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AR109141A1 - Compuestos herbicidas de pirimidina - Google Patents

Compuestos herbicidas de pirimidina

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Publication number
AR109141A1
AR109141A1 ARP170102071A ARP170102071A AR109141A1 AR 109141 A1 AR109141 A1 AR 109141A1 AR P170102071 A ARP170102071 A AR P170102071A AR P170102071 A ARP170102071 A AR P170102071A AR 109141 A1 AR109141 A1 AR 109141A1
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AR
Argentina
Prior art keywords
alkyl
carbonyl
alkoxy
amino
haloalkylthio
Prior art date
Application number
ARP170102071A
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English (en)
Original Assignee
Basf Se
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Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of AR109141A1 publication Critical patent/AR109141A1/es

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
    • C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
    • C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
    • C07D239/32—One oxygen, sulfur or nitrogen atom
    • C07D239/34—One oxygen atom
    • C07D239/36—One oxygen atom as doubly bound oxygen atom or as unsubstituted hydroxy radical
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
    • C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
    • C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D403/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
    • C07D403/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings
    • C07D403/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
    • C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
    • C07D405/04—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
    • C07D409/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings
    • C07D409/04—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/32—Ingredients for reducing the noxious effect of the active substances to organisms other than pests, e.g. toxicity reducing compositions, self-destructing compositions

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)

Abstract

