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ATE185154T1 - Amido-siladiylverbrückte katalysatorkomponente, verfahren zur herstellung und verwendung - Google Patents

Amido-siladiylverbrückte katalysatorkomponente, verfahren zur herstellung und verwendung

Info

Publication number
ATE185154T1
ATE185154T1 AT94925817T AT94925817T ATE185154T1 AT E185154 T1 ATE185154 T1 AT E185154T1 AT 94925817 T AT94925817 T AT 94925817T AT 94925817 T AT94925817 T AT 94925817T AT E185154 T1 ATE185154 T1 AT E185154T1
Authority
AT
Austria
Prior art keywords
amido
catalyst component
siladiyl
production
bridged catalyst
Prior art date
Application number
AT94925817T
Other languages
English (en)
Inventor
Masahide Murata
Terry John Burkhardt
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Application granted granted Critical
Publication of ATE185154T1 publication Critical patent/ATE185154T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
AT94925817T 1993-08-26 1994-08-10 Amido-siladiylverbrückte katalysatorkomponente, verfahren zur herstellung und verwendung ATE185154T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/112,491 US5486585A (en) 1993-08-26 1993-08-26 Amidosilyldiyl bridged catalysts and method of polymerization using said catalysts.

Publications (1)

Publication Number Publication Date
ATE185154T1 true ATE185154T1 (de) 1999-10-15

Family

ID=22344175

Family Applications (1)

Application Number Title Priority Date Filing Date
AT94925817T ATE185154T1 (de) 1993-08-26 1994-08-10 Amido-siladiylverbrückte katalysatorkomponente, verfahren zur herstellung und verwendung

Country Status (7)

Country Link
US (2) US5486585A (de)
EP (1) EP0739361B1 (de)
AT (1) ATE185154T1 (de)
DE (1) DE69420975T2 (de)
ES (1) ES2139094T3 (de)
GR (1) GR3032161T3 (de)
WO (1) WO1995006071A1 (de)

