AU592079B2 - Analysis of multi-phase mixtures - Google Patents

Description

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AU-AT 5 5 8 96 WORLD INTELLECTUAL PROPERTY ORG International Bureau PCT 9 INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY ('PCT) (51) International Patent Classification 4 (11) International Publication Number: WO 86/ 05586 G01N 9/36, 33/28, E21B 43/12 Al (43) International Publication Date: September 1986 (25.09.86) (21) International Application Number: PCT/AU86/00067 (81) Designated States: AT (European patent), AU, BE (European patent), CH (European patent), DE (Euro- (22) International Filing Date: 18 March 1986 (18.03,86) pean patent), FR (European patent), GB, GB (European patent), IT (European patent), JP, LU (European patent), NL, NL (European patent), NO SE (31) Priority Application Number: PG 9815/85 (European patent), US.

(32) Priority Date: 19 March 1985 (19.03.85) Published (33) Priority Country: AU With international search re.port.

SECTION .341)(a) DIRECTION SEE FOI.I NAME DIRECTED Conoc.o p.ec.IQ '-oclc.s c ,ti) Inventors; aunu 7 Inventors/Applicants (for US only) PRENDEGAST, Gavan, Joseph, James [AU/AU]; 3 Seaton Court, iMt A.

Waverley, VIC 3149 WEBB, David, Andrew O.J.p. 198 fAU/AU]; 4 Simla Court, Heathmont, VIC 3135 (AU).

(74) Agents: SMEETON, Anthony, R. et al.; Davies Col- AUSTRALIAN lison, I Little Collins Street, Melbourne, VIC 3000 13 0CT 986 PATENT

OFFICE

(54) Title: ANALYSIS OF MULTI-PHASE MIXTURES (57) Abstract /13 Method and apparatus for analysing rulti-phase mixtures and particularly for the analysis of the mixture d'scharge from an oil well, the ap- 1 0 paratus including means which may be in the form of a mass flow meter 11) for measuring the mass flow rate and density at one or more points along the flow path and means which may be in the form of a choke valve (13) for causing a characteristic 0 change between two points along the flow path. From the information provided, selected properties of the phases in the mixture can be determined. This method and apparatus can be used for controlling the discharge from an oil well head, 1 I I t 9 WO 86/05586 PCT/AU8600067 -1- "ANALYSIS OF MULTI-PHASE MIXTURES" This invention relates generally to a method and apparatus for determining selected properties of a multi-phase mixture.

Whilst it will be appreciated by those persons skilled in the art that the method and apparatus of the invention are readily applicable to the analysis of a wide variety of multi-phase mixtures, one particularly advantageous application relates to the analysis of the oil mixture discharged from an oil well. It will be convenient therefore to hereinafter describe the invention with reference to that particular application.

It is often necessary to be able to monitor and/or determine the various properties of the oil/gas/ wattr mixture being discharged from an oil well.

The properties of the mixture which are particularly important are the volume rate and density, of each phase. It is the current practice when analysing the mixture discharged from an oil well to feed a relatively large quantity of the mixture to a "test separator". The "test separator" separates the multi-phase mixture into discrete phases before flow measurement is effected.

I

1 2 3 4 6 7 8 9 11 12 13 14 16 17 S 18 S 19 oo 20 21 S 22 23 24 25 S26 27 *Deeo. 28 29 31 S: 32 33 34 36 37 Separators of this general type are known and it is not proposed to provide a detailed description here. The major disadvantages of separators of this type are that they are relatively bulky and take up considerable space particularly when used on off-shore platforms. As a result each offshore platform usually has only one test separator, and thistest separator is employed to take measurements from one well at a time. A further disadvantage is that they are relatively expensive.

It is an objection of the present invention to provide a relatively simple method and apparatus for analysing multi-phase mixtures and with reference to the specific application referred to above, it is an object to alleviate one or more of the aforementioned advantages.

According to one aspect of the present invention there is provided a method of continuous analysis of mixtures for determining selective properties of components in the mixture flowing along a flow path, the method including the steps of: Firstly, directly measuring and/or calculating the pressure, temperature, density and mass flow rate of the mixture at a first point upstream of a characteristic change zone in the flow path: causing a change in the characteristics of the mixture flow in said characteristic change zone; thereafter measuring directly and/or calculating the pressure, temperature, density and mass flow rate at a second point downstream of said characteristic change zone; and determining the selective properties of the mixture on the basis of the information collected together with known parameters using algorithms.

