AU2002306555A1 - Method for manufacturing a dental restoration - Google Patents
Method for manufacturing a dental restorationInfo
- Publication number
- AU2002306555A1 AU2002306555A1 AU2002306555A AU2002306555A AU2002306555A1 AU 2002306555 A1 AU2002306555 A1 AU 2002306555A1 AU 2002306555 A AU2002306555 A AU 2002306555A AU 2002306555 A AU2002306555 A AU 2002306555A AU 2002306555 A1 AU2002306555 A1 AU 2002306555A1
- Authority
- AU
- Australia
- Prior art keywords
- providing
- restoration
- oxide
- accordance
- cohesion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims description 25
- 238000004519 manufacturing process Methods 0.000 title claims description 11
- 239000000463 material Substances 0.000 claims description 35
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 22
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 22
- 239000000843 powder Substances 0.000 claims description 21
- 239000011230 binding agent Substances 0.000 claims description 14
- VQCBHWLJZDBHOS-UHFFFAOYSA-N erbium(iii) oxide Chemical compound O=[Er]O[Er]=O VQCBHWLJZDBHOS-UHFFFAOYSA-N 0.000 claims description 10
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 8
- 239000000654 additive Substances 0.000 claims description 7
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 claims description 4
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims description 4
- MMKQUGHLEMYQSG-UHFFFAOYSA-N oxygen(2-);praseodymium(3+) Chemical compound [O-2].[O-2].[O-2].[Pr+3].[Pr+3] MMKQUGHLEMYQSG-UHFFFAOYSA-N 0.000 claims description 4
- 229910003447 praseodymium oxide Inorganic materials 0.000 claims description 4
- 229910010293 ceramic material Inorganic materials 0.000 claims description 3
- 239000002241 glass-ceramic Substances 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 229910052573 porcelain Inorganic materials 0.000 claims description 3
- 238000005245 sintering Methods 0.000 claims description 3
- 230000000996 additive effect Effects 0.000 claims 4
- 238000004040 coloring Methods 0.000 description 7
- 239000000919 ceramic Substances 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000009434 installation Methods 0.000 description 4
- 238000010146 3D printing Methods 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 238000005520 cutting process Methods 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 230000018109 developmental process Effects 0.000 description 3
- 235000013980 iron oxide Nutrition 0.000 description 3
- 238000013001 point bending Methods 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- 239000008107 starch Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 208000002064 Dental Plaque Diseases 0.000 description 1
- 239000004150 EU approved colour Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- WQHONKDTTOGZPR-UHFFFAOYSA-N [O-2].[O-2].[Mn+2].[Fe+2] Chemical compound [O-2].[O-2].[Mn+2].[Fe+2] WQHONKDTTOGZPR-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000011162 core material Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000011351 dental ceramic Substances 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 210000004394 hip joint Anatomy 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000011344 liquid material Substances 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 229940006093 opthalmologic coloring agent diagnostic Drugs 0.000 description 1
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- HASDHSVWTCCGIM-UHFFFAOYSA-N zinc iron(2+) oxygen(2-) Chemical class [O-2].[O-2].[Fe+2].[Zn+2] HASDHSVWTCCGIM-UHFFFAOYSA-N 0.000 description 1
Description
METHOD FOR MANUFACTURING A DENTAL RESTORATION
The present invention relates to a method for manufacturing a dental restoration.
Different methods are known in the art for manufacturing a dental restoration, wherein these methods are mainly determined by the type of materials used.
Ceramic materials have been successfully applied for many years in dental restorations . The two most important functions of restorative ceramics are aesthetics and strength. However, most dental ceramics do not fulfil both functions. Different porcelains and glass ceramics are used for aesthetic applications. These have a natural tooth colour and translucence but have a relatively low three-point bending strength (50- 200 MPa) .
