; Phialophora spp., such as in grapes (e.g. P. tracheiphila and P. tetraspora) and soybeans (e.g. P. gregata: stem rot); Phoma lingam (syn. Leptosphaeria biglobosa and L. maculans: stem and root rot) on canola and cabbage, P. betae (root rot, leaf spot and damping-off) on sugar beet and P. zeae-maydis (syn. Phyllostica zeae) in maize; Phomopsis spp. in sunflower, grapes (eg P. viticola: leaf spot and can) and soybean (eg stem rot: P. phaseoli, teleomorph: Diaporthe phaseolorum); Physoderma maydis (brown spots) on corn; Phytophthora spp. (withering and rotting of roots, leaves, fruits and stems) of various plants such as paprika and squash (e.g. P. capsici), soybeans (e.g. P.

megasperm, yes. P. soyae), potatoes and tomatoes (eg P. infestans: late blight) and broadleaf trees (eg P. ramorum: sudden death of oak); Plasmodiophora brassicae (cabbage hernia) on cabbage, canola, radish and other plants; Plasmopara spp., such as P. viticola (grape downy mildew) on grapes and P. halstedii on sunflower; Podosphaera spp. (powder mildew) on rosaceous plants, hops, pomes and soft fruits (e.g. P.

leucotricha on apples) and pumpkins (P. xanthii); Polymyxa spp, for example in cereals such as barley and wheat (P. graminis) and sugar beet (P. betae) and viral diseases transmitted in this way; Pseudocercosporella herpotrichoides (syn. Oculimacula yallundae, O. acuformis: mad bed, teleomorph: Tapesia yallundae) in cereals such as wheat or barley; Pseudoperonospora (downy mildew) on various plants, such as P. cubensis on pumpkins or P. humili on hops; Pseudopezicula tracheiphila (fire red disease or “brenner rot”, anamorph: Phialophora) in grapes; Puccinia spp. (rusts) on various plants, such as P. triticina (leaf rust or brown), P. striiformis (streaked or yellow rust), P. hordei (dwarf rust), P. graminis (black or stem rust), or P. recondita (brown or leaf rust) on cereals such as wheat, barley or rye, P. kuehnii (orange rust) on sugar cane and P. asparagi on asparagus; Pyrenopeziza spp., such as P. brassicae on canola; Pyrenophora (anamorph: Drechslera) tritici-repentis (brown spot) on wheat or P. teres (reticular spot) on barley; Pyricularia spp., such as P. oryzae (teleomorph: Magnaporthe grisea: rice blast) on rice and P. grisea on grass and cereals; Pythium spp. (tipping) on grass, rice, corn, wheat, cotton, canola, sunflower, soybeans, sugar beet, legumes, vegetables and various other plants (eg P. ultimum or P. aphanidermatum) and P.

oligandrum in mushrooms; Ramularia spp., such as R. collo-cygni (Ramularia leaf spots, physiological leaf spots) on barley and R.

beticola in beetroot; Rhizoctonia spp. in cotton, rice, potato, grass,

corn, canola, potato, sugar beet, legumes, vegetables and various other plants such as R. solani (stem and root rot) on soybeans, R. solani (sheath rust) on rice or R. cerealis (spring rust) from Rhizoctonia) on wheat or barley; Rhizopus stolonifer (black mold, soft root) on strawberries, carrots, cabbage, grapes and tomatoes; Rhynchosporium secalis and R. commune (burn) on barley, rye and triticale; Sarocladium oryzae and S.

attenuatum (sheath rot) in rice; Sclerotinia spp. (stem rot or white mold) in vegetables (S. minor and S. sclerotiorum) and field crops such as canola, sunflower (eg, S. sclerotiorum) and soybean, S.

rolfsii (syn. Athelia rolfsii) in soybeans, peanuts, legumes, vegetables, corn, cereals and ornamental plants; Septoria spp. in various plants, such as S. glycines (brown spot) on soybean, S. tritici (syn. Zymoseptoria tritici, Septoria rust) on wheat and S. (syn. Stagonospora) nodorum (Stagonospora spot) on cereals; Uncinula (syn. Erysiphe) necator (powder mildew, anamorph: Oidium tuckeri) on grapes; Setosphaeria spp. (leaf rust) on maize (eg S. turcicum, sin. Helminthosporium turcicum) and grass; Sphacelotheca spp. (soot) in maize (eg S. reiliana, syn. Ustilago reiliana: superior soot), sorghum and sugar cane; Sphaerotheca fuliginea (syn.

Podosphaera xanthii (powder mildew)) on pumpkins; Spongospora subterranea (powdery scab) on potatoes and viral diseases transmitted in this way; Stagonospora spp. in cereals, such as S. nodorum (Stagonospora spot, teleomorph: Leptosphaeria (syn. Phaeosphaeria) nodorum, syn.

Septoria nodorum) in wheat; Synchytrium endobioticum in potatoes (warts); Taphrina spp., such as T. deformans (leaf curl) on peaches and T.

pruni (plum leprosy) on plums; Thielaviopsis spp. (black root rot) on tobacco, drupes, legumes, vegetables, soybeans and cotton, such as T. basicola (syn. Chalara elegans); Tilletia spp. (common bulge or fetid soot) in cereals, such as T. tritici (syn. T. caries, wheat bulge) and T. controversial (dwarf bulge) in wheat; Trichoderma harzianum on mushrooms; Typhula incarnata (gray snow mould) on barley or wheat; Urocystis spp., such as U.

occulta (stem soot) on rye; Uromyces spp. (rust) on vegetables such as beans (eg U. appendiculatus, sin. U. phaseoli), beets (eg U. betae or U. beticola) and pulses (eg U. vignae, U. . pisi, U. viciae-fabae and U. fabae); Ustilago spp. (loose soot) in cereals (eg U. nuda and U. avaenae), maize (eg U. maydis: corn soot) and sugar cane; Venturia spp. (scab) in apples (eg V. inaequalis) and pears; and Verticillium spp. (withering) on various plants, such as fruits and ornamentals, grapes, soft fruits, vegetables, and field crops, such as V. longisporum on canola, V. dahliae on strawberries, canola, potatoes and tomatoes, and V. fungicola in mushrooms; Zymoseptoria tritici in cereals; Phaeosphaeria maydis and Puccinia polysora.

[052] Preferably, the mixtures of the invention are suitable for controlling the following fungal diseases in soybeans: Alternaria spp. (Alternaria leaf spot); Cercospora spp. (leaf spots on Cercospora), eg C. sojina or C. kikuchii); Colletotrichum (teleomorph: Glomerella) spp. (anthracnose), e.g. C. truncatum or C.

gloeosporioides); Corynespora cassiicola (leaf spots); Dematophora (teleomorph: Rosellinia) necatrix (root and stem rot); Diaporthe spp., eg D. phaseolorum (damp-off); Fusarium (teleomorph: Gibberella) spp. (root rot or stem wilt), e.g. F.

tucumaniae and F. brasiliense, each of which causes sudden death syndrome in soybeans; Macrophomina phaseolina (synonym; phaseoli) (root and stem rot); Microsphaera diffusa (powdery mildew); Peronospora spp. (downy mildew), for example, P. manshurica; Phakopsora pachyrhizi and P. meibomiae (soybean rust); Phialophora spp., eg P. gregata: stem rot; Phomopsis spp., eg stem rot: P. phaseoli

(teleomorph: Diaporthe phaseolorum); Pythium spp. (tipping); Phytophthora spp. (withered root, leaf, fruit and stem), e.g. P.

megasperm, synonym; P. soya); Rhizoctonia spp., eg R. solani (root and stem rot); Sclerotinia spp. (stem rot or white mold); Septoria spp., eg S. glycines (brown spot); S.

rolfsii (synonym; Athelia rolfsii); Thielaviopsis spp. (black root rot).

[053] More preferably, the mixtures of the invention are suitable for controlling the following fungal diseases in soybean: Alternaria spp. (Alternaria leaf spot); Cercospora spp. (leaf spots on Cercospora), eg C. sojina or C. kikuchii); Colletotrichum (teleomorph: Glomerella) spp. (anthracnose), e.g. C. truncatum or C.

gloeosporioides); Corynespora cassiicola (leaf spots); Diaporthe spp., eg D. phaseolorum (damp-off); Fusarium (teleomorph: Gibberella) spp. (withered root or stem), for example, F. tucumaniae and F. brasiliense, each of which causes sudden death syndrome in soybeans; Macrophomina phaseolina (sin. phaseoli) (root and stem rot); Peronospora spp. (downy mildew), for example, P. manshurica; Phakopsora pachyrhizi and P. meibomiae (soybean rust); Phomopsis spp., eg stem rot: P. phaseoli (teleomorph: Diaporthe phaseolorum); Phytophthora spp. (root, leaf, fruit and root of withered stems), e.g. P.

megasperm, yes. P. soya); Rhizoctonia spp., eg R. solani (root and stem rot); Septoria spp., eg S. glycines (brown spot).

