AU610714B2 - Eyelash make-up composition based on wax and keratin hydrolysate - Google Patents

Description

Seal of Company and Signatures of its Offi e r, 00 pre.,crlyd ny Its ArtLfeo of M oCf 4_0 By; 6~ Loui Gebhardt 06 Registered. Patent Attorney TIIE COMMISSIONER Or PATENTS.

Ed Watems Sons, ylei~ none, )w _91 Form COMMONWEALTH OF AUSTRALIA PATENTS ACT 1952-69 COMPLETE SPECIFICA-TION

(ORIGINAL)

Class Application Number: Lodged: Int. Class Complete Specification Lodged: Accepted; Published: Priority: Related Art: d 4 m !j ki.d i, iNJame of Applicant; Address of Applicant 0 Actual Inventor: 0 Address for Service: L' OREAL Company constitute under the French Law A Joint Stock 14, rue Royale 75008 Paris, France.

JEAN-PIERRE ARRAUDEAU, JEANNE PATRAUD and DIDlER (GAGNEBIEN EDWD. WATERS SONS, 50 QUE EN STREET, MELBOURNE, AUSTRALIA, 3000.

Complete Specification for the invention entitled: EYELASH MAKE-UP COMPOSITION BASED ON WAX AND KERATIN HYDROLYSATE The followins statement Is a 1tall dioscription of this invention, including the best methad of performing It known~ to -u

I.I

ine oasic dppltcLuLi 11 I-Li-c.u t i yad ay the first application made in a Convention country in respect of the invention the subject of the application.

DE LParis, France CLAR Signature.

Edwd, Waters& Sons, I y r 1 t 0 00 0 o 0 0 000 000 01)0 0 o 0a S0 0 0 0 oo oo 0 00 o o 0 00 °0 0 0 0 00 0 00 0 ooo .oo 0 o o a QO 0 o Go -2- EYELASH MAKE-UP COMPOSITION BASED ON WAX AND KERATIN HYDROLYSATE The present invention relates to a composition for eyelash make-up, generally called mascara.

To obtain a satisfactory eyelash make-up, the mascaras must have a certain number of characteristics: they must provide a homegeneous coating of the eyelashes which is stable over time, they must provide lengthening of the eyelashes and enable rapid application.

The mascaras used are generally wax-based.

However, it has been observed that when waxes alone are used, a non-homogeneous film is obtained after applicaLion on the eyelashes which forms cracking flakes immediately after drying. To overcome this disadvantage, it has been 15 proposed to add various additives to the wax. By the addition of a thickening agent, such as hydroxyethylcellulose, the homogeneity of the film deposited on the eyelashes is improved. However, the stability of this film is not sufficient because cracking flakes appear 20 after a few hours. Moreover, the lengthening of the eyelashes is inadequate.

It has also been proposed to add to the mixture of wax and thickening agent a cohesion agent, such as colophony and Its derivatives.

25 Mascaras are also known which are based on mixtures of waxes and anionic and cationic polymers.

These mascaras provide perfect coating of the eyelash and substantially increase the lengthening of the eyelash. Unfortunately, these cosmetics require a certain 30 time for application in order to obtain the perfect coating of the eyelashes.

U.S. patent application Serial No. 799,496 describes mascaras containing waxes and derivatives of sulfonated keratin having the formula: cq ac 000 00 00 0 0000 00 00: 00 0 0 0 0~ 0 0 00 0 0 00 0 0 a 0 0 00 00 0 00 0000 a0 0 0 a00 0 .0 0 000 0 0 0 0 0 0 0 -3- K _SO,

M

-A

wherein: K represents the keratin residue; 1° represents H a cation derived from an alkaline metal or magnesium, or indeed Ne(R) 4 wherein the R o oo 15 radicals are identical or different and represent a hydrogen 0 0 0 o atom or even an alkyl or hydroxyalkyl radical having at most o0 o 4 carbon atoms, with the symbol A representing from 3 to ,ooo. by weight of the keratinic derivative.