Higher-strength materials have been developed as basic core material . These materials have a three-point bending strength of 150 to 500 MPa, but are generally too opaque and must be combined with translucent porcelain veneered thereon. The fracture toughness however remains low compared to metal alloys, whereby these ceramics are susceptible to production errors and stress concentrations, such as occur when there is a less than optimal fit between prepared tooth and the restorative ceramic.
Medically pure yttrium-stabilized tetragonal zirconium oxide (Y-TZP) is characterized by both aesthetics and a high three-point bending strength, higher than 1000 MPa, with a great toughness and an excellent resistance to slow crack development. Zirconium oxide has heretofore been applied very
successfully in orthopaedics as hip-joint ball. It has also been very successfully introduced in dentistry for root pins . It has further been found to have a very low susceptibility to dental plaque. However, zirconium oxide has a white colour not suitable for dental restorations and must be coloured with a colour corresponding with the tooth colours .
In DE 4207179 Al (1992) Yoshida describes a method of colouring orthodontic zirconium oxide components by adding a mixture of erbium-, praseodymium-, iron- and zinc oxides. Some additives, such as zinc, result in serious degradation of the physical properties of the sintered zirconium oxide. In DE 19938143 Al erbium-, iron- and manganese oxide are mainly applied as colouring oxides .
Effect of suitable colour additives to sintered Y-TZP zirconium oxide
These are first dissolved in hydrochloric acid and added to zirconium oxide and admixtures dissolved in hydrochloric acid. By hydrolysis with ammonia, annealing of the deposition and fine-grinding, an homogeneously coloured zirconium oxide powder is obtained which can be further processed. This takes place by mixing the powder with binders (for instance 2% by weight polyvinyl alcohol and 0.15% by weight oleic acid), and making this
into a geometrical shape by pressing. The binder is burnt out for 0.5 to 2 hours at a temperature of 850- 1000 °C. A dental restoration, enlarged by the sintering shrinkage factor, is then cut out by means of a CAD/CAM system and the product is sintered to increase density at 1300-1500 °C for 2-4 hours. The result is a monochrome coloured restoration.
It is however desired in dentistry to colour the restoration locally. The base structure of a crown, in the form of a cap, is thus coloured slightly browner at the bottom, the so-called shoulder portion, and lighter yellow in the sections in the cutting edge area.
At the moment the restorations are further produced in automatic manner with fairly traditional cutting technique, with proportionately high material loss. With the use of zirconium oxide the price of the material is considerable and a net-shape production method would be desirable. Accurate colouring with locally occurring variations is complex here, if not impossible. Up to the present there has been no possibility of making restorations using rapid prototyping or even in automated manner which have locally different properties or colours. In addition to the absence of an experimental configuration, there has also been no possibility of locally colouring product files.
In order to obviate or at least reduce the above stated and other problems and drawbacks of the known art, a new method for manufacturing a dental restoration is provided according to the present invention, which is distinguished by the combination of measures of claim 1. With a method according to the invention it is possible to manufacture a restoration with a very natural appearance, in respect of both colour, translucence and so on and the shape thereof.
A possible embodiment of a method according to the invention can be designated as 3D printing. Experimental configurations have recently been constructed, particularly at the Massachusetts Institute of Technology (MIT, Boston, USA) , with which it is possible using software to determine the colours of the STL files (input files for rapid prototyping machines) . Owing to the development of new materials and machines, the possibilities in the field of 3D printing have recently been greatly expanded, although there is still no application known for using this technology for dental restorations. The printer is used to apply an organic binder to a powder compacted using a roller, whereby complex shapes can be produced. The principle of 3D printing (3DP) is known. The method was developed by the institute of technology of Boston, MIT. Market developments of the principle have since taken place. Zcorporation for instance has however used starch, which has little environmental impact and is freely available, as binder.
A drawback to the use of starch as binder is that it increases the shrinkage of the bound ceramic powder and that the shrinkage can moreover not be predicted in all directions. This makes starch less useful for the accuracy desired in dentistry. This in contrast to cold isostatic pressed (more than 2000 bar) ceramic, which after cutting and sintering results in a sufficiently accurate restoration. A new material, ZP100, was developed as an alternative, with which thin-walled and complex products such as dental restorations can indeed be printed in 3D with sufficient accuracy.