[054] More preferably, the mixtures of the invention are suitable for controlling Phakopsora pachyrhizi and P. meibomiae (soybean rust) on soybeans.

[055] The mixtures according to the present invention,

respectively, they are also suitable for combating harmful fungi in the protection of stored or harvested products and in the protection of materials.

[056] The term “materials protection” should be understood to mean the protection of technical and non-living materials, such as adhesives, glues, wood, paper and cardboard, textiles, leather, paint dispersions, plastics, cooling lubricants, fiber or fabrics, against infestation and destruction by harmful microorganisms such as fungi and bacteria. As for the protection of wood and other materials, special attention is paid to the following harmful fungi: Ascomycetes such as Ophiostoma spp., Ceratocystis spp., Aureobasidium pullulans, Sclerophoma spp., Chaetomium spp., Humicola spp., Petriella spp., Trichurus spp.; Basidiomycetes such as Coniophora spp., Coriolus spp., Gloeophyllum spp., Lentinus spp., Pleurotus spp., Poria spp., Serpula spp. and Tyromyces spp., Deuteromycetes such as Aspergillus spp., Cladosporium spp., Penicillium spp., Trichoderma spp., Alternaria spp., Paecilomyces spp. and Zygomycetes such as Mucor spp., and additionally in the protection of stored and harvested products the following yeasts of note: Candida spp. and Saccharomyces cerevisae.

[057] They are particularly important for controlling a large number of fungi in various cultivated plants such as bananas, cotton, plant species (eg cucumbers, beans and cucurbits), cereals such as wheat, rye, barley, rice, oats; coffee, potato, corn, fruit species, soybeans, tomatoes, vines, ornamental plants, sugar cane and also a large number of seeds. In a preferred embodiment, the mixtures of the invention are used in soybeans (soybeans), cereals and corn.

[058] In general, "pesticideally effective amount" means the amount required of the mixtures of the invention or of compositions comprising the mixtures to achieve an observable effect on growth, including the effects of necrosis, retardation of death, prevention and removal, destruction, or otherwise decrease in the occurrence and activity of the target organism. The pesticidally effective amount may vary for the various mixtures/compositions used in the invention. A pesticidally effective amount of the mixtures/compositions will also vary according to prevailing conditions, such as desired pesticidal effect and duration, climate, target species, desired location and mode of application, and the like.

[059] As noted above, the present invention comprises a method of improving the health of plants, wherein the plant, the location where the plant is growing or is expected to grow, or the plant propagation material, from which the plant grows, is treated with a phytosanitary effective amount of a mixture of the invention.

[060] The term "plant effective amount" means an amount of the mixtures of the invention which is sufficient to achieve the effects on plant health, as defined below. More exemplary information on amounts, forms of application and proportions suitable for use is provided below. In any case, the person skilled in the art is well aware of the fact that an amount can vary over a wide range and is dependent on many factors, for example, the cultivated plant or material and climatic conditions.

[061] When mixtures are prepared, it is preferred to employ the pure active compounds, to which other active compounds against pests can be added, such as insecticides, herbicides, fungicides or other active compounds, herbicidal or growth regulators or fertilizers as active components. additional as needed.

[062] The mixtures of the invention are employed by treating the fungi or plants, plant propagation material (preferably seeds), materials or soil to be protected from fungal attack with a pesticidally effective amount of the active compounds. Application can be carried out before and after infection of the materials, plants or plant propagation materials (preferably seeds) by pests.

[063] In the context of the present invention, the term plant refers to an entire plant, a part of the plant or the plant propagation material.

[064] The mixtures of the invention and their compositions are particularly important in the control of a multitude of phytopathogenic fungi in various cultivated plants, such as cereals, for example wheat, rye, barley, triticale, oats or rice; beet, for example sugar beet or fodder beet; fruits, such as pomes, stone fruits or soft fruits, for example apples, pears, plums, peaches, almonds, cherries, strawberries, raspberries, blackberries or blackcurrants; leguminous plants such as lentils, peas, alfalfa or soybeans; oil plants such as rapeseed, canola; mustard, olives, sunflowers, coconut, cocoa, castor, palm, peanut or soy; cucurbits, such as pumpkins, cucumbers or melons; fibrous plants such as cotton, flax, hemp or jute; citrus fruits such as oranges, lemons, grapefruits or tangerines; vegetables, such as spinach, lettuce, asparagus, cabbage, carrots, onions, tomatoes, potatoes, cucurbits or paprika; lauraceous plants such as avocado, cinnamon or camphor; raw materials for energy, such as corn, soy, rapeseed, sugar cane or palm; corn; tobacco; nuts; coffee; tea; bananas; vines (table grapes and grapes for juice and vine grapes); hop; peat; fennel (also called Stevia); natural rubber plants or ornamental and forestry plants, such as flowers, shrubs, broadleaf trees or pines, for example conifers; and on plant propagation material, such as seeds, and harvest material from these plants.

[065] Preferably, the mixtures of the invention and their compositions are used to control a variety of fungi in crops, such as potatoes, sugar beet, tobacco, wheat, rye, barley, oats, rice, corn, cotton, soybeans, rapeseed, pulses. , sunflower, coffee or sugar cane; fruits; vines; ornamental plants; or vegetables such as cucumbers, tomatoes, beans or pumpkins.

[066] Preferably, the treatment of plant propagation materials with the mixtures of the invention and their compositions, respectively, is used to control a multitude of fungi in cereals, such as wheat, rye, barley and oats; potatoes; tomatoes; grape; rice, corn, cotton and soy.

[067] The term “cultivated plants” is also intended to include plants that have been modified by breeding, mutagenesis or genetic engineering, including but not limited to agricultural biotechnology products on the market or under development (cf. http://cera -gmc.org/, consult the GM crop database). Genetically modified plants are plants in which the genetic material has been modified using recombinant DNA techniques that, under natural circumstances, could not be easily obtained by crossing, mutation or natural recombination.

Typically, one or more genes are integrated into the genetic material of a genetically modified plant in order to improve certain properties of the plant. These genetic modifications include, but are not limited to, targeted post-translational modification of protein(s), oligo- or polypeptides, for example, by glycosylation or polymer additions, such as prenylated, acetylated or farnesylated moieties or PEG moieties.

[068] Plants that have been modified by breeding, mutagenesis or genetic engineering, for example, have been made tolerant to applications of specific classes of herbicides, such as auxin herbicides such as dicamba or 2,4-D; bleaching herbicides such as dioxygenase inhibitors (HPPD hydroxylphenylpyruvate) or phytoenyl desaturase inhibitors (PDS); acetolactate synthase (ALS) inhibitors such as sulfonylureas or imidazolinones; enolpyruvylshikimate-3-phosphate (EPSPS) inhibitors such as glyphosate; glutamine synthetase (GS) inhibitors such as glufosinate; protoporphyrinogen oxidase-IX inhibitors; lipid biosynthesis inhibitors such as acetyl-CoA carboxylase (ACCase) inhibitors; or oxynyl herbicides (ie bromoxynil or yoxynil) as a result of conventional breeding or genetic engineering methods.

In addition, plants have been made resistant to multiple classes of herbicides through multiple genetic modifications, such as resistance to glyphosate and glufosinate, or to glyphosate and a herbicide of another class, such as ALS inhibitors, HPPD inhibitors, auxin herbicides, or ACCase inhibitors. These herbicide resistance technologies are, for example, described in Pest Management Sci. 61, 2005, 246; 61, 2005, 258; 61, 2005, 277; 61, 2005, 269; 61, 2005, 286; 64, 2008, 326; 64, 2008, 332; Weed Sci. 57, 2009, 108; Southern. J. Agricultural. Res. 58, 2007, 708; Science 316, 2007, 1185; and the references cited therein. Several crop plants have been made tolerant to herbicides by conventional breeding methods (mutagenesis), e.g. Clearfield® summer rape (Canola, BASF SE, Germany) tolerant to imidazolinones, e.g. imazamox, or ExpressSun® sunflowers (DuPont, USA), sulfonylurea tolerant, e.g. Tribenuron. Genetic engineering methods have been used to make cultivated plants, such as soybeans, cotton, corn, sugar beets and rapeseed, tolerant to herbicides such as glyphosate and glufosinate, some of which are commercially available under the tradenames RoundupReady® (RoundupReady®). glyphosate, Monsanto, USA) and LibertyLink ® (glufosinate tolerant, Bayer CropScience, Germany)).

