BR102023006165A2 - OXIDIZING ACID COMPOSITION FOR DISINFECTION OF SURFACES - Google Patents
OXIDIZING ACID COMPOSITION FOR DISINFECTION OF SURFACES Download PDFInfo
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- BR102023006165A2 BR102023006165A2 BR102023006165-6A BR102023006165A BR102023006165A2 BR 102023006165 A2 BR102023006165 A2 BR 102023006165A2 BR 102023006165 A BR102023006165 A BR 102023006165A BR 102023006165 A2 BR102023006165 A2 BR 102023006165A2
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- Prior art keywords
- sodium
- acid composition
- disinfecting surfaces
- composition
- oxidizing
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- 239000000203 mixture Substances 0.000 title claims abstract description 20
- 239000002253 acid Substances 0.000 title claims abstract description 15
- 230000001590 oxidative effect Effects 0.000 title claims abstract description 11
- 238000004659 sterilization and disinfection Methods 0.000 title description 6
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 8
- 150000004965 peroxy acids Chemical class 0.000 claims abstract description 8
- 239000004094 surface-active agent Substances 0.000 claims abstract description 4
- 150000007524 organic acids Chemical class 0.000 claims abstract description 3
- 235000005985 organic acids Nutrition 0.000 claims abstract description 3
- 230000000249 desinfective effect Effects 0.000 claims abstract 6
- 150000007513 acids Chemical class 0.000 claims description 4
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 3
- 239000003945 anionic surfactant Substances 0.000 claims description 3
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 claims 1
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 claims 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 235000019820 disodium diphosphate Nutrition 0.000 claims 1
- GYQBBRRVRKFJRG-UHFFFAOYSA-L disodium pyrophosphate Chemical compound [Na+].[Na+].OP([O-])(=O)OP(O)([O-])=O GYQBBRRVRKFJRG-UHFFFAOYSA-L 0.000 claims 1
- SMVRDGHCVNAOIN-UHFFFAOYSA-L disodium;1-dodecoxydodecane;sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC SMVRDGHCVNAOIN-UHFFFAOYSA-L 0.000 claims 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims 1
- 229960001484 edetic acid Drugs 0.000 claims 1
- GWBBVOVXJZATQQ-UHFFFAOYSA-L etidronate disodium Chemical compound [Na+].[Na+].OP(=O)([O-])C(O)(C)P(O)([O-])=O GWBBVOVXJZATQQ-UHFFFAOYSA-L 0.000 claims 1
- MNWFXJYAOYHMED-UHFFFAOYSA-N heptanoic acid group Chemical group C(CCCCCC)(=O)O MNWFXJYAOYHMED-UHFFFAOYSA-N 0.000 claims 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid group Chemical group C(CCCCC)(=O)O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims 1
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N pentanoic acid group Chemical group C(CCCC)(=O)O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 claims 1
- 229940096992 potassium oleate Drugs 0.000 claims 1
- 229940114930 potassium stearate Drugs 0.000 claims 1
- MLICVSDCCDDWMD-KVVVOXFISA-M potassium;(z)-octadec-9-enoate Chemical compound [K+].CCCCCCCC\C=C/CCCCCCCC([O-])=O MLICVSDCCDDWMD-KVVVOXFISA-M 0.000 claims 1
- ANBFRLKBEIFNQU-UHFFFAOYSA-M potassium;octadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCCCC([O-])=O ANBFRLKBEIFNQU-UHFFFAOYSA-M 0.000 claims 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 claims 1
- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical compound [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 claims 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims 1
- 235000012207 sodium gluconate Nutrition 0.000 claims 1
- 229940005574 sodium gluconate Drugs 0.000 claims 1
- 239000000176 sodium gluconate Substances 0.000 claims 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims 1
- 230000000087 stabilizing effect Effects 0.000 claims 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 claims 1
- 238000009472 formulation Methods 0.000 abstract description 4
- 235000013361 beverage Nutrition 0.000 abstract description 2
- 238000003860 storage Methods 0.000 abstract description 2
- 230000006378 damage Effects 0.000 abstract 1
- 239000003651 drinking water Substances 0.000 abstract 1
- 235000020188 drinking water Nutrition 0.000 abstract 1
- 230000000415 inactivating effect Effects 0.000 abstract 1
- 244000000010 microbial pathogen Species 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 239000002738 chelating agent Substances 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 150000002978 peroxides Chemical class 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 2
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 2
- 241000233866 Fungi Species 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 230000003115 biocidal effect Effects 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 239000000645 desinfectant Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 125000002081 peroxide group Chemical group 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 1