It is furthermore possible to "build in" a natural colour layer by layer by adding Pr-oxide (yellow) , Fe- oxide (brown) and Er-oxide (violet) as pigment to the binder. The quantities to be applied amount for each of
these colour additives to between for instance 0.05% and 2.0% of the weight.
In a preferred embodiment a method according to the invention has the characteristics of claim 2. By providing the material layer by layer, the depth to which this material must be processed to provide it with cohesion remains limited. The production process hereby remains readily manageable and leads to good results. Particularly good results are achieved in respect of the appearance of the restoration to be produced (colour, translucence and so on) , if the measures of claim 3 are herein also applied. Colour variations can thus be realized in a three-dimensional direction over the outer surface of the restoration to be produced, while colour variations could only be realized in the direction in which the layers are successively provided on each other when layers to be provided separately have a homogenous composition. According to claim 3 a variation resulting in colour variation can also be realized in the layers, so that even more natural variations can be obtained. In yet another preferred embodiment the non- cohesive form of the material to be applied can be one of powder form, liquid, thin slices and so on. This is related to the method to be applied for providing cohesion therein. In a powder form the cohesion can for instance be given by selectively adding binder to the powder or by subjecting the powder to the action of at least one laser. Particularly in the case of liquid forms of the material to be applied, an arrangement with two lasers can be used depending on the capacity of this liquid material to transmit laser light, where the intended effect of providing cohesion, for instance solidifying, only occurs where the laser beams coming from the lasers cross each other. In an embodiment with thin slices colour variations can be realized per slice
around the periphery thereof, or the slices can be manufactured from homogenous material .
The material to be applied in the method is for instance ceramic material, porcelain, glass ceramic, and so on, but preferably yttrium-stabilized tetragonal zirconium oxide, to which the invention is however not limited. This has properties which are very advantageous in respect of the invention.
In order to allow variation in the appearance over the outer surface of the restoration to be manufactured, for instance in respect of the colour thereof, many materials can be used, such as erbium oxide, iron oxide and praseodymium oxide, manganese oxide and so on. Such materials can be combined well with the materials to be applied in the restoration to be manufactured, particularly zirconium oxide.
The present invention will be elucidated on the basis of an embodiment hereinbelow and a description of the one annexed drawing, which shows schematically a partly cut-away perspective view of an embodiment of the invention.
The figure shows a possible embodiment of an installation as implementation of the present invention. Installation 1 comprises a holder (not shown) in which layers of powder-form yttrium-stabilized tetragonal zirconium oxide (Y-TZP) can be placed one over another. The zirconium oxide is in powder form so that a body 2 of this powder is formed as the stacking of said layers onto each other progresses. The layers are arranged using a powder holder 3, which in this embodiment is funnel-shaped and adapted to pour a measured quantity. Powder holder 3 is provided for this purpose with a flap 4 with which the pouring opening of powder holder 3 can be closed.
If a quantity of powder-form zirconium oxide from powder holder 3 is poured, either at one location or spread over the upper surface of the body 2 formed so far, the upper surface is levelled using a driven roller 5 which is coupled to a motor 6. The powder-form zirconium oxide is not only levelled, but also compressed and compacted to the desired extent. The installation further comprises a laser generator 7 connected to a control 8. The focal point 9 of the laser generator acts on the upper surface of body 2 to give the powder-form zirconium oxide cohesion in the upper layer, which has just been poured from powder holder 3 and levelled and compacted by roller 5. Under the influence of the action of the focal point of laser generator 7 there also occurs adhesion to the material lying beneath the last poured layer. Any random shape can thus be generated in a layered structure, precisely this being advantageous in the case of dental restorations because of the usually erratic shapes thereof.