0°o o The mascaras obtained provide very rapid o. oo 20 application, substantial lengthening of the eyelashes and o good stability.

In the present application, it has been found that by using another keratin derivative, a hydrolyzed keratin, 0ooo excellent results were also obtained. The hydrolyzed oo 25 keratin has the advantage of being used in much smaller 0 00 o0 0o quantities. the following description, "keratin Shydrolysate" will mean a partially hydrolyzed keratin.

oo o" The object of the present invention, therefore, is a composition foz eyelash make-up, or mascara, comprising, 30 in a cosmetically acceptable support, at least one wax oo0 0 having a melting point of between 60 and 110*C, o0" characterized by the fact that' it contains -a-ae- t ekeratVin hydrolysate having an average molecular weight of between 50,000 and 200,000, with the weight ratio of the quantity of keratin hydrolysate used to the quantity of wax(es) used being between 0.005 and Hydrolysates having a molecular weight of approximately 100,000 are particularly suitable.

o tvr 0 i^

M

0 00 0" o 0 0. 0 0000 00 0 o 00 o0 0 0 0O 00 00 0 0 oq o o ,o0 o oo 0 0 0 0 0 0 -4- When the molecular weight is less than 50,000, the mascara does not provide satisfactory coating of the eyelashes. The filmogenic properties of the mascara are not satisfactory.

The keratin from which the keratin hydrolysate is prepared can come from hair, wool, hooves, horn, fur, silks or feathers.

Preferably, the keratin from skin is used since it is richer in sulfur compounds.

Preferably, the keratin hydrolysate used a Erc th 1 obtained by moderate alkaline hydrolysis.

In the alkaline hydrolysis method, the keratinic substance (hair, fur, hooves, etc.) is treated with a base mineral, such as sodium, potassium, barium hydroxide, 15 lithium hydroxide, sodium carbonate, potassium carbonate or lithium carbonate, sodium silicate or borax. The hydrolysis reaction is monitored so as to have a product with a molecular weight which is greater than 50,000.

The keratin hydrolysate gives good results in a 20 rela'7 vely low amount, between 0.05 and 5% by weight in relation to the total weight of the composition.

In general, the waxes selected have a melting point of between 60 and 110 0 C and a needle penetration, at 25 0

C,

of 3 to 40, as measured in accordance with U.S. Standard 25 ASTM D5 or in accordance with French Standard NFT 004. The principle of the measurement of the penetration of a needle in accordance with Standards ASTM D5 and NFT 004 consists of measuring the depth, expressed in tenths of millimeters to which a standardized needle (weighing 2.5 g placed in a 30 needle-holder weighing 47.5 g, or a total of 50 g) penetrates when placed on the wax for 5 seconds.

The waxes used in accordance with the invention are selected from among the animal waxes, the vegetable waxes, the mineral waxes, the synthetic waxes and the various fractions of natural waxes, with all such waxes having the two characteristics indicated above.

o oo o 0 0 o o o 0 00 0n 0 0000 Do 0 o 00 00 0o oo oo 0 0 00 0 0 0 0 0 o 0 o 0 0 00 0 0 0 00 0 0 00 0 0 00 Among the animal waxes, beeswaxes, lanolin waxes and China insect waxes can be mentioned.

Among the vegetable waxes, Carnauba waxes, Candelilla waxes, Ouricurry waxes, cork fiber waxes, sugar cane waxes and Japan waxes can be mentioned.

For the mineral waxes, paraffins, microcrystalline waxes, Montan waxes and ozocerites in particular can be mentioned.

For the synthetic waxes, polyethylene waxes, the waxes obtained by the Fisher and Tropsch synthesis and the waxy copolymers as well as their estera can in particular be mentioned.

These waxes are well known in the art. In accordance with the invention the wax(es) is (are) present 15 in the mascara compositions in amounts of between 2 and by weight in relation to the total weight of the composition.

The waxes which can be used in accordance with the present invention are preferably solid and rigid at a 20 temperature of less than 50 0

C.