The characteristic which is changed can be any one of a suitable group. For example, the characteristic changed may be a pressure change or a temperature change or at least a partial separation of the phases in the mixture.

89i681IARSSPE.01g.55896claims.

S WO 86/05586 PCT/A U86/00067 3- The characteristic change may also be effected by adding a substance to the mixture between the two points. This substance may be in the form of a chemical to cause a reaction or may be by the provision of a side stream of gas. In another arrangement, the characteristic change can be initiated by a change at some other point in the flow path which thereby causes the characteristic change. For example, a pressure differential upstream of the two points may be sufficient to cause a change between the points.

By using the above method, it is possible to determine the properties of the various phases of the mixture such as, for example, the volume and density of each particular phase. To determine these properties it may be necessary to carry out more than two density and/or mass flow measurements or calculations and where two or more measurements are carried out a corresponding flow characteristic changes are required between the adjacent measuring points. In some instances not all variables may be required to be determined purely from the mass flow measurement technique. For example, in mixtures such as the oil mixture from oil wells it may be convenient to assume that the density of the water phase and the oil phase remain constant along each pressure differential. From the information collected, it may be possible to produce suitable algorithms from which the required i characteristics can be determined.

Thus in the particular example of a mixture 30 discharged from an oil well, a series of equations can be written from which the various properties of the phases of the mixture can be determined.

r- WO 86/05586 PCT/A U86/00067 r I i Il ILI-~Il 3- i ar*C 1 WO 86/05586 PCT/AU86/00067 -4- In a typical example, it is reasonable to assume that the density of the oil and water remain substantially constant throughout the mixture flow.

As such, it is possible to determine these values in any suitable manner. Using the method of the present invention the following properties are measured: The density of the mixture at points 1 and 2 (P1 and /P 2 The mass flow rate of the mixture (MT1) (where the characteristic change is a pressure differential, the mass flow rate remains constant).

The temperature and pressure at points 1 and 2.

The density of the oil (Po) and water (Pw) (As mentioned earlier the density of the oil and water are measured separately).

r WO086/05586 PCT/A U&6/00067

P

2 -A~2 ,P2T2 MT1 MT2 MT1 /glVgl W~l o Vo 1 (4) MT2 /'2g /2Vw2 /'40 2 Vo 2 Vwl Vw2- (6) Vol Vo2- VTl Vqi1+ V01+ Vw (8) VT2 Vg2 +Vo2+ Vw2 (9 V is volume subscript g is gas o is oil w is water If (fjJ, /9ol' 2 (O2 and 1 are assumed or Shand measured it is therefore possible to determine VglP Vg2, fgl, lag 2 Vol, Vo 2 Vwl, Vw2, VT1, VT2.

invent~ion. there is provided apparatus for ana ing multi -phase mixtures comprising means directly measuring the density of a mixtu at at least two selected points along a f path of the mixture, means for measurin e mass flow rate of the mixture at at least of the points and means for c ausn change in the flow characteristics of 215 ~tr betweem tle.~ relt I Y11 5a 1 2 3 4 6 7 8 9 11 12 13 14 15 16 17 18 18 19 21 22 23 24 26 27 28 29 31 o S 33 34 36 'E 8 According to another aspect of the present invention there is provided apparatus for continuous analysis of mixtures for determining selective properties of components in the mixture flowing along a flow path, the apparatus comprising: a first mass flow meter for directly measuring the density and mass flow rate at a first point upstream of a characteristic change zone in the flow path: means for causing a change in the characteristics of the mixture flowing in said characteristic change zone; and a second mass flow meter for directly measuring the density and the mass flow rate of the mixture at a second point downstream of the characteristic change zone, the arrangement being such that selected properties of the mixture can be determined on the basis of the information collected together with known parameters using algorithms.

896816, IARSSPE.019,55896c1aim..