Compuestos de pirimidina o sus derivados o sales aceptables en la agricultura como herbicidas, composiciones que los comprenden y su uso como herbicidas, es decir, para controlar plantas dañinas, y a un método para controlar la vegetación no deseada, que comprende permitir que una cantidad eficaz como herbicida de al menos un compuesto de pirimidina actúe en las plantas, en sus semillas y/o en su hábitat. Reivindicación 1: Los compuestos de pirimidina caracterizados por la fórmula (1), en donde la línea punteada (- - - - -) es un enlace simple o un enlace doble; R¹ es C₁₋₆-alquilo, C₁₋₆-haloalquilo, HO-C₁₋₆-alquilo, C₂₋₆-alquenilo, C₂₋₆-haloalquenilo, C₂₋₆-alquinilo, C₃₋₆-haloalquinilo, C₁₋₆-alcoxi-C₁₋₆-alquilo, C₁₋₆-alcoxi, C₃₋₆-alqueniloxi, C₃₋₆-haloalqueniloxi, C₃₋₆-alquiniloxi, C₃₋₆-haloalquiniloxi, C₁₋₆-haloalcoxi, C₃₋₆-cicloalcoxi, C₃₋₆-halocicloalcoxi, C₃₋₆-cicloalqueniloxi, C₃₋₆-halocicloalqueniloxi, C₁₋₆-alquiltio, C₁₋₆-haloalquiltio, (C₁₋₆-alquil)amino, di(C₁₋₆-alquil)amino, C₁₋₆-alquilsulfinilo, C₁₋₆-alquilsulfonilo, C₃₋₆-cicloalquilo, C₃₋₆-cicloalquenilo, C₃₋₆-halocicloalquilo, C₃₋₆-halocicloalquenilo, [1-(C₁₋₆-alquil)]-C₃₋₆-cicloalquilo, [1-(C₂₋₆-alquenil)]-C₃₋₆-cicloalquilo, [1-(C₂₋₆-alquinil)]-C₃₋₆-cicloalquilo, [1-(C₁₋₆-haloalquil)]-C₃₋₆-cicloalquilo, [1-(C₂₋₆-haloalquenil)]-C₃₋₆-cicloalquilo, [1-(C₃₋₆-haloalquinil)]-C₃₋₆-cicloalquilo, C₃₋₆-cicloalquil-C₁₋₆-alquilo, C₃₋₆-cicloalquil-C₁₋₆-haloalquilo, C₃₋₆-cicloalquil-C₁₋₆-alcoxi, C₃₋₆-cicloalquil-C₁₋₆-haloalcoxi, fenilo, heteroarilo de 5 ó 6 miembros, o heterociclilo de 3 a 6 miembros; en donde los grupos cíclicos de R¹ son no sustituidos o sustituidos con Rᵃ; R² es H, halógeno, C₁₋₆-alquilo, C₁₋₆-haloalquilo, C₁₋₆-alquilcarbonil-C₁₋₆-alquilo, C₁₋₆-alcoxicarbonil-C₁₋₆-alquilo, C₁₋₆-haloalquilcarbonil-C₁₋₆-alquilo, C₁₋₆-haloalcoxicarbonil-C₁₋₆-alquilo, C₁₋₆-alquilcarbonil-C₁₋₆-haloalquilo, C₁₋₆-alcoxicarbonil-C₁₋₆-haloalquilo, C₁₋₆-haloalquilcarbonil-C₁₋₆-haloalquilo, C₁₋₆-haloalcoxicarbonil-C₁₋₆-haloalquilo, OH, C₁₋₆-alcoxi, C₁₋₆-alcoxi-C₁₋₆-alcoxi, C₁₋₆-haloalcoxi-C₁₋₆-alcoxi, C₁₋₆-alcoxi-C₁₋₆-haloalcoxi, C₁₋₆-haloalcoxi-C₁₋₆-haloalcoxi, C₁₋₆-alcoxi-C₁₋₆-alcoxi-C₁₋₆-alcoxi, C₁₋₆-haloalcoxi, C₁₋₆-cianoalcoxi, C₁₋₆-hidroxialcoxi, C₃₋₆-alqueniloxi, C₃₋₆-alqueniloxi-C₁₋₆-alcoxi, C₃₋₆-haloalqueniloxi-C₁₋₆-haloalcoxi, C₃₋₆-alqueniloxi-C₁₋₆-haloalcoxi, C₃₋₆-haloalqueniloxi, C₃₋₆-alquiniloxi, C₃₋₆-haloalquiniloxi, C₃₋₆-alquiniloxi-C₁₋₆-alcoxi, C₃₋₆-haloalquiniloxi-C₁₋₆-haloalcoxi, C₃₋₆-alquiniloxi-C₁₋₆-haloalcoxi, C₃₋₆-alquiniloxi-C₃₋₆-alqueniloxi, C₃₋₆-haloalquiniloxi-C₃₋₆-alqueniloxi, C₃₋₆-alquiniloxi-C₃₋₆-haloalqueniloxi, C₃₋₆-haloalquiniloxi-C₃₋₆-haloalqueniloxi, C₃₋₆-alquiniloxi-C₃₋₆-alquiniloxi, C₃₋₆-haloalquiniloxi-C₃₋₆-alquiniloxi, C₃₋₆-alquiniloxi-C₃₋₆-haloalquiniloxi, C₃₋₆-haloalquiniloxi-C₃₋₆-haloalquiniloxi, (C₁₋₆-alquil)-carbonil-C₁₋₆-alcoxi, (C₁₋₆-haloalquil)carbonil-C₁₋₆-haloalcoxi, (C₁₋₆-haloalquil)carbonil-C₁₋₆-alcoxi, (C₁₋₆-alquil)carbonil-C₁₋₆-haloalcoxi, (C₁₋₆-alcoxi)carbonil-C₁₋₆-alcoxi, (C₁₋₆-haloalcoxi)carbonil-C₁₋₆-alcoxi, (C₁₋₆-alcoxi)-carbonil-C₁₋₆-haloalcoxi, (C₁₋₆-haloalcoxi)carbonil-C₁₋₆-haloalcoxi, (C₁₋₆-alcoxi-C₁₋₆-alquil)carbonil-C₁₋₆-alcoxi, (C₁₋₆-haloalcoxi-C₁₋₆-alquil)carbonil-C₁₋₆-alcoxi, (C₁₋₆-alcoxi-C₁₋₆-haloalquil)carbonil-C₁₋₆-alcoxi, (C₁₋₆-alcoxi-C₁₋₆-alquil)carbonil-C₁₋₆-haloalcoxi, (C₁₋₆-haloalcoxi-C₁₋₆-haloalquil)carbonil-C₁₋₆-alcoxi, (C₁₋₆-haloalcoxi-C₁₋₆-alquil)carbonil-C₁₋₆-haloalcoxi, (C₁₋₆-alcoxi-C₁₋₆-haloalquil)carbonil-C₁₋₆-haloalcoxi, (C₁₋₆-haloalcoxi-C₁₋₆-haloalquil)carbonil-C₁₋₆-haloalcoxi, (C₁₋₆-alquiltio)carbonil-C₁₋₆-alcoxi, (C₁₋₆-haloalquiltio)carbonil-C₁₋₆-alcoxi, (C₁₋₆-alquiltio)carbonil-C₁₋₆-haloalcoxi, (C₁₋₆-haloalquiltio)carbonil-C₁₋₆-haloalcoxi, (C₁₋₆-alquiltio-C₁₋₆-alquil)carbonil-C₁₋₆-alcoxi, (C₁₋₆-haloalquiltio-C₁₋₆-alquil)carbonil-C₁₋₆-alcoxi, (C₁₋₆-alquiltio-C₁₋₆-haloalquil)carbonil-C₁₋₆-alcoxi, (C₁₋₆-alquiltio-C₁₋₆-alquil)carbonil-C₁₋₆-haloalcoxi, (C₁₋₆-haloalquiltio-C₁₋₆-haloalquil)carbonil-C₁₋₆-alcoxi, (C₁₋₆-haloalquiltio-C₁₋₆-alquil)carbonil-C₁₋₆-haloalcoxi, (C₁₋₆-alquiltio-C₁₋₆-haloalquil)carbonil-C₁₋₆-haloalcoxi, (C₁₋₆-haloalquiltio-C₁₋₆-haloalquil)carbonil-C₁₋₆-haloalcoxi, C₃₋₆-cicloalcoxi, C₃₋₆-halocicloalcoxi, (C₃₋₆-cicloalquil)C₁₋₆-alcoxi, (C₃₋₆-halocicloalquil)C₁₋₆-alcoxi, (C₃₋₆-cicloalquil)C₁₋₆-haloalcoxi, aminocarbonil-C₁₋₆-alcoxi, (C₃₋₆-halocicloalquil)C₁₋₆-haloalcoxi, aminocarbonil-C₁₋₆-haloalcoxi, N-(C₁₋₆-alquil)-aminocarbonil-C₁₋₆-alcoxi, N-(C₁₋₆-alquil)-aminocarbonil-C₁₋₆-haloalcoxi, N,N-di(C₁₋₆-alquil)-aminocarbonil-C₁₋₆-alcoxi, N,N-di(C₁₋₆-alquil)-aminocarbonil-C₁₋₆-haloalcoxi, (difenil)C=N-O, (C₁₋₆-alquil)(fenil)C=N-O, (di(C₁₋₆-alquil))C=N-O, (C₁₋₆-alquil)₃silil-C₁₋₆-alcoxi, C₁₋₆-alquiltio, C₁₋₆-haloalquiltio, C₁₋₆-alcoxi-C₁₋₆-alquiltio, C₁₋₆-haloalcoxi-C₁₋₆-alquiltio, C₁₋₆-alcoxi-C₁₋₆-haloalquiltio, C₁₋₆-haloalcoxi-C₁₋₆-haloalquiltio, C₁₋₆-alcoxi-C₁₋₆-alcoxi-C₁₋₆-alquiltio, C₁₋₆-cianoalquiltio, C₃₋₆-alqueniltio, C₂₋₆-haloalqueniltio, C₃₋₆-alqueniloxi-C₁₋₆-alquiltio, C₃₋₆-haloalqueniloxi-C₁₋₆-alquiltio, C₃₋₆-alqueniloxi-C₁₋₆-haloalquiltio, C₃₋₆-haloalqueniloxi-C₁₋₆-haloalquiltio, C₃₋₆-alquiniltio, C₂₋₆-haloalquiltio, C₃₋₆-alquiniloxi-C₁₋₆-alquiltio, C₃₋₆-haloalquiniloxi-C₁₋₆-haloalquiltio, C₃₋₆-alquiniloxi-C₁₋₆-haloalquiltio, C₃₋₆-alquiniloxi-C₃₋₆-alqueniltio, C₃₋₆-haloalquiniloxi-C₃₋₆-alqueniltio, C₃₋₆-alquiniloxi-C₂₋₆-haloalqueniltio, C₃₋₆-haloalquiniloxi-C₂₋₆-haloalqueniltio, C₃₋₆-alquiniloxi-C₃₋₆-alquiniltio, C₃₋₆-haloalquiniloxi-C₃₋₆-alquiniltio, C₃₋₆-alquiniloxi-C₂₋₆-haloalquiniltio, C₃₋₆-haloalquiniloxi-C₂₋₆-haloalquiniltio, (C₁₋₆-alquil)carbonil-C₁₋₆-alquiltio, (C₁₋₆-haloalquil)carbonil-C₁₋₆-alquiltio, (C₁₋₆-alquil)carbonil-C₁₋₆-haloalquiltio, (C₁₋₆-haloalquil)carbonil-C₁₋₆-haloalquiltio, (C₁₋₆-alcoxi)carbonil-C₁₋₆-alquiltio, (C₁₋₆-haloalcoxi)carbonil-C₁₋₆-alquiltio, (C₁₋₆-alcoxi)carbonil-C₁₋₆-haloalquiltio, (C₁₋₆-haloalcoxi)carbonil-C₁₋₆-haloalquiltio, (C₁₋₆-alcoxi-C₁₋₆-alquil)carbonil-C₁₋₆-alquiltio, (C₁₋₆-haloalcoxi-C₁₋₆-alquil)carbonil-C₁₋₆-alquiltio, (C₁₋₆-alcoxi-C₁₋₆-haloalquil)carbonil-C₁₋₆-alquiltio, (C₁₋₆-alcoxi-C₁₋₆-alquil)carbonil-C₁₋₆-haloalquiltio, (C₁₋₆-haloalcoxi-C₁₋₆-haloalquil)carbonil-C₁₋₆-alquiltio, (C₁₋₆-haloalcoxi-C₁₋₆-alquil)carbonil-C₁₋₆-haloalquiltio, (C₁₋₆-alcoxi-C₁₋₆-haloalquil)carbonil-C₁₋₆-haloalquiltio, (C₁₋₆-haloalcoxi-C₁₋₆-haloalquil)carbonil-C₁₋₆-haloalquiltio, (C₁₋₆-alquiltio)carbonil-C₁₋₆-alquiltio, (C₁₋₆-haloalquiltio)carbonil-C₁₋₆-alquiltio, (C₁₋₆-alquiltio)carbonil-C₁₋₆-haloalquiltio, (C₁₋₆-haloalquiltio)carbonil-C₁₋₆-haloalquiltio, (C₁₋₆-alquiltio-C₁₋₆-alquil)carbonil-C₁₋₆-alquiltio, (C₁₋₆-haloalquiltio-C₁₋₆-alquil)carbonil-C₁₋₆-alquiltio, (C₁₋₆-alquiltio-C₁₋₆-haloalquil)carbonil-C₁₋₆-alquiltio, (C₁₋₆-alquiltio-C₁₋₆-alquil)carbonil-C₁₋₆-haloalquiltio, (C₁₋₆-haloalquiltio-C₁₋₆-haloalquil)carbonil-C₁₋₆-alquiltio, (C₁₋₆-haloalquiltio-C₁₋₆-alquil)carbonil-C₁₋₆-haloalquiltio, (C₁₋₆-alquiltio-C₁₋₆-haloalquil)carbonil-C₁₋₆-haloalquiltio, (C₁₋₆-haloalquiltio-C₁₋₆-haloalquil)carbonil-C₁₋₆-haloalquiltio, C₃₋₆-cicloalquiltio, C₃₋₆-halocicloalquiltio, (C₃₋₆-cicloalquil)C₁₋₆-alquiltio, (C₃₋₆-cicloalquil)C₁₋₆-haloalquiltio, (C₃₋₆-halocicloalquil)C₁₋₆-alquiltio, (C₃₋₆-halocicloalquil)C₁₋₆-haloalquiltio, aminocarbonil-C₁₋₆-alquiltio, aminocarbonil-C₁₋₆-haloalquiltio, N-(C₁₋₆-alquil)-aminocarbonil-C₁₋₆-alquiltio, N-(C₁₋₆-haloalquil)-aminocarbonil-C₁₋₆-alquiltio, N-(C₁₋₆-alquil)-aminocarbonil-C₁₋₆-haloalquiltio, N-(C₁₋₆-haloalquil)-aminocarbonil-C₁₋₆-haloalquiltio, N,N-di(C₁₋₆-alquil)-aminocarbonil-C₁₋₆-alquiltio, N,N-di(C₁₋₆-haloalquil)-aminocarbonil-C₁₋₆-alquiltio, N,N-di(C₁₋₆-alquil)-aminocarbonil-C₁₋₆-haloalquiltio, N,N-di(C₁₋₆-haloalquil)-aminocarbonil-C₁₋₆-haloalquiltio, NH₂, (C₁₋₆-alquil)amino, hidroxiamino, (C₁₋₆-alcoxi)amino, (C₃₋₆-cicloalcoxi)amino, (C₁₋₆-alquil)sulfinilamino, (C₁₋₆-alquil)sulfonilamino, -(amino)sulfinilamino, [(C₁₋₆-alquil)amino]sulfinilamino, (amino)sulfonilamino, [(C₁₋₆-alquil)amino]sulfonilamino, [di(C₁₋₆-alquil)amino]sulfonilamino, di(C₁₋₆-alquil)amino, (hidroxi)(C₁₋₆-alquil)amino, (hidroxi)(C₁₋₆-cicloalquil)amino, (C₁₋₆-alcoxi)(C₁₋₆-alquil)amino, (C₁₋₆-alcoxi)(C₃₋₆-cicloalquil)amino, (C₃₋₆-cicloalcoxi)(C₁₋₆-alquil)amino, (C₃₋₆-cicloalcoxi)(C₃₋₆-cicloalquil)amino, [(C₁₋₆-alquil)sulfinil](C₁₋₆-alquil)amino, [(C₁₋₆-alquil)sulfonil](C₁₋₆-alquil)amino, [di(C₁₋₆-alquil)amino]sulfinilamino, [di(C₁₋₆-alquil)amino]sulfonilamino, feniloxi, fenil-C₁₋₆-alcoxi, feniltio, fenil-C₁₋₆-alquiltio, fenilamino, (C₁₋₆-alquil)(fenil)amino, [(C₁₋₆-alquil)carbonil]amino, [(C₁₋₆-alquil)carbonil](C₁₋₆-alquil)amino, [(C₁₋₆-haloalquil)carbonil]amino, [(C₁₋₆-haloalquil)carbonil](C₁₋₆-alquil)amino, C₃₋₆-cicloalquilcarbonilamino, [(C₃₋₆-cicloalquil)carbonil](C₁₋₆-alquil)amino, fenilcarbonilamino, (fenilcarbonil)(C₁₋₆-alquil)amino, heterociclilcarbonilamino, (heterociclilcarbonil)(C₁₋₆-alquil)amino, heteroarilcarbonilamino, (heteroarilcarbonil)(C₁₋₆-alquil)amino, [(C₁₋₆-alquil)carbonil](C₁₋₆-alcoxi)amino, [(C₁₋₆-haloalquil)carbonil](C₁₋₆-alcoxi)amino, [(C₃₋₆-cicloalquil)carbonil](C₁₋₆-alquiloxi)amino, (fenilcarbonil)(C₁₋₆-alcoxi)amino, (heterociclilcarbonil)(C₁₋₆-alcoxi)amino, (heteroarilcarbonil)(C₁₋₆-alcoxi)amino, [(C₁₋₆-alquil)carbonil](C₂₋₆-alquenil)amino, [(C₁₋₆-haloalquil)carbonil](C₂₋₆-alquenil)amino, [(C₃₋₆-cicloalquil)carbonil](C₂₋₆-alquenil)amino, (fenilcarbonil)(C₂₋₆-alquenil)amino, (heterociclilcarbonil)(C₂₋₆-alquenil)amino, (heteroarilcarbonil)(C₂₋₆-alquenil)amino, [(C₁₋₆-alquil)carbonil](C₃₋₆-alquinil)amino, [(C₁₋₆-haloalquil)carbonil](C₃₋₆-alquinil)amino, [(C₃₋₆-cicloalquil)carbonil](C₃₋₆-alquinil)amino, (fenilcarbonil)(C₃₋₆-alquinil)amino, (heterociclilcarbonil)(C₃₋₆-alquinil)amino, (heteroarilcarbonil)(C₃₋₆-alquinil)amino, [(C₂₋₆-alquenil)carbonil]amino, [(C₂₋₆-alquenil)carbonil](C₁₋₆-alquil)amino, [(C₂₋₆-alquenil)carbonil](C₁₋₆-alcoxi)amino, [(C₃₋₆-alquinil)carbonil]amino, [(C₃₋₆-alquinil)carbonil](C₁₋₆-alquil)amino, [(C₃₋₆-alquinil)carbonil](C₁₋₆-alcoxi)amino, [di(C₁₋₆-alquil)amino]carbonilamino, [di(C₁₋₆-alquil)aminocarbonil](C₁₋₆-alquil)amino, [di(C₁₋₆-alquil)aminocarbonil](C₁₋₆-alcoxi)amino, (heteroaril)oxi, heteroaril-C₁₋₆-alcoxi, (heterociclil)oxi, o