AU9063991A - Light-duty dishwashing detergent composition containing an alkyl ethoxy carboxylate surfactant and calcium or magnesium ions - Google Patents

Light-duty dishwashing detergent composition containing an alkyl ethoxy carboxylate surfactant and calcium or magnesium ions

Info

Publication number: AU9063991A
Authority: AU; Australia
Prior art keywords: alkyl; calcium; composition according; composition; compositions
Prior art date: 1990-11-16
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Abandoned

Application number

AU90639/91A

Other languages

English (en)

Inventor

Thomas Anthony Cripe

Kofi Ofosu-Asante

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Procter and Gamble Co

Original Assignee

Procter and Gamble Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1990-11-16

Filing date

1991-11-08

Publication date

1992-06-11

1991-11-08 Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co

1992-06-11 Publication of AU9063991A publication Critical patent/AU9063991A/en

Status Abandoned legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims description 222
-1 alkyl ethoxy carboxylate Chemical compound 0.000 title claims description 96
239000004094 surface-active agent Substances 0.000 title claims description 64
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 title claims description 35
239000011575 calcium Substances 0.000 title claims description 35
JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 title claims description 33
229910001425 magnesium ion Inorganic materials 0.000 title claims description 32
229910001424 calcium ion Inorganic materials 0.000 title claims description 30
239000003599 detergent Substances 0.000 title claims description 19
238000004851 dishwashing Methods 0.000 title claims description 16
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 61
125000000217 alkyl group Chemical group 0.000 claims description 50
239000002738 chelating agent Substances 0.000 claims description 32
235000014113 dietary fatty acids Nutrition 0.000 claims description 27
239000000194 fatty acid Substances 0.000 claims description 27
229930195729 fatty acid Natural products 0.000 claims description 27
239000007788 liquid Substances 0.000 claims description 26
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 22
239000011777 magnesium Substances 0.000 claims description 22
229910052749 magnesium Inorganic materials 0.000 claims description 22
150000004665 fatty acids Chemical class 0.000 claims description 21
230000015572 biosynthetic process Effects 0.000 claims description 20
229910052791 calcium Inorganic materials 0.000 claims description 20
239000002244 precipitate Substances 0.000 claims description 19
150000001768 cations Chemical class 0.000 claims description 18
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 17
239000007998 bicine buffer Substances 0.000 claims description 15
FSVCELGFZIQNCK-UHFFFAOYSA-N N,N-bis(2-hydroxyethyl)glycine Chemical compound OCCN(CCO)CC(O)=O FSVCELGFZIQNCK-UHFFFAOYSA-N 0.000 claims description 14
150000001412 amines Chemical class 0.000 claims description 14
239000006172 buffering agent Substances 0.000 claims description 14
239000000463 material Substances 0.000 claims description 14
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 12
229910052783 alkali metal Inorganic materials 0.000 claims description 11
239000007864 aqueous solution Substances 0.000 claims description 10
229910000019 calcium carbonate Inorganic materials 0.000 claims description 9
239000000344 soap Substances 0.000 claims description 9
150000008051 alkyl sulfates Chemical class 0.000 claims description 8
CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 claims description 4
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 4
UYBWIEGTWASWSR-UHFFFAOYSA-N 1,3-diaminopropan-2-ol Chemical compound NCC(O)CN UYBWIEGTWASWSR-UHFFFAOYSA-N 0.000 claims description 3
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 3
150000004996 alkyl benzenes Chemical class 0.000 claims description 3
FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 claims description 3
PFARUPKOWSCVRX-UHFFFAOYSA-N 2-[carboxymethyl(2,3-dihydroxypropyl)amino]acetic acid Chemical compound OCC(O)CN(CC(O)=O)CC(O)=O PFARUPKOWSCVRX-UHFFFAOYSA-N 0.000 claims description 2
JYXGIOKAKDAARW-UHFFFAOYSA-N N-(2-hydroxyethyl)iminodiacetic acid Chemical compound OCCN(CC(O)=O)CC(O)=O JYXGIOKAKDAARW-UHFFFAOYSA-N 0.000 claims description 2
108010077895 Sarcosine Proteins 0.000 claims description 2
239000003093 cationic surfactant Substances 0.000 claims description 2
239000012188 paraffin wax Substances 0.000 claims description 2
150000003871 sulfonates Chemical class 0.000 claims description 2
229940043230 sarcosine Drugs 0.000 claims 1
235000019441 ethanol Nutrition 0.000 description 59
229960005069 calcium Drugs 0.000 description 30
125000004432 carbon atom Chemical group C* 0.000 description 29
238000004140 cleaning Methods 0.000 description 21
238000009472 formulation Methods 0.000 description 21
239000004519 grease Substances 0.000 description 21
239000011734 sodium Substances 0.000 description 20
229910052708 sodium Inorganic materials 0.000 description 20
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 19
238000000034 method Methods 0.000 description 19
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 18
238000003860 storage Methods 0.000 description 17
239000000047 product Substances 0.000 description 16
BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 15
235000002639 sodium chloride Nutrition 0.000 description 15
239000003054 catalyst Substances 0.000 description 14
239000000243 solution Substances 0.000 description 14
150000001298 alcohols Chemical class 0.000 description 13
DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 12
