BE901215A - Amorceurs anioniques multifonctionnels, leur procede de preparation et leur utilisation dans la polymerisation. - Google Patents
Amorceurs anioniques multifonctionnels, leur procede de preparation et leur utilisation dans la polymerisation.Info
- Publication number
- BE901215A BE901215A BE0/214117A BE214117A BE901215A BE 901215 A BE901215 A BE 901215A BE 0/214117 A BE0/214117 A BE 0/214117A BE 214117 A BE214117 A BE 214117A BE 901215 A BE901215 A BE 901215A
- Authority
- BE
- Belgium
- Prior art keywords
- multifunctional anionic
- polymerization
- preparation process
- hydrogen
- aromatic
- Prior art date
Links
- 238000006116 polymerization reaction Methods 0.000 title 1
- 238000002360 preparation method Methods 0.000 title 1
- -1 N, N-disubstituted amides Chemical class 0.000 abstract 2
- 125000000129 anionic group Chemical group 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 2
- 239000003999 initiator Substances 0.000 abstract 2
- XUGNJOCQALIQFG-UHFFFAOYSA-N 2-ethenylquinoline Chemical class C1=CC=CC2=NC(C=C)=CC=C21 XUGNJOCQALIQFG-UHFFFAOYSA-N 0.000 abstract 1
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical class C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 238000007334 copolymerization reaction Methods 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- 150000001993 dienes Chemical class 0.000 abstract 1
- 150000002118 epoxides Chemical class 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 150000003951 lactams Chemical class 0.000 abstract 1
- 150000002596 lactones Chemical class 0.000 abstract 1
- 125000005395 methacrylic acid group Chemical group 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 150000002825 nitriles Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
- C08G69/14—Lactams
- C08G69/16—Preparatory processes
- C08G69/18—Anionic polymerisation
- C08G69/20—Anionic polymerisation characterised by the catalysts used
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
- C07F1/02—Lithium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/46—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
- C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
- C08G65/08—Saturated oxiranes
- C08G65/10—Saturated oxiranes characterised by the catalysts used
- C08G65/12—Saturated oxiranes characterised by the catalysts used containing organo-metallic compounds or metal hydrides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
- C08G75/02—Polythioethers
- C08G75/06—Polythioethers from cyclic thioethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G85/00—General processes for preparing compounds provided for in this subclass
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Pyridine Compounds (AREA)
- Polymerization Catalysts (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
Abstract
Les amorceurs anioniques multifonctionnels ont la formule (I) dans laquelle Me est un métal alcalin, n est un nombre entier compris entre 2 et 5, R' est un groupe alkyle, amide ou de l'hydrogène, R est l'hydrogène, un radical alkyle, de préférence possédant un atome de carbone tertiaire directement lié au noyau aromatique, cycloalkyle, alcoxy ou un radical aromatique, R comprend de 0 à 18 atomes de carbone. Un procédé d'homopolymérisation ou de copolymérisation de diènes, de composés vinyl-aromatiques, d'esters ou de nitriles, ou d'amides N,N-disubstitués de composés acryliques ou méthacryliques, de vinylpyridines ou de vinylquinoléines et de leurs dérivés, d'épisulfures, d'époxydes, de lactones, de lactames, de siloxanes, caractérisé par l'utilisation des amorceurs anioniques multifonctionnels.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT24019/83A IT1167671B (it) | 1983-12-05 | 1983-12-05 | Iniziatori anionici multifunzionali e loro impiego |
