AR039719A1 - Derivados de ftalamida - Google Patents
Derivados de ftalamidaInfo
- Publication number
- AR039719A1 AR039719A1 ARP030102204A ARP030102204A AR039719A1 AR 039719 A1 AR039719 A1 AR 039719A1 AR P030102204 A ARP030102204 A AR P030102204A AR P030102204 A ARP030102204 A AR P030102204A AR 039719 A1 AR039719 A1 AR 039719A1
- Authority
- AR
- Argentina
- Prior art keywords
- formula
- compounds
- halogen
- optionally substituted
- alkyl
- Prior art date
Links
- 229910052736 halogen Inorganic materials 0.000 abstract 9
- 150000001875 compounds Chemical class 0.000 abstract 8
- 150000002367 halogens Chemical group 0.000 abstract 7
- 238000002360 preparation method Methods 0.000 abstract 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 3
- 239000012442 inert solvent Substances 0.000 abstract 3
- 239000003377 acid catalyst Substances 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- NAYYNDKKHOIIOD-UHFFFAOYSA-N phthalamide Chemical class NC(=O)C1=CC=CC=C1C(N)=O NAYYNDKKHOIIOD-UHFFFAOYSA-N 0.000 abstract 2
- 125000004687 alkyl sulfinyl alkyl group Chemical group 0.000 abstract 1
- 125000004688 alkyl sulfonyl alkyl group Chemical group 0.000 abstract 1
- 125000006350 alkyl thio alkyl group Chemical group 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- 230000000749 insecticidal effect Effects 0.000 abstract 1
- 239000002917 insecticide Substances 0.000 abstract 1
- 239000007800 oxidant agent Substances 0.000 abstract 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 125000000547 substituted alkyl group Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
- C07D209/44—Iso-indoles; Hydrogenated iso-indoles
- C07D209/48—Iso-indoles; Hydrogenated iso-indoles with oxygen atoms in positions 1 and 3, e.g. phthalimide
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/04—Sulfonic acids; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
- C07C309/63—Esters of sulfonic acids
- C07C309/64—Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to acyclic carbon atoms
- C07C309/65—Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to acyclic carbon atoms of a saturated carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
- C07C309/63—Esters of sulfonic acids
- C07C309/64—Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to acyclic carbon atoms
- C07C309/65—Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to acyclic carbon atoms of a saturated carbon skeleton
- C07C309/66—Methanesulfonates
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C317/00—Sulfones; Sulfoxides
- C07C317/26—Sulfones; Sulfoxides having sulfone or sulfoxide groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton
- C07C317/28—Sulfones; Sulfoxides having sulfone or sulfoxide groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton with sulfone or sulfoxide groups bound to acyclic carbon atoms of the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
- C07C323/23—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton
- C07C323/24—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton
- C07C323/25—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being acyclic and saturated
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
- C07C323/23—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton
- C07C323/39—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton at least one of the nitrogen atoms being part of any of the groups, X being a hetero atom, Y being any atom
- C07C323/40—Y being a hydrogen or a carbon atom
- C07C323/42—Y being a carbon atom of a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/77—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D307/87—Benzo [c] furans; Hydrogenated benzo [c] furans
- C07D307/89—Benzo [c] furans; Hydrogenated benzo [c] furans with two oxygen atoms directly attached in positions 1 and 3
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/77—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D307/87—Benzo [c] furans; Hydrogenated benzo [c] furans
- C07D307/90—Benzo [c] furans; Hydrogenated benzo [c] furans with an oxygen atom in position 1 and a nitrogen atom in position 3, or vice versa
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/02—Systems containing only non-condensed rings with a three-membered ring
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Indole Compounds (AREA)
Abstract
Derivados de ftalamida y procedimientos para su preparación y su uso como agentes insecticidas en el campo agrícola y hortícola; composición insecticida y procedimiento de preparación de la misma. Reivindicación 1: Derivados de ftalamida representados por la fórmula (1) en donde: R1 representa alquilo que puede estar opcionalmente sustituido con halógeno; R2 representa alquilo que puede estar opcionalmente sustituido o cicloalquilo que puede estar opcionalmente sustituido; R3 representa un átomo de hidrógeno, halógeno o alquilo que puede estar opcionalmente sustituido con halógeno; R4 representa un átomo de hidrógeno, alquilo sustituido con halógeno, alcoxi sustituido con halógenom, fenilo sustituido con halógeno o fenoxi sustituido con halógeno y R5 representa un átomo de hidrógeno, halógeno o alquilo que puede estar opcionalmente sustituido con halógeno. Reivindicación 5: Procedimiento para la preparación de los compuestos de fórmula (1) según la reivindicación 1, caracterizado porque a) compuestos de fórmula (2) en donde R1, R3, R4 y R5 se definen como en la reivindicación 1, se hacen reaccionar con compuestos de fórmula H2N-R2 en donde R2 se define como en la reivindicación 1, en presencia de disolventes inertes y, si resulta adecuado, en presencia, de una base, o b) compuestos de fórmula (3) en donde R1 y R2 se definen como en la reivindicación 1, se hacen reaccionar con compuestos de fórmula (4) en donde R3, R4 y R5 se definen como en la reivindicación 1, en presencia de disolventes inertes y, si resulta adecuado, en presencia de un catalizador ácido; o c) compuestos de fórmula (5) en donde R1, R3, R4 y R5 se definen como en la reivindicación 1, se hacen reaccionar con compuestos de fórmula H2N-R2 en donde R2 se define como en la reivindicación 1, en presencia de disolventes inertes y, si resulta adecuado, en presencia de un catalizador ácido; o d) en el caso de la preparación de los compuestos de fórmula (1) en donde R2 representa alquilsulfinilalquilo o alquilsulfonilalquilo: compuestos de fórmula (6) en donde R2d representa alquiltioalquilo, R1, R3, R4 y R5 se definen como en la reivindicación 1, se hacen reaccionar con un agente oxidante, en presencia de disolventes inertes.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2002180028A JP2004018506A