The mascara compositions in accordance with the present invention can contain pigments in addition to the keratin hydrolysate and the waxes, Due to the presence of the above-identified keratin hydrolysates, good distribution 25 of said pigments in the compositions is obtained as is an improvement in their fixing on the eyelashes.

The pigments which can be used in accordance with the invention are selected from among the mineral pigments, the organic pigments and the pearly pigments.

30 By way of example of mineral pigments, titanium dioxide (rutile or annatase) possibly surface treated and codified in the Color Index under the reference CI 77 891, black, yellow, red and brown iron oxides, codified under the eferences CI 77 499, 77 492, 77 491, manganese violet (CI77 742), ultramarine blue (CI 77 007), chromium oxide (CI 77 288), chromium hydrate (CI 77 28) and ferric blue (CI 77 510) can be mentioned.

0 00 0 0 000 00 0 0o o Oa o 0 0 0 0 0 o o a o o o 0 00 ooo0 00 o 0 00 0 0 0 o o S QO The organic pigments are selected, in particular, from among the D and C red No. 19 (CI 45 170), D and C red No. 9 (CI 15 575), D and C red No. 21 (I 45 380), D and C orange No. 4 (CI 15 512), D and C orange No. 5 (CI 45 370), D and C red No. 27 (CI 45 410), D and C red No. 13 (CI 630), D and C red No. 7 (CI 15 850), D and C red No. 6 (CI 850), D and C yellow No. 5 (CI 19 140), D and C red No.

36 (CI 12 085), D and C orange No. 10 (CI 45 425), D and C yellow No. 6 (CI 15 985), D and C red No. 30 (CI 73 370), D and C red No. 3 (CI 45 430) pigments and lacquers based on cochineal carmine (CI. 75 470).

The pearly-pg4inaes- can be selected from among the white pearly pigments, such as mica covered with titanium oxide, bismuth oxychloride, the colored pearly pigments such 15 as titanium mica with iron oxides, titanium mica with ferric blue, chromium oxide, etc., titanium mica with an organic pigment of the above-identified type as well as those based on biCmuth oxychloride.

When the pigments are used, they are present in 20 amounts of 3 to 30% by weight in relation to the total weight of the composition depending on the coloration and the intensity of the coloration which it is sought to obtain.

The compositions in aczordance with the present 25 invention can in particular be in the form of oil-in-water or water-in-oil emulsions, or in the form of suspensions in a solvent medium, or even in an anhydrous solid or paste.

The methods for the preparation of these various types of compositions are well known to the skilled artisan.

When they are used in the form of emulsions, the srrcecompositions can contain -active agents which are well known in the art.

A particularly preferred embodiment consists of preparing anionic or non-ionic emulsions using anionic or non-ionic 4-active agents in amounts preferably between 2 and 30% by weight in relation to the total weight of the composition.

L -7- Surace3 Among the anionic -s-ai-Ge-active agents which can be used alone or in combination, the following can in particular be mentioned: the alkaline salts, the ammonium salts, the amine salts or the aminoalcohol salts of the following compounds: alkylsufates, alkylether sulfates, alkylamide sulfates and ether sulfates, alkylarylnolyetthersulfates, monogylce ride sulfates ,I alkylsulfonates, alkyl amide sulfonates, alkylarylsulfonates, c-oJefin sulfonates, paraffin sulfonates, alkylsulfosuccinates, alkylethersulfosuccinates, alkylamidL svlfosuccinates, aIkylsulfosuccinamates, alkylsulfoacetates, alkylpolyglycerol carboxy-- 0 ,0 15 lates, al kyl pho spha t es/al kyl ethe rpho spha te s 00 0 alkylsarcosinates, alkylpolypeptidates, alkylamidopolypeptidates, alkylisothionates, alkyltaurates.

0 0 0The alkyl radial in all these compounds generally designates a chain of 12 to 18 carbon atoms.

o0 other anionic ten-s-e-active agents are composed of fatty acid salts such as oleic, ricJino)leic, palmitic or stearic acids, copra oil acids or hydrogenated copra oil and particular the amine salts, such as amine stearates.