Publications (1)
Publication Number | Publication Date |
---|---|
BE901215A true BE901215A (fr) | 1985-06-05 |
Family
ID=11211505
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BE0/214117A BE901215A (fr) | 1983-12-05 | 1984-12-05 | Amorceurs anioniques multifonctionnels, leur procede de preparation et leur utilisation dans la polymerisation. |
Country Status (11)
Country | Link |
---|---|
US (1) | US4680407A (fr) |
JP (1) | JPS60139704A (fr) |
BE (1) | BE901215A (fr) |
CA (1) | CA1279321C (fr) |
DE (1) | DE3444028A1 (fr) |
ES (2) | ES8605541A1 (fr) |
FR (1) | FR2555991B1 (fr) |
GB (1) | GB2152053B (fr) |
IT (1) | IT1167671B (fr) |
NL (1) | NL8403702A (fr) |
ZA (1) | ZA849290B (fr) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0667970B2 (ja) * | 1987-11-16 | 1994-08-31 | ザ ダウ ケミカル カンパニー | 陰イオン重合用のアミン含有開始剤システム |
US6835778B2 (en) * | 1995-08-29 | 2004-12-28 | Chevron Phillips Chemical Company Lp | Conjugated diene/monovinylarene block copolymers blends |
US20050166551A1 (en) * | 2004-02-02 | 2005-08-04 | Keane J. A. | Multilayer high clarity shrink film comprising monovinylarene-conjugated diene copolymer |
KR101044070B1 (ko) * | 2008-09-23 | 2011-06-27 | 주식회사 엘지화학 | 이관능성 유기 리튬 개시제 및 이를 이용하여 생산되는 공역디엔계 공중합체 및 이들의 제조방법 |
US20100272975A1 (en) * | 2009-04-23 | 2010-10-28 | Chevron Phillips Chemical Company Lp | System and method for the production and use of lamination films |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3954894A (en) * | 1973-05-18 | 1976-05-04 | Lithium Corporation Of America | Organotrilithium polymerization initiators |
DD138071A1 (de) * | 1974-10-04 | 1979-10-10 | Klaus Gehrke | Verfahren zur herstellung von polymeren aus konjugierten dienen mit hohem 1,4-strukturanteil |
IT1195303B (it) * | 1981-12-22 | 1988-10-12 | Anic Spa | Iniziatori anionici multifunzionali e loro impiego |
-
1983
- 1983-12-05 IT IT24019/83A patent/IT1167671B/it active
-
1984
- 1984-11-28 ZA ZA849290A patent/ZA849290B/xx unknown
- 1984-12-03 GB GB08430490A patent/GB2152053B/en not_active Expired
- 1984-12-03 US US06/677,344 patent/US4680407A/en not_active Expired - Lifetime
- 1984-12-03 DE DE19843444028 patent/DE3444028A1/de active Granted
- 1984-12-04 CA CA000469326A patent/CA1279321C/fr not_active Expired - Fee Related
- 1984-12-04 FR FR848418485A patent/FR2555991B1/fr not_active Expired - Fee Related
- 1984-12-04 ES ES538707A patent/ES8605541A1/es not_active Expired
- 1984-12-05 BE BE0/214117A patent/BE901215A/fr not_active IP Right Cessation
- 1984-12-05 NL NL8403702A patent/NL8403702A/nl not_active Application Discontinuation
- 1984-12-05 JP JP59255847A patent/JPS60139704A/ja active Pending
-
1985
- 1985-11-12 ES ES549501A patent/ES8607344A1/es not_active Expired
Also Published As
Publication number | Publication date |
---|---|
FR2555991A1 (fr) | 1985-06-07 |
DE3444028C2 (fr) | 1987-06-11 |
GB2152053B (en) | 1987-08-05 |
GB8430490D0 (en) | 1985-01-09 |
ES538707A0 (es) | 1986-03-16 |
ES549501A0 (es) | 1986-05-16 |
ES8607344A1 (es) | 1986-05-16 |
ES8605541A1 (es) | 1986-03-16 |
IT8324019A0 (it) | 1983-12-05 |
IT1167671B (it) | 1987-05-13 |
JPS60139704A (ja) | 1985-07-24 |
US4680407A (en) | 1987-07-14 |
NL8403702A (nl) | 1985-07-01 |
DE3444028A1 (de) | 1985-06-13 |
GB2152053A (en) | 1985-07-31 |
ZA849290B (en) | 1985-07-31 |
CA1279321C (fr) | 1991-01-22 |
FR2555991B1 (fr) | 1990-01-19 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
RE | Patent lapsed |
Owner name: ENICHEM ELASTOMERI S.P.A. Effective date: 19961231 |