BR0214697B1 - processo para produÇço de Ácidos (met)acrÍlicos. - Google Patents
processo para produÇço de Ácidos (met)acrÍlicos.Info
- Publication number
- BR0214697B1 BR0214697B1 BRPI0214697-5A BR0214697A BR0214697B1 BR 0214697 B1 BR0214697 B1 BR 0214697B1 BR 0214697 A BR0214697 A BR 0214697A BR 0214697 B1 BR0214697 B1 BR 0214697B1
- Authority
- BR
- Brazil
- Prior art keywords
- meth
- production
- acrylic acids
- acrylic
- acids
- Prior art date
Links
- 150000001253 acrylic acids Chemical class 0.000 title 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
- C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/14—Fractional distillation or use of a fractionation or rectification column
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/14—Fractional distillation or use of a fractionation or rectification column
- B01D3/16—Fractionating columns in which vapour bubbles through liquid
- B01D3/22—Fractionating columns in which vapour bubbles through liquid with horizontal sieve plates or grids; Construction of sieve plates or grids
- B01D3/225—Dual-flow sieve trays
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/14—Fractional distillation or use of a fractionation or rectification column
- B01D3/16—Fractionating columns in which vapour bubbles through liquid
- B01D3/24—Fractionating columns in which vapour bubbles through liquid with sloping plates or elements mounted stepwise
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/14—Fractional distillation or use of a fractionation or rectification column
- B01D3/32—Other features of fractionating columns ; Constructional details of fractionating columns not provided for in groups B01D3/16 - B01D3/30
- B01D3/322—Reboiler specifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J14/00—Chemical processes in general for reacting liquids with liquids; Apparatus specially adapted therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0053—Details of the reactor
- B01J19/006—Baffles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0053—Details of the reactor
- B01J19/0066—Stirrers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/18—Stationary reactors having moving elements inside
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
- B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
- B01J8/224—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement
- B01J8/228—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement externally, i.e. the particles leaving the vessel and subsequently re-entering it
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00265—Part of all of the reactants being heated or cooled outside the reactor while recycling
- B01J2208/00283—Part of all of the reactants being heated or cooled outside the reactor while recycling involving reactant liquids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00265—Part of all of the reactants being heated or cooled outside the reactor while recycling
- B01J2208/00292—Part of all of the reactants being heated or cooled outside the reactor while recycling involving reactant solids
- B01J2208/003—Part of all of the reactants being heated or cooled outside the reactor while recycling involving reactant solids involving reactant slurries
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00796—Details of the reactor or of the particulate material
