[go: up one dir, main page]

BR112018012155A2 - revestimento antibioincrustação baseado em resina epóxi e polissiloxano amina-funcional - Google Patents

revestimento antibioincrustação baseado em resina epóxi e polissiloxano amina-funcional

Info

Publication number
BR112018012155A2
BR112018012155A2 BR112018012155-0A BR112018012155A BR112018012155A2 BR 112018012155 A2 BR112018012155 A2 BR 112018012155A2 BR 112018012155 A BR112018012155 A BR 112018012155A BR 112018012155 A2 BR112018012155 A2 BR 112018012155A2
Authority
BR
Brazil
Prior art keywords
amine
epoxy resin
coating
fouling
contact angle
Prior art date
Application number
BR112018012155-0A
Other languages
English (en)
Inventor
Huang Yan
Chen Hongyu
Cao Xinyu
Zhang Yu
J. Popa Paul
Lin Yuteng
A. Roper John
A. Vandezande Gerald
Original Assignee
Dow Global Technologies Llc
Rohm And Haas Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Llc, Rohm And Haas Company filed Critical Dow Global Technologies Llc
Publication of BR112018012155A2 publication Critical patent/BR112018012155A2/pt

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/24Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/14Polycondensates modified by chemical after-treatment
    • C08G59/1494Polycondensates modified by chemical after-treatment followed by a further chemical treatment thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/4007Curing agents not provided for by the groups C08G59/42 - C08G59/66
    • C08G59/4085Curing agents not provided for by the groups C08G59/42 - C08G59/66 silicon containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50Amines
    • C08G59/504Amines containing an atom other than nitrogen belonging to the amine group, carbon and hydrogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50Amines
    • C08G59/56Amines together with other curing agents
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/66Mercaptans
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04Polysiloxanes
    • C08G77/22Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
    • C08G77/26Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen nitrogen-containing groups
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1606Antifouling paints; Underwater paints characterised by the anti-fouling agent
    • C09D5/1637Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1656Antifouling paints; Underwater paints characterised by the film-forming substance
    • C09D5/1662Synthetic film-forming substance
    • C09D5/1675Polyorganosiloxane-containing compositions
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Paints Or Removers (AREA)
  • Epoxy Resins (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

composições de revestimento curáveis para prevenir a bioincrustação incluem a) pelo menos uma resina epóxi; b) pelo menos um polímero de poli(dialquilssiloxano)amina-funcional numa quantidade de 1 a 70% com base nos pesos combinados dos componentes a) e b); e c) pelo menos um agente de cura epóxi de alquileno poliamina, polialquileno poliamina ou polimercaptano; em que os componentes b) e c) proporcionam em conjunto cerca de 0,75 a 1,5 equivalentes de átomos de nitrogênio de amina e/ou grupos tiol por equivalente de grupos epóxi proporcionados pelo componente a). quando curado para formar um revestimento anti-incrustação, o revestimento exibe um ângulo de contato com a água de pelo menos 100° medido utilizando um medidor de ângulo de contato ótico a 22°c. a composição de revestimento adere bem a muitos substratos, fornece boa proteção anticorrosiva e é uma medida anti-bioincrustação eficaz.
BR112018012155-0A 2015-12-30 2015-12-30 revestimento antibioincrustação baseado em resina epóxi e polissiloxano amina-funcional BR112018012155A2 (pt)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/CN2015/099767 WO2017113149A1 (en) 2015-12-30 2015-12-30 Anti-biofouling coating based on epoxy resin and amine-functional polysiloxane

Publications (1)

Publication Number Publication Date
BR112018012155A2 true BR112018012155A2 (pt) 2018-11-27

Family

ID=59224192

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112018012155-0A BR112018012155A2 (pt) 2015-12-30 2015-12-30 revestimento antibioincrustação baseado em resina epóxi e polissiloxano amina-funcional

Country Status (8)