[069] In addition, plants are also covered by the use of recombinant DNA techniques capable of synthesizing one or more insecticidal proteins, especially those known from the bacterial genus Bacillus,

particularly from Bacillus thuringiensis, such as δ-endotoxins, for example CryIA(b), CryIA(c), CryIF, CryIF(a2), CryIIA(b), CryIIIA, CryIIIB(b1) or

Cry9c; vegetative insecticidal proteins (VIP), for example, VIP1, VIP2, VIP3 or VIP3A; insecticidal proteins from nematode colonizing bacteria, eg Photorhabdus spp. or Xenorhabdus spp.; toxins produced by animals, such as scorpion toxins, arachnid toxins, wasp toxins, or other insect-specific neurotoxins; fungi produced toxins such as streptomycete toxins, plant lectins such as pea or barley lectins; agglutinins; proteinase inhibitors such as trypsin inhibitors, serine protease inhibitors, patatin, cystatin or papain inhibitors; ribosome inactivating proteins (RIP),

such as ricin, corn RIP, abrin, luffinin, saporin or bryodine; steroid metabolism enzymes, such as 3-hydroxysteroid oxidase, ecdysteroid-

IDP-glycosyl-transferase, cholesterol oxidases, ecdysone inhibitors or

HMG-CoA-reductase; ion channel blockers, such as sodium or calcium channel blockers; juvenile hormone esterase; diuretic hormone receptors (helicokinin receptors); stilbene synthase, bibenzyl synthase,

chitinases or glucanases.

In the context of the present invention such insecticidal proteins or toxins are also to be expressly understood as pre-toxins, hybrid proteins, truncated or otherwise modified proteins.

Hybrid proteins are characterized by a novel combination of protein domains, (see, for example, WO document

02/015701). Other examples of such toxins or genetically modified plants capable of synthesizing such toxins are disclosed, for example,

in EP-A 374 753, WO 93/007278, WO 95/34656, EP-A 427 529, EP-A 451 878, WO 03/18810 and WO 03/52073. Methods for producing such genetically modified plants are generally known to those skilled in the art and are described, for example, in the publications mentioned above. These insecticidal proteins contained in genetically modified plants provide protection for plants that produce these proteins against harmful pests belonging to all taxonomic groups of arthropod insects, especially beetles (Coleoptera), two-winged insects (Diptera), moths (Lepidoptera) and nematode parasites (Nematoda). Genetically modified plants capable of synthesizing one or more insecticidal proteins are, for example, described in the publications mentioned above, some of which are commercially available, such as YieldGard® (corn cultivars that produce the Cry1Ab toxin), YieldGard® Plus ( corn that produce Cry1Ab and Cry3Bb1 toxins), Starlink® (corn cultivars that produce Cry9c toxin), Herculex RW® (corn cultivars that produce Cry34Ab1, Cry35Ab1 and the enzyme phosphinothricin-N-acetyltransferase [PAT]); NuCOTN ® 33B (cotton cultivars that produce Cry1Ac toxin), Bollgard® I (cotton cultivars that produce Cry1Ac toxin) Bollgard® II (cotton cultivars that produce Cry1Ac and Cry2Ab2 toxins); VipCot® (cotton cultivars that produce a VIP toxin); NewLeaf® (potato cultivars that produce the Cry3A toxin); Bt-Xtra®, NatureGard®, KnockOut®, BiteGard®, Proteta®, Bt11 (e.g. Agrisure® CB) and Bt176 from Syngenta Seeds SAS, France, (corn cultivars that produce Cry1Ab toxin and PAT Enzyme) , MIR604 from Syngenta Seeds SAS, France (maize cultivars that produce a modified version of the Cry3A toxin, WO 03/018810), MON 863 from Monsanto Europe SA, Belgium (maize cultivars that produce the Cry3Bb1 toxin), IPC 531 from Monsanto Europe SA, Belgium (cotton cultivars that produce a modified version of the Cry1Ac toxin) and 1,507 from Pioneer Overseas Corporation, Belgium (corn cultivars that produce the Cry1F toxin and the PAT enzyme).

[070] In addition, plants that, through the use of recombinant DNA techniques, are able to synthesize one or more proteins to increase the resistance or tolerance of said plants to bacterial, viral or fungal pathogens are also covered. Examples of such proteins, termed “pathogenesis-related proteins” (PR proteins, see e.g. EP-A 0392225), plant disease resistance genes (e.g. potato cultivars, which express resistance genes acting against Phytophthora infestans derived from the Mexican wild potato Solanum bulbocastanum) or T4-Lysozyme (for example, potato cultivars that have the capacity to synthesize these proteins with greater resistance against the bacteria Erwinia amylvora). Methods for producing such genetically modified plants are generally known to those skilled in the art and are described, for example, in the publications mentioned above.

[071] In addition, plants that, through the use of recombinant DNA techniques, are able to synthesize one or more proteins to increase productivity (for example, greater biomass production, grain yield, starch content, oil or protein content), tolerance to drought, salinity or other environmental factors limiting growth or tolerance to fungal, viral or bacterial pests and pathogens of these plants.

[072] In addition, plants that, through the use of recombinant DNA techniques, contain a modified amount of content substances or new substances, specifically to improve human or animal nutrition, for example, oilseed crops that produce long-chain omega-3 fatty acids or health-promoting unsaturated omega-9 fatty acids (eg, Nexera ® from Dow Agro Sciences, Canada).

[073] In addition, plants are also covered which, through the use of recombinant DNA techniques, contain a modified amount in the content of substances or new substances, specifically to improve the production of raw material, for example, potatoes that produce increased amounts of amylopectin (eg Amflora ® potato, BASF SE, Germany).

[074] The separate or joint application of the compounds of the mixtures of the invention is carried out by spraying or atomizing the seeds, seedlings, plants or the soils before or after sowing the plants, or before or after the emergence of the plants.

[075] The mixtures of the invention and the compositions comprising them can be used to protect wooden materials such as trees, fences, sleepers, etc. and buildings such as houses, outbuildings, factories, but also building materials, furniture, leathers, fibers, vinyl items, electrical wires and cables, etc. from pests such as ants and/or termites, and to control ants and termites from causing damage to crops or humans (eg when pests invade homes and public facilities).

[076] Usual application rates in the protection of materials are, for example, from 0.01 g to 1000 g of active compound per m 2 of treated material, and desirably from 0.1 g to 50 g per m2.

[077] For use in spray compositions, the active ingredient content is from 0.001 to 80% by weight, preferably from 0.01 to 50% by weight, and more preferably from 0.01 to 15% by weight .

STOVE

[078] Solutions for spraying were prepared in several steps: - The stock solution (standard solution) was prepared: a mixture of acetone and/or dimethyl sulfoxide and the wetting/emulsifying agent Wettol,

which is based on ethoxylated alkylphenols, in a solvent-emulsifier (volume) ratio of 99 to 1 was added to the initial weight of the compound to give a total volume of 5 mL; - Then, water was added to the total volume of 100 mL; and - This stock solution was diluted with the described solvent-emulsifier-water mixture at the given concentration.

EXAMPLE 1

PROTECTIVE CONTROL OF SOYBEAN RUST CAUSED BY PHAKOPSORA PACHYRHIZI

[079] Leaves of soybean seedlings grown in pots were sprayed to runoff with an aqueous suspension containing the concentration of active ingredient or its mixture as described below. The plants were left to air dry. The test plants were grown for two days in a greenhouse at 23-27 ºC and a relative humidity between 60 and 80%. Then, the plants were inoculated with spores of Phakopsora pachyrhizi. To ensure the success of the artificial inoculation, the plants were transferred to a humid chamber with a relative humidity of about 95% and a temperature of 20 to 24 ºC for 24 h. The test plants were grown for fourteen days in a greenhouse at 23-27 ºC and a relative humidity between 60 and 80%. The extent of fungal attack on leaves was visually evaluated as a % diseased leaf area.

[080] Diseases were converted into efficacy ratings.

[081] An efficacy of 0 means that the level of infection of treated plants corresponds to that of untreated control plants; an efficacy of 100 means that the treated plants were not infected.

[082] The expected efficacies of mixtures of active compounds were determined using the formula of Colby [R.S.

Colby, “Calculating synergistic and antagonistic responses of herbicide combinations”, Weeds, 15,

20-22, (1967)] and compared with observed efficacies.