150000002500 ions Chemical class 0.000 description 12
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 11
229960003237 betaine Drugs 0.000 description 11
150000007942 carboxylates Chemical class 0.000 description 10
238000009826 distribution Methods 0.000 description 10
238000006243 chemical reaction Methods 0.000 description 9
125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 9
VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 9
239000000347 magnesium hydroxide Substances 0.000 description 9
229910001862 magnesium hydroxide Inorganic materials 0.000 description 9
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 8
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 8
230000008901 benefit Effects 0.000 description 8
229910052700 potassium Inorganic materials 0.000 description 8
239000011591 potassium Substances 0.000 description 8
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 7
229910052784 alkaline earth metal Inorganic materials 0.000 description 7
239000002585 base Substances 0.000 description 7
239000004615 ingredient Substances 0.000 description 7
239000004471 Glycine Substances 0.000 description 6
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
150000001340 alkali metals Chemical class 0.000 description 6
150000001336 alkenes Chemical class 0.000 description 6
150000001408 amides Chemical class 0.000 description 6
239000003945 anionic surfactant Substances 0.000 description 6
239000006227 byproduct Substances 0.000 description 6
KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 5
FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 description 5
229940106681 chloroacetic acid Drugs 0.000 description 5
150000001875 compounds Chemical class 0.000 description 5
150000002191 fatty alcohols Chemical class 0.000 description 5
235000000346 sugar Nutrition 0.000 description 5
238000012935 Averaging Methods 0.000 description 4
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 4
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 4
LLSDKQJKOVVTOJ-UHFFFAOYSA-L calcium chloride dihydrate Chemical compound O.O.[Cl-].[Cl-].[Ca+2] LLSDKQJKOVVTOJ-UHFFFAOYSA-L 0.000 description 4
150000002194 fatty esters Chemical class 0.000 description 4
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
239000002304 perfume Substances 0.000 description 4
239000012071 phase Substances 0.000 description 4
239000011541 reaction mixture Substances 0.000 description 4
150000003839 salts Chemical class 0.000 description 4
239000011780 sodium chloride Substances 0.000 description 4
229960004418 trolamine Drugs 0.000 description 4
IOAOAKDONABGPZ-UHFFFAOYSA-N 2-amino-2-ethylpropane-1,3-diol Chemical compound CCC(N)(CO)CO IOAOAKDONABGPZ-UHFFFAOYSA-N 0.000 description 3
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 3
244000060011 Cocos nucifera Species 0.000 description 3
235000013162 Cocos nucifera Nutrition 0.000 description 3
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 3
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
239000007983 Tris buffer Substances 0.000 description 3
240000008042 Zea mays Species 0.000 description 3
235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 3
235000002017 Zea mays subsp mays Nutrition 0.000 description 3
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
230000002378 acidificating effect Effects 0.000 description 3
125000002252 acyl group Chemical group 0.000 description 3
150000001342 alkaline earth metals Chemical class 0.000 description 3
125000003342 alkenyl group Chemical group 0.000 description 3
WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 3
239000003715 calcium chelating agent Substances 0.000 description 3
AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 3
239000000920 calcium hydroxide Substances 0.000 description 3
229910001861 calcium hydroxide Inorganic materials 0.000 description 3
239000003795 chemical substances by application Substances 0.000 description 3
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
235000005822 corn Nutrition 0.000 description 3
125000004122 cyclic group Chemical group 0.000 description 3
229940043237 diethanolamine Drugs 0.000 description 3
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 3
239000003208 petroleum Substances 0.000 description 3
238000001556 precipitation Methods 0.000 description 3
239000008234 soft water Substances 0.000 description 3
239000002689 soil Substances 0.000 description 3
239000002904 solvent Substances 0.000 description 3
241000894007 species Species 0.000 description 3
239000006188 syrup Substances 0.000 description 3
235000020357 syrup Nutrition 0.000 description 3
229910052725 zinc Inorganic materials 0.000 description 3
239000011701 zinc Substances 0.000 description 3
125000004178 (C1-C4) alkyl group Chemical group 0.000 description 2
OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 2
125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 2
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 2
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 2
SEQKRHFRPICQDD-UHFFFAOYSA-N N-tris(hydroxymethyl)methylglycine Chemical compound OCC(CO)(CO)[NH2+]CC([O-])=O SEQKRHFRPICQDD-UHFFFAOYSA-N 0.000 description 2
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
150000001242 acetic acid derivatives Chemical class 0.000 description 2
150000001447 alkali salts Chemical class 0.000 description 2
125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 2
125000002947 alkylene group Chemical group 0.000 description 2
229910000323 aluminium silicate Inorganic materials 0.000 description 2
CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 2
GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 description 2
230000003139 buffering effect Effects 0.000 description 2
229910002091 carbon monoxide Inorganic materials 0.000 description 2
BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 2
238000009833 condensation Methods 0.000 description 2
230000005494 condensation Effects 0.000 description 2
239000000356 contaminant Substances 0.000 description 2
238000005520 cutting process Methods 0.000 description 2
230000001419 dependent effect Effects 0.000 description 2
ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
239000003085 diluting agent Substances 0.000 description 2
125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 2
238000002845 discoloration Methods 0.000 description 2
ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical compound CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 description 2
239000008103 glucose Substances 0.000 description 2
125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 2
150000004820 halides Chemical class 0.000 description 2
HSEMFIZWXHQJAE-UHFFFAOYSA-N hexadecanamide Chemical compound CCCCCCCCCCCCCCCC(N)=O HSEMFIZWXHQJAE-UHFFFAOYSA-N 0.000 description 2
125000001183 hydrocarbyl group Chemical group 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
238000005984 hydrogenation reaction Methods 0.000 description 2
230000002209 hydrophobic effect Effects 0.000 description 2
125000001165 hydrophobic group Chemical group 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
229910010272 inorganic material Inorganic materials 0.000 description 2
230000003993 interaction Effects 0.000 description 2
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
DHRRIBDTHFBPNG-UHFFFAOYSA-L magnesium dichloride hexahydrate Chemical compound O.O.O.O.O.O.[Mg+2].[Cl-].[Cl-] DHRRIBDTHFBPNG-UHFFFAOYSA-L 0.000 description 2
229910052751 metal Inorganic materials 0.000 description 2
239000002184 metal Substances 0.000 description 2
OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Natural products OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 2
JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 2
125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 2
238000002156 mixing Methods 0.000 description 2
230000007935 neutral effect Effects 0.000 description 2
229910052759 nickel Inorganic materials 0.000 description 2
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
239000002736 nonionic surfactant Substances 0.000 description 2
LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 2
239000003921 oil Substances 0.000 description 2
235000019198 oils Nutrition 0.000 description 2
230000003647 oxidation Effects 0.000 description 2
238000007254 oxidation reaction Methods 0.000 description 2
229910052760 oxygen Inorganic materials 0.000 description 2
238000010979 pH adjustment Methods 0.000 description 2
238000012856 packing Methods 0.000 description 2
230000000737 periodic effect Effects 0.000 description 2
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
239000002243 precursor Substances 0.000 description 2
150000003138 primary alcohols Chemical class 0.000 description 2
150000003141 primary amines Chemical class 0.000 description 2
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
150000003254 radicals Chemical class 0.000 description 2
239000002994 raw material Substances 0.000 description 2
239000000376 reactant Substances 0.000 description 2
238000006268 reductive amination reaction Methods 0.000 description 2
229920006395 saturated elastomer Polymers 0.000 description 2
150000004760 silicates Chemical class 0.000 description 2
239000003381 stabilizer Substances 0.000 description 2
230000000087 stabilizing effect Effects 0.000 description 2
150000008163 sugars Chemical class 0.000 description 2
150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
239000003760 tallow Substances 0.000 description 2
238000012546 transfer Methods 0.000 description 2
150000003626 triacylglycerols Chemical class 0.000 description 2
LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 2
DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
NNWAARLSYSBVPB-UHFFFAOYSA-N 1h-imidazole-4,5-dicarboxamide Chemical compound NC(=O)C=1N=CNC=1C(N)=O NNWAARLSYSBVPB-UHFFFAOYSA-N 0.000 description 1
HOBGCONPBCCQHM-UHFFFAOYSA-N 2-(methylamino)ethane-1,1-diol Chemical class CNCC(O)O HOBGCONPBCCQHM-UHFFFAOYSA-N 0.000 description 1
HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
UXFQFBNBSPQBJW-UHFFFAOYSA-N 2-amino-2-methylpropane-1,3-diol Chemical compound OCC(N)(C)CO UXFQFBNBSPQBJW-UHFFFAOYSA-N 0.000 description 1
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239000010936 titanium Substances 0.000 description 1
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UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
235000015870 tripotassium citrate Nutrition 0.000 description 1
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LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 1
HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
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Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/06—Ether- or thioether carboxylic acids
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/042—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on anionic surface-active compounds and soap
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/003—Colloidal solutions, e.g. gels; Thixotropic solutions or pastes
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/143—Sulfonic acid esters
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/521—Carboxylic amides (R1-CO-NR2R3), where R1, R2 and R3 are alkyl or alkenyl groups
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/525—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain two or more hydroxy groups per alkyl group, e.g. R3 being a reducing sugar rest
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Dispersion Chemistry (AREA)
Detergent Compositions (AREA)
Cosmetics (AREA)

