BE1006794A5 - Subject matter type composite plastic. - Google Patents
Subject matter type composite plastic. Download PDFInfo
- Publication number
- BE1006794A5 BE1006794A5 BE9300782A BE9300782A BE1006794A5 BE 1006794 A5 BE1006794 A5 BE 1006794A5 BE 9300782 A BE9300782 A BE 9300782A BE 9300782 A BE9300782 A BE 9300782A BE 1006794 A5 BE1006794 A5 BE 1006794A5
- Authority
- BE
- Belgium
- Prior art keywords
- plastic
- composite type
- type according
- plastic material
- structural component
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/68—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts by incorporating or moulding on preformed parts, e.g. inserts or layers, e.g. foam blocks
- B29C70/681—Component parts, details or accessories; Auxiliary operations
- B29C70/683—Pretreatment of the preformed part, e.g. insert
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
- B29C45/14311—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles using means for bonding the coating to the articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
- B29C45/14778—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles the article consisting of a material with particular properties, e.g. porous, brittle
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2061/00—Use of condensation polymers of aldehydes or ketones or derivatives thereof, as moulding material
- B29K2061/04—Phenoplasts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2309/00—Use of inorganic materials not provided for in groups B29K2303/00 - B29K2307/00, as reinforcement
- B29K2309/08—Glass
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2705/00—Use of metals, their alloys or their compounds, for preformed parts, e.g. for inserts
- B29K2705/02—Aluminium
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Composite Materials (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
- Laminated Bodies (AREA)
Abstract
L'objet en matière plastique de type composite selon l'invention est caractérisé en ce qu'il comprend un corps en matière plastique, présentant, d'un seul tenant avec lui et y adhérant, une pièce constitutive structurale, ladite pièce constitutive structurale ayant, au voisinage du corps en matière plastique, au moins une région de surfaceen aluminium ou matériau similaire, qui a été anodisée.The plastic object of the composite type according to the invention is characterized in that it comprises a plastic body, having, integrally with it and adhering thereto, a structural component, said structural component having , in the vicinity of the plastic body, at least one surface region of aluminum or similar material, which has been anodized.
Description
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OBJETS EN MATIERE PLASTIQUE DE TYPE COMPOSITE
La présente invention porte sur un objet de type composite en matière plastique, présentant, formée d'un seul tenant avec lui, une pièce constitutive structurale, telle qu'un insert en matière relativement ductile, à module d'élasticité élevé.
Un problème qui peut se présenter dans la fabrication d'un objet en matière plastique de type composite est celui de l'obtention d'un joint collé requis entre le corps et une pièce constitutive structurale de l'article. Ceci peut être une difficulté particulière s'il est nécessaire de créer un joint étanche aux fluides entre le corps et les pièces constitutives. Alors qu'il peut être possible de réaliser un joint étanche aux fluides d'un type à verrouillage réciproque mécanique si la pièce constitutive est faite d'une matière telle que le laiton, l'utilisation de cette matière n'est pas toujours acceptable ; par exemple, dans le cas d'un objet fabriqué par une technique à noyau perdu, la matière de noyau du moule, fusible, destinée à être retirée par fusion, est trouvée avoir tendance à adhérer de façon indésirable à la pièce constitutive.
Cela peut présenter des difficultés particulières si la pièce constitutive comprend une structure à filets de vis, étant donné qu'il n'est pas facile de retirer des filets de vis toute matière de noyau restante.
Conformément à l'un de ses aspects, la présente invention propose un objet en matière plastique de type composite, comprenant un corps en matière plastique, présentant, d'un seul tenant avec lui et y adhérant, une pièce constitutive structurale, ladite pièce constitutive structurale ayant, au voisinage du corps en matière plastique, au moins une région de surface en aluminium ou matière similaire, qui a été anodisée.
La référence à l'aluminium ou à une matière similaire comprend les alliages d'aluminium et signifie ici une matière métallique d'une sorte qui peut être anodisée.
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De préférence, la couche anodisée a été formée par une anodisation à l'acide sulfurique.
De préférence, la couche anodisée aura une épaisseur qui ne dépasse pas 20 microns et, de façon davantage préférée, qui ne dépasse pas 12 microns.
La présente invention envisage de préférence que la couche anodisée soit une couche formée par un mode opératoire d'anodisation qui met en jeu l'utilisation d'une différence de potentiel électrique comprise entre 4 et 14 volts, de façon davantage préférée, entre 8 et 10 volts, d'une température se situant dans la plage de 15 à 250C et, de façon davantage préférée, dans la plage de 18 à 22OC, et d'une durée d'anodisation d'au moins 10 minutes et, de façon davantage préférée, d'au moins 20 minutes.