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WO 86/05586 PCT/AU86/00067 -6- The apparatus of the present invention may comprise means for directly measuring the density of a mixture at at least two selected points along the path of travel of the mixture, means for measuring the mass flow rate of the mixture at at least one of the points and means for causing a change in the flow characteristics of the mixture between the points.

It will be appreciated that this apparatus can be interfaced with a suitably programmed computer so that, for example, the properties of the mixture utilizing the equations above can be quickly determined.

The means for directly measuring the density and mass flow rate of the mixture may be in the form of a mass flow meter. A typical example of a suitable mass 13 flow meter is sold under the trademark Micro Motion and is described in United States patent specification 422,338 and reissue patent 31450. It may also be necessary to measure the temperature and pressure of the mixture at the mass flow meters and this can be done in any suitable manner. In another arrangement the density of the mixture could be measured by an on-line density meter one example of which is sold under the trademark SOLARTRON by the company Solartron Schlumberger.

If the characteristic change is a pressure differential then this can be caused by any suitable device such as a choke or the like.

.If the characteristic change is a phase separation then in one preferred form a hydro cyclone of the type which is for example described in International application PCT/AU84/00195 which has been specifically developed for the treatment of oily water.can be used.

In one form the mass flow measurement may be taken at the inlet to the hydro cyclone and the outlet therefrom 'i I .I- 7- 1 2 3 4 6 7 8 9 11 12 13 14 16 17 18 S 19 20 o 21 21

S.

22 23 24 26 26 27 28 29 31 S32 33 34 36 37 containing the oil/gas phase which is removed from the oil water mixture. In certain instances, it may be necessary to use additional mass flow measurement meters with two or more hydro cyclones in series.

In the above described arrangement the mass flow measurement is of the total flow. It is possible however tomerely take a sample of the flow and pass that sample through a device comprising two mass flow measurement meters with a pressure differential therebetween. Using such an arrangement however it is only possible to determine the relative percentage volumes of the phases.

According to another aspect of the present invention there is provided a method of controlling discharge from a well head comprising the steps of analysing the multi-phase mixture being discharged from the well head as described above and from the results obtained controlling the discharge conditions in a selected manner.

According to yet another aspect of the present invention there is provided apparatus for controlling discharge from a well head the apparatus being characterized by multi-phase analysis apparatus for analysing multi-phase mixtures as described above a choke operatively connected to the discharge line from the well head and control means (P) for controlling opening and closing of said choke said control Ineans being operable in response to information received from said multi-phase analysis apparatus.

According to yet another aspect of the present invention there is provided apparatus for controlling discharge from a well head, the apparatus being characterized by multi-phase analysis apparatus as described above means for delivering gas to the well having valve means cornt-lling the quantity of gas delivered and control means for controlling opening or closing of id valve means said control means being operable in response to information received from said multi-phase analysis apparatus.

896816,IARSSPE.019,55896Claims, 7a- 1 Preferred embodiments of the invention will hereinafter 2 be described with reference to the accompanying drawings in 3 which:- 4 Figure 1 is a schematic circuit drawing showing the general principle of the invention; 6 Figure 2 is a schematic circuit drawing incorporating- 7 one form of device according to the invention; 8 Figure 3 shows an arrangement by which a sample of the 9 mixture is taken from the main line; Figures 4 and 5 show a form of the apparatus when used 11 with hydro cyclones; 12 Figure 6 is a circuit diagram showing a use of the 13 apparatus in relation to gas optimization; 14 Figure 7 is a circuit diagram showing a use of apparatus for controlling discharge from an oil well head; S16 and 0* o. 17 Figure 8 is a circuit diagram of apparatus used in the 18 example.

19 Figure 1 shows schematically what may be required to be 20 measured on-line at points 1 and 2 and with a characteristic 21 change and C to determine the desired properties of the 22 various phases in the miXture.

23 Referring to Figure 2 of the drawings, there is shown 24 an oil rig 1 comprising oll wells 2, 3 and 4, eee o e* 0816, SSPE 55896 890816, IARSSPE.019,55896calBmB, +-uu WO 86/05586 PCT/AU86/00067 -8 a discharge line 6 for delivering the mixture to a separator (not shown). The device of the present invention comprises a pair of mass flow meters and 11 having a choke 13 therebetween. The mass flow meters can measure the mass flow as well as the density of the mixture.