The figure shows such a dental restoration 10. The method for manufacture hereof is being performed, so that the dental restoration 10 is only partly shown. A part of the body 2 of loose powder is further cut away in the view in order to show the dental restoration 10. The focal point 9 of laser generator 7 follows a pattern in the material of the last spread layer such that, after processing a number of layers in this manner, a desired three-dimensional form of the dental restoration can be obtained.
In the areas 11 and 12 of the dental restoration 10 material is added to the powder-form zirconium oxide prior to the action of focal point 9. This may be for instance iron oxide, erbium oxide or praseodymium oxide. These materials have an effect on the colour, wherein
iron oxide produces a brown discolouration and erbium oxide a light violet discolouration, while praseodymium oxide has a deep yellow colouring effect.
It is shown clearly in the figure that, round the periphery on the upper side of the dental restoration 10 formed so far in fig. 1, variations are arranged in the depth in internal direction of layers 11 and 12, which can otherwise also be doped with colouring agents differing from those stated above. Colour variation is thus possible in all directions over the outer surface of the dental restoration 10 to be formed. The properties of the material for doping in areas 11 and 12 can be varied from the bottom to the top, just as around the surface shown in fig. 1 of a cross-section of a dental restoration 10 to be formed.
The installation 1 as shown in fig. 1 is also referred to as a colour printer.
As an alternative within the scope of the present invention to the laser generator 7 shown in fig. 1, it is also possible to work with a binder which gives the non-cohesive powder-form zirconium oxide cohesion locally and where desired. As shown in fig. 1, this can also take place in a structure with layers. The binder is active up to a depth to which the binder is able to give cohesion to the powder-form zirconium oxide. In such an application this active depth is of course greater than the thickness of a layer of powder-form zirconium oxide which has been applied or is to be applied, so that the adhesion to underlying parts of the restoration 10 to be formed is also brought about.
Dental restorations are manufactured with colour printer 1 from a loose, dry zirconium oxide powder with 3% yttrium oxide. The geometry for the restorations originates from a scan-design system such as a CAD-CAM system. Printer 1 is used to apply an organic binder to
powder compacted with the roller, whereby complex shapes can be produced. A solution of 4% by weight 4AC (Hercules, USA) is made as binder. Three print suspensions are made herefrom by adding respectively 0.05% Pr-oxide, 0.05% Fe-oxide and 0.05% Er-oxide. The pigment is added to the binder as micronized powder and mixed in a turbine agitator. In a colour printer a bridge is printed with an STL data file, with differentiated colouring, obtained from a CAD system for dental restorations. After construction the bridge is heated to 650 *C at 5°C/min. The restoration is then heated to 1500 "C at lO'C/min and held there for 2 hours. The bridge exhibits the designed local differentiated colouring .
Claims (10)
1. Method for manufacturing a dental restoration, comprising of:
- determining an external form and dimensions available for a completed restoration, for instance with a CAD-CAM system;
- obtaining an image of a natural tooth to be replaced with the restoration or a tooth corresponding therewith, wherein the image comprises at least the external surface visible in use of the to be replaced or corresponding tooth, with variations in the appearance therein;
- defining locally on and at least to visible depth below the surface of appearance-determining properties of at least one material to be applied for the restoration in accordance with the obtained image and the variations in the appearance therein;
- constructing the restoration, comprising of : providing at least one material to be applied in non-cohesive form; and providing cohesion to the material in accordance with the available form and dimensions.
2. Method as claimed in claim 1, comprising of providing layer by layer in non-cohesive form at least one material to be applied; and providing cohesion to the material in each of the layers in accordance with the available form and dimensions as well as providing adhesion to a preceding layer before providing a subsequent layer.
3. Method as claimed in claim 2 , wherein the providing of at least one material to be applied comprises of: varying the at least one material to be applied in accordance with variations in the image in a plane defined by each of the layers.
4. Method as claimed in claim 1, 2 or 3 , wherein the non-cohesive form is at least one of the forms from the group comprising: powder form, liquid, thin slices etc.