'0 0 25The following can also be mentioned: .0 01 the acyl lactylata, the acyl radical of which contains 8 to 20 carbon. atoms, 00 a0 the carboxylic acids of polyglycolic ethers corresponding to the forniula:.

Alk (ocH 2 -CH 2 )~-OCH COOHi 0 0 in the acid or salt form in which the Alk substituent 0:00 corresponds to a linear chain having from 12 to 18 carbon atoms and where n is an inteqer of between 5 and cJrYPOCce Among the non-ionic -ef-eG-active agents which can be used alone or in ec ombination# the following in particular can be mentioned: alcohols, polyethoxylated, polypropoxylated or polyglycerolated alkylphenols and fatty acids with -8a fatty chain containing 8 to 18 carbon atoms. The following can also be mentioned: ethylene and propylene oxide copolymers, ethylene and propylene oxide condensates on fatty alcohols, polyethoxylated fatty amides, polyethoxylated fatty amines, ethanolamides, glycol fatty acid esters, oxyethylenated or non-oxyethylenated sorbitan fatty acid esters, saccharose fatty acid esters, polyethylene-glycol fatty acid esters, phosphoric triasters, fatty acid esters or glucose derivatives.

Other compounds in this class are the condensation products of an a-diol, a monoalcohol, an alkylphenol, an amide or a diglycolamide with glycidol or a glycidol precursor. In particular, these condensation are: those of the formula: S 15 R 4 CHOH CH 2 O (CH 2 CHOH CH O H 0 00 0. wherein R 4 designates an aliphatic, cycloaliphatic or 0400 00 arylaliphatic radical preferably having between 7 and 21 00o carbon atoms and mixtures thereof, with the aliphatic chains X capable of containing ether, thioether or hydroxymethylene 20 groups, and where p is between 1 and 10 inclusive, such as O0 0 described in French Patent 2,091,516: those of the formula:

R

5 3 0 (CH 2 OH)- H Q0 wherein Rg designates an alkyl, alkenyl or alkylaryl radical o 25 and q is a statistical value of between 1 and 10 inclusive, o 00 aoo such as described in French Patent 1,477,048; or those of the formula: 00 so o R, -CONH-CH -CH 2

O-CH

2

-CH

2 -CHOH-CH2 wherein R6 designates a radical or a mixture of linear or 30 branched, saturated or unsaturated aliphatic radicals which uoo0 can possibly contain one or several hydroxyl group(s), 00o having between 8 and 30 carbon atoms, of synthetic or natural origin, r represents an integer or decimal number from 1 to 5 and designates the degree of average condensation, such as are described in French Patent 2,328,763.

o 0O 0 0 0oo 0 0o 0oo 00 0 oo o o a 0000 O 00 o oo 00 00 0 0 00 0 0 00 0 00 0 C 0 0 0o o00 o oo -9- The non-ionic emulsions are principally composed of a mixture of oil and/or fatty alcohol, or polyethoxylated or polyglycerolated alcohols, such as polyethoxylated stearylic or cetylstearylic alcohols.

The anionic emulsions are preferably constituted from amin- stearates. e ew-e In addition to the-a-beme-m ion d- ingredients, the compositions in accordance with the present invention can contain ingredients which are conventionally used in particular in make-up compositions and which are selected from among softeners, preservatives, sequesterin agents, perfumes, thickeners, oils, silicones, cohesion agents and polymers as well as the alkalizing or acidifying agents normally used in the cosmetic field.

15 The thickeners which can be used can be natural or synthetic. Among the natural thickeners, gums of various sorts, such as gum Arabic, guar or carob gum can be mentioned. Among the synthetic thickeners, cellulose derivatives such as hydroxyethylcellulose, carboxymethycell- 20 ulose, starch derivatives, cellulose ether derivatives having quaternary ammonium groups, cationic polysaccharides, acrylic or methacrylic polymer salts, polyenes or polysiloxanes can be mentioned.