AU90639/91A 1990-11-16 1991-11-08 Light-duty dishwashing detergent composition containing an alkyl ethoxy carboxylate surfactant and calcium or magnesium ions Abandoned AU9063991A (en)

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date
US61453190A	1990-11-16	1990-11-16
US61453290A	1990-11-16	1990-11-16
US614532		1990-11-16
US614531		2003-07-07

Publications (1)

Publication Number	Publication Date
AU9063991A true AU9063991A (en)	1992-06-11

Family

ID=27087270

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
AU90639/91A Abandoned AU9063991A (en)	1990-11-16	1991-11-08	Light-duty dishwashing detergent composition containing an alkyl ethoxy carboxylate surfactant and calcium or magnesium ions

Country Status (22)

Country	Link
EP (1)	EP0557426B1 (zh)
JP (1)	JP3009464B2 (zh)
CN (1)	CN1062371A (zh)
AR (1)	AR244795A1 (zh)
AT (1)	ATE149561T1 (zh)
AU (1)	AU9063991A (zh)
BR (1)	BR9106983A (zh)
CZ (1)	CZ87393A3 (zh)
DE (1)	DE69125022T2 (zh)
DK (1)	DK0557426T3 (zh)
ES (1)	ES2101078T3 (zh)
FI (1)	FI932199A (zh)
GR (1)	GR3023502T3 (zh)
HU (1)	HUT64782A (zh)
MA (1)	MA22342A1 (zh)
MX (1)	MX9102078A (zh)
MY (1)	MY131210A (zh)
NO (1)	NO931738L (zh)
PT (2)	PT99527A (zh)
SK (1)	SK48093A3 (zh)
TR (1)	TR26532A (zh)
WO (1)	WO1992008777A1 (zh)