heterociclil-C₁₋₆-alcoxi; en donde los grupos cíclicos de R² son no sustituidos o sustituidos con Rᵃ; Z es un anillo bicíclico de 9 ó 10 miembros que comprende A; A es C*, CR³, NR³A, N, O ó S; C* es un puente carbono del anillo bicíclico Z; R³ es halógeno, CN, CHO, NO₂, C₁₋₆-alquilo, C₁₋₆-haloalquilo, C₁₋₆-alquilcarbonilo, C₂₋₆-alquenilo, C₂₋₆-haloalquenilo, C₂₋₆-alquenilo, C₂₋₆-haloalquenilo, C₁₋₆-alcoxi, C₁₋₆-haloalcoxi, C₃₋₆-alqueniloxi, C₃₋₆-haloalqueniloxi, C₃₋₆-alqueniloxi, C₃₋₆-haloalqueniloxi, C₁₋₆-alcoxi-C₁₋₆-alcoxi, hidroxicarbonilo, C₁₋₆-alcoxicarbonilo, C₁₋₆-alquiltio, C₁₋₆-haloalquiltio, NH₂, (C₁₋₆-alquil)amino, di(C₁₋₆-alquil)amino, (C₁₋₆-alquil)sulfinilo, (C₁₋₆-alquil)sulfonilo, C₃₋₆-cicloalquilo, (C₃₋₆-cicloalquil)oxi, o fenilo; en donde los grupos cíclicos de R³ son no sustituidos o sustituidos con sustituyentes Rᵃ; R³A es H, C₁₋₆-alquilo, C₁₋₆-haloalquilo, C₁₋₆-alquilcarbonilo, C₂₋₆-alquenilo, C₂₋₆-haloalquenilo, C₂₋₆-alquenilo, C₂₋₆-haloalquenilo, C₁₋₆-alcoxi, C₁₋₆-haloalcoxi, C₃₋₆-alqueniloxi, C₃₋₆-haloalqueniloxi, C₃₋₆-alqueniloxi, C₃₋₆-haloalqueniloxi, C₁₋₆-alcoxi-C₁₋₆-alcoxi, hidroxicarbonilo, C₁₋₆-alcoxicarbonilo, C₁₋₆-alquiltio, C₁₋₆-haloalquiltio, NH₂, (C₁₋₆-alquil)amino, di(C₁₋₆-alquil)amino, (C₁₋₆-alquil)sulfinilo, (C₁₋₆-alquil)sulfonilo, C₃₋₆-cicloalquilo, (C₃₋₆-cicloalquil)oxi, o fenilo; en donde los grupos cíclicos de R³A son no sustituidos o sustituidos con Rᵃ; R⁴ es halógeno, CN, CHO, NO₂, C₁₋₆-alquilo, C₁₋₆-haloalquilo, C₁₋₆-alquil-carbonilo, C₂₋₆-alquenilo, C₂₋₆-haloalquenilo, C₂₋₆-alquenilo, C₂₋₆-haloalquenilo, C₁₋₆-alcoxi, C₁₋₆-haloalcoxi, C₃₋₆-alqueniloxi, C₃₋₆-haloalqueniloxi, C₃₋₆-alqueniloxi, C₃₋₆-haloalqueniloxi, C₁₋₆-alcoxi-C₁₋₆-alcoxi, hidroxicarbonilo, C₁₋₆-alcoxicarbonilo, C₁₋₆-alquiltio, C₁₋₆-haloalquiltio, NH₂, (C₁₋₆-alquil)amino, di(C₁₋₆-alquil)amino, (C₁₋₆-alquil)sulfinilo, (C₁₋₆-alquil)sulfonilo, C₃₋₆-cicloalquilo, (C₃₋₆-cicloalquil)oxi, o fenilo; en donde los grupos cíclicos de R⁴ son no sustituidos o sustituidos con Rᵃ; Rᵃ es halógeno, CN, NO₂, C₁₋₆-alquilo, C₁₋₆-haloalquilo, C₁₋₆-alcoxi o C₁₋₆-haloalcoxi; m es 0, 1, 2, ó 3; siempre que, si el anillo Z es naftaleno no sustituido, m sea 1, 2 ó 3; y derivados o sales aceptables en la agricultura de los compuestos de la fórmula (1) que tienen una funcionalidad ácida.
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