ATE523479T1 - Verfahren zur herstellung von cyclohexylbenzen - Google Patents
Verfahren zur herstellung von cyclohexylbenzenInfo
- Publication number
- ATE523479T1 ATE523479T1 AT08785025T AT08785025T ATE523479T1 AT E523479 T1 ATE523479 T1 AT E523479T1 AT 08785025 T AT08785025 T AT 08785025T AT 08785025 T AT08785025 T AT 08785025T AT E523479 T1 ATE523479 T1 AT E523479T1
- Authority
- AT
- Austria
- Prior art keywords
- cyclohexylbenzene
- molecular sieve
- inorganic oxide
- producing cyclohexylbenzene
- hydrogenation metal
- Prior art date
Links
- HHNHBFLGXIUXCM-GFCCVEGCSA-N cyclohexylbenzene Chemical compound [CH]1CCCC[C@@H]1C1=CC=CC=C1 HHNHBFLGXIUXCM-GFCCVEGCSA-N 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 2
- 238000005984 hydrogenation reaction Methods 0.000 abstract 2
- 229910052809 inorganic oxide Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 239000002808 molecular sieve Substances 0.000 abstract 2
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 239000002131 composite material Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
- C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
- C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
- C07C6/126—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of more than one hydrocarbon
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
- C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/74—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition with simultaneous hydrogenation
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/06—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by conversion of non-aromatic six-membered rings or of such rings formed in situ into aromatic six-membered rings, e.g. by dehydrogenation
- C07C37/07—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by conversion of non-aromatic six-membered rings or of such rings formed in situ into aromatic six-membered rings, e.g. by dehydrogenation with simultaneous reduction of C=O group in that ring
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/08—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by decomposition of hydroperoxides, e.g. cumene hydroperoxide
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C407/00—Preparation of peroxy compounds
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C409/00—Peroxy compounds
- C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
- C07C409/14—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom belonging to a ring other than a six-membered aromatic ring
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
- C07C45/53—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of zinc, cadmium or mercury
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/14—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of germanium, tin or lead
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/44—Palladium
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/46—Ruthenium, rhodium, osmium or iridium
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/75—Cobalt
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/755—Nickel
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US96487407P | 2007-08-25 | 2007-08-25 | |
PCT/EP2008/006072 WO2009021604A1 (en) | 2007-08-15 | 2008-07-11 | Process for producing cyclohexylbenzene |
Publications (1)
Publication Number | Publication Date |
---|---|
ATE523479T1 true ATE523479T1 (de) | 2011-09-15 |
Family
ID=38983550
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AT08785025T ATE523479T1 (de) | 2007-08-25 | 2008-07-11 | Verfahren zur herstellung von cyclohexylbenzen |
Country Status (9)
Country | Link |
---|---|
US (1) | US7910778B2 (de) |
EP (1) | EP2176200B1 (de) |
JP (1) | JP5529737B2 (de) |
KR (1) | KR101574809B1 (de) |
CN (1) | CN101796000B (de) |
AT (1) | ATE523479T1 (de) |
ES (1) | ES2373189T3 (de) |
TW (1) | TWI455910B (de) |
WO (1) | WO2009021604A1 (de) |
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EP2282984B1 (de) | 2008-05-01 | 2012-11-21 | Exxonmobil Chemical Patents Inc. | Verfahren zur herstellung von cyclohexylbenzol |
CN102216215B (zh) * | 2008-07-28 | 2014-03-26 | 埃克森美孚化学专利公司 | 使用emm-12制备烷基芳族化合物的方法 |
US8212096B2 (en) * | 2008-07-28 | 2012-07-03 | Exxonmobil Chemical Patents Inc. | Hydroalkylation of aromatic compounds using EMM-13 |
EP2346803A1 (de) * | 2008-08-29 | 2011-07-27 | ExxonMobil Chemical Patents Inc. | Verfahren zur herstellung von phenol |
CN102333747A (zh) | 2009-02-26 | 2012-01-25 | 埃克森美孚化学专利公司 | 生产环己基苯的方法 |
US8633343B2 (en) | 2009-05-26 | 2014-01-21 | Exxonmobil Chemical Patents Inc. | Transalkylation of polycyclohexylbenzenes |