Efficacy Active compound / mixture Concentration Calculated Efficacy of Active Mixture (ppm) observed according to Colby (%)

Control untreated 90% disease Products alone Fenpropimorph 250 - 54 63 - 16 16 - 6 Fluxapyroxad 4 - 84 1 - 24 Copper oxychloride 250 - 20 63 - 12 16 - 1 Three-component mixtures Phenpropimorph 63 16 : 4 : 16 98 88 Fluxapyroxad 4 Copper Oxychloride 63 Phenpropimorph 250 250 : 1 : 250 90 72 Fluxapyroxad 1 Copper Oxychloride 250

Claims (13)

1. FUNGICIDAL MIXTURES, characterized in that they comprise, as active components: (1) phenpropimorph as compound I, and (2) a fungicidal compound II, wherein compound II is a succinate dehydrogenase inhibitor and is selected from the group consisting of in: 2-(difluoromethyl)-N-(1,1-dimethyl-3-propyl-indan-4-yl)pyridine-3-carboxamide, 2-(difluoromethyl)-N-[(3R)-1,1- dimethyl-3-propyl-indan-4-yl]pyridine-3-carboxamide, 2-(difluoromethyl)-N-(1,1,3-trimethylindan-4-yl)pyridine-3-carboxamide, 2-(difluoromethyl) -N-[(3R)-1,1,3-trimethylindan-4-yl]pyridine-3-carboxamide, 2-(difluoromethyl)-N-(3-ethyl-1,1-dimethyl-indan-4-yl )pyridine-3-carboxamide, 2-(difluoromethyl)-N-[(3R)-3-ethyl-1,1-dimethyl-indan-4-yl]pyridine-3-carboxamide, 2-(difluoromethyl)-N- (3-Isobutyl-1,1-dimethyl-indan-4-yl)pyridine-3-carboxamide, 2-(difluoromethyl)-N-[(3R)-3-isobutyl-1,1-dimethyl-indan-4- yl]pyridine-3-carboxamide, inpirfluxam, bixafem, pidiflumetophem, benzovindiflupyr, fluxapyroxad, fluindapyr, isoflucipram, sedaxane, and (3) a fungicidal compound III, wherein compound III is selected from the group consisting of: N'-(2,5-dimethyl-4-phenoxy-phenyl)-N-ethyl-N-methyl-formamidine, N'-[5-bromo-2-methyl-6-(1-methyl-2-propoxy-ethoxy)-3-pyridyl]-N-ethyl-N-methyl-formamidine, N'-[4-[[3] -[(4-chlorophenyl)methyl]-1,2,4-thiadiazol-5-yl]oxy]-2,5-dimethyl-phenyl]-N-ethyl-N-methyl-formamidine, copper oxychloride, fluazinam, methiram, dithianone, propyneb, chlorothalonil, mancozeb, florylpicoxamide. 2. MIXTURE according to claim 1, characterized in that it is selected from: Compound I Compound II Compound III fenpropimorph inpirfluxam copper oxychloride fenpropimorph inpirfluxam fluazinam fenpropimorph inpirfluxam methyram fenpropimorph inpirfluxam dithianone fenpropimorph inpirfluxam propineb fenpropimorph bixaphem oxyfenxamphemide copper fluchloride bixaphene fenpropimorph bixafem metiram fenpropimorph bixafem dithianon fenpropimorph bixafem propineb fenpropimorph pidiflumetofem fenpropimorph pidiflumetofem copper oxychloride fluazinam fenpropimorph pidiflumetofem metiram fenpropimorph pidiflumetofem dithianon fenpropimorph pidiflumetofem propineb fenpropimorph benzovindiflupir fenpropimorph copper oxychloride benzovindiflupir fluazinam fenpropimorph benzovindiflupir metiram fenpropimorph benzovindiflupir dithianon fenpropimorph benzovindiflupir propineb fenpropimorph fluxapyroxad oxychloride copper fenpropimorph fluxapyroxad fluazinam fenpropimorph fluxapyroxad metiram fenpropimorph fenpropimorph fluxapyroxad dithianon fluxapyroxad propineb fenpropimorph fenpropimorph fluindapir chlorothalonil fluindapir mancozeb fluindapir fenpropimorph fenpropimorph copper oxychloride fluindapir fluazinam fenpropimorph fenpropimorph fluindapir metiram fluindapir dithianon fenpropimorph fluindapir propineb fenpropimorph fenpropimorph isoflucipram chlorothalonil mancozeb isoflucipram Compound I Compound II Compound III fenpropimorph fenpropimorph isoflucipram copper oxychloride isoflucipram fluazinam fenpropimorph fenpropimorph isoflucipram metiram isoflucipram dithianon fenpropimorph fenpropimorph isoflucipram propineb sedaxano chlorothalonil fenpropimorph fenpropimorph sedaxano mancozeb sedaxano copper oxychloride sedaxano fluazinam fenpropimorph fenpropimorph fenpropimorph sedaxano metiram sedaxano dithianon fenpropimorph fenpropimorph sedaxano propineb 2- ( difluoromethyl)-N-(1,1,3-chlorothalonyl trimethylindan-4-yl)pyridine-3-carboxamide fenpropimorph 2-(difluoromethyl)-N-(1,1,3-mancozeb trimethylindan-4-yl)pyridine-3 - carboxamide fenpropimorph 2-(difluoromethyl)-N-(1,1,3- copper oxychloride trimethylindan-4-yl)pyridine-3-carboxamide fenpropimorph 2-(difluoromethyl)-N-(1,1,3-fluazinam trimethylindan -4-yl)pyridine-3-carboxamide fenpropimorph 2-(difluoromethyl)-N-(1,1,3-methyram trimethylindan-4-yl)pyridine-3-carboxamide fenpropimorph 2-(difluoromethyl)-N-(1, 1.3-d itianone trimethylindan-4-yl)pyridine-3-carboxamide phenpropimorph 2-(difluoromethyl)-N-(1,1,3-propineb trimethylindan-4-yl)pyridine-3-carboxamide fenpropimorph 2-(difluoromethyl)-N-[ (3R)-1,1,3-chlorothalonyl trimethylindan-4-yl]pyridine-3-carboxamide fenpropimorph 2-(difluoromethyl)-N-[(3R)-1,1,3-mancozeb trimethylindan-4-yl]pyridine -3-carboxamide phenpropimorph 2-(difluoromethyl)-N-[(3R)-1,1,3- copper oxychloride trimethylindan-4-yl]pyridine-3-carboxamide fenpropimorph 2-(difluoromethyl)-N-[(3R )-1,1,3-fluazinam trimethylindan-4-yl]pyridine-3-carboxamide Compound I Compound II Compound III fenpropimorph 2-(difluoromethyl)-N-[(3R)-1,1,3-methyram trimethylindan-4-yl]pyridine-3-carboxamide fenpropimorph 2-(difluoromethyl)-N-[(3R )-1,1,3-dithianone trimethylindan-4-yl]pyridine-3-carboxamide fenpropimorph 2-(difluoromethyl)-N-[(3R)-1,1,3-propineb trimethylindan-4-yl]pyridine-3 - carboxamide fenpropimorph 2-(difluoromethyl)-N-(3-ethyl-1,1-dimethyl-chlorothalonyl indan-4-yl)pyridine-3-carboxamide fenpropimorph 2-(difluoromethyl)-N-(3-ethyl-1, 1-dimethyl-mancozeb indan-4-yl)pyridine-3-carboxamide phenpropimorph 2-(difluoromethyl)-N-(3-ethyl-1,1-dimethyl-copper oxychloride indan-4-yl)pyridine-3-carboxamide fenpropimorph 2-(difluoromethyl)-N-(3-ethyl-1,1-dimethyl-fluazinam indan-4-yl)pyridine-3-carboxamide fenpropimorph 2-(difluoromethyl)-N-(3-ethyl-1,1- dimethylmethyram