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ATE146T1 - PROCESS FOR OBTAINING ANHYDROUS OR SUBSTANTIALLY ANHYDROUS FORMIC ACID. - Google Patents

PROCESS FOR OBTAINING ANHYDROUS OR SUBSTANTIALLY ANHYDROUS FORMIC ACID.

Info

Publication number
ATE146T1
ATE146T1 AT79104857T AT79104857T ATE146T1 AT E146 T1 ATE146 T1 AT E146T1 AT 79104857 T AT79104857 T AT 79104857T AT 79104857 T AT79104857 T AT 79104857T AT E146 T1 ATE146 T1 AT E146T1
Authority
AT
Austria
Prior art keywords
formic acid
section
column
anhydrous
hydrolysis
Prior art date
Application number
AT79104857T
Other languages
German (de)
Inventor
Kaspar Dr. Dipl.-Chem. Bott
Gerd Kaibel
Herwig Dr. Dipl.-Chem. Hoffmann
Otto Dr. Dipl.-Chem. Kratzer
Rudolf Dr. Dipl.-Chem. Irnich
Original Assignee
Basf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag filed Critical Basf Ag
Application granted granted Critical
Publication of ATE146T1 publication Critical patent/ATE146T1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
    • C07C51/44—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/48—Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Medicines That Contain Protein Lipid Enzymes And Other Medicines (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

A process for the production of anhydrous or substantially anhydrous formic acid by hydrolysis of methyl formate which is carried out in a column having an upper fractionating section, a middle hydrolysis section and a lower extraction section and in which (a) the hydrolysis is carried out in the middle section of the columm, with water and methyl formate in countercurrent, (b) the resulting formic acid is extracted, in the lower section of the column, by means of a carboxylic acid amide which is fed into the lower end of the middle section of the column, (c) the extract phase, consisting in the main of formic acid and the carboxylic acid amide, is distillatively dehydrated, or substantially dehydrated, in the lower section of the column, (d) the methanol and uncovered methyl formate are removed by fractional distillation in the upper section of the column and (e) the pure formic acid or concentrated aqueous formic acid is distilled from the anhydrous or substantially anhydrous extract phase in a second column, leaving the carboxylic acid amide.
AT79104857T 1978-12-14 1979-12-04 PROCESS FOR OBTAINING ANHYDROUS OR SUBSTANTIALLY ANHYDROUS FORMIC ACID. ATE146T1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19782853991 DE2853991A1 (en) 1978-12-14 1978-12-14 METHOD FOR DETERMINING WATER-FREE OR MOSTLY WATER-FREE FORMIC ACID
EP79104857A EP0012321B1 (en) 1978-12-14 1979-12-04 Process for the obtention of water-free or substantially water-free formic acid

Publications (1)

Publication Number Publication Date
ATE146T1 true ATE146T1 (en) 1981-09-15

Family

ID=6057174

Family Applications (1)

Application Number Title Priority Date Filing Date
AT79104857T ATE146T1 (en) 1978-12-14 1979-12-04 PROCESS FOR OBTAINING ANHYDROUS OR SUBSTANTIALLY ANHYDROUS FORMIC ACID.

Country Status (7)

Country Link
US (1) US4262140A (en)
EP (1) EP0012321B1 (en)
JP (1) JPS5583730A (en)
AT (1) ATE146T1 (en)
CA (1) CA1135281A (en)
DE (2) DE2853991A1 (en)
NO (1) NO149470C (en)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2914671A1 (en) * 1979-04-11 1980-10-23 Basf Ag METHOD FOR DETERMINING WATER-FREE OR MOSTLY WATER-FREE FORMIC ACID
NL8103517A (en) * 1981-07-24 1983-02-16 Badger Bv METHOD FOR SEPARATING CARBONIC ACIDS FROM MIXTURES WITH NON-ACIDS BY AN ABSORPTION STRIP TREATMENT.
DE3319651A1 (en) * 1983-05-31 1984-12-06 Basf Ag, 6700 Ludwigshafen METHOD FOR THE DISTILLATIVE PRODUCTION OF FORMIC ACID
DE3411384A1 (en) * 1984-03-28 1985-10-10 Basf Ag, 6700 Ludwigshafen METHOD FOR THE EXTRACTION OF WATER-FREE OR MOSTLY WATER-FREE FORMIC ACID BY HYDROLYSIS OF METHYLFORMIAT
DE3417790A1 (en) * 1984-05-14 1985-11-14 Basf Ag, 6700 Ludwigshafen METHOD FOR PRODUCING FORMIC ACID
US4735690A (en) * 1986-03-10 1988-04-05 Lloyd Berg Dehydration of impure formic acid by extractive distillation
US4670105A (en) * 1986-04-07 1987-06-02 Lloyd Berg Dehydration of propanoic acid by extractive distillation
DE4211141A1 (en) * 1992-04-03 1993-10-07 Basf Ag Process for the preparation of formic acid by thermal cleavage of quaternary ammonium formates
DE19934410C1 (en) 1999-07-22 2000-12-14 Consortium Elektrochem Ind Separation and purification of aqueous mixtures of acetic acid, formic acid and high boiling fractions uses apparatus with separation and distillation columns containing organic solvent
DE19934411C1 (en) 1999-07-22 2001-03-22 Consortium Elektrochem Ind Process for the separation and purification of an aqueous mixture of the main components acetic acid and formic acid
DE10002794A1 (en) * 2000-01-24 2001-07-26 Basf Ag Production of anhydrous formic acid involves hydrolysis of methyl formate, steam distillation, extraction with amide and further distillations, with prior use of steam for stripping aqueous extraction residue
DE10002791A1 (en) * 2000-01-24 2001-07-26 Basf Ag Production of anhydrous formic acid by hydrolyzing methyl formate comprises introducing methanol-containing methyl formate into distillation column used to distil hydrolysis mixture
US7618725B2 (en) * 2004-09-21 2009-11-17 The Board Of Trustees Of The University Of Illinois Low contaminant formic acid fuel for direct liquid fuel cell
WO2010030617A1 (en) * 2008-09-09 2010-03-18 Meadwestvaco Corporation A method of recovering levulinic acid
DE102009035387B4 (en) * 2009-07-30 2012-08-09 Siemens Aktiengesellschaft A method and apparatus for converting carbon monoxide and water to carbon dioxide and hydrogen with the separation of at least one product gas
WO2013030162A1 (en) * 2011-08-27 2013-03-07 Taminco Process of formic acid production by hydrolysis of methyl formate
CN108707062A (en) * 2018-06-08 2018-10-26 聊城市鲁西化工工程设计有限责任公司 A kind of technique for sylvite recovery processing
WO2020044380A1 (en) * 2018-08-30 2020-03-05 Nextchem S.R.L. Method and apparatus to produce fatty acids from methyl esters throughout non-catalytic process
CN114644549A (en) * 2022-04-24 2022-06-21 聊城市鲁西化工工程设计有限责任公司 Production system and production process of formic acid

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2545658C2 (en) * 1975-10-11 1985-12-19 Basf Ag, 6700 Ludwigshafen Process for the production of carboxylic acids from their aqueous solutions
DE2545730A1 (en) * 1975-10-11 1977-04-21 Basf Ag METHOD FOR REPRESENTING ANTIC ACID
US4143066A (en) * 1976-12-16 1979-03-06 The Dow Chemical Company Separation and recovery of carboxylic acids from water
NO138803C (en) * 1977-03-30 1978-11-15 Norsk Hydro As PROCEDURE FOR PREPARATION OF ACTIC ACID
DE2744313A1 (en) * 1977-10-01 1979-04-12 Basf Ag PROCESS FOR THE PRODUCTION OF FORM ACID

Also Published As

Publication number Publication date
NO794080L (en) 1980-06-17
EP0012321B1 (en) 1981-08-12
JPS6230973B2 (en) 1987-07-06
NO149470C (en) 1984-04-25
EP0012321A1 (en) 1980-06-25
DE2960646D1 (en) 1981-11-12
JPS5583730A (en) 1980-06-24
CA1135281A (en) 1982-11-09
NO149470B (en) 1984-01-16
US4262140A (en) 1981-04-14
DE2853991A1 (en) 1980-07-03

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Legal Events

Date Code Title Description
EELA Cancelled due to lapse of time