In Figure 3, there is shown an embodiment where a sample is taken from the main delivery line 6, the sample passing through mass flow meters 10 and 11 and choke 13.

In Figures 4 and 5 there is shown the arrangement of mass flow meters 10, 11 13 and 14 with hydro cyclones 15 and 16. In this particular arrangement the characteristic change as effected by phase separation. For example, in Figure 4 mass flow meter measures the mass flow and density of the mixture in total and mass flow meter 11 measures the mass flow and density of the oil and gas phases,. It is therefore possible to devide equations to determine the desired properties of each phase.

One application of the invention elates to gas optimization of oil wells. To bring the oil water mixture to the surface of a well,gas is delivered down the well and thereby reduces the mass of the mass of the column of mixture within the production tubing.

As a result of this mass reduction, the reservoir pressure causes the column to rise to the surface.

The amount of gas fed down the well will affect the oil/water/gas mixture delivered to the surface. Thus, by controlling the gas flow the desired oil/water/gas mixture can be controlled. Figure 6 is one example of how the gas flow can be controlled using the method and apparatus of the presnet invention.

WO 86/05586 i PCT/AU86/00067 -9 Gas is fed under pressure along line 30 through throttling valve 20 down the well where it mixes with the column of oil/water and sometimes gas to bring the mixture to the surface. The properties of the mixture are determined through mass flow meters 10 and 11 and choke valve 13 and the information fed to controller C. The controller then opens or closes throttling valve 20 as required.

In figure 7 there is shown an arrangement whereby well flow is controlled by the control of the well head choke. In this installation, two mass flow meters and 11 are operatively connected to the well output line, the meters being disposed on opposite sides of the choke 13. The instrumentation provided at each poin consists of a temperature transmitter, a pressure transmitter and a density transmitter.

The transmitter measurements are adapted to be fed to a processor P such as a computer containing data and algorithms regarding characterization of gas pressure/ temperature/volume/density relationships, mass balance relationships and data regarding oil and water properties as a function of temperature and pressure.

The processor P uses this data and the transmitter signals to determine oil, water and gas mass and volumetric flow rates. This information is used as a basis for controlling the position of thi choke.

This may be done automatically or manually, By employing the multi-phase analysis system of the invention, for example, on un off-shore platform 30 with multiple wells, continuous measurement of production from each well can be achieved This cn lead to improved rese.voi. aTm he, ana.la46i also provides for a more resreV: tiaU ~i.w measurement from the well .b proved WO 86/05586 PCT/AU86/00067 response time compared to the "test separator" discussed earlier.

In the particular example given above, the system is likely to be able to monitor slugging flow whereas the "test separator" cannot effectively owing to its poor response time.

An example of multi-phase measureme.'- according to the present invention is given below for measurement of a distillate fuel oil/water/air mixture, the measurement being done in a laboratory.

Figure 8 shows the layout of the test installation.

The mixture tested was a mixture of diesel, water and air. The water, diesel and air were fed into the system via flow meters M 1 M2 and M 3 and through gate valves V 8

V

9 and V 10 respectively. M 1 was a Fisher and Porter Rotameter M 2 a VAF positive displacement vane meter and M 3 a Fisher and Porter Purge Rotameter. The gate valves were used to vary the inlet flows.

The flow of the various phases passed to a static flow mixer 1 which provided for a. homogeneous three phase flow. A clear pipe section 2 was provided for enabling visual inspection.

The mixture passed to the test circuit section of the installation where measurement of the flow rate was made by meter M 4 which was a Micrometer D40 mass flow meter with the DT7 density and temperature and flow rate and flow stabilization units. The flow meters Ml, M 2 and i13 were calibrated against meter M 4 before the test and the meter M 4 was volumetrically calibrated before the test.

The pressure gauge measured the pressure at the meter M 4 and the pressure gauge /a was used in conjunction with meter M 3 to give the inlet air flow.

c WO 86/05586 PCT/AU86/00067 -11- The valves V 1

V

2

V

3 V4, V 5 and V 6 were arranged to control the direction of flow and V 7 was the pressure dropping gate valve. This valving arrangement was used to simulate upstream and downstream of the pressure dropping valve V 7 As such, it was only necessary to use one meter M 4 rather than two.