indan-4-yl)pyridine-3-carboxamide phenpropimorph 2-(difluoromethyl)-N-(3-ethyl-1,1-dimethyldithianone indan-4-yl)pyridine-3-carboxamide fenpropimorph 2-( difluoromethyl)-N-(3-ethyl-1,1-dimethyl-propyn ebe indan-4-yl)pyridine-3-carboxamide fenpropimorph 2-(difluoromethyl)-N-[(3R)-3-ethyl-1,1-chlorothalonyl dimethyl-indan-4-yl]pyridine-3-carboxamide fenpropimorph 2 -(difluoromethyl)-N-[(3R)-3-ethyl-1,1-mancozeb dimethyl-indan-4-yl]pyridine-3-carboxamide fenpropimorph 2-(difluoromethyl)-N-[(3R)-3- copper ethyl-1,1-oxychloride dimethyl-indan-4-yl]pyridine-3-carboxamide fenpropimorph 2-(difluoromethyl)-N-[(3R)-3-ethyl-1,1-fluazinam dimethyl-indan-4 -yl]pyridine-3-carboxamide fenpropimorph 2-(difluoromethyl)-N-[(3R)-3-ethyl-1,1-methyl-dimethyl-indan-4-yl]pyridine-3-carboxamide fenpropimorph 2-(difluoromethyl) -N-[(3R)-3-ethyl-1,1-dithianone dimethyl-indan-4-yl]pyridine-3-carboxamide fenpropimorph 2-(difluoromethyl)-N-[(3R)-3-ethyl-1, 1-propineb dimethyl-indan-4-yl]pyridine-3-carboxamide phenpropimorph 2-(difluoromethyl)-N-(1,1-dimethyl-3-chlorothalonyl propyl-indan-4-yl)pyridine-3-carboxamide Compound I Compound II Compound III fenpropimorph 2-(difluoromethyl)-N-(1,1-dimethyl-3-mancozeb propyl-indan-4-yl)pyridine-3-carboxamide fenpropimorph 2-(difluoromethyl)-N-(1, copper 1-dimethyl-3-oxychloride propyl-indan-4-yl)pyridine-3-carboxamide fenpropimorph 2-(difluoromethyl)-N-(1,1-dimethyl-3-fluazinam propyl-indan-4-yl)pyridine -3-carboxamide fenpropimorph 2-(difluoromethyl)-N-(1,1-dimethyl-3-methyram propyl-indan-4-yl)pyridine-3-carboxamide fenpropimorph 2-(difluoromethyl)-N-(1,1- dimethyl-3-dithianone propyl-indan-4-yl)pyridine-3-carboxamide fenpropimorph 2-(difluoromethyl)-N-(1,1-dimethyl-3-propineb propyl-indan-4-yl)pyridine-3-carboxamide fenpropimorph 2-(difluoromethyl)-N-[(3R)-1,1-dimethyl-chlorothalonyl 3-propyl-indan-4-yl]pyridine-3-carboxamide fenpropimorph 2-(difluoromethyl)-N-[(3R)- 1,1-dimethyl-mancozeb 3-propyl-indan-4-yl]pyridine-3-carboxamide fenpropimorph 2-(difluoromethyl)-N-[(3R)-1,1-dimethyl-copper oxychloride 3-propyl-indan -4-yl]pyridine-3-carboxamide phenpropyl rfe 2-(difluoromethyl)-N-[(3R)-1,1-dimethyl-fluazinam 3-propyl-indan-4-yl]pyridine-3-carboxamide fenpropimorph 2-(difluoromethyl)-N-[(3R)- 1,1-dimethyl-methyram 3-propyl-indan-4-yl]pyridine-3-carboxamide phenpropimorph 2-(difluoromethyl)-N-[(3R)-1,1-dimethyl-dithianone 3-propyl-indan-4 -yl]pyridine-3-carboxamide fenpropimorph 2-(difluoromethyl)-N-[(3R)-1,1-dimethyl-propineb 3-propyl-indan-4-yl]pyridine-3-carboxamide fenpropimorph 2-(difluoromethyl) -N-(3-Isobutyl-1,1-chlorothalonyl dimethyl-indan-4-yl)pyridine-3-carboxamide fenpropimorph 2-(difluoromethyl)-N-(3-isobutyl-1,1-mancozeb dimethyl-indan-4 -yl)pyridine-3-carboxamide phenpropimorph 2-(difluoromethyl)-N-(3-isobutyl-1,1-copper oxychloride dimethyl-indan-4-yl)pyridine-3-carboxamide fenpropimorph 2-(difluoromethyl)-N -(3-isobutyl-1,1-fluazinam dimethyl-indan-4-yl)pyridine-3-carboxamide Compound I Compound II Compound III phenpropimorph 2-(difluoromethyl)-N-(3-isobutyl-1,1-methyl-dimethyl-indan-4-yl)pyridine-3-carboxamide fenpropimorph 2-(difluoromethyl)-N-(3- isobutyl-1,1-dithianone dimethyl-indan-4-yl)pyridine-3-carboxamide phenpropimorph 2-(difluoromethyl)-N-(3-isobutyl-1,1-propineb dimethyl-indan-4-yl)pyridine-3 - phenpropimorph carboxamide 2-(difluoromethyl)-N-[(3R)-3-isobutyl-chlorothalonyl 1,1-dimethyl-indan-4-yl]pyridine-3-carboxamide fenpropimorph 2-(difluoromethyl)-N-[(3R) )-3-isobutylmancozeb 1,1-dimethyl-indan-4-yl]pyridine-3-carboxamide phenpropimorph 2-(difluoromethyl)-N-[(3R)-3-isobutyl-copper oxychloride 1,1-dimethyl -indan-4-yl]pyridine-3-carboxamide fenpropimorph 2-(difluoromethyl)-N-[(3R)-3-isobutyl-fluazinam 1,1-dimethyl-indan-4-yl]pyridine-3-carboxamide fenpropimorph 2 -(difluoromethyl)-N-[(3R)-3-isobutylmethyl-1,1-dimethyl-indan-4-yl]pyridine-3-carboxamide fenpropimorph 2-(difluoromethyl)-N-[(3R)-3- isobutyl-dithianone 1,1-dimethyl-indan-4-yl]pyridin-3-c arboxamide fenpropimorph 2-(difluoromethyl)-N-[(3R)-3-isobutyl-propineb 1,1-dimethyl-indan-4-yl]pyridine-3-carboxamide fenpropimorph inpirfluxam florylpicoxamide fenpropimorph inpirfluxam N'-[5-bromo- 2-methyl-6-(1-methyl-2-propoxy-ethoxy)-3-pyridyl]-N-ethyl-N-methyl-formamidine fenpropimorph inpirfluxam N'-(2,5-dimethyl-4-phenoxy-phenyl) -N-ethyl-N-methyl-formamidine fenpropimorph inpirfluxam N'-[4-[[3-[(4-chlorophenyl)methyl]-1,2,4-thiadiazol-5-yl]oxy]-2,5- dimethyl-phenyl]-N-ethyl-N-methyl-formamidine fenpropimorph bixafen florylpicoxamide fenpropimorph bixaphem N'-[5-bromo-2-methyl-6-(1-methyl-2-propoxy-ethoxy)-3-pyridyl]- N-ethyl-N-methyl-formamidine fenpropimorph bixafen N'-(2,5-dimethyl-4-phenoxy-phenyl)-N-ethyl-N-methyl-formamidine Compound I Compound II Compound III fenpropimorph bixafen N'-[4-[[3-[(4-chlorophenyl)methyl]-1,2,4-thiadiazol-5-yl]oxy]-2,5-dimethyl-phenyl] -N-Ethyl-N-methyl-formamidine fenpropimorph pidiflumethofen florylpicoxamide fenpropimorph pidiflumetophem N'-[5-bromo-2-methyl-6-(1-methyl-2-propoxy-ethoxy)-3-pyridyl]-N-ethyl- N-methyl-formamidine fenpropimorph pidiflumetophem N'-(2,5-dimethyl-4-phenoxy-phenyl)-N-ethyl-N-methyl-formamidine fenpropimorph pidiflumetophem N'-[4-[[3-[(4-chlorophenyl) )methyl]-1,2,4-thiadiazol-5-yl]oxy]-2,5-dimethyl-phenyl]-N-ethyl-N-methyl-formamidine fenpropimorph benzovindiflupyr florylpicoxamide fenpropimorph benzovindiflupyr N'-[5-bromo- 2-methyl-6-(1-methyl-2-propoxy-ethoxy)-3-pyridyl]-N-ethyl-N-methyl-formamidine phenpropimorph benzovindiflupyr N'-(2,5-dimethyl-4-phenoxy-phenyl) -N-ethyl-N-methyl-formamidine fenpropimorph benzovindiflupyr N'-[4-[[3-[(4-chlorophenyl)methyl]-1,2,4-thiadiazol-5-yl]oxy]-2,5- dimethyl-phenyl]-N-ethyl-N-methyl-formamidine fenpropimorph