La matière plastique de l'objet peut être un corps de composé de moulage phénolique, par exemple une résine renforcée par du verre, phénolique de type thermodurcie.
De préférence, la pièce constitutive structurale en aluminium ou matière similaire est une pièce qui a été traitée dans un bain d'anodisation de type acide sulfurique et qui a une couche anodisée d'une épaisseur non supérieure à 8 microns.
Un mode de réalisation de la présente invention va maintenant être décrit à titre d'exemple seulement, en référence à un boîtier de thermostat en matière plastique moulée, d'une sorte comprenant un corps de résine renforcée par du verre, thermodurcie, présentant, d'un seul tenant avec lui, plusieurs inserts comportant des filets de vis, qui facilitent la fixation de l'objet à une structure de support.
Les inserts comportant des filets de vis sont faits d'un alliage d'aluminium, tel qu'un alliage en conformité à BS 1474 (1987) 6082, et qui a été soumis à un traitement d'anodisation à l'acide sulfurique.
Dans le traitement d'anodisation, les inserts en aluminium sont placés pendant un laps de temps allant jusqu'à 30 minutes dans un bain d'anodisation d'acide sulfurique d'une concentration de 18%, à une température de 20 z 2 C et
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avec une différence de potentiel de 9 1 volts. La partie comportant les filets de vis de la surface de l'insert peut être recouverte pendant l'anodisation, de façon que seules les autres surfaces de l'insert, telles que les surfaces pour la liaison à une matière de corps, thermo-durcie, soient totalement soumises au traitement d'anodisation.
Par la suite, les inserts sont positionnés dans un moule, dans une relation requise par rapport à un élément de noyau préformé d'une matière fusible, destinée à être retirée par fusion. La matière plastique chaude est ensuite injectée dans le moule, et amenée à durcir chimiquement pour donner un corps de boîtier rigide qui enrobe partiellement les surfaces anodisées des inserts et adhère à celles-ci.
L'assemblage ainsi formé est ensuite chauffé de façon suffisante pour provoquer le retrait par fusion de la matière fusible de l'élément de noyau.
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COMPOSITE-TYPE PLASTIC OBJECTS
The present invention relates to an object of the composite plastic type, having, formed integrally with it, a structural component, such as an insert made of relatively ductile material, with a high modulus of elasticity.
A problem which may arise in the manufacture of a plastic object of the composite type is that of obtaining a glued joint required between the body and a structural component of the article. This can be a particular difficulty if it is necessary to create a fluid tight seal between the body and the constituent parts. While it may be possible to make a fluid tight seal of a mechanical interlocking type if the component is made of a material such as brass, the use of this material is not always acceptable; for example, in the case of an object manufactured by a lost core technique, the fusible mold core material intended to be removed by melting is found to tend to adhere undesirably to the component part.
This can present particular difficulties if the component part comprises a screw thread structure, since it is not easy to remove any remaining core material from the screw threads.
In accordance with one of its aspects, the present invention provides an object of plastic material of the composite type, comprising a body of plastic material, having, integrally with it and adhering thereto, a structural component part, said component part structural having, in the vicinity of the plastic body, at least one surface region of aluminum or similar material, which has been anodized.
The reference to aluminum or a similar material includes aluminum alloys and here means a metallic material of a kind which can be anodized.
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Preferably, the anodized layer was formed by anodization with sulfuric acid.
Preferably, the anodized layer will have a thickness which does not exceed 20 microns and, more preferably, which does not exceed 12 microns.
The present invention preferably contemplates that the anodized layer is a layer formed by an anodization procedure which involves the use of an electrical potential difference of between 4 and 14 volts, more preferably between 8 and 10 volts, with a temperature in the range of 15 to 250C and more preferably in the range of 18 to 22OC, and an anodization time of at least 10 minutes and more preferred, at least 20 minutes.
The plastic of the object can be a body of phenolic molding compound, for example a glass-reinforced resin, phenolic of the thermoset type.
Preferably, the structural component part of aluminum or similar material is a part which has been treated in an anodizing bath of the sulfuric acid type and which has an anodized layer with a thickness of not more than 8 microns.
An embodiment of the present invention will now be described by way of example only, with reference to a thermostat housing of molded plastic material, of a kind comprising a glass-reinforced, thermoset resin body, having, 'in one piece with it, several inserts with screw threads, which facilitate the attachment of the object to a support structure.