Initial readings were taken of the three inlet flows and upstream conditions at the meter M 4 thereafter the system was reversed to simulate downstream conditions and further readings were taken. Table 1 sets out the results of four tests conducted.

The mathematics involved with test number 2 are given below.

Initial Known Data Density Density Density water pw) diesel d) air pg)

(UPSTREAM)

1.00s.g.

0.828s.g.

-3 1.29X10- (0C 1 Atmos) After Valve V 7 (DOWNSTREAM) Before Valve V 7

MTI

P

1 T1 /Tl 19.2 330 19.4 .825 Kg/min KPng

°C

S .g.

MT2 P2 T2 ?T2 19.2 265 19.4 .812 ~hWidn a 4 Irarr~ "1 WO 86/05586 PCT/AU86/00067 -12- Inlet Conditions Vd' 10.7 Vmin 10.4 A/min :Vg' 2.2 £/min The above flows were corrected to calibrated flows from original readings.

Calculating volume flows from above .VTI M 1 Al 23.2 /min aVT VT2 VT1 VT2 MT2 A2 23.6 /min 0.4 /min VTI Vd' Vw' Vg' 23.3 A /min The expected change in VT due to the change in gas volume induced across VT can be calculated from PV nRT (ideal gas).

For this case nRT is constant.

SVg2 Vgl (using Vg' 1.7 Z/min 470 KPng) P2 VgI 2.2 /miin Vg2 2.6 Z/min

Z

l~i AVg= Vg2-Vgl 0. 4 Y /min (This result compares with AVT as measured by M 4 of 0.4 /min).

Given that the volume flow rates of diesel and 20 water will remain constant across V 7 that is Vdl Vwl Vd2 Vw2 then the measured change in volume flow rate across V 7 is the flow rate change in the gas phase; that is WO 8605586PCT/A U86/00067 VT2 VTl Vg2 Vd2 VW~ 2 Vgl Vdl -Vwl =Vg2 -Vgl aVg 9 0.4 Z/min Using the ideal gas law in this instance Vg2 Vg1 'Vg =nf RT1 A Vg flRT2 P1 P2 nR eiVg T2 _Ti P2 P1 From the above result 1AVg= 0. 4 Z/min Tl T2 19 .4 0

C

P1 330 KPag P2 =265*KPag nR 3.3 At meter M 3 Pa 470 KPag T= 20 0

C

Vg 3.3X 293 1. 7 X/min 571 This compaxes with the calibrated inlet volume of 1 .7 k/min .Changing the above flow rate to) the flow rates ait the upstream and downstream Vgl 2.2 Z/min IVg2 2.6 z /min To find the gas density at the above c'jnditions it is necessary to know its moleculal weight M 29 ),g/kmol

A

WO 86105586 PC/A U86/00067 14- )Ogi 1 g/z =4.3 g/z The calculation of the water and diesel flow rates can be found from the following equations V7w= MTl Mgl +/Od (Vgi VT1) 1Rw 0 d Vd MTl Mgl Ow( Vgl -VTl /Od -A'O Substituting values into the above Vw ='10.5 Vd=l10.5 These are comparable to the' inlet flows TABLE 1 BEFORE' VALVE (UPSTREAM) M T PI T I Density V TI kg/min kPag c AFTER VALVE (DOIWWSTREAM) MT2 P2 2 Dest V T 2 jOT2 INLET CONDITIbNS jOiesel Water AiLr Vd Vw Vg M Tf-7JVd'*?AVw' 19.4 22.0 19.0 325 19-2 330 19-0 360 17.4 325 19.5 21.8 23.2 24.3 23-2 19.0 19.2 19.0 17.4 19.4 23.6 24.3 10.8 10.7 10.8 14.5 9-.9 10.4 9-8 5.2 1.72 3.7 3.4 18.7 -19.3 18.7 17.2 vT =MT

'IT

AVT -vT2 Ti Avg -Vgl Vg2, Vgl,2 calculated from gas law and pressures at measurement points.