fluxapyroxad florylpicoxamide fenpropim orphe fluxapyroxad N'-[5-bromo-2-methyl-6-(1-methyl-2-propoxy-ethoxy)-3-pyridyl]-N-ethyl-N-methyl-formamidine fenpropimorph fluxapyroxade N'-(2, 5-dimethyl-4-phenoxy-phenyl)-N-ethyl-N-methyl-formamidine fenpropimorph fluxapyroxad N'-[4-[[3-[(4-chlorophenyl)methyl]-1,2,4-thiadiazol-5 -yl]oxy]-2,5-dimethyl-phenyl]-N-ethyl-N-methyl-formamidine fenpropimorph flundapyr florylpicoxamide fenpropimorph fluindapyr N'-[5-bromo-2-methyl-6-(1-methyl-2- propoxy-ethoxy)-3-pyridyl]-N-ethyl-N-methyl-formamidine fenpropimorph fluindapyr N'-(2,5-dimethyl-4-phenoxy-phenyl)-N-ethyl-N-methyl-formamidine fenpropimorph fluindapyr N '-[4-[[3-[(4-chlorophenyl)methyl]-1,2,4-thiadiazol-5-yl]oxy]-2,5-dimethyl-phenyl]-N-ethyl-N-methyl- formamidine fenpropimorph isoflucipram florylpicoxamide fenpropimorph isoflucipram N'-[5-bromo-2-methyl-6-(1-methyl-2-propoxy-ethoxy)-3-pyridyl]-N-ethyl-N-methyl-formamidine phenpropimorph isoflucipram N' -(2,5-dimethyl-4-phenoxy-phenyl)-N-ethyl-N-methyl-formamidine Compound I Compound II Compound III fenpropimorph isoflucipram N'-[4-[[3-[(4-chlorophenyl)methyl]-1,2,4-thiadiazol-5-yl]oxy]-2,5-dimethyl-phenyl] -N-ethyl-N-methyl-formamidine fenpropimorph sedaxane florylpicoxamide fenpropimorph sedaxane N'-[5-bromo-2-methyl-6-(1-methyl-2-propoxy-ethoxy)-3-pyridyl]-N-ethyl- N-methyl-formamidine fenpropimorph sedaxane N'-(2,5-dimethyl-4-phenoxy-phenyl)-N-ethyl-N-methyl-formamidine fenpropimorph sedaxane N'-[4-[[3-[(4-chlorophenyl) )methyl]-1,2,4-thiadiazol-5-yl]oxy]-2,5-dimethyl-phenyl]-N-ethyl-N-methyl-formamidine fenpropimorph 2-(difluoromethyl)-N-(1,1 ,3-florylpicoxamide trimethylindan-4-yl)pyridine-3-carboxamide fenpropimorph 2-(difluoromethyl)-N-(1,1,3-N'-[5-bromo-2-methyl-6-(1-methyl- 2-Trimethylindan-4-yl)pyridin-3-propoxy-ethoxy)-3-pyridyl]-N-ethyl-N-methyl-carboxamide formamidine phenpropimorph 2-(difluoromethyl)-N-(1,1,3-N' -(2,5-dimethyl-4-phenoxy-phenyl)-N-ethyl-N-trimethylindan-4-yl)pyridin-3-methyl-formamidine carboxamide fenpropimorph 2-(difluoromethyl)-N-(1,1,3 - N'-[4- [[3-[(4-chlorophenyl)methyl]-1,2,4-trimethylindan-4-yl)pyridin-3-thiadiazol-5-yl]oxy]-2,5-dimethyl-phenyl]-N-carboxamide ethyl-N-methyl-formamidine fenpropimorph 2-(difluoromethyl)-N-[(3R)-1,1,3-florylpicoxamide trimethylindan-4-yl]pyridine-3-carboxamide fenpropimorph 2-(difluoromethyl)-N-[( 3R)-1,1,3-N'-[5-bromo-2-methyl-6-(1-methyl-2-trimethylindan-4-yl]pyridin-3-propoxy-ethoxy)-3-pyridyl]- N-ethyl-N-methyl-carboxamide formamidine fenpropimorph 2-(difluoromethyl)-N-[(3R)-1,1,3-N'-(2,5-dimethyl-4-phenoxy-phenyl)-N-ethyl -N-trimethylindan-4-yl]pyridin-3-methyl-formamidine carboxamide fenpropimorph 2-(difluoromethyl)-N-[(3R)-1,1,3-N'-[4-[[3-[(4) -chlorophenyl)methyl]-1,2,4-trimethylindan-4-yl]pyridin-3-thiadiazol-5-yl]oxy]-2,5-dimethyl-phenyl]-N-carboxamide ethyl-N-methyl-formamidine fenpropimorph 2-(difluoromethyl)-N-(3-ethyl-1,1-dimethyl-florylpicoxamide indan-4-yl)pyridine-3-carboxamide fenpropimorph 2-(difluoromethyl)-N-(3-ethyl-1,1- dimethyl-N'-[5-bromo-2-methyl-6-(1-methyl-2-indan-4-yl)pyridine-3-carboxamine from propoxy-ethoxy)-3-pyridyl]-N-ethyl-N-methyl-formamidine phenpropimorph 2-(difluoromethyl)-N-(3-ethyl-1,1-dimethyl-N'-(2,5-dimethyl- 4-phenoxy-phenyl)-N-ethyl-N-indan-4-yl)pyridine-3-carboxamide methyl-formamidine phenpropimorph 2-(difluoromethyl)-N-(3-ethyl-1,1-dimethyl-N'- [4-[[3-[(4-chlorophenyl)methyl]-1,2,4-indan-4-yl)pyridine-3-carboxamide thiadiazol-5-yl]oxy]-2,5-dimethyl-phenyl] -N-ethyl-N-methyl-formamidine Compound I Compound II Compound III fenpropimorph 2-(difluoromethyl)-N-[(3R)-3-ethyl-1,1-florylpicoxamide dimethyl-indan-4-yl]pyridine-3-carboxamide fenpropimorph 2-(difluoromethyl)-N -[(3R)-3-ethyl-1,1-N'-[5-bromo-2-methyl-6-(1-methyl-2-dimethyl-indan-4-yl]pyridine-3-propoxy-ethoxy )-3-pyridyl]-N-ethyl-N-methyl-carboxamide formamidine phenpropimorph 2-(difluoromethyl)-N-[(3R)-3-ethyl-1,1-N'-(2,5-dimethyl-4 -phenoxy-phenyl)-N-ethyl-N-dimethyl-indan-4-yl]pyridin-3-methyl-formamidine carboxamide fenpropimorph 2-(difluoromethyl)-N-[(3R)-3-ethyl-1,1- N'-[4-[[3-[(4-chlorophenyl)methyl]-1,2,4-dimethyl-indan-4-yl]pyridin-3-thiadiazol-5-yl]oxy]-2,5- dimethyl-phenyl]-N-carboxamide ethyl-N-methyl-formamidine phenpropimorph 2-(difluoromethyl)-N-(1,1-dimethyl-3-florylpicoxamide propyl-indan-4-yl)pyridine-3-carboxamide fenpropimorph 2- (difluoromethyl)-N-(1,1-dimethyl-3-N'-[5-bromo-2-methyl-6-(1-methyl-2-propyl-indan-4-yl)pyridine-3-propoxy- ethoxy)-3-pyridyl]-N-ethyl-N-methyl-carboxamide formamidine fenpropimorph 2-(difluoro omethyl)-N-(1,1-dimethyl-3-N'-(2,5-dimethyl-4-phenoxy-phenyl)-N-ethyl-N-propyl-indan-4-yl)pyridine-3-methyl -formamidine carboxamide fenpropimorph 2-(difluoromethyl)-N-(1,1-dimethyl-3-N'-[4-[[3-[(4-chlorophenyl)methyl]-1,2,4-propyl-indan- 4-yl)pyridin-3-thiadiazol-5-yl]oxy]-2,5-dimethyl-phenyl]-N-carboxamide ethyl-N-methyl-formamidine fenpropimorph 2-(difluoromethyl)-N-[(3R)- 1,1-dimethyl-florylpicoxamide 3-propyl-indan-4-yl]pyridine-3-carboxamide fenpropimorph 2-(difluoromethyl)-N-[(3R)-1,1-dimethyl-N'-[5-bromo- 2-Methyl-6-(1-methyl-2-3-propyl-indan-4-yl]pyridin-3-propoxy-ethoxy)-3-pyridyl]-N-ethyl-N-methyl-carboxamide formamidine fenpropimorph 2- (difluoromethyl)-N-[(3R)-1,1-dimethyl-N'-(2,5-dimethyl-4-phenoxy-phenyl)-N-ethyl-N-3-propyl-indan-4-yl] pyridine-3-methyl-formamidine carboxamide fenpropimorph 2-(difluoromethyl)-N-[(3R)-1,1-dimethyl-N'-[4-[[3-[(4-chlorophenyl)methyl]-1,2 ,4-3-propyl-indan-4-yl]pyridin-3-thiadiazol-5-yl]oxy]-2,5-dimethyl-phenyl]-N-carboxamide ethyl-N-methyl-formamidine fenpropimorph 2 -(difluoromethyl)-N-(3-isobutyl-1,1-florylpicoxamide dimethyl-indan-4-yl)pyridine-3-carboxamide phenpropimorph 