The inserts having screw threads are made of an aluminum alloy, such as an alloy in accordance with BS 1474 (1987) 6082, and which has been subjected to an anodization treatment with sulfuric acid.
In the anodizing treatment, the aluminum inserts are placed for a period of up to 30 minutes in an anodizing bath of sulfuric acid with a concentration of 18%, at a temperature of 20 z 2 C and
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with a potential difference of 9 1 volts. The part with the screw threads of the surface of the insert can be covered during anodization, so that only the other surfaces of the insert, such as the surfaces for bonding to a body material, thermoset , are fully subjected to the anodizing treatment.
Thereafter, the inserts are positioned in a mold, in a required relationship with respect to a preformed core element of a fusible material, intended to be removed by fusion. The hot plastic material is then injected into the mold, and caused to harden chemically to give a rigid casing body which partially coats and adheres to the anodized surfaces of the inserts.
The assembly thus formed is then heated sufficiently to cause the meltable material to be removed from the core member.
Claims (13)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB9216064A GB2269775B (en) | 1992-07-28 | 1992-07-28 | Composite type plastics articles |
Publications (1)
Publication Number | Publication Date |
---|---|
BE1006794A5 true BE1006794A5 (en) | 1994-12-13 |
Family
ID=10719460
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BE9300782A BE1006794A5 (en) | 1992-07-28 | 1993-07-27 | Subject matter type composite plastic. |
Country Status (4)
Country | Link |
---|---|
BE (1) | BE1006794A5 (en) |
DE (1) | DE4324716A1 (en) |
FR (1) | FR2694231B1 (en) |
GB (1) | GB2269775B (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19811655A1 (en) * | 1998-03-18 | 1999-09-23 | Schaeffler Waelzlager Ohg | Aluminum-coated plastic component useful as a sliding seal especially in a vehicle hydraulic clutch disengaging system |
EP2063001A1 (en) * | 2007-11-20 | 2009-05-27 | Alcan Technology & Management Ltd. | Container made of an aluminium sheet back-moulded with plastic |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5339946A (en) * | 1976-09-25 | 1978-04-12 | Sankyo Aruminiumu Kougiyou Kk | Surface treatment of aluminum |
DE3201307A1 (en) * | 1981-08-19 | 1983-07-28 | Walter Klein GmbH & Co. KG, 5600 Wuppertal | Ram-guard profiled decorative strip with aluminium insert and high-gloss anodised visible or bare region |
JPH04129577A (en) * | 1990-09-21 | 1992-04-30 | Yokohama Rubber Co Ltd:The | Golf club head |
FR2694230A1 (en) * | 1992-07-28 | 1994-02-04 | Dunlop Automotives Composites | Process for manufacturing a plastic object of the composite type. |
-
1992
- 1992-07-28 GB GB9216064A patent/GB2269775B/en not_active Expired - Fee Related
-
1993
- 1993-07-23 DE DE19934324716 patent/DE4324716A1/en not_active Withdrawn
- 1993-07-27 FR FR9309240A patent/FR2694231B1/en not_active Expired - Fee Related
- 1993-07-27 BE BE9300782A patent/BE1006794A5/en not_active IP Right Cessation
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5339946A (en) * | 1976-09-25 | 1978-04-12 | Sankyo Aruminiumu Kougiyou Kk | Surface treatment of aluminum |
DE3201307A1 (en) * | 1981-08-19 | 1983-07-28 | Walter Klein GmbH & Co. KG, 5600 Wuppertal | Ram-guard profiled decorative strip with aluminium insert and high-gloss anodised visible or bare region |
JPH04129577A (en) * | 1990-09-21 | 1992-04-30 | Yokohama Rubber Co Ltd:The | Golf club head |
FR2694230A1 (en) * | 1992-07-28 | 1994-02-04 | Dunlop Automotives Composites | Process for manufacturing a plastic object of the composite type. |
Non-Patent Citations (2)
Title |
---|
DATABASE WPI Derwent World Patents Index; AN 78-37287A * |
DATABASE WPI Derwent World Patents Index; AN 92-196848 * |
Also Published As
Publication number | Publication date |
---|---|
GB9216064D0 (en) | 1992-09-09 |
GB2269775B (en) | 1995-11-01 |
GB2269775A (en) | 1994-02-23 |
DE4324716A1 (en) | 1994-02-17 |
FR2694231A1 (en) | 1994-02-04 |
FR2694231B1 (en) | 1995-08-04 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
RE | Patent lapsed |
Owner name: *SIEMENS AUTOMOTIVES SYSTEMS LTD Effective date: 20020731 |