- 241000192125 Firmicutes Species 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000002599 biostatic effect Effects 0.000 description 1
- 210000000234 capsid Anatomy 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 210000000170 cell membrane Anatomy 0.000 description 1
- 210000002421 cell wall Anatomy 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- -1 from 6 carbons Chemical class 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 239000000174 gluconic acid Substances 0.000 description 1
- 235000012208 gluconic acid Nutrition 0.000 description 1
- 210000005061 intracellular organelle Anatomy 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 125000005473 octanoic acid group Chemical class 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 150000003009 phosphonic acids Chemical class 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/02—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
Abstract
Refere-se a Patente de Invenção da “COMPOSIÇÃO ÁCIDA OXIDANTE PARA DESINFECÇÃO DE SUPERFÍCIES”, a qual relata formulação para inativação ou morte de microrganismos patogênicos em amplo espectro a níveis muito seguros usando o produto a concentrações bastante baixas. A combinação e sinergia de ácidos e perácidos orgânicos na presença de pelo menos um tensoativo e pelo menos um estabilizante do tipo quelante confere à solução eficiência e eficácia por longos períodos de estocagem. A composição, a qual inclui ainda peróxido de hidrogênio em equilíbrio, é indicada para indústrias de alimentos e bebidas e pode ser dissolvida em água potável a uma concentração mínima de 0,2%, apresentando potencial para a destruição de esporos.Refers to the Invention Patent of the “OXIDIZING ACID COMPOSITION FOR DISINFECTING SURFACES”, which reports a formulation for inactivating or killing pathogenic microorganisms in a broad spectrum at very safe levels using the product at very low concentrations. The combination and synergy of organic acids and peracids in the presence of at least one surfactant and at least one chelating stabilizer gives the solution efficiency and effectiveness for long storage periods. The composition, which also includes hydrogen peroxide in equilibrium, is indicated for food and beverage industries and can be dissolved in drinking water at a minimum concentration of 0.2%, presenting potential for the destruction of spores.
Description
[001] A presente invenção refere-se a uma mistura líquida para eliminação de bactérias gram-negativas e gram-positivas, vírus, fungos, leveduras e alguns tipos de esporos em superfícies em geral, como tubulações, enchedoras, silos, banhos germicidas, aquecedores de placas, tanques de estocagem, tanques de transporte e em sistemas CIP.[001] The present invention relates to a liquid mixture for eliminating gram-negative and gram-positive bacteria, viruses, fungi, yeasts and some types of spores on surfaces in general, such as pipes, fillers, silos, germicidal baths, plate heaters, storage tanks, transport tanks and in CIP systems.
[002] A preparação cuja principal função é bactericida inclui ácidos acético a octanoico, peróxido de hidrogênio, perácidos acético a octanoico, água, pelo menos um tensoativo aniônico e pelo menos um agente quelante.[002] The preparation whose main function is bactericidal includes acetic to octanoic acids, hydrogen peroxide, acetic to octanoic peracids, water, at least one anionic surfactant and at least one chelating agent.
[003] A ação desinfetante da “Composição Ácida Oxidante para Desinfecção de Superfícies” origina-se do potencial biocida e biostático de ácidos orgânicos, perácidos, peróxidos e tensoativos, os quais provocam a desestruturação de membranas e paredes celulares permitindo o acesso dos ativos às organelas intracelulares.[003] The disinfectant action of the “Oxidizing Acid Composition for Surface Disinfection” originates from the biocidal and biostatic potential of organic acids, peracids, peroxides and surfactants, which cause the destructuring of membranes and cell walls, allowing the active ingredients to access intracellular organelles.
[004] Os ácidos, peróxidos e perácidos desinfetantes necessitam ter acesso e permeabilidade sobre membranas, paredes celulares e capsídeos de bactérias, fungos e esporos. Para isso, sujidades devem ser removidas em sua quase totalidade previamente a um processo de desinfecção profundo. A “Composição Ácida Oxidante para Desinfecção de Superfícies” deve então ser aplicada, diluída, após rotinas de limpeza em fábricas de alimentos e bebidas.[004] Disinfectant acids, peroxides and peracids need to have access and permeability over membranes, cell walls and capsids of bacteria, fungi and spores. To this end, dirt must be removed in its almost totality prior to a deep disinfection process. The “Oxidizing Acid Composition for Surface Disinfection” must then be applied, diluted, after cleaning routines in food and beverage factories.