- B01J2208/00823—Mixing elements
- B01J2208/00831—Stationary elements
- B01J2208/0084—Stationary elements inside the bed, e.g. baffles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00002—Chemical plants
- B01J2219/00004—Scale aspects
- B01J2219/00006—Large-scale industrial plants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
- B01J2219/00094—Jackets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00245—Avoiding undesirable reactions or side-effects
- B01J2219/00247—Fouling of the reactor or the process equipment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00245—Avoiding undesirable reactions or side-effects
- B01J2219/00252—Formation of deposits other than coke
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00761—Details of the reactor
- B01J2219/00763—Baffles
- B01J2219/00765—Baffles attached to the reactor wall
- B01J2219/0077—Baffles attached to the reactor wall inclined
- B01J2219/00774—Baffles attached to the reactor wall inclined in the form of cones
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Combustion & Propulsion (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BRBR122012016826-2A BR122012016826B1 (pt) | 2001-12-04 | 2002-12-04 | Método para decompor o subproduto formado durante a produção dos ácidos (met)acrílicos |
BRBR122012016827-0A BR122012016827B1 (pt) | 2001-12-04 | 2002-12-04 | Método para instalação de medidor de nível do líquido |
Applications Claiming Priority (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2001369636A JP4132799B2 (ja) | 2001-12-04 | 2001-12-04 | 液面計の設置方法 |
JP2001371608A JP4192465B2 (ja) | 2001-12-05 | 2001-12-05 | (メタ)アクリル酸類製造時の副生物の分解方法 |
JP2001385168 | 2001-12-18 | ||
JP2001392058 | 2001-12-25 | ||
JP2002141162 | 2002-05-16 | ||
JP2002141194 | 2002-05-16 | ||
PCT/JP2002/012709 WO2003048100A1 (fr) | 2001-12-04 | 2002-12-04 | Procede de production d'un compose d'acide (meth)acrylique |
Publications (2)
Publication Number | Publication Date |
---|---|
BR0214697A BR0214697A (pt) | 2004-09-14 |
BR0214697B1 true BR0214697B1 (pt) | 2013-02-05 |
Family
ID=27555026
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BRBR122012016827-0A BR122012016827B1 (pt) | 2001-12-04 | 2002-12-04 | Método para instalação de medidor de nível do líquido |
BRBR122012016826-2A BR122012016826B1 (pt) | 2001-12-04 | 2002-12-04 | Método para decompor o subproduto formado durante a produção dos ácidos (met)acrílicos |
BRPI0214697-5A BR0214697B1 (pt) | 2001-12-04 | 2002-12-04 | processo para produÇço de Ácidos (met)acrÍlicos. |
Family Applications Before (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BRBR122012016827-0A BR122012016827B1 (pt) | 2001-12-04 | 2002-12-04 | Método para instalação de medidor de nível do líquido |
BRBR122012016826-2A BR122012016826B1 (pt) | 2001-12-04 | 2002-12-04 | Método para decompor o subproduto formado durante a produção dos ácidos (met)acrílicos |
Country Status (7)
Country | Link |
---|---|
US (2) | US7348455B2 (pt) |
EP (4) | EP2311791B1 (pt) |
CN (6) | CN1260201C (pt) |
AU (1) | AU2002354084A1 (pt) |
BR (3) | BR122012016827B1 (pt) |
ES (4) | ES2552378T3 (pt) |
WO (1) | WO2003048100A1 (pt) |
Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102004008575A1 (de) * | 2004-02-19 | 2005-09-08 | Stockhausen Gmbh | Spaltung oligomerer (Meth)acrylsäure in flüssiger Phase unter Druck |