(1) (2) (3) (4) o _2 0.4

Claims (4)

16- THE CLAIMS DEFINING THE INVENTION ARE AS FOLLOWS:- 1 A method of continuous analysis of mixtures for determining selective properties of components in the mixture flowing along a flow path, the method including the steps of: Firstly, directly measuring and/or calculating the pressure, temperature, density and mass flow rate of the mixture at a firEjt point upstream of a characteristic change zone in the flow path: causing a change in the characteristics of .the mixture flow in said characteristic change zone; thereafter measuring directly and/or calculating the pressure, temperature, density and mass flow rate at a second point downstream of said characteristic change zone; and determining the selective properties of the mixture on the basis of the information collected together with known parameters using algorithms. so G. 2. A method according to claim 1 wherein the characteristic which is changed is a pressure change. 3. A method according to claim 1 wherein the characteristic which is changed is a temperature change. *00 4. A method according to claim 1 wherein the S characteristic which is changed is at least a partial A" separation of the phases in the mixture. I: 5. A method according to claim 1 wherein said *I characteristic change is initiated by a change other than between said two points which causes said characteristic change. 6. A method according to claim 1 including the step of S utilizing an interfaced computer to determine the selected Si properties. 896816, IARSSPE.019,55896dlaims, I

17- 7. Apparatus for continuous analysis of mixtures for determining selective properties of components in the mixture flowing along a flow path, the apparatus comprising: a first mass flow meter for directly measuring the density and mass flow rate at a first point upstream of a characteristic change zone in the flow path: means for causing a change in the characteristics of the mixture flowing in said characteristic change zone; and a second mass flow meter for directly measuring the density and the mass flow rate of tIe mixture at a second point downstream of the characteristic change zone, the arrangement being such that selected properties of the mixture can be determined on the basis of the information collected together with known parameters using algorithms. de 8 Apparatus according to claim 7 including a. computer arranged so that the properties of the mixture can be S: determined from the information obtained from the other S parts the apparatus. S 9. Apparatus according to claim 8 wherein said means for directly measuring the density and mass flow rate of the mixture is in the form of a mass flow meter. 10. Apparatus according to claim 7 wherein said means for directly measuring the density and mass flow rate of the mixture is in the form of a mass flow meter. 11. Apparatus according to claim 7, wherein the characteristic changed is a pressure differential caused by 9 a choke valve. 0* S 12. Apparatus according to claim 7 wherein the characteristic changed is a phase separation by a hydro cyclone. 13. A method of controlling discharge from a well head S890816,tARSSPE.01955896clalm8. -18 comprising the steps of analysing the multi-phase mixture being discharged from the well head in accordance with claim 1 and from the results obtained controlling the discharge conditions in a selected manner. 14. A method according to claim 13 wherein the discharge of the mixture from the well is controlled by a choke, the method including operating the choke in response to the results obtained. A method according to claim 13 wherein the discharge of the mixture from the well is controlled by the delivery of gas to the well the method including controlling the Sdelivery of the gas in response to the results obtained. 16. Apparatus for controlling discharge from a well head the apparatus being characterized by multi-phase analysis apparatus for analysing multi-phase mixtures according to claim 7 a choke operatively connected to the discharge line from the well head and control means controlling opening and closing of said choke said control means being operable in response to information received from said multi-phase analysis apparatus. S 55 17. Apparatus for controlling discharge from a well head, the apparatus being characterized by multi-phase analysis apparatus according to claim 7 means for delivering gas to S the well having valve means controlling the quantity of gas delivered and control means for controlling opening or closing of said valve means said control means being operable in response to information received from said multi-phase analysis apparatus.

18. A method of continuous analysis of mixtures substantially as hereinbefore described with reference to the drawiigs. 839d816, IARSSPE.O19,bS89661aims. -19

19. Apparatus for the continuous analysis of mixtures substantially as hereinbefore described with reference to the drawings. Dated this 16th day of August, 1989 DAVIES GOLLISON Patent Attorneys for NOEL CARROLL Sese 0 0 0@ S. 6S 0 0 S. 0 *5 S. S 0 S S 0 0S S S S S SSS S eSee OS SS S 55 S S. *S S S S. S 00 55 S S S S @5 S S S S 55 I ARSSPE.019i*55896claims, I