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AT55244B - Process for the preparation of nitric acid. - Google Patents

Process for the preparation of nitric acid.

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Publication number
AT55244B
AT55244B AT55244DA AT55244B AT 55244 B AT55244 B AT 55244B AT 55244D A AT55244D A AT 55244DA AT 55244 B AT55244 B AT 55244B
Authority
AT
Austria
Prior art keywords
nitric acid
oxygen
preparation
absorption
gases
Prior art date
Application number
Other languages
German (de)
Original Assignee
Hoechst Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst Ag filed Critical Hoechst Ag
Application granted granted Critical
Publication of AT55244B publication Critical patent/AT55244B/en

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  • Treatment Of Water By Oxidation Or Reduction (AREA)

Description

  

   <Desc/Clms Page number 1> 
 



  Verfahren zur Darstellung von Salpetersäure. 



   Seitdem konzentrierte Stickoxydgase auf einfache und billige   Weise zugänglich sind   (vergl. z. B. D. R. P. Nr. 220539), bedient man sich zur   Überführung   dieser Gase in Salpetersäure bei Gegenwart von Wasser oder wässriger Lösungen vorteilhaft des reinen Sauerstoffs anstatt der Luft, weil die erreichbare Konzentration der Salpetersäure höher ist und die erforderlichen   Absorptionsräumo   geringer werden. Zum Befördern der Flüssigkeit in die Absorptionsgefässe verwendet man dabei in den meisten Fällen Apparate, welche mit Druckluft betrieben werden, beispielsweise Druckfässer. automatische Druckbirnen, Emulseure usw. Die sogenannte Abluft lässt man entweder ins Freie treten, wobei aber ganz erhebliche Verluste an   Stickoxydgasen bzw.

   Salpetersäure   auftreten oder man führt die Al) luft in das   Absorptionssystem   ein. Man vermeidet im letzteren Falle zwar direkte Verluste an Salpetersäure, hat aber den Nachteil, dass   Sticks'')   in die Absorptionslage gelangt und die Gase verdünnt. Ist man, wie es in der Praxis vielfach der Fall ist, 
 EMI1.1 
 dabei die   Verdünnung   der Gase durch den eingeführten Stickstoff so gross werden, dass ein Vorteil in der Verwendung von reinem Sauerstoff nicht mehr besteht. 



     Diese Übelständo   lassen sich nun, wie gefunden wurde, vermeiden, wenn man zum   Befördern   der Absorptionstüssigkeit nicht Druckluft, sondern komprimierten Sauerstoff verwendet und den aus   den Druckgefässon austretenden Sauerste 7ugloich mit den etw. t   mitgerissenen Stickstoffoxydgasen bzw. Salpetersäuredämpfen wieder in das Absorptions- 
 EMI1.2 
 verbrauch an Sauerstoff nicht erforderlich, sondern es muss lediglich die Kompressiousarbeit geleistet werden, den Sauerstoff auf die notwendige Spannung zu bringen. 

**WARNUNG** Ende DESC Feld kannt Anfang CLMS uberlappen**.



   <Desc / Clms Page number 1>
 



  Process for the preparation of nitric acid.



   Since concentrated nitrogen oxide gases have been accessible in a simple and cheap way (see e.g. BDRP No. 220539), pure oxygen is advantageously used instead of air to convert these gases into nitric acid in the presence of water or aqueous solutions, because the achievable concentration of Nitric acid is higher and the required absorption space is lower. In most cases, apparatus operated with compressed air, such as pressure barrels, is used to convey the liquid into the absorption vessels. automatic pressure bulbs, emulsifiers, etc. The so-called exhaust air is either allowed to enter the open air, with considerable losses of nitrogen oxide gases or

   Nitric acid occur or the Al) air is introduced into the absorption system. In the latter case, direct losses of nitric acid are avoided, but the disadvantage is that sticks '') get into the absorption layer and dilute the gases. Is one, as is often the case in practice,
 EMI1.1
 the dilution of the gases by the nitrogen introduced become so great that there is no longer any advantage in using pure oxygen.



     These evils can now, as has been found, be avoided if compressed oxygen is not used to convey the absorption liquid, but rather compressed oxygen and the acidic matter escaping from the pressure vessel is returned to the absorption chamber with the nitric oxide gases or nitric acid vapors that may be entrained.
 EMI1.2
 consumption of oxygen is not necessary, only the compressive work has to be done to bring the oxygen to the necessary tension.

** WARNING ** End of DESC field may overlap beginning of CLMS **.

 

Claims (1)

PATENT-ANSPRUCH : Verfahren zur Darstellung von Salpetersäure aus Stickoxyden und Sauerstoff in Gegenwart von Wasser oder wässriger Lösungen, dadurch gekennzeichnet, dass die zum Transport der Flüssigkeit in den Absortionssystemen dienenden Apparate mit Sauerstoff betrieben werden und der aus den Apparaten austretende Sauerstoff zugleich mit dun mitgerissenen salpetersäurebaltigen Dämpfen in das Absorptionssystem zurückgeführt wird **WARNUNG** Ende CLMS Feld Kannt Anfang DESC uberlappen**. PATENT CLAIM: Process for the preparation of nitric acid from nitrogen oxides and oxygen in the presence of water or aqueous solutions, characterized in that the apparatus used to transport the liquid in the absorption systems is operated with oxygen and the oxygen emerging from the apparatus is simultaneously transported into the with vapors containing nitric acid Absorption system is returned ** WARNING ** End of CLMS field may overlap beginning of DESC **.
AT55244D 1911-04-06 1911-08-18 Process for the preparation of nitric acid. AT55244B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE55244X 1911-04-06

Publications (1)

Publication Number Publication Date
AT55244B true AT55244B (en) 1912-09-10

Family

ID=5628315

Family Applications (1)

Application Number Title Priority Date Filing Date
AT55244D AT55244B (en) 1911-04-06 1911-08-18 Process for the preparation of nitric acid.

Country Status (1)

Country Link
AT (1) AT55244B (en)

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