JP2005239636A (ja) * | 2004-02-26 | 2005-09-08 | Mitsubishi Chemicals Corp | 高粘性物質の取扱い方法 |
KR100714631B1 (ko) | 2004-04-29 | 2007-05-07 | 주식회사 엘지화학 | 아크릴산의 회수 방법 |
WO2006082224A1 (de) * | 2005-02-03 | 2006-08-10 | Basf Aktiengesellschaft | Verfahren zur entsorgung von bei der acrylsäureester- oder methacrylsäureester-herstellung anfallenden nebenkomponenten |
KR100932467B1 (ko) * | 2005-12-06 | 2009-12-17 | 니폰 쇼쿠바이 컴파니 리미티드 | 아크릴산의 제조방법 |
US20090134369A1 (en) | 2007-11-26 | 2009-05-28 | Applied Nanoworks, Inc. | Metal alkoxides, apparatus for manufacturing metal alkoxides, related methods and uses thereof |
DE102008054587A1 (de) * | 2008-12-12 | 2010-06-17 | Basf Se | Verfahren zur Rückspaltung von in einer Flüssigkeit F enthaltenen Michael-Addukten, die bei der Herstellung von Acrylsäure oder deren Ester gebildet wurde |
DE102009002861A1 (de) * | 2009-05-06 | 2010-11-18 | Evonik Röhm Gmbh | Verfahren und Anlage zur Aufreinigung von Monomeren |
WO2011000808A2 (de) | 2009-07-01 | 2011-01-06 | Basf Se | Verfahren der abtrennung von acrylsäure aus dem produktgasgemisch einer heterogen katalysierten partiellen gasphasenoxidation wenigstens einer c3-vorläuferverbindung |
DE102010001228A1 (de) | 2010-01-26 | 2011-02-17 | Basf Se | Verfahren der Abtrennung von Acrylsäure aus dem Produktgasgemisch einer heterogen katalysierten partiellen Gasphasenoxidation wenigstens einer C3-Vorläuferverbindung |
EP2471594A1 (de) * | 2010-12-29 | 2012-07-04 | LANXESS International SA | Reaktor und Verfahren zur kontinuierlichen Polymerisation |
CN103193617B (zh) * | 2013-03-25 | 2016-08-10 | 中国石油集团东北炼化工程有限公司吉林设计院 | 丙烷一步法制丙烯酸生产中的尾气循环工艺 |
CN105324163B (zh) * | 2013-06-28 | 2017-10-31 | 陶氏环球技术有限责任公司 | 用于制造化合物的防积垢蒸馏塔和方法 |
KR101984280B1 (ko) * | 2015-11-27 | 2019-05-30 | 주식회사 엘지화학 | (메트)아크릴산의 제조 방법 |
KR102662145B1 (ko) * | 2017-08-17 | 2024-04-29 | 바스프 에스이 | 아크릴산 n-부틸 에스테르 또는 아크릴산 이소부틸 에스테르를 연속적으로 제조하는 방법 |
FR3091871B1 (fr) * | 2019-01-22 | 2020-12-18 | Arkema France | Procede de purification d’esters (meth)acryliques a l’aide d’une colonne a partition |
CN109942424A (zh) * | 2019-04-19 | 2019-06-28 | 泰兴金江化学工业有限公司 | 一种丙烯酸正丁酯重组分回收工艺及装置 |
KR20220027726A (ko) * | 2019-06-28 | 2022-03-08 | 아사히 가세이 가부시키가이샤 | 메타크릴산메틸의 제조 방법 |
CN110372509A (zh) * | 2019-07-19 | 2019-10-25 | 江门谦信化工发展有限公司 | 一种丙烯酸正丁酯重组分的裂解回收工艺 |
CN110665450B (zh) * | 2019-09-30 | 2021-05-18 | 东营市科德化工有限公司 | 一种顺酐生产中轻组分脱除装置 |
CN111249761B (zh) * | 2020-03-04 | 2022-01-28 | 中国科学院上海应用物理研究所 | 一种熔盐蒸馏纯化方法及设备 |
US20240253007A1 (en) * | 2021-08-12 | 2024-08-01 | Lg Chem, Ltd. | Polymerization Reaction Device for High Viscosity Resin |
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US3868410A (en) | 1972-08-03 | 1975-02-25 | Celanese Corp | Conversion of oligomeric acrylates to acrylate monomers |
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IL105574A (en) | 1992-05-07 | 1996-05-14 | Great Lakes Aqua Sales Service | Method and device for storing and treating wastewater grout |
TW305830B (pt) | 1993-03-26 | 1997-05-21 | Sulzer Chemtech Ag | |
JPH0733804A (ja) | 1993-07-23 | 1995-02-03 | Mitsubishi Chem Corp | 吸水性樹脂の製造法 |
FR2727964B1 (fr) | 1994-12-12 | 1997-01-24 | Atochem Elf Sa | Procede de recuperation des produits nobles legers contenus dans les residus de distillation des procedes de fabrication de l'acide acrylique et de ses esters |