2-(difluoromethyl)-N-(3-isobutyl-1,1-N' -[5-bromo-2-methyl-6-(1-methyl-2-dimethyl-indan-4-yl)pyridin-3-propoxy-ethoxy)-3-pyridyl]-N-ethyl-N-methyl-carboxamide Formamidine phenpropimorph 2-(difluoromethyl)-N-(3-isobutyl-1,1-N'-(2,5-dimethyl-4-phenoxy-phenyl)-N-ethyl-N-dimethyl-indan-4-yl) pyridine-3-methyl-formamidine carboxamide fenpropimorph 2-(difluoromethyl)-N-(3-isobutyl-1,1-N'-[4-[[3-[(4-chlorophenyl)methyl]-1,2,4 - dimethyl-indan-4-yl)pyridin-3-thiadiazol-5-yl]oxy]-2,5-dimethyl-phenyl]-N-carboxamide ethyl-N-methyl-formamidine Compound I Compound II Compound III fenpropimorph 2-(difluoromethyl)-N-[(3R)-3-isobutyl-florylpicoxamide 1,1-dimethyl-indan-4-yl]pyridine-3-carboxamide fenpropimorph 2-(difluoromethyl)-N -[(3R)-3-isobutyl-N'-[5-bromo-2-methyl-6-(1-methyl-2-1,1-dimethyl-indan-4-yl]pyridine-3-propoxy-ethoxy )-3-pyridyl]-N-ethyl-N-methyl-carboxamide formamidine phenpropimorph 2-(difluoromethyl)-N-[(3R)-3-isobutyl-N'-(2,5-dimethyl-4-phenoxy-phenyl )-N-ethyl-N-1,1-dimethyl-indan-4-yl]pyridin-3-methyl-formamidine carboxamide fenpropimorph 2-(difluoromethyl)-N-[(3R)-3-isobutyl-N'-[ 4-[[3-[(4-chlorophenyl)methyl]-1,2,4-1,1-dimethyl-indan-4-yl]pyridin-3-thiadiazol-5-yl]oxy]-2,5- dimethyl-phenyl]-N-carboxamide ethyl-N-methyl-formamidine 3. MIXTURE according to claim 1 or 2, characterized in that it is selected from: Compound I Compound II Compound III fenpropimorph inpirfluxam copper oxychloride fenpropimorph inpirfluxam fluazinam fenpropimorph pidiflumetophem copper oxychloride phenpropimorph pidiflumetofem fluazinam fenpropimorph benzovindiflupyr copper oxychloride fendimorph benzovindimorph benzovindimorph oxychloride copper benzovindimorph fluazinam fenpropimorph fluxapyroxad copper oxychloride fenpropimorph fluxapyroxad fluazinam fenpropimorph fluxapyroxad methyl fenpropimorph fluxapyroxad dithianone fenpropimorph fluxapyroxad propineb fenpropimorph 2-(difluoromethyl)-N-(1,1-dimethyl-3-chlorothalonyl propylboxindan-3-yl)pyridine fenpropimorph 2-(difluoromethyl)-N-(1,1-dimethyl-3-mancozeb propyl-indan-4-yl)pyridine-3-carboxamide fenpropimorph 2-(difluoromethyl)-N-(1,1-dimethyl-3- copper oxychloride propyl-indan-4-yl)pyridine-3-carboxamide phenpropimorph 2-(difluoromethyl)-N-(1,1-dimethyl-3-fluazinam propyl-indan-4-yl)pyridine-3 - carboxamide fenpropimorph 2-(difluoromethyl)-N-(1,1-dimethyl-3-methyram propyl-indan-4-yl)pyridine-3-carboxamide fenpropimorph 2-(difluoromethyl)-N-(1,1-dimethyl- 3-dithianone propyl-indan-4-yl)pyridine-3-carboxamide Compound I Compound II Compound III fenpropimorph 2-(difluoromethyl)-N-(1,1-dimethyl-3-propineb-propyl-indan-4-yl)pyridine-3-carboxamide fenpropimorph inpirfluxam N'-(2,5-dimethyl- 4-phenoxy-phenyl)-N-ethyl-N-methyl-formamidine fenpropimorph inpirfluxam N'-[4-[[3-[(4-chlorophenyl)methyl]-1,2,4-thiadiazol-5-yl]oxy ]-2,5-dimethyl-phenyl]-N-ethyl-N-methyl-formamidine fenpropimorph bixafen N'-(2,5-dimethyl-4-phenoxy-phenyl)-N-ethyl-N-methyl-formamidine fenpropimorph bixafen N'-[4-[[3-[(4-chlorophenyl)methyl]-1,2,4-thiadiazol-5-yl]oxy]-2,5-dimethyl-phenyl]-N-ethyl-N-methyl -formamidine fenpropimorph pidiflumetophem N'-[5-bromo-2-methyl-6-(1-methyl-2-propoxy-ethoxy)-3-pyridyl]-N-ethyl-N-methyl-formamidine fenpropimorph benzovindiflupyr florylpicoxamide fenpropimorph benzovindiflupyr N '-[5-bromo-2-methyl-6-(1-methyl-2-propoxy-ethoxy)-3-pyridyl]-N-ethyl-N-methyl-formamidine fenpropimorph fluxapyroxad florylpicoxamide fenpropimorph fluxapyroxad N'-(2, 5-dimethyl-4-phenoxy-phenyl)-N-ethyl-N-methyl-formamidine fenpropimorph iso flucipram N'-(2,5-dimethyl-4-phenoxy-phenyl)-N-ethyl-N-methyl-formamidine fenpropimorph isoflucipram N'-[4-[[3-[(4-chlorophenyl)methyl]-1, 2,4-thiadiazol-5-yl]oxy]-2,5-dimethyl-phenyl]-N-ethyl-N-methyl-formamidine fenpropimorph sedaxane N'-(2,5-dimethyl-4-phenoxy-phenyl)- N-ethyl-N-methyl-formamidine phenpropimorph 2-(difluoromethyl)-N-(1,1,3-N'-(2,5-dimethyl-4-phenoxy-phenyl)-N-ethyl-N-trimethylindan- 4-yl)pyridin-3-methyl-formamidine carboxamide fenpropimorph 2-(difluoromethyl)-N-(1,1,3-N'-[4-[[3-[(4-chlorophenyl)methyl]-1,2 ,4-trimethylindan-4-yl)pyridin-3-thiadiazol-5-yl]oxy]-2,5-dimethyl-phenyl]-N-carboxamide ethyl-N-methyl-formamidine fenpropimorph 2-(difluoromethyl)-N- [(3R)-1,1,3-N'-(2,5-dimethyl-4-phenoxy-phenyl)-N-ethyl-N-trimethylindan-4-yl]pyridin-3-methyl-formamidine carboxamide fenpropimorph 2 -(difluoromethyl)-N-[(3R)-1,1,3-N'-[4-[[3-[(4-chlorophenyl)methyl]-1,2,4-trimethylindan-4-yl]pyridine -3-thiadiazol-5-yl]oxy]-2,5-dimethyl-phenyl]-N-carboxamide ethyl-N-methyl-formamidine fenpropimorph 2-(difluoromethyl)- N-(3-ethyl-1,1-N'-(2,5-dimethyl-4-phenoxy-phenyl)-N-ethyl-N-dimethyl-indan-4-yl)pyridine-3-methyl-formamidine carboxamide Compound I Compound II Compound III fenpropimorph 2-(difluoromethyl)-N-(3-ethyl-1,1-N'-[4-[[3-[(4-chlorophenyl)methyl]-1,2,4-dimethyl -indan-4-yl)pyridin-3-thiadiazol-5-yl]oxy]-2,5-dimethyl-phenyl]-N-carboxamide ethyl-N-methyl-formamidine fenpropimorph 2-(difluoromethyl)-N-[( 3R)-3-ethyl-1,1-N'-(2,5-dimethyl-4-phenoxy-phenyl)-N-ethyl-N-dimethyl-indan-4-yl]pyridine-3-methyl-formamidine carboxamide fenpropimorph 2-(difluoromethyl)-N-[(3R)-3-ethyl-1,1-N'-[4-[[3-[(4-chlorophenyl)methyl]-1,2,4-dimethyl-indan -4-yl]pyridin-3-thiadiazol-5-yl]oxy]-2,5-dimethyl-phenyl]-N-carboxamide ethyl-N-methyl-formamidine fenpropimorph 2-(difluoromethyl)-N-(1,1 -dimethyl-3-N'-(2,5-dimethyl-4-phenoxy-phenyl)-N-ethyl-N-propyl-indan-4-yl)pyridin-3-methyl-formamidine carboxamide fenpropimorph 2-(difluoromethyl) -N-(1,1-dimethyl-3-N'-[4-[[3-[(4-chlorophenyl)methyl]-1,2,4-propyl-indan-4-yl)pyridine-3-thiadiazole -5-yl]oxy]-2,5-dimethyl-phenyl]-N-carboxamide ethyl-N-methyl-formamidine fenpropimorph 2-(difluoromethyl)-N-[(3R)-1,1-dimethyl-N'- (2.5-d imethyl-4-phenoxy-phenyl)-N-ethyl-N-3-propyl-indan-4-yl]pyridin-3-methyl-formamidine