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ES2161919T3 (es) 1994-11-22 2001-12-16 Atofina Res Metalocenos puenteados para uso en sistemas cataliticos para la polimerizacion de olefinas.
ES2124054T3 (es) * 1995-06-12 1999-01-16 Targor Gmbh Compuesto de metal de transicion.
AT403376B (de) * 1995-07-03 1998-01-26 Danubia Petrochem Polymere Metallocene mit silylsubstituierten brücken und deren einsatz für die olefinpolymerisation
EP0857180B1 (de) * 1995-10-27 1999-11-24 The Dow Chemical Company Metallische komplexe, die geträgert werden können
AU704366B2 (en) * 1995-10-27 1999-04-22 Dow Chemical Company, The Supportable biscyclopentadienyl metal complexes
IT1276084B1 (it) * 1995-11-07 1997-10-24 Enichem Spa Ciclopentadienil derivati pontati e procedimento per la loro preparazione
US6002033A (en) * 1995-11-22 1999-12-14 Fina Research, S.A. Bridged metallocenes for use in catalyst systems
US5679814A (en) * 1995-12-11 1997-10-21 Albemarle Corporation Purification of metallocenes
US6077806A (en) * 1997-03-06 2000-06-20 Equistar Chemicals, Lp Catalyst system containing reaction product of liquid silicone and polyamine
US5744417A (en) * 1996-05-02 1998-04-28 Lyondell Petrochemical Company Supported catalyst
US5710299A (en) * 1996-06-27 1998-01-20 Albemarle Corporation Production of bridged metallocene complexes and intermediates therefor
US6207608B1 (en) * 1996-08-09 2001-03-27 University Of Iowa Research Foundation Olefin polymerization with direct use of ansa-metallocene amide complexes as catalysts
US5760262A (en) * 1996-09-17 1998-06-02 Albemarle Corporation Enhanced production of bridged hafnocenes
DE19642353A1 (de) * 1996-10-14 1998-04-16 Basf Ag Katalysatorsysteme, enthaltend Metallkomplexe mit adamantanähnlicher Struktur
DE19642354A1 (de) * 1996-10-14 1998-04-16 Basf Ag Metalkomplexe mit adamantanähnlicher Struktur
US5936108A (en) * 1996-10-17 1999-08-10 Albemarle Corporation Metallocene synthesis
US6100354A (en) * 1997-02-24 2000-08-08 Exxon Chemical Patents Inc. Olefin copolymers from bridged bis(arylamido) Group 4 catalyst compounds
US6335303B1 (en) * 1997-04-04 2002-01-01 The Regents Of The University Of California Polymerization catalysts containing electron-withdrawing amide ligands
US6677265B1 (en) 1997-12-08 2004-01-13 Albemarle Corporation Process of producing self-supported catalysts
US6551955B1 (en) 1997-12-08 2003-04-22 Albemarle Corporation Particulate group 4 metallocene-aluminoxane catalyst compositions devoid of preformed support, and their preparation and their use
EP1037931B1 (de) 1997-12-08 2004-02-04 Albemarle Corporation Katalysatorzusammensetzungen mit gesteigertem leistungsvermögen
UA57864C2 (uk) * 1998-10-08 2003-07-15 Бп Кемікалз Лімітед Спосіб полімеризації олефінів з використанням місточкових металевих комплексів
DE60122396T2 (de) * 2000-02-08 2007-09-06 Exxonmobil Chemical Patents Inc., Baytown Schlagzähe Propylencopolymerisate
WO2003010207A1 (fr) 2001-07-23 2003-02-06 Shanghai Institute Of Organic Chemistry, Chinese Academy Of Sciences Catalyseurs de polymerisation ou de copolymerisation d'olefines, leur procede de preparation et leur utilisation
US7241500B2 (en) 2003-10-06 2007-07-10 Certainteed Corporation Colored roofing granules with increased solar heat reflectance, solar heat-reflective shingles, and process for producing same
FR2884111B1 (fr) 2005-04-07 2007-05-18 Saint Gobain Mat Constr Sas Granule biocide, notamment pour la fabrication de bardeau d'asphalte
US7422989B2 (en) * 2005-09-07 2008-09-09 Certainteed Corporation Solar heat reflective roofing membrane and process for making the same
US9044921B2 (en) 2005-09-07 2015-06-02 Certainteed Corporation Solar heat reflective roofing membrane and process for making the same
US7749593B2 (en) 2006-07-07 2010-07-06 Certainteed Corporation Solar heat responsive exterior surface covering
US8361597B2 (en) 2007-04-02 2013-01-29 Certainteed Corporation Solar heat-reflective roofing granules, solar heat-reflective shingles, and process for producing same
US20100203336A1 (en) 2007-05-24 2010-08-12 Ming Liang Shiao Roofing granules with high solar reflectance, roofing products with high solar reflectance, and processes for preparing same
WO2009145968A1 (en) 2008-03-31 2009-12-03 Certainteed Corporation Coating compositions for roofing granules, dark colored roofing granules with increased solar heat reflectance, solar heat-reflective shingles, and process for producing the same
US8394498B2 (en) * 2008-12-16 2013-03-12 Certainteed Corporation Roofing granules with high solar reflectance, roofing materials with high solar reflectance, and the process of making the same
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US10730799B2 (en) 2016-12-31 2020-08-04 Certainteed Corporation Solar reflective composite granules and method of making solar reflective composite granules

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Also Published As

Publication number Publication date
US5541350A (en) 1996-07-30
EP0739361B1 (de) 1999-09-29
DE69420975D1 (de) 1999-11-04
ES2139094T3 (es) 2000-02-01
WO1995006071A1 (en) 1995-03-02
US5486585A (en) 1996-01-23
EP0739361A1 (de) 1996-10-30
GR3032161T3 (en) 2000-04-27
DE69420975T2 (de) 2000-05-11

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