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DE69624451T2 (de) | 1995-07-04 | 2003-08-14 | Mitsubishi Rayon Co., Ltd. | Verfahren zur aufflockung von dienpolymerkautschuklatex unter erhöhung der partikelgrösse, pfropfpolymer und thermoplastische zusammensetzung |
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JP3938646B2 (ja) | 2000-01-14 | 2007-06-27 | 株式会社日本触媒 | アクリル酸の製造方法 |
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2002
- 2002-12-04 ES ES10190824.2T patent/ES2552378T3/es not_active Expired - Lifetime
- 2002-12-04 ES ES02786024T patent/ES2387564T3/es not_active Expired - Lifetime
- 2002-12-04 WO PCT/JP2002/012709 patent/WO2003048100A1/ja active Application Filing
- 2002-12-04 ES ES10190826T patent/ES2715315T3/es not_active Expired - Lifetime
- 2002-12-04 ES ES10190825.9T patent/ES2547412T3/es not_active Expired - Lifetime
- 2002-12-04 EP EP10190826.7A patent/EP2311791B1/en not_active Expired - Lifetime
- 2002-12-04 BR BRBR122012016827-0A patent/BR122012016827B1/pt active IP Right Grant
- 2002-12-04 EP EP10190825.9A patent/EP2311790B1/en not_active Expired - Lifetime
- 2002-12-04 AU AU2002354084A patent/AU2002354084A1/en not_active Abandoned
- 2002-12-04 CN CN200410069856.0A patent/CN1260201C/zh not_active Expired - Lifetime
- 2002-12-04 BR BRBR122012016826-2A patent/BR122012016826B1/pt active IP Right Grant
- 2002-12-04 CN CN200410069857.5A patent/CN1260202C/zh not_active Expired - Lifetime
- 2002-12-04 EP EP10190824.2A patent/EP2311789B1/en not_active Expired - Lifetime
- 2002-12-04 EP EP02786024A patent/EP1452518B1/en not_active Expired - Lifetime
- 2002-12-04 CN CN200410069853.7A patent/CN1247515C/zh not_active Expired - Lifetime
- 2002-12-04 CN CN200410069854.1A patent/CN1272304C/zh not_active Expired - Lifetime
- 2002-12-04 BR BRPI0214697-5A patent/BR0214697B1/pt active IP Right Grant
- 2002-12-04 CN CN200410069855.6A patent/CN1240662C/zh not_active Expired - Lifetime
- 2002-12-04 CN CNB028243188A patent/CN100494155C/zh not_active Expired - Lifetime
-
2004
- 2004-06-03 US US10/859,221 patent/US7348455B2/en not_active Expired - Lifetime
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2007
- 2007-02-13 US US11/674,247 patent/US20070129571A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
EP2311790A1 (en) | 2011-04-20 |
BR122012016826B1 (pt) | 2015-07-14 |
CN1572774A (zh) | 2005-02-02 |
EP2311791B1 (en) | 2019-01-23 |
CN1272304C (zh) | 2006-08-30 |
US7348455B2 (en) | 2008-03-25 |
CN100494155C (zh) | 2009-06-03 |
EP2311791A1 (en) | 2011-04-20 |
ES2547412T3 (es) | 2015-10-06 |
EP1452518A1 (en) | 2004-09-01 |
EP1452518B1 (en) | 2012-06-20 |
ES2552378T3 (es) | 2015-11-27 |
CN1610655A (zh) | 2005-04-27 |
CN1562948A (zh) | 2005-01-12 |
EP1452518A4 (en) | 2005-01-12 |
EP2311789A1 (en) | 2011-04-20 |
AU2002354084A1 (en) | 2003-06-17 |
CN1260201C (zh) | 2006-06-21 |
CN1572776A (zh) | 2005-02-02 |
ES2715315T3 (es) | 2019-06-03 |
CN1572775A (zh) | 2005-02-02 |
WO2003048100A1 (fr) | 2003-06-12 |
BR122012016827B1 (pt) | 2015-07-14 |
CN1572773A (zh) | 2005-02-02 |
CN1260202C (zh) | 2006-06-21 |
CN1247515C (zh) | 2006-03-29 |
EP2311789B1 (en) | 2015-10-07 |
BR0214697A (pt) | 2004-09-14 |
EP2311790B1 (en) | 2015-07-29 |
ES2387564T3 (es) | 2012-09-26 |
US20040220426A1 (en) | 2004-11-04 |
CN1240662C (zh) | 2006-02-08 |
US20070129571A1 (en) | 2007-06-07 |
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