Country Link
US (1) US20180355189A1 (pt)
EP (1) EP3397706A4 (pt)
JP (1) JP6681988B2 (pt)
KR (1) KR20180098575A (pt)
CN (1) CN108431149B (pt)
BR (1) BR112018012155A2 (pt)
CA (1) CA3009958A1 (pt)
WO (1) WO2017113149A1 (pt)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20210005862A (ko) * 2018-04-27 2021-01-15 다우 글로벌 테크놀로지스 엘엘씨 폴리실록산 수지 조성물
US11802204B2 (en) 2018-08-10 2023-10-31 Board Of Trustees Of Michigan State University Thermoset omniphobic compositions with improved barrier properties, related articles, and related methods
CN112703230A (zh) * 2018-10-12 2021-04-23 湛新奥地利有限公司 具有改善的防腐性的双包装环氧涂料
WO2020139639A1 (en) * 2018-12-26 2020-07-02 Momentive Performance Materials Inc. Curable silicone-based compositions and applications thereof cross reference to related applications
US11135617B2 (en) 2019-02-13 2021-10-05 Board Of Trustees Of Michigan State University Omniphobically coated fluid channels and related methods
EP4069766A1 (en) * 2019-12-05 2022-10-12 Dow Global Technologies LLC Weatherable and durable coating compositions
US11459482B2 (en) 2020-06-19 2022-10-04 Pall Corporation Icephobic coating and coated articles
US11427714B2 (en) 2020-11-02 2022-08-30 Innovative HVAC Products LLC Antifouling coating and device for a condensate drain pipe and associated methods
CN112500787B (zh) * 2020-11-18 2021-10-15 吉林大学 一种多层结构仿生荧光防污抗冲蚀涂层及其制备方法
CN112760015B (zh) * 2021-01-27 2021-12-14 江苏朝晖化工有限公司 一种铜铝冷凝管涂料及其使用方法
CN113980354B (zh) * 2021-12-06 2023-07-04 湖南航天三丰科工有限公司 一种建筑铝合金模板涂料用改性纳米SiO2、氟硅改性涂料及其制备方法和应用
CN114539884A (zh) * 2022-04-08 2022-05-27 江西理工大学 复合超润滑涂层材料及其制备方法和复合超润滑涂层和应用
CN116716008B (zh) * 2023-06-01 2024-04-26 北京印刷学院 一种防污涂料及其制备方法和使用方法、防污涂层的应用
CN116875190B (zh) * 2023-07-10 2024-05-24 信和新材料股份有限公司 一种弹性有机硅面漆连接涂层及其制备方法和应用
CN118725693A (zh) * 2024-07-12 2024-10-01 山东皓尊生物科技有限公司 一种机械性能灵活调控的透明无氟光滑防污涂层的制备方法

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH021774A (ja) * 1988-06-09 1990-01-08 Nitto Denko Corp 湿潤面施工用防汚塗料組成物
JP2815452B2 (ja) * 1990-02-27 1998-10-27 関西ペイント株式会社 シリコーン系防汚塗料用下塗塗料組成物及び防汚塗膜形成方法
JPH10251598A (ja) * 1997-03-17 1998-09-22 Toyo Ink Mfg Co Ltd 硬化性樹脂組成物
JP2002212488A (ja) * 2001-01-23 2002-07-31 Nippon Paint Co Ltd 架橋樹脂粒子を含有するカチオン電着塗料組成物
WO2005010115A1 (en) * 2003-07-16 2005-02-03 Dow Corning Corporation Coating compositions comprising epoxy resins and aminofunctional silicone resins
JP4858149B2 (ja) * 2005-12-16 2012-01-18 三菱瓦斯化学株式会社 エポキシ樹脂用硬化剤組成物及びエポキシ樹脂組成物
MY143579A (en) * 2006-02-17 2011-05-31 Chugoku Marine Paints Curable organopolysiloxane composition and antifouling composite coating film
WO2009021989A1 (de) * 2007-08-14 2009-02-19 Momentive Performance Materials Gmbh Neue polyharnstoff- und/oder polyurethan-polyorganosiloxan-verbindungen
CN101434805A (zh) * 2008-12-08 2009-05-20 中国船舶重工集团公司第七二五研究所 一种自分层低表面能防污涂料
CN102757728A (zh) * 2011-04-25 2012-10-31 陶氏环球技术有限公司 湿气固化防污涂料组合物
CN102964974A (zh) * 2011-04-25 2013-03-13 陶氏环球技术有限公司 湿气固化防污涂料组合物
DE102012202389A1 (de) * 2012-02-16 2013-08-22 Wacker Chemie Ag Hydrophobiermittel für Beschichtungen
KR102221253B1 (ko) * 2013-02-15 2021-03-02 모멘티브 퍼포먼스 머티리얼즈 인크. 실리콘 하이드로겔을 포함하는 파울링 방지 시스템
CN104312398B (zh) * 2014-10-22 2016-08-17 武汉长江科创科技发展有限公司 聚脲-聚硅氧烷有机无机杂化混凝土生物污染防护材料及其制备方法