IT1395594B1 (it) * | 2009-06-29 | 2012-10-16 | Polimeri Europa Spa | Processo per la preparazione di fenolo e cicloesanone |
WO2011115704A1 (en) | 2010-03-19 | 2011-09-22 | Exxonmobil Chemical Patents Inc. | Dealkylation process |
WO2011146167A2 (en) * | 2010-05-20 | 2011-11-24 | Exxonmobil Chemical Patents Inc. | Hydroalkylation processes |
SG186980A1 (en) * | 2010-09-14 | 2013-02-28 | Exxonmobil Chem Patents Inc | Cyclohexylbenzene compositions |
CN103052618B (zh) * | 2010-09-14 | 2015-08-05 | 埃克森美孚化学专利公司 | 生产苯酚的方法 |
US9545622B2 (en) | 2010-10-11 | 2017-01-17 | Exxonmobil Chemical Patents Inc. | Activation and use of hydroalkylation catalysts |
JP6014943B2 (ja) * | 2010-12-17 | 2016-10-26 | エクソンモービル ケミカル パテンツ インコーポレイテッド | 脱水素触媒及び方法 |
CN103261125B (zh) * | 2010-12-21 | 2016-03-30 | 埃克森美孚化学专利公司 | 生产单环烷基取代的芳族化合物的方法 |
EP2675772B1 (de) | 2011-02-18 | 2015-09-16 | ExxonMobil Chemical Patents Inc. | Verfahren zur herstellung von cyclohexylbenzen |
US9017641B2 (en) * | 2011-02-21 | 2015-04-28 | Exxonmobil Chemical Patents Inc. | Hydrogen purification process |
WO2013058882A1 (en) | 2011-10-17 | 2013-04-25 | Exxonmobil Chemical Patents Inc. | Process for producing cyclohexylbenzene |
SG11201404618UA (en) * | 2012-02-29 | 2014-10-30 | Exxonmobil Chem Patents Inc | Process for producing phenol comprising a step of hydroalkylation of benzene to cyclohexylbenzene |
US9555403B2 (en) | 2012-07-24 | 2017-01-31 | Exxonmobil Chemical Patents Inc. | Activation and use of hydroalkylation catalysts |
US9233888B2 (en) | 2012-08-14 | 2016-01-12 | Exxonmobil Chemical Patents Inc. | Process for producing cyclohexylbenzene |
SG11201501863TA (en) | 2012-10-12 | 2015-04-29 | Exxonmobil Chem Patents Inc | Activation and use of hydroalkylation catalysts for the preparation of cycloalkylaromatic compounds, phenol and cyclohexanone |
CN105050716A (zh) * | 2013-03-25 | 2015-11-11 | 埃克森美孚化学专利公司 | 制造烷基化芳族化合物的方法 |
EP2978526A1 (de) * | 2013-03-25 | 2016-02-03 | ExxonMobil Chemical Patents Inc. | Verfahren zur herstellung einer alkylierten aromatischen verbindung |
CN105636692A (zh) * | 2013-10-18 | 2016-06-01 | 埃克森美孚化学专利公司 | 包括加氢烷基化催化剂的活化的加氢烷基化方法和苯酚与环己酮的制备方法 |
US9908829B2 (en) | 2013-12-20 | 2018-03-06 | Exxonmobil Chemical Patents Inc. | Process for making phenol and/or cyclohexanone |
CN105899477A (zh) | 2013-12-20 | 2016-08-24 | 埃克森美孚化学专利公司 | 环己基苯组合物 |
CN105439802B (zh) * | 2014-08-27 | 2018-01-09 | 中国石油化工股份有限公司 | 加氢烷基化制备环己基苯的方法 |
CN105582990B (zh) * | 2014-10-24 | 2018-06-08 | 中国石油化工股份有限公司 | 环己基苯生产用催化剂 |
CN108993577A (zh) * | 2018-06-13 | 2018-12-14 | 厦门大学 | 一种苯加氢制环己基苯的催化剂及其制备方法和应用 |
CN111250148B (zh) * | 2020-03-25 | 2021-01-29 | 厦门大学 | 一种用于苯加氢烷基化制环己基苯的催化剂及其制备方法和应用 |
CN113926485A (zh) * | 2021-11-15 | 2022-01-14 | 北京化工大学 | 一种钌锌复合双功能催化剂及其制备方法和应用 |
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DK2056964T3 (da) * | 2006-07-28 | 2019-05-06 | Exxonmobil Chemical Patents Inc | Hidtil ukendt molekylsigtesammensætning, fremgangsmåde til fremstilling deraf og fremgangsmåde til anvendelse deraf |
EP2051806B1 (de) * | 2006-07-28 | 2016-08-17 | ExxonMobil Chemical Patents Inc. | Molsiebzusammensetzung (emm-10), herstellungsverfahren dafür und verwendung für kohlenwasserstoffumwandlungen |
JP5192546B2 (ja) | 2007-09-21 | 2013-05-08 | エクソンモービル ケミカル パテンツ インコーポレイテッド | シクロヘキシルベンゼンの製造プロセス |
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2008
- 2008-07-11 US US12/665,154 patent/US7910778B2/en active Active
- 2008-07-11 ES ES08785025T patent/ES2373189T3/es active Active
- 2008-07-11 KR KR1020107005501A patent/KR101574809B1/ko not_active IP Right Cessation
- 2008-07-11 AT AT08785025T patent/ATE523479T1/de not_active IP Right Cessation
- 2008-07-11 JP JP2010520442A patent/JP5529737B2/ja not_active Expired - Fee Related
- 2008-07-11 EP EP08785025A patent/EP2176200B1/de not_active Not-in-force
- 2008-07-11 WO PCT/EP2008/006072 patent/WO2009021604A1/en active Application Filing
- 2008-07-11 CN CN2008801030168A patent/CN101796000B/zh not_active Expired - Fee Related
- 2008-07-14 TW TW097126652A patent/TWI455910B/zh not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
CN101796000B (zh) | 2013-07-10 |
JP2010535822A (ja) | 2010-11-25 |
KR20100055466A (ko) | 2010-05-26 |
ES2373189T3 (es) | 2012-02-01 |
KR101574809B1 (ko) | 2015-12-04 |
US20100191017A1 (en) | 2010-07-29 |
TWI455910B (zh) | 2014-10-11 |
TW200922908A (en) | 2009-06-01 |
EP2176200B1 (de) | 2011-09-07 |
CN101796000A (zh) | 2010-08-04 |
US7910778B2 (en) | 2011-03-22 |
JP5529737B2 (ja) | 2014-06-25 |
EP2176200A1 (de) | 2010-04-21 |
WO2009021604A1 (en) | 2009-02-19 |
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