A thickener foc the compositions can also be 25 obtained with a mixture of polyethyleneglycol and polyethyleneglycol stearate and/or distearate or with a mixture of phosphoric esters and fatty amides.

The compositions in accordance with the invention also contain components which are generally considered ad a cosmetically acceptable support, a solvent or a mixture of aqueous or anyhydrous solvents.

The present invention also relates to a method of manufacture of a composition in accordance with the invention consisting of combining a cosmetically acceptable support with a wax having a melting point of between 60 and O1 0 C and a keratin hydrolysate having an average molecular weight of between 50,000 and 200,000, with the ratio by weight of the quantity of keratine hydrolysate used to the quantity of wax(es) used being between 0.005 and A further object of the invention is a method for ,aking up eyelashes using a composition such as defined above.

in order to better understand the object of the invention, by way of purely illustrative and non-limiting examples, several methods of use will be described be~low.

in the examples given below, A keratin hydrolysate was used, which is sold by CRODA CHEMICALS LTD. under the name 'KEfASOL", which has an average molecular weight of 100,000 and which has the following composition in by weight: 0 00 000q 000 000 00 00 00 00 0 0 a0C 0 00 00 00 0 0 o 0 o 0 00 0 0 0 0 0 0 00 00 0 0 0 0 0 -Isolpucine 15 -Leucine...

Lysine -Methionine -Cystn e -PhenylAlanine 20 -Threonine..

-TytQsine -Wine -4rqnine 9.

e. 0. q. C. C .CC. 419 10.6 3,9 4.8 1.4 5.2 7.6 3.8 4,2 -Alanine -Aspartic acid .eCee6eei~..ee.. 911 30 -Serine 8.3 it was used in the form of a solution containing 14% protein hydrolysate, 15% prfopyleneglycolo 3% Nacl and 67% water, with a pH of 5-7.

i 0 0 0 0000 0 00000 0 0 0 0 0 00 00 o0 o' 0 000 0o 0 0 0 0 0 000 0 -11- EXAMPLE 1 The mascara composition with the li.owing formula was prepared: Carnauba wax 5 g Candelilla wax 5 g Ethyl alcohol 3 g Montmorillonite modified with an organic substance 4 g Keratine hydrolysate (calculated by dry weight) 0.3 g Talc 10 g Black iron oxide 10 g Isoparaffin quantity sufficient for 100 g The method was the following: 15 The waxes were heated to 80°C. The talc and the pigments were added. The montmorillonite which had been modified with an organic substance and part of the isoparaffin were then incorporated. At approximately 40 0

C,

the keratin hydrolysate, thq ethyl alcohol and the remainder 20 of the isoparaffin were added. The mixture was passed through a grinder.

This mascara, with a very rapid application time, provided a good make-up by coating the eyelashes and increasing their length.

The following Examples 2 to 7 relate to maasara compositions in emulsion form. These mascaras are ready 4oo use. The general method was the following: The waxes were melted. The pigments were incorporated. The aqueous phase containing, depending on 30 the case, the gums and/or the hydroxyethykcellulose and the keratin hydrolysate were heated to the same temperature as the wax phase. The two phases were mixed and vigorously stirred.

The mascaras obtained in this manner, the formulations of which are given below, require relatively short application times but, however, provide good make-ups.

accordance with claim 1, in accordance with which a cosmetically acceptable support is combined with a wax having a melting point of between 60 and 110'C and a keratifle hydrolysate having an average molecular weight of -12- EXAMPLE 2 The mcscara cOmn-sition with the following formula was prepared: Triethanolamine g 3 g 2 g 10 g Propyl 0.20 g Methyl parahydroxybenzoate................ 0.20 g Gum 0.50 g Zeratin hydrolysate (calculated by dry 0.15 g -Black iron g Aluminosilicate 5 g Water.........quantity sufficient g EXAMPLE 3 The mascara composition with the following formula was Prepared: 2-amino 2-methyl 1-propanol stearate 25 g Canclelilla 5 g Beeswax 8 g Methyl 0.l5 g Propyl parahydroxybe:azoate............. 0.15 g Carob gum 3 g -Xanthara 3 g K Ieratin hydrolysate (calculated by dry 0.08 g B Blak iron 8 -Water quantity Sufficient for 100 g EXAMPLE 4 The mascar-a composition with the folloving formula~ was prepared: -Triethanolarine Stearate .120 g Mircytlii a .6.60. 5 g -Carnawba wax,...j 10 g -Beeswax 3 'C

