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AR095518A1 - 4-amino-6-(heterocíclico)picolinatos y 6-amino-2-(heterocíclico)pirimidin-4-carboxilatos y su uso como herbicidas - Google Patents

4-amino-6-(heterocíclico)picolinatos y 6-amino-2-(heterocíclico)pirimidin-4-carboxilatos y su uso como herbicidas

Info

Publication number
AR095518A1
AR095518A1 ARP140101126A ARP140101126A AR095518A1 AR 095518 A1 AR095518 A1 AR 095518A1 AR P140101126 A ARP140101126 A AR P140101126A AR P140101126 A ARP140101126 A AR P140101126A AR 095518 A1 AR095518 A1 AR 095518A1
Authority
AR
Argentina
Prior art keywords
alkyl
hydrogen
haloalkyl
alkoxy
amino
Prior art date
Application number
ARP140101126A
Other languages
English (en)
Inventor
M Satchivi Norbert
Richard Schmitzer Paul
D Eckelbarger Joseph
L Siddall Thomas
Original Assignee
Dow Agrosciences Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Agrosciences Llc filed Critical Dow Agrosciences Llc
Publication of AR095518A1 publication Critical patent/AR095518A1/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
    • C07D413/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings
    • C07D413/10—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a carbon chain containing aromatic rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K31/00—Medicinal preparations containing organic active ingredients
    • A61K31/33—Heterocyclic compounds
    • A61K31/395—Heterocyclic compounds having nitrogen as a ring hetero atom, e.g. guanethidine or rifamycins
    • A61K31/435—Heterocyclic compounds having nitrogen as a ring hetero atom, e.g. guanethidine or rifamycins having six-membered rings with one nitrogen as the only ring hetero atom
    • A61K31/44—Non condensed pyridines; Hydrogenated derivatives thereof
    • A61K31/4427—Non condensed pyridines; Hydrogenated derivatives thereof containing further heterocyclic ring systems
    • A61K31/443—Non condensed pyridines; Hydrogenated derivatives thereof containing further heterocyclic ring systems containing a five-membered ring with oxygen as a ring hetero atom
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K31/00—Medicinal preparations containing organic active ingredients
    • A61K31/33—Heterocyclic compounds
    • A61K31/395—Heterocyclic compounds having nitrogen as a ring hetero atom, e.g. guanethidine or rifamycins
    • A61K31/495—Heterocyclic compounds having nitrogen as a ring hetero atom, e.g. guanethidine or rifamycins having six-membered rings with two or more nitrogen atoms as the only ring heteroatoms, e.g. piperazine or tetrazines
    • A61K31/505—Pyrimidines; Hydrogenated pyrimidines, e.g. trimethoprim
    • A61K31/506—Pyrimidines; Hydrogenated pyrimidines, e.g. trimethoprim not condensed and containing further heterocyclic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
    • C07D413/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings
    • C07D413/04—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D417/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
    • C07D417/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings
    • C07D417/04—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings directly linked by a ring-member-to-ring-member bond

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Pyridine Compounds (AREA)

Abstract

Reivindicación 1: Un compuesto de fórmula (1); X es N o CY, en la que Y es hidrógeno, halógeno, alquilo C₁₋₃, haloalquilo C₁₋₃, alcoxi C₁₋₃, haloalcoxi C₁₋₃, alcoxi C₁₋₃, alquiltio C₁₋₃ o haloalquiltio C₁₋₃; R¹ es OR¹ o NR¹R¹, donde R¹ es hidrógeno, alquilo C₁₋₈ o arilalquilo C₇₋₁₀, y R¹ y R¹ son independientemente hidrógeno, alquilo C₁₋₁₂, alquenilo C₃₋₁₂ o alquinilo C₃₋₁₂; R² es halógeno, alquilo C₁₋₄, haloalquilo C₁₋₄, alquenilo C₂₋₄, haloalquenilo C₂₋₄, alquinilo C₂₋₄, alcoxi C₁₋₄, haloalcoxi C₁₋₄, alquiltio C₁₋₄, haloalquiltio C₁₋₄, amino, alquilamino C₁₋₄, haloalquilamino C₂₋₄, formilo, alquilcarbonilo C₁₋₃, haloalquilcarbonilo C₁₋₃, ciano, o un grupo de la fórmula -CR¹⁷=CR¹⁸-SiR¹⁹R²⁰R²¹, en la que R¹⁷ es hidrógeno, F, o Cl; R¹⁸ es hidrógeno, F, Cl, alquilo C₁₋₄ o haloalquilo C₁₋₄; y R¹⁹, R²⁰, y R²¹ son independientemente alquilo C₁₋₁₀, cicloalquilo C₃₋₆, fenilo, fenilo sustituido, alcoxi C₁₋₁₀ o OH; R³ y R⁴ son independientemente hidrógeno, alquilo C₁₋₆, haloalquilo C₁₋₆, alquenilo C₃₋₆, haloalquenilo C₃₋₆, alquinilo C₃₋₆, formilo, alquilcarbonilo C₁₋₃, haloalquilcarbonilo C₁₋₃, alcoxicarbonilo C₁₋₆, alquilcarbamilo C₁₋₆, alquilsulfonilo C₁₋₆, trialquilsililo C₁₋₆, dialquilfosfonilo C₁₋₆, o R³ y R⁴ tomados junto con N es un anillo saturado o insaturado de 5 ó 6 miembros, o R³ y R⁴ tomados juntos representan =CR³(R⁴), en la que R³ y R⁴ son independientemente hidrógeno, alquilo C₁₋₆, alquenilo C₃₋₆, alquinilo C₃₋₆, alcoxi C₁₋₆ o alquilamino C₁₋₆, o, R³ y R⁴ tomados junto con =C representan un anillo saturado de 5 ó 6 miembros; Ar es uno de los grupos Ar1 a Ar4 seleccionados del grupo de fórmulas (2); R⁵, si es aplicable al grupo Ar, es hidrógeno, halógeno, alquilo C₁₋₄, haloalquilo C₁₋₄, alquenilo C₂₋₄, alcoxi C₁₋₃, haloalcoxi C₁₋₃, alquiltio C₁₋₃, haloalquiltio C₁₋₃, amino, alquilamino C₁₋₄ o haloalquilamino C₂₋₄; R⁶ es hidrógeno, halógeno, alquilo C₁₋₄, haloalquilo C₁₋₄, alcoxi C₁₋₃, haloalcoxi C₁₋₃, alquiltio C₁₋₃, haloalquiltio C₁₋₃, amino, aminoalquilo C₁₋₄ o haloaminoalquilo C₂₋₄; R⁶ es hidrógeno o halógeno; R⁶, si es aplicable al grupo Ar, es hidrógeno, halógeno, alquilo C₁₋₄, haloalquilo C₁₋₄, ciclopropilo, halociclopropilo, alquenilo C₂₋₄, haloalquenilo C₂₋₄, alquinilo C₂₋₄, alcoxi C₁₋₃, haloalcoxi C₁₋₃, alquiltio C₁₋₃, haloalquiltio C₁₋₃, amino, aminoalquilo C₁₋₄ o haloaminoalquilo C₂₋₄, CN o NO₂; o un N-óxido o una sal agrícolamente aceptable de estos.
ARP140101126A 2013-03-15 2014-03-14 4-amino-6-(heterocíclico)picolinatos y 6-amino-2-(heterocíclico)pirimidin-4-carboxilatos y su uso como herbicidas AR095518A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US201361790112P 2013-03-15 2013-03-15