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WO1993005132A1 (en) *	1991-09-06	1993-03-18	The Procter & Gamble Company	Detergent compositions containing calcium and polyhydroxy fatty acid amide
US5298195A (en) *	1992-03-09	1994-03-29	Amway Corporation	Liquid dishwashing detergent
NL9201339A (nl) *	1992-07-24	1994-02-16	Chem Y Gmbh	Vloeibare geconcentreerde oplossingen van alkylethercarbonzuurzouten in water.
WO1994005769A1 (en) *	1992-09-01	1994-03-17	The Procter & Gamble Company	Liquid or gel dishwashing detergent containing alkyl ethoxy carboxylate, divalent ions and alkylpolyethoxypolycarboxylate
US5269974A (en) *	1992-09-01	1993-12-14	The Procter & Gamble Company	Liquid or gel dishwashing detergent composition containing alkyl amphocarboxylic acid and magnesium or calcium ions
US5545354A (en) *	1992-09-01	1996-08-13	The Procter & Gamble Company	Liquid or gel dishwashing detergent containing a polyhydroxy fatty acid amide, calcium ions and an alkylpolyethoxypolycarboxylate
JPH08500630A (ja) *	1992-09-01	1996-01-23	ザ、プロクター、エンド、ギャンブル、カンパニー	カルシウムとその安定剤を含む液体又はゲル洗剤組成物
AU5618294A (en) *	1992-11-30	1994-06-22	Procter & Gamble Company, The	Detergent compositions with calcium ions and polyhydroxy fatty acid amide nonionic/selected anionic/soap surfactant mixture
US5474710A (en) *	1993-08-27	1995-12-12	Ofosu-Asanta; Kofi	Process for preparing concentrated surfactant mixtures containing magnesium
US5415814A (en) *	1993-08-27	1995-05-16	The Procter & Gamble Company	Concentrated liquid or gel light duty dishwashing detergent composition containing calcium xylene sulfonate
US5417893A (en) *	1993-08-27	1995-05-23	The Procter & Gamble Company	Concentrated liquid or gel light duty dishwashing detergent compositions containing calcium ions and disulfonate surfactants
US5415801A (en) *	1993-08-27	1995-05-16	The Procter & Gamble Company	Concentrated light duty liquid or gel dishwashing detergent compositions containing sugar
CZ76096A3 (en) *	1993-09-14	1996-08-14	Procter & Gamble	Slightly foamy liquid or gel-like protease-containing detergent for washing-up
EP2199386A1 (en)	1993-10-08	2010-06-23	Novozymes A/S	Amylase variants
WO1995023202A1 (en)	1994-02-23	1995-08-31	Ecolab Inc.	Alkaline cleaners based on alcohol ethoxy carboxylates
CA2147674C (en) *	1994-05-16	1999-03-30	David Robert Zint	Shaped semi-solid or solid dishwashing detergent
ZA955295B (en) *	1994-06-27	1996-02-13	Diversey Corp	Non-silicated soft metal safe product
US7404967B2 (en)	1994-12-21	2008-07-29	Cosmederm, Inc.	Topical product formulations containing strontium for reducing skin irritation
US5958436A (en) *	1995-12-21	1999-09-28	Cosmederm Technologies	Formulations and methods for reducing skin irritation
WO1998028392A1 (en) *	1996-12-20	1998-07-02	The Procter & Gamble Company	Dishwashing detergent compositions containing alkanolamine
AR017745A1 (es) *	1999-02-08	2001-09-12	Procter & Gamble	Composiciones detergentes para lavar vajilla, que contienen diaminas organicas y magnesio, para una mejor limpieza con aguas blandas.
JP4509292B2 (ja) *	2000-04-04	2010-07-21	ライオン株式会社	界面活性剤組成物
WO2008112459A2 (en)	2007-03-09	2008-09-18	Danisco Us Inc., Genencor Division	Alkaliphilic bacillus species a-amylase variants, compositions comprising a-amylase variants, and methods of use
WO2009149271A2 (en)	2008-06-06	2009-12-10	Danisco Us Inc.	Production of glucose from starch using alpha-amylases from bacillus subtilis
DK2297312T3 (da)	2008-06-06	2013-12-16	Danisco Us Inc	Alpha-amylasevarianter af Bacillus subtilis og fremgangsmåder til anvendelse heraf
CN102112618A (zh)	2008-06-06	2011-06-29	丹尼斯科美国公司	糖化酶组合物及其糖化方法
EP2264136B1 (en)	2009-06-19	2013-03-13	The Procter & Gamble Company	Liquid hand dishwashing detergent composition
ES2412707T5 (es) *	2009-06-19	2023-06-12	Procter & Gamble	Composición detergente líquida para lavado de vajillas a mano
MX356389B (es)	2009-10-23	2018-05-28	Danisco Us Inc	Metodos para reducir sacaridos azules.
SE1250261A1 (sv) *	2011-10-31	2013-05-01	Billerudkorsnaes Gaevle Froevi Ab	Bestrykningskomposition, ett förfarande för bestrykning av ett substrat, ettbestruket substrat, ett förpackningsmaterial och vätskeförpackning
US9096818B2 (en) *	2011-12-09	2015-08-04	Clariant International Ltd.	Automatic dishwashing detergent compositions comprising ethercarboxylic acids or their salts and nonionic surfactants with a high cloud point
US10227550B2 (en)	2012-12-07	2019-03-12	Colgate-Palmolive Company	Cleaning composition
MY194073A (en) *	2014-11-18	2022-11-10	Basf Se	Method of mineral oil production
NZ733676A (en) *	2015-01-15	2022-01-28	Ecolab Inc	Long lasting cleaning foam
CN109126622A (zh) *	2017-06-27	2019-01-04	华南师范大学	一种阴离子表面活性剂、洗涤剂和洗涤剂组合物
JP2020090606A (ja) *	2018-12-05	2020-06-11	株式会社コープクリーン	洗浄剤組成物

