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ATE161538T1 - Chirale katalysatoren und dadurch katalysierte epoxydierungsreaktionen - Google Patents

Chirale katalysatoren und dadurch katalysierte epoxydierungsreaktionen

Info

Publication number
ATE161538T1
ATE161538T1 AT91907292T AT91907292T ATE161538T1 AT E161538 T1 ATE161538 T1 AT E161538T1 AT 91907292 T AT91907292 T AT 91907292T AT 91907292 T AT91907292 T AT 91907292T AT E161538 T1 ATE161538 T1 AT E161538T1
Authority
AT
Austria
Prior art keywords
epoxydation
chiral catalysts
reactions catalysed
catalysts
chiral
Prior art date
Application number
AT91907292T
Other languages
English (en)
Inventor
Eric N Jacobsen
Wei Zhang
Original Assignee
Res Corp Technologies Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Res Corp Technologies Inc filed Critical Res Corp Technologies Inc
Application granted granted Critical
Publication of ATE161538T1 publication Critical patent/ATE161538T1/de

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2204Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208Oxygen, e.g. acetylacetonates
    • B01J31/2226Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/2243At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C251/00Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C251/02Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups
    • C07C251/24Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups having carbon atoms of imino groups bound to carbon atoms of six-membered aromatic rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D301/00Preparation of oxiranes
    • C07D301/02Synthesis of the oxirane ring
    • C07D301/03Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/14Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic peracids, or salts, anhydrides or esters thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D303/00Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02Compounds containing oxirane rings
    • C07D303/04Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D303/00Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02Compounds containing oxirane rings
    • C07D303/48Compounds containing oxirane rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms, e.g. ester or nitrile radicals
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D493/00Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
    • C07D493/02Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
    • C07D493/04Ortho-condensed systems
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D493/00Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
    • C07D493/02Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
    • C07D493/10Spiro-condensed systems
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F13/00Compounds containing elements of Groups 7 or 17 of the Periodic Table
    • C07F13/005Compounds without a metal-carbon linkage
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F19/00Metal compounds according to more than one of main groups C07F1/00 - C07F17/00
    • C07F19/005Metal compounds according to more than one of main groups C07F1/00 - C07F17/00 without metal-C linkages
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02Silicon compounds
    • C07F7/08Compounds having one or more C—Si linkages
    • C07F7/0803Compounds with Si-C or Si-Si linkages
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02Silicon compounds
    • C07F7/08Compounds having one or more C—Si linkages
    • C07F7/0803Compounds with Si-C or Si-Si linkages
    • C07F7/081Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B01J2231/72Epoxidation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0241Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
    • B01J2531/0252Salen ligands or analogues, e.g. derived from ethylenediamine and salicylaldehyde
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62Chromium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70Complexes comprising metals of Group VII (VIIB) as the central metal
    • B01J2531/72Manganese
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84Metals of the iron group
    • B01J2531/842Iron
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84Metals of the iron group
    • B01J2531/845Cobalt
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84Metals of the iron group
    • B01J2531/847Nickel
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00Systems containing only non-condensed rings
    • C07C2601/12Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Epoxy Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
  • Medicines Containing Plant Substances (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Medicinal Preparation (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
AT91907292T 1990-03-21 1991-03-21 Chirale katalysatoren und dadurch katalysierte epoxydierungsreaktionen ATE161538T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US49699290A 1990-03-21 1990-03-21

Publications (1)

Publication Number Publication Date
ATE161538T1 true ATE161538T1 (de) 1998-01-15

Family

ID=23975023

Family Applications (1)

Application Number Title Priority Date Filing Date
AT91907292T ATE161538T1 (de) 1990-03-21 1991-03-21 Chirale katalysatoren und dadurch katalysierte epoxydierungsreaktionen

Country Status (10)

Country Link
EP (1) EP0521099B1 (de)
JP (2) JP3487847B2 (de)
AT (1) ATE161538T1 (de)
AU (1) AU648301B2 (de)
CA (1) CA2077541C (de)
DE (1) DE69128528T2 (de)
DK (1) DK0521099T3 (de)
ES (1) ES2113374T3 (de)
GR (1) GR3032114T3 (de)
WO (1) WO1991014694A1 (de)