[005] A adição de tensoativos a uma composição contendo ácidos e perácidos de cadeias longas, principalmente a partir de 6 carbonos, permite a sua solubilização e espalhamento úmido sobre a superfície a ser desinfetada, sendo que os tensoativos aniônicos possuem maior poder de umectação em relação aos tensoativos não-iônicos. Já os tensoativos catiônicos não são interessantes para a “Composição Ácida Oxidante para Desinfecção de Superfícies” pois sua biodegradabilidade é extremamente baixa.[005] The addition of surfactants to a composition containing long-chain acids and peracids, mainly from 6 carbons, allows their solubilization and wet spreading over the surface to be disinfected, with anionic surfactants having greater wetting power compared to non-ionic surfactants. Cationic surfactants, on the other hand, are not interesting for the “Oxidizing Acid Composition for Surface Disinfection” because their biodegradability is extremely low.
[006] A composição possui mais de um tipo de fonte de oxigênio ativo entre peróxidos e perácidos pois apresentam diferentes velocidades de reação ou decomposição em água e ácidos. Isto permite que o produto tenha ativos tanto de ação rápida como de ação mais lenta na sua aplicação, bem como o equilíbrio entre as espécies permite maior estabilidade da formulação em estoque. Adicionalmente, perácidos de cadeias carbônicas maiores toleram temperaturas mais elevadas. Alguns modelos reacionais são mostrados a seguir: CH3COOOH ^ CH3COOH + I/2O2 (liberação de oxigênio ativo) H2O2 ^ H2O + 1/2O2 (liberação de oxigênio ativo) RCO2H + H2O2 ^ RCO3H + H2O (manutenção de oxigênio ativo)[006] The composition has more than one type of active oxygen source among peroxides and peracids because they have different reaction or decomposition rates in water and acids. This allows the product to have both fast-acting and slower-acting actives in its application, as well as the balance between the species allows greater stability of the formulation in stock. Additionally, peracids with longer carbon chains tolerate higher temperatures. Some reaction models are shown below: CH3COOOH ^ CH3COOH + I/2O2 (release of active oxygen) H2O2 ^ H2O + 1/2O2 (release of active oxygen) RCO2H + H2O2 ^ RCO3H + H2O (maintenance of active oxygen)
[007] É sabido que a presença de metais de transição interna aceleram a velocidade de decomposição de grupos peróxido (-O-O-), a exemplo de ferro, cromo, cobre, manganês, níquel e zinco. Por isso faz-se necessária a adição de quelantes à composição, prevenindo contra possíveis variações da qualidade da água, garantindo a estabilidade da formulação bem como uma ação mais consistente quando da sua aplicação diluída.[007] It is known that the presence of internal transition metals accelerates the decomposition rate of peroxide groups (-O-O-), such as iron, chromium, copper, manganese, nickel and zinc. Therefore, it is necessary to add chelating agents to the composition, preventing possible variations in water quality, ensuring the stability of the formulation as well as a more consistent action when applied diluted.
[008] De maneira geral, os diferentes tipos de quelantes são ricos em oxigênios capazes de doar densidade eletrônica aos metais. Entre os agentes quelantes mais utilizados para formulações contendo grupos peróxido em solução estão os polifosfatos, ácidos fosfônicos e seus sais de sódio, a depender do pH de aplicação. Contudo, uma vez que diferentes tipos de quelantes possuem diferentes afinidades por metais de diferentes raios iônicos, faz-se interessante a inserção de quelantes de outra natureza, a exemplo do EDTA e seus sais de sódio, do ácido glucônico e seus sais de sódio.[008] In general, the different types of chelators are rich in oxygen capable of donating electron density to metals. Among the most commonly used chelating agents for formulations containing peroxide groups in solution are polyphosphates, phosphonic acids and their sodium salts, depending on the pH of application. However, since different types of chelators have different affinities for metals of different ionic radii, it is interesting to include chelators of another nature, such as EDTA and its sodium salts, gluconic acid and its sodium salts.
[009] Entre seus benefícios de uso, a “Composição Ácida Oxidante para Desinfecção de Superfícies” é eficiente e eficaz a concentrações tão baixas como 0,2% e sua ação biocida é tanto maior quanto melhor a qualidade da água utilizada. Recomendam-se períodos em torno de 10 minutos de contato e deve-se enxaguar a superfície ao final do tratamento. Além disso, seus resíduos de reação são inócuos, de baixas demandas química e bioquímica de oxigênio e altamente biodegradáveis, sem alterar as condições de operação de estações de tratamento de efluentes.[009] Among its benefits of use, the “Oxidizing Acid Composition for Surface Disinfection” is efficient and effective at concentrations as low as 0.2% and its biocidal action is greater the better the quality of the water used. Contact periods of around 10 minutes are recommended and the surface must be rinsed at the end of the treatment. In addition, its reaction residues are harmless, have low chemical and biochemical oxygen demands and are highly biodegradable, without altering the operating conditions of effluent treatment plants.
Claims (5)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR102023006165A2 true BR102023006165A2 (en) | 2024-10-08 |
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