carboxamide fenpropimorph 2-(difluoromethyl)-N-[(3R)-1,1 -dimethyl-N'-[4-[[3-[(4-chlorophenyl)methyl]-1,2,4-3-propyl-indan-4-yl]pyridin-3-thiadiazol-5-yl]oxy] -2,5-dimethyl-phenyl]-N-carboxamide ethyl-N-methyl-formamidine fenpropimorph 2-(difluoromethyl)-N-(3-isobutyl-1,1-N'-(2,5-dimethyl-4- phenoxy-phenyl)-N-ethyl-N-dimethyl-indan-4-yl)pyridin-3-methyl-formamidine carboxamide phenpropimorph 2-(difluoromethyl)-N-(3-isobutyl-1,1-N'-[4] -[[3-[(4-chlorophenyl)methyl]-1,2,4-dimethyl-indan-4-yl)pyridin-3-thiadiazol-5-yl]oxy]-2,5-dimethyl-phenyl]- N-carboxamide ethyl-N-methyl-formamidine phenpropimorph 2-(difluoromethyl)-N-[(3R)-3-isobutyl-N'-(2,5-dimethyl-4-phenoxy-phenyl)-N-ethyl-N - 1,1-dimethyl-indan-4-yl]pyridin-3-methyl-formamidine carboxamide fenpropimorph 2-(difluoromethyl)-N-[(3R)-3-isobutyl-N'-[4-[[3-[ (4-chlorophenyl)methyl]-1,2,4-1,1-dimethyl-indan-4-yl]pyridin-3-thiadiazol-5-yl]oxy]-2,5-dimethyl-phenyl]-N- ethyl-N-me carboxamide til formamidine 4. MIXTURE according to any one of claims 1 to 3, characterized in that it is selected from: Compound I Compound II Compound III fenpropimorph inpirfluxam copper oxychloride fenpropimorph inpirfluxam fluazinam fenpropimorph fluxapyroxad copper oxychloride phenpropimorph 2-(difluoromethyl)-N -(1,1-dimethyl-3-chlorothalonyl propyl-indan-4-yl)pyridine-3-carboxamide fenpropimorph 2-(difluoromethyl)-N-(1,1-dimethyl-3-mancozeb propyl-indan-4-yl )pyridine-3-carboxamide Compound I Compound II Compound III fenpropimorph inpyrfluxam N'-(2,5-dimethyl-4-phenoxy-phenyl)-N-ethyl-N-methyl-formamidine fenpropimorph bixafen N'-(2,5-dimethyl-4-phenoxy- phenyl)-N-ethyl-N-methyl-formamidine phenpropimorph pidiflumetophem N'-[5-bromo-2-methyl-6-(1-methyl-2-propoxy-ethoxy)-3-pyridyl]-N-ethyl-N - methyl-formamidine phenpropimorph benzovindiflupyr florylpicoxamide fenpropimorph benzovindiflupyr N'-[5-bromo-2-methyl-6-(1-methyl-2-propoxy-ethoxy)-3-pyridyl]-N-ethyl-N-methyl-formamidine phenpropimorph fluxapyroxad florylpicoxamide fenpropimorph fluxapyroxade N'-(2,5-dimethyl-4-phenoxy-phenyl)-N-ethyl-N-methyl-formamidine fenpropimorph isoflucipram N'-(2,5-dimethyl-4-phenoxy-phenyl)-N -ethyl-N-methyl-formamidine fenpropimorph sedaxane N'-(2,5-dimethyl-4-phenoxy-phenyl)-N-ethyl-N-methyl-formamidine fenpropimorph 2-(difluoromethyl)-N-(1,1, 3-N'-(2,5-dimethyl-4-phenoxy-phenyl)-N-ethyl-trimethylindan-4-yl)pyridin-3-N-methyl-formamidine carboxamide fenpropimorph 2-(difluoromethyl)-N-[( 3R)-1,1,3-N'-(2,5-dimethyl-4 -phenoxy-phenyl)-N-ethyl-trimethylindan-4-yl]pyridin-3-N-methyl-formamidine carboxamide fenpropimorph 2-(difluoromethyl)-N-(3-ethyl-1,1-dimethyl-N'-( 2,5-dimethyl-4-phenoxy-phenyl)-N-ethyl-indan-4-yl)pyridine-3-carboxamide N-methyl-formamidine phenpropimorph 2-(difluoromethyl)-N-[(3R)-3-ethyl -1,1- N'-(2,5-dimethyl-4-phenoxy-phenyl)-N-ethyl-dimethyl-indan-4-yl]pyridin-3-N-methyl-formamidine carboxamide fenpropimorph 2-(difluoromethyl) -N-(1,1-dimethyl-3-N'-(2,5-dimethyl-4-phenoxy-phenyl)-N-ethyl-propyl-indan-4-yl)pyridin-3-N-methyl-formamidine carboxamide phenpropimorph 2-(difluoromethyl)-N-[(3R)-1,1-dimethyl-N'-(2,5-dimethyl-4-phenoxy-phenyl)-N-ethyl-3-propyl-indan-4- yl]pyridine-3-N-methyl-formamidine carboxamide phenpropimorph 2-(difluoromethyl)-N-(3-isobutyl-1,1-N'-(2,5-dimethyl-4-phenoxy-phenyl)-N-ethyl - dimethyl-indan-4-yl)pyridine-3-N-methyl-formamidine carboxamide phenpropimorph 2-(difluoromethyl)-N-[(3R)-3-isobutyl-N'-(2,5-dimethyl-4-phenoxy -phenyl)-N-ethyl-1,1-dimethyl-indan-4-yl]pyridin-3-N-methyl-formamidine carboxamide 5. MIXTURE, according to any one of the claims 1 to 4, characterized in that it is selected from: Compound I Compound II Compound III fenpropimorph inpirfluxam N'-(2,5-dimethyl-4-phenoxy-phenyl)-N-ethyl-N-methyl-formamidine fenpropimorph bixafen N' -(2,5-dimethyl-4-phenoxy-phenyl)-N-ethyl-N-methyl-formamidine fenpropimorph benzovindiflupyr florylpicoxamide fenpropimorph fluxapyroxad florylpicoxamide fenpropimorph isoflucipram N'-(2,5-dimethyl-4-phenoxy-phenyl)-N -ethyl-N-methyl-formamidine phenpropimorph 2-(difluoromethyl)-N-(1,1-dimethyl-3-N'-(2,5-dimethyl-4-phenoxy-phenyl)-N-ethyl-N-propyl -indan-4-yl)pyridine-3-methyl-formamidine carboxamide 6. MIXTURE according to any one of claims 1 to 5, characterized in that it is: Compound I Compound II Compound III fenpropimorph 2-(difluoromethyl)-N-(1,1-dimethyl-3-N'-(2,5) -dimethyl-4-phenoxy-phenyl)-N-ethyl-propyl-indan-4-yl)pyridin-3-N-methyl-formamidine carboxamide 7. PESTICIDE COMPOSITION, characterized in that it comprises a liquid or solid carrier and a mixture as defined in any one of claims 1 to 6. 8. USE OF THE MIXTURE, as defined in any one of claims 1 to 6, or of the pesticidal composition as defined in claim 7, characterized in that it is to control harmful phytopathogenic fungi. 9. USE, according to claim 8, characterized in that it is for controlling harmful phytopathogenic fungi in soybeans. 10. USE according to any one of claims 8 and 9, for controlling Phakopsora pachyrhizi and P. meibomiae (soybean rust). 11. METHOD TO CONTROL PHYTOPATOGENIC PESTS, characterized by the pest, its habitat, its breeding sites, its sites or the plants that will be protected against the attack of said pests, the soil or plant propagation material being treated with an effective amount of the mixture as defined in any one of claims 1 to 6. 12. METHOD, according to claim 11, characterized in that the mixture as defined in any one of claims 1 to 5 is applied in an amount of 0.01 g to 10 kg per 100 kg of plant propagation material. 13. METHOD according to any one of claims 11 to 12, characterized in that the mixture as defined in any one of claims 1 to 6 is applied simultaneously, jointly or separately, or successively.