5. Method as claimed in claim 1, comprising of providing as the material to be applied at least one of the materials from the group comprising: ceramic material, porcelain, glass ceramic, yttrium-stabilized tetragonal zirconium oxide (Y-TZP) etc.
6. Method as claimed in claims 3 and 5, comprising of adding an additive to the material in order to bring the appearance of the restoration to be thus formed into accordance with the image.
7. Method as claimed in claim 6, wherein the additive is at least one of the materials from the group comprising: erbium oxide (Er203) , iron oxide (Fe203) ; and praseodymium oxide (Pr203) , manganese oxide (Mg203) etc.
8. Method as claimed in claim 1, wherein the providing of cohesion to the material comprises of: applying a binder, such as the action of at least one laser and/or the addition of a binding additive.
9. Method as claimed in claim 8, followed by sintering out of binding additive.
10. Method as claimed in claim 2, further comprising of: levelling a provided layer of material, particularly in powder form, prior to providing the material with cohesion.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL1017907 | 2001-04-23 | ||
| NL1017907A NL1017907C2 (en) | 2001-04-23 | 2001-04-23 | Method for the manufacture of a dental restoration. |
| PCT/NL2002/000259 WO2002085242A1 (en) | 2001-04-23 | 2002-04-19 | Method for manufacturing a dental restoration |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU2002306555A1 true AU2002306555A1 (en) | 2003-04-17 |
| AU2002306555B2 AU2002306555B2 (en) | 2006-04-27 |
Family
ID=19773286
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2002306555A Ceased AU2002306555B2 (en) | 2001-04-23 | 2002-04-19 | Method for manufacturing a dental restoration |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US7686989B2 (en) |
| EP (1) | EP1383442B1 (en) |
| JP (1) | JP4371659B2 (en) |
| AT (1) | ATE397421T1 (en) |
| AU (1) | AU2002306555B2 (en) |
| BR (1) | BR0209109B1 (en) |
| CA (1) | CA2444875C (en) |
| DE (1) | DE60226966D1 (en) |
| ES (1) | ES2307756T3 (en) |
| NL (1) | NL1017907C2 (en) |
| WO (1) | WO2002085242A1 (en) |
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| US6712856B1 (en) * | 2000-03-17 | 2004-03-30 | Kinamed, Inc. | Custom replacement device for resurfacing a femur and method of making the same |
| US20060008777A1 (en) * | 2004-07-08 | 2006-01-12 | Peterson David S | System and mehtod for making sequentially layered dental restoration |
| US8173562B2 (en) | 2006-05-23 | 2012-05-08 | Ivoclar Vivadent Ag | Shaded zirconia ceramics |
| EP2353542B1 (en) | 2006-05-23 | 2016-05-11 | Ivoclar Vivadent AG | Method for manufacturing coloured blanks and dental moulded parts |
| EP1870073A1 (en) * | 2006-06-23 | 2007-12-26 | Aepsilon Rechteverwaltungs GmbH | Material and blank for dentures |
| EP2610232B1 (en) * | 2006-07-25 | 2019-06-26 | Tosoh Corporation | Zirconia sintered bodies with high total light transmission |
| WO2008023053A2 (en) * | 2006-08-25 | 2008-02-28 | Ceramtec Ag | Process for producing coloured sintered ceramic bodies, in particular for dental applications |
| DE502006009446D1 (en) * | 2006-09-13 | 2011-06-16 | Ivoclar Vivadent Ag | Multicolored molded body |
| US9655690B2 (en) | 2007-08-15 | 2017-05-23 | Ez Pedo, Inc. | Pedodontic/veterinary dental crown system |
| US20100028835A1 (en) * | 2007-08-15 | 2010-02-04 | Hansen John P | Pedodontic/veterinary dental crown system |