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GB1225218A (zh) *	1968-07-31	1971-03-17
US4098818A (en) *	1976-12-10	1978-07-04	The Procter & Gamble Company	Process for making carboxyalkylated alkyl polyether surfactants with narrow polyethoxy chain distribution
DE2754210A1 (de) *	1976-12-10	1978-06-15	Procter & Gamble	Oberflaechenaktives mittel auf basis von carboxyalkylierten alkylpolyethern
DE3370164D1 (en) *	1982-10-28	1987-04-16	Procter & Gamble	Liquid detergent compositions
DE3905938A1 (de) *	1989-02-25	1990-08-30	Huels Chemische Werke Ag	Detergentienzusammensetzungen mit erhoehter viskositaet
AU5575090A (en) *	1989-05-22	1990-11-22	Procter & Gamble Company, The	Light-duty liquid or gel dishwashing detergent composition containing an alkyl ethoxy carboxylate surfactant

1991
- 1991-11-08 AU AU90639/91A patent/AU9063991A/en not_active Abandoned
- 1991-11-08 SK SK480-93A patent/SK48093A3/sk unknown
- 1991-11-08 WO PCT/US1991/008280 patent/WO1992008777A1/en active IP Right Grant
- 1991-11-08 CZ CS93873A patent/CZ87393A3/cs unknown
- 1991-11-08 BR BR919106983A patent/BR9106983A/pt not_active Application Discontinuation
- 1991-11-08 AT AT92900582T patent/ATE149561T1/de not_active IP Right Cessation
- 1991-11-08 DK DK92900582.5T patent/DK0557426T3/da active
- 1991-11-08 DE DE69125022T patent/DE69125022T2/de not_active Expired - Fee Related
- 1991-11-08 HU HU9301418A patent/HUT64782A/hu unknown
- 1991-11-08 ES ES92900582T patent/ES2101078T3/es not_active Expired - Lifetime
- 1991-11-08 EP EP92900582A patent/EP0557426B1/en not_active Expired - Lifetime
- 1991-11-08 JP JP4502258A patent/JP3009464B2/ja not_active Expired - Lifetime
- 1991-11-15 MY MYPI91002116A patent/MY131210A/en unknown
- 1991-11-15 PT PT99527A patent/PT99527A/pt not_active Application Discontinuation
- 1991-11-15 MA MA22625A patent/MA22342A1/fr unknown
- 1991-11-15 AR AR91321165A patent/AR244795A1/es active
- 1991-11-15 PT PT99530A patent/PT99530A/pt not_active Application Discontinuation
- 1991-11-15 MX MX9102078A patent/MX9102078A/es not_active IP Right Cessation
- 1991-11-15 TR TR91/1103A patent/TR26532A/xx unknown
- 1991-11-16 CN CN91111874.8A patent/CN1062371A/zh active Pending
1993
- 1993-05-13 NO NO93931738A patent/NO931738L/no unknown
- 1993-05-14 FI FI932199A patent/FI932199A/fi unknown
1997
- 1997-05-20 GR GR970401152T patent/GR3023502T3/el unknown

Also Published As

Publication number	Publication date
HUT64782A (en)	1994-02-28
EP0557426A1 (en)	1993-09-01
ATE149561T1 (de)	1997-03-15
MX9102078A (es)	1992-06-01
BR9106983A (pt)	1993-08-24
GR3023502T3 (en)	1997-08-29
TR26532A (tr)	1995-03-15
JP3009464B2 (ja)	2000-02-14
PT99530A (pt)	1992-09-30
PT99527A (pt)	1992-09-30
JPH06502884A (ja)	1994-03-31
AR244795A1 (es)	1993-11-30
NO931738D0 (no)	1993-05-13
NO931738L (no)	1993-07-15
WO1992008777A1 (en)	1992-05-29
MA22342A1 (fr)	1992-07-01
DE69125022T2 (de)	1997-09-25
FI932199A0 (fi)	1993-05-14
EP0557426B1 (en)	1997-03-05
CZ87393A3 (en)	1994-07-13
HU9301418D0 (en)	1993-09-28
MY131210A (en)	2007-07-31
DE69125022D1 (de)	1997-04-10
SK48093A3 (en)	1994-01-12
CN1062371A (zh)	1992-07-01
ES2101078T3 (es)	1997-07-01
FI932199A (fi)	1993-05-14
DK0557426T3 (da)	1997-09-01

Publication	Publication Date	Title
US5376310A (en)	1994-12-27	Alkaline light duty dishwashing detergent composition containing an alkyl ethoxy carboxylate surfactant, magnesium ions, chelator and buffer
EP0557426B1 (en)	1997-03-05	Light-duty dishwashing detergent composition containing an alkyl ethoxy carboxylate surfactant and calcium or magnesium ions
US5378409A (en)	1995-01-03	Light duty dishwashing detergent composition containing an alkyl ethoxy carboxylate surfactant and ions
US5269974A (en)	1993-12-14	Liquid or gel dishwashing detergent composition containing alkyl amphocarboxylic acid and magnesium or calcium ions
EP0715651B1 (en)	1998-10-21	Concentrated liquid or gel dishwashing detergent composition containing calcium xylene sulfonate
US5417893A (en)	1995-05-23	Concentrated liquid or gel light duty dishwashing detergent compositions containing calcium ions and disulfonate surfactants
US5739092A (en)	1998-04-14	Liquid or gel dishwashing detergent containing alkyl ethoxy carboxylate divalent ok ions and alkylpolyethoxypolycarboxylate
EP0399752B1 (en)	1997-08-06	Light-duty liquid or gel dishwashing detergent composition containing an alkyl ethoxy carboxylate surfactant
US5415801A (en)	1995-05-16	Concentrated light duty liquid or gel dishwashing detergent compositions containing sugar
US5230823A (en)	1993-07-27	Light-duty liquid or gel dishwashing detergent composition containing an alkyl ethoxy carboxylate surfactant
EP0658186B1 (en)	1997-04-09	Liquid or gel dishwashing detergent containing a polyhydroxy fatty acid amide, calcium ions and an alkylpolyethoxypolycarboxylate
EP0518925A4 (en)	1993-01-13	Light-duty liquid dishwashing detergent compositions
US5474710A (en)	1995-12-12	Process for preparing concentrated surfactant mixtures containing magnesium
CA2055045C (en)	1996-11-12	Light-duty dishwashing detergent composition containing an alkyl ethoxy carboxylate surfactant and calcium ions
CA2012172C (en)	1995-03-21	Light-duty liquid dishwashing detergent composition containing an alkyl ethoxy carboxylate surfactant