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CA2116335C (en) * 1991-08-26 1999-08-24 Eric N. Jacobsen Chiral catalysts, catalytic oxidation and disproportionation reactions, and methods of producing epoxychromans and taxol
US5352814A (en) * 1991-08-30 1994-10-04 Nissan Chemical Industries, Ltd. Asymmetric epoxidation reaction
FI930148A (fi) * 1992-01-18 1993-07-19 Hoechst Ag Foerfarande foer enantioselektiv epoxidation av i 6-staellning substituerade kromener
GB9203596D0 (en) * 1992-02-20 1992-04-08 Smithkline Beecham Plc Novel process
CN1043425C (zh) * 1992-08-06 1999-05-19 史密丝克莱恩比彻姆有限公司 亚水杨基氨基过渡金属配合物及其制法
WO1994022442A1 (en) * 1993-04-02 1994-10-13 Nissan Chemical Industries, Ltd. Heart failure remedy
US6031115A (en) * 1993-05-14 2000-02-29 Smithkline Beecham Plc Process for preparing epoxides
EP0630964B1 (de) * 1993-06-19 1998-08-05 Ciba SC Holding AG Inhibierung der Wiederabsorption von migrierenden Farbstoffen in der Waschlösung
DE69532849T2 (de) * 1994-02-04 2005-04-28 Smithkline Beecham Plc, Brentford Verfahren zum Epoxidieren prochiraler Olefine
US5599957A (en) * 1994-02-23 1997-02-04 Nissan Chemical Industries, Ltd. Asymmetric epoxidation reaction
ES2221665T3 (es) * 1994-07-21 2005-01-01 Ciba Specialty Chemicals Holding Inc. Composicion de blanqueo de tejidos.
US5786496A (en) * 1994-08-22 1998-07-28 Northwestern University High oxidation state metal oxo complexes of the PHAB ligand
GB9425296D0 (en) * 1994-12-15 1995-02-15 Ciba Geigy Ag Inhibition of dye migration
US5665890A (en) * 1995-03-14 1997-09-09 President And Fellows Of Harvard College Stereoselective ring opening reactions
US6262278B1 (en) 1995-03-14 2001-07-17 President And Fellows Of Harvard College Stereoselective ring opening reactions
IL128170A0 (en) 1996-07-26 1999-11-30 Nissan Chemical Ind Ltd Chroman derivatives
DE19719397A1 (de) * 1997-05-07 1998-11-12 Clariant Gmbh Bleichaktive Metall-Komplexe
US5981424A (en) * 1997-07-31 1999-11-09 Sunoco, Inc. (R&M) Catalysts for hydroxylation and ammination of aromatics using molecular oxygen as the terminal oxidant without coreductant
ATE279502T1 (de) 1997-09-09 2004-10-15 Ciba Sc Holding Ag Verfahren zur gewebepflege
TW408203B (en) 1998-04-06 2000-10-11 Ciba Sc Holding Ag Process for treating textile materials and the relevant compounds
US6521561B1 (en) * 1998-05-01 2003-02-18 President And Fellows Of Harvard College Main-group metal based asymmetric catalysts and applications thereof
DE69921815T2 (de) 1998-06-03 2005-11-10 Nissan Chemical Industries, Ltd. Indanderivate
JP2002030079A (ja) * 1999-08-03 2002-01-29 Mitsubishi Chemicals Corp 光学活性1,2−二置換−2,3−エポキシプロパン類の製造法
AU7319800A (en) 1999-09-24 2001-04-24 Nissan Chemical Industries Ltd. 4-oxybenzopyran derivative
EP1218367A1 (de) 1999-10-05 2002-07-03 Nissan Chemical Industries, Ltd. 4-oxobenzopyranderivate
AU5891201A (en) * 2000-05-24 2001-12-03 Rstech Co., Ltd. Novel chiral salen catalysts, and a process for preparing chiral compounds from racemic epoxides for using them