| DE102008060860A1 (en) * | 2008-12-09 | 2010-06-10 | Josef Hintersehr | Method for accurately manufacturing dental components using a sinter or SLM method |
| JP5454887B2 (en) * | 2009-10-16 | 2014-03-26 | 学校法人 日本歯科大学 | Method for manufacturing crown restoration |
| DE102010037160A1 (en) | 2010-08-25 | 2012-03-01 | Amann Girrbach Ag | Process for the production of dentures |
| US8641938B2 (en) | 2011-09-27 | 2014-02-04 | Cmp Industries Llc | Denture and method and apparatus of making same |
| WO2013122662A1 (en) * | 2012-02-13 | 2013-08-22 | 3M Innovative Properties Company | Dental milling block containing individualized dental article and process of production |
| EP2849672B1 (en) | 2012-05-10 | 2019-10-16 | Renishaw Plc. | Method of manufacturing an article |
| US9468509B2 (en) | 2013-03-15 | 2016-10-18 | Cmp Industries Llc | Dental crowns and bridges and method of making same |
| JP2015043793A (en) * | 2013-08-27 | 2015-03-12 | ディーダブルエス エス・アール・エル | Method for manufacturing artificial teeth |
| US9545302B2 (en) | 2013-11-20 | 2017-01-17 | Dermagenesis Llc | Skin printing and auto-grafting |
| EP3322377B1 (en) * | 2015-07-16 | 2019-03-27 | 3M Innovative Properties Company | A method of making a dental article |
| EP3108849B2 (en) | 2016-04-25 | 2025-03-12 | Solventum Intellectual Properties Company | Multi-layered zirconia dental mill blank and process of production |
| CN108175529A (en) * | 2017-12-25 | 2018-06-19 | 深圳市盛世智能装备有限公司 | A kind of quick device and method for preparing zirconium oxide artificial tooth |
| CN113501712A (en) * | 2021-07-28 | 2021-10-15 | 南京金鲤新材料有限公司 | Nano brown zirconium oxide powder and preparation method thereof |
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| JP2571646B2 (en) | 1991-03-06 | 1997-01-16 | ホーヤ株式会社 | Ivory-colored zirconia sintered body and its use |
| BE1008372A3 (en) * | 1994-04-19 | 1996-04-02 | Materialise Nv | METHOD FOR MANUFACTURING A perfected MEDICAL MODEL BASED ON DIGITAL IMAGE INFORMATION OF A BODY. |
| US5823778A (en) * | 1996-06-14 | 1998-10-20 | The United States Of America As Represented By The Secretary Of The Air Force | Imaging method for fabricating dental devices |
| NL1007059C2 (en) * | 1997-09-17 | 1998-10-09 | Cordent Multi Media B V | Dental image processing |
| US6322728B1 (en) * | 1998-07-10 | 2001-11-27 | Jeneric/Pentron, Inc. | Mass production of dental restorations by solid free-form fabrication methods |
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-
2001
- 2001-04-23 NL NL1017907A patent/NL1017907C2/en not_active IP Right Cessation
-
2002
- 2002-04-19 WO PCT/NL2002/000259 patent/WO2002085242A1/en active Application Filing
- 2002-04-19 AU AU2002306555A patent/AU2002306555B2/en not_active Ceased
- 2002-04-19 CA CA002444875A patent/CA2444875C/en not_active Expired - Fee Related
- 2002-04-19 AT AT02733585T patent/ATE397421T1/en active
- 2002-04-19 EP EP02733585A patent/EP1383442B1/en not_active Expired - Lifetime
- 2002-04-19 US US10/474,605 patent/US7686989B2/en not_active Expired - Fee Related
- 2002-04-19 JP JP2002582823A patent/JP4371659B2/en not_active Expired - Fee Related
- 2002-04-19 DE DE60226966T patent/DE60226966D1/en not_active Expired - Lifetime
- 2002-04-19 BR BRPI0209109-7A patent/BR0209109B1/en not_active IP Right Cessation
- 2002-04-19 ES ES02733585T patent/ES2307756T3/en not_active Expired - Lifetime
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