Also Published As

Publication number Publication date
KR20180098575A (ko) 2018-09-04
EP3397706A4 (en) 2019-09-04
JP2019503410A (ja) 2019-02-07
JP6681988B2 (ja) 2020-04-28
WO2017113149A1 (en) 2017-07-06
EP3397706A1 (en) 2018-11-07
US20180355189A1 (en) 2018-12-13
CN108431149A (zh) 2018-08-21
CN108431149B (zh) 2020-11-20
CA3009958A1 (en) 2017-06-07

Similar Documents

Publication Publication Date Title
BR112018012155A2 (pt) revestimento antibioincrustação baseado em resina epóxi e polissiloxano amina-funcional
BR112016024139A2 (pt) método para a provisão de uma superfície metálica ou concreta de uma instalação química com um revestimento, instalação química, e composição de revestimento adequada para a provisão de uma superfície metálica ou concreta de uma instalação química com um revestimento
BR112012032202A2 (pt) formulação de revestimento para a preparação de um revestimento hidrofílico.
BR112017012816A2 (pt) agente de cura para revestimentos epóxi, e, formulação de revestimento.
BRPI0516696A (pt) composição de revestimento com alto teor de sólidos de cura ambiente, processo para preparar uma composição de revestimento com alto teor de sólidos de cura ambiente, processo para preparar um substrato revestido e artigo revestido
MX2021013209A (es) Composicion de dos componentes con un alto grado de resistencia.
BR112017006267A2 (pt) composição de revestimento, método para revestir um substrato, uso de uma composição de revestimento, e, substrato revestido.
ES2531144T3 (es) Composiciones curables a base de resinas epoxídicas sin alcohol bencílico
BR112018003401A2 (pt) adesivos de epóxi endurecidos de um componente com adesão melhorada a superfícies oleosas e alta resistência à lavagem
BR112017006751A2 (pt) método para tratar uma formação subterrânea e composição curável para tratamento de uma formação subterrânea
BR112017023722A2 (pt) composição formadora de película curável, substrato revestido e método para revestir um substrato
BR112017015236A2 (pt) adesivos curáveis em baixa temperatura e uso dos mesmos
BR112018016525A2 (pt) película líquida de baixa emissão para vedação de edifícios
BR112015019199A2 (pt) composição de revestimento de polímero de epóxi-polissiloxano, substrato revestido e método para proteger uma superfície de um substrato de efeitos indesejados de um ou mais de substâncias químicas, corrosão e intempéries
BR112017011030A2 (pt) composição sol-gel formadora de película curável, artigo revestido e método para formar um revestimento anti-brilho sobre um substrato
AR112827A1 (es) Composiciones para recubrimiento, recubrimientos de barrera elásticos formados a partir de ellas y métodos de aplicación de dichos recubrimientos
MX378669B (es) Recubrimiento protector transparente reversible con agua para los sustratos.
BR112019006982A2 (pt) composição de resina epóxi e estrutura
BR112015020062A2 (pt) formulação de adesivo de ligação de metal galvanizado e processo para o uso desta
BR112021026178A2 (pt) Uso de composições de revestimento para pás de turbina eólica
BR112013016067A2 (pt) "composição reticulável e/ou endurecível, composição e elastómero de silicone, uso da composição de silicone, suporte sólido revestido e processo de revestimento sobre um suporte flexível"
MX368297B (es) Composicion curable formadora de pelicula que demuestra resistencia a pulido y poco brillo.
BR112018071255A2 (pt) composição, vedante curado, peça e método para vedar uma peça
BR112015030059A2 (pt) composição de revestimento em pó, uso da composição de revestimento em pó, e substrato revestido com uma camada curada da composição
BR112014016778A2 (pt) composição de revestimento curável na temperatura ambiente; método de revestimento de um substrato; e substrato revestido

Legal Events

Date Code Title Description
B06U Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]
B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B09B Patent application refused [chapter 9.2 patent gazette]
B09B Patent application refused [chapter 9.2 patent gazette]

Free format text: MANTIDO O INDEFERIMENTO UMA VEZ QUE NAO FOI APRESENTADO RECURSO DENTRO DO PRAZO LEGAL.MANTIDO O INDEFERIMENTO UMA VEZ QUE NAO FOI APRESENTADO RECURSO DENTRO DO PRAZO LEGAL.