Q

I 0 003 o 044 04 6 0 0 0 0 4 0 00 4 0' 0 Oa o 0 0 04 0 0 o 0 0 0 0 0 00 0 C0 0O -13- Tragacanch gum 5 g Keratin hydrolysate (calculated by dry weight) 0.6 g Black Iron Oxide 5 g Water quantity sufficient for 100 g EXAMPLE The mascara composition with the following formula was prepared: Triethanolamine stearate 15 g Candelilla wax 8 g Carnauba wax 10 g Hydroxyethylcellulose 0.9 g Keratin hydrolysate (calculated by dry weight) 0.75 g 15 Black iron oxide 8 g Methyl parahydroxybenzoate 0.15 g Propyl parahydroxybenzoate 0.15 g Water quantity sufficient for 100 q EXAMPLE 6 20 The mascara compcsition with the following formula was prepared; Triethanolamine stearate 10 g Candelilla wax 15 g Beeswax 17 g Xanthan gum 1 g Keratin hydrolysate (calculated by dry weight) 0.15 g Black iron oxode 5 g Aluminosilicate polysulfide (ultramarin blue) 4 g 30 Preservative Sufficient Quantity Water quantity sufficient for 100 g EXAMPLE' 7 The mascara composition with the following formula was prepared: Triethanolamine stearate 10 g Carnauba wax 8 g Beeswax 8 g The followingj statement is a l~ull description of this invention, including the best mezhod of performing it known to:- u -14- Keratin hydrolysate (calculated by dry weight) 1 g Black iron g Aluminosilicate g quantity quantity sufficient g EXAMPLE 8 An anhydrous block of mascara with the following formula was prepared: Triethanolamine g 6 g Microcrystalline g Saturated fatty acid 11 g -Methyl g Propyl g Gum Arabic 5.70 g Keratin hydrolysate (calculated by dry a 00 weight) 0.25 g .0 R ed iron g Black iron oxide 5 g 000 The method wras the following: 00 Q o0 .0 The waxes were melted. The pigments were added.

00 00Q 0 '1 The gum Arabic and the kfratin hydrolysatp were incorporated. Thti mixture was passed through a heating grinder. The remaining ingredients were added. The entire mixture was again melted and poured~ into molds while 00 stirring lightly.

,)OOQDGood eyelash make-up is obtained in a very short C, 0 0 appl.ication time.

0 .000 000 0 0000 0 0 00 00 0 0 0 O V 00 N

Claims (19)

1. A cosmetic composition for making up eyelashes comprising, in a cosmetically acceptable support, at least one wax having a melting point of between 60 and 110 0 C, at characterized by the fact that it contains at leat :-on keratin hydrolysate having an average molecular weight of between 50,000 and 200,000, with the weight ratio of the quantity of keratine hydrolysate used to the quantity of wax(es) used being between 0.005 and

2. The composition in accordance with claim 1, wherein the keratin hydrolysate has a molecular weight of approximately 100,000.

3. The composition in accordance with claim 1, wherein the keratin hydrolysate comes from hair, wool, hooves, horn, fur, silks or feathers.

4. The composition in accordance with claim 1, wherein o the wax is an animal wax, a vegetable wax, a mineral wax, a 0 0 0 o0o synt-hetic wax, various fractions of natural waxes, or 0 o00 0 mixtures thereof.