Publications (1)

Publication Number Publication Date
AR095518A1 true AR095518A1 (es) 2015-10-21

Family

ID=51529784

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP140101126A AR095518A1 (es) 2013-03-15 2014-03-14 4-amino-6-(heterocíclico)picolinatos y 6-amino-2-(heterocíclico)pirimidin-4-carboxilatos y su uso como herbicidas

Country Status (9)

Country Link
US (1) US9006250B2 (es)
EP (1) EP2970186B1 (es)
JP (2) JP6513073B2 (es)
CN (1) CN105377830B (es)
AR (1) AR095518A1 (es)
BR (1) BR102014006357B8 (es)
ES (1) ES2811084T3 (es)
UY (1) UY35473A (es)
WO (1) WO2014151009A1 (es)

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JP6513073B2 (ja) * 2013-03-15 2019-05-15 ダウ アグロサイエンシィズ エルエルシー ４−アミノ−６−（複素環式）ピコリネートおよび６−アミノ−２−（複素環式）ピリミジン−４−カルボキシレートならびに除草剤としてのそれらの使用
US10711138B2 (en) 2016-04-08 2020-07-14 Merck Patent Gmbh Intermediates and procedures for the synthesis of functional materials
MX2018014174A (es) 2016-05-19 2019-03-14 Dow Agrosciences Llc Sintesis de 6-aril-4-aminopicolinatos y 2-aril-6-aminopirimidin-4- carboxilatos mediante acoplamiento suzuki directo.
JP6721723B2 (ja) 2016-06-27 2020-07-15 モグ リサーチ センター リミテッドＭｏｇｈｕ Ｒｅｓｅａｒｃｈ Ｃｅｎｔｅｒ Ｌｔｄ． イソキサゾリン環を含むピリジン系化合物及び除草剤としての該用途
US11401242B2 (en) * 2018-09-19 2022-08-02 Corteva Agriscience Llc Preparation of halogen analogs of picloram
CN110790711A (zh) * 2019-11-29 2020-02-14 都创(上海)医药科技有限公司 一种2-氯-4-氨基-6-甲基嘧啶化合物制备方法
EP4121414A1 (en) 2020-03-18 2023-01-25 Corteva Agriscience LLC Improved synthesis of 4-amino-6-(heterocyclic)picolinates

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DE602007008052D1 (de) 2006-01-13 2010-09-09 Dow Agrosciences Llc 2-(polysubstituiertes aryl)-6-amino-5-halogen-4-pyrimidincarbonsäuren und deren verwendung als herbizide
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JP6513073B2 (ja) * 2013-03-15 2019-05-15 ダウ アグロサイエンシィズ エルエルシー ４−アミノ−６−（複素環式）ピコリネートおよび６−アミノ−２−（複素環式）ピリミジン−４−カルボキシレートならびに除草剤としてのそれらの使用

Also Published As

Publication number Publication date
EP2970186A4 (en) 2016-10-12
CN105377830A (zh) 2016-03-02
CN105377830B (zh) 2018-04-13
UY35473A (es) 2014-10-31
JP6513073B2 (ja) 2019-05-15
JP2019112408A (ja) 2019-07-11
EP2970186A1 (en) 2016-01-20
BR102014006357B8 (pt) 2022-09-06
BR102014006357B1 (pt) 2020-06-02
WO2014151009A1 (en) 2014-09-25
US9006250B2 (en) 2015-04-14
JP2016518327A (ja) 2016-06-23
BR102014006357A2 (pt) 2014-10-21
EP2970186B1 (en) 2020-06-10
US20140274702A1 (en) 2014-09-18
ES2811084T3 (es) 2021-03-10
JP6869277B2 (ja) 2021-05-12

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