KR100342659B1 (en) * 2000-12-15 2002-07-04 Rstech Co Ltd Chiral polymer salene catalyst and process for preparing chiral compounds from racemic epoxide using the same
CZ20033469A3 (cs) 2001-06-25 2004-04-14 Nissan Chemical Industries, Ltd. Substituované benzopyranové deriváty proti arytmiím
US7368582B2 (en) 2003-10-17 2008-05-06 Solvay Pharmaceuticals Gmbh Amidomethyl-substituted 2-(4-sulfonylamino)-3-hydroxy-3,4-dihydro-2H-chromen-6-yl compounds, a process and intermediates for their production, and pharmaceutical compositions containing them
FR2875500A1 (fr) * 2004-09-21 2006-03-24 Centre Nat Rech Scient Complexe chiraux macrocycliques utilisables comme catalyseurs
US7714150B2 (en) 2005-04-12 2010-05-11 Solvay Pharmaceuticals Gmbh Aminoalkyl-amidomethyl-substituted 2-(4-sulphonylamino)-3-hydroxy-3,4-dihydro-2H-chroman-6-yl derivatives
JP2008255086A (ja) * 2007-03-10 2008-10-23 Nissan Chem Ind Ltd 光学活性エポキシ化合物の製造方法
WO2010028362A1 (en) 2008-09-08 2010-03-11 Novomer, Inc. Polycarbonate polyol compositions and methods
EP2264024A1 (de) 2008-10-14 2010-12-22 LEK Pharmaceuticals d.d. Verfahren zur Herstellung einer enantiomerisch-angereicherte Protonpumpenhemmer
TWI426090B (zh) * 2011-05-31 2014-02-11 Tsrc Corp 製造環氧化聚合物的方法
EP2734532B1 (de) * 2011-07-18 2019-05-01 Saudi Aramco Technologies Company Metallkomplexe
KR102096761B1 (ko) 2012-08-24 2020-04-03 사우디 아람코 테크놀로지스 컴퍼니 금속 착물
WO2014170913A2 (en) * 2013-04-17 2014-10-23 Reliance Industries Limited A novel transition metal based pro-catalyst and a process for its preparation
WO2018151019A1 (ja) * 2017-02-14 2018-08-23 セントラル硝子株式会社 立体選択的な二置換ハロゲン化エポキシドの製造方法
US11180609B2 (en) 2018-08-02 2021-11-23 Saudi Aramco Technologies Company Sustainable polymer compositions and methods
US12195576B2 (en) 2021-06-23 2025-01-14 Saudi Aramco Technologies Company Polyol compositions and methods

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FR2588265B3 (fr) * 1985-10-04 1988-01-15 Inst Francais Du Petrole Procede d'adoucissement d'une charge d'hydrocarbures contenant des produits soufres
DE3539268A1 (de) * 1985-11-06 1987-05-07 Degussa Verfahren zur katalytischen epoxidation von olefinen mit wasserstoffperoxid

Also Published As

Publication number Publication date
CA2077541A1 (en) 1991-09-22
DE69128528T2 (de) 1998-07-30
AU648301B2 (en) 1994-04-21
JP2004148290A (ja) 2004-05-27
DK0521099T3 (da) 1998-09-07
JPH05507645A (ja) 1993-11-04
WO1991014694A1 (en) 1991-10-03
EP0521099A4 (en) 1993-10-20
JP3487847B2 (ja) 2004-01-19
CA2077541C (en) 1998-08-18
ES2113374T3 (es) 1998-05-01
AU7555391A (en) 1991-10-21
DE69128528D1 (de) 1998-02-05
EP0521099B1 (de) 1997-12-29
GR3032114T3 (en) 2000-04-27
EP0521099A1 (de) 1993-01-07

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UEP Publication of translation of european patent specification
EELA Cancelled due to lapse of time