The composition in accordance with claim 4, containing an animal wax selected from the group formed by 0oo beeswaxes, lanolin waxes and China insect waxes. 00 0

6. The composition in accordance with claim 4, o o0 containing a vegetable wax selected from the group formed by 0.0 0 Carnauba waxes, Candelilla waxes, Ouricurry waxes, cork fiber waxes, sugar can waxes and Japan waxes. 0 00 0 0 a

7. The composition in accordance with claim 4, 0 0 0 containing a mineral wax selected from the group formed by paraffins, microcyrstalline waxes, Montan waxes and Ozocerites. Hydrolysates' having a molecular weight of approximately 100,000 are particularly suitable. IV '7 Qt -16-

8. The composition in accordance with claim 4, containing a synthetic wax selected from the group formed by polyethylene waxes, the waxes obtained by the Fisher and 'ropsch synthesis and the waxy copolymers as well as their esters.

9. The composition in accordance with claim 1 containing from 2 to 40% by weight of waxes in relation to the total weight of the composition.

The composition in accordance with claim 1, wherein the weight ratio of the quantity of keratin hydrolysate used is between 0.05 and 5% by weight in relation to the total weight of the composition.

11. The composition in accordance with claim 1, containing at least one mineral pigment, organic pigment or 0) -0 000 pearly pigment. 00 0 0.V0

12. The composition in accordance with claim 11, 0 containing a mineral pigment selected from the group formed o0 0 by titanium dioxide, possibly surface treated, black, 00 00 000 00 yellow, red and brown iron oxides, manganese violet, ultramarine blue, chromium oxide, chromium hydrate and ferric blue. 0 0 13. The composition in accordance with claim 11, 0 00cnann nogncpgetslce rmtegopfre 0' 0 by the D and C red No. 19, D and C red No 9, D and C red 0 0' 0 No. 21, D and C orange No. 4j D andl C orange No. 5, D and C red No. 27, D and C red No.

13, D ;i'id C red No. 7, D and C red No. 6, D and C yellow No. 5,'p &nd C red No. 36, D and C )0000 orange No. 10, D and C yellow No. 6, D and C red No* 30, D 0 0 and C red No. 3 pigments and lacquers based on cochineal 0 00 carmine 1 r- I I ci I I I I r- I P. ii i S I -17-

14. The composition in accordance with claim 11, containing a pearly pigment selected from the group formed by mica covered with titanium oxide, bismuth oxychloride, titanium mica colored with iron oxides, titanium mica colored with ferric blue, chromium oxide, and the like, titanium mica colored with an organic pigment of the above- identified type as well as colored bismuth oxychloride.

The composition in accordance with claim 11, in which the pigment (or pigments) is (are) present in an amount of 3 to 20% by weight in relation to the total weight of the composition.

16. The composition in accordance with claim 1, in the form of an oil-in-water or water-in-oil emulsion, or in the form of a suspension in a solvent medium, or further in an anhydrous solid or paste form. 0 00 00 0 oooo 0000 0 o

17. The composition in accordance with claim 1, 00 0 Cc9e- containing at least one -ens-i-e-active agent present in an o o amount of between 2 and 30% by weight in relation to the 0 0o 0 ,o total weight of the composition. 00 00 0 0 0 0 0

18. The composition in accordance with claim 1, containing at least one additive selected from among softeners, preservatives, sequestering agents, perfumes, g thickeners, oils, silicones, cohesion agents and polymers as oo 0 1 1 well as alkalizing or acidifying agents.

19. A method for the preparation of a composition in 06 C 0 accordance with claim 1, in accordance with which a cosmetically acceptable support is combined with a wax oo having a melting point of between 60 and 110°C and a o 0 keratine hydrolysate having an average molecular weight of 0 0o Sbetween 50,000 and 200,000, with the weight ratio of the quantity of keratin hydrosysate used to the quantity of wax(es) used being between 0.005 and r 510) can be mentioned.' A method for making up eyelashes using a composition in accordance with claim 1. DATED this 5th day of April, 1989. L IOREAL WATERMARK PATENT QUEEN STREET MELBOURNE, VIC. ATTORNEYS

3000. 0.4 4 0 0 0 04 0400 0 0 4 04 0 I PUytl' t k h 'j e~ tt I~ f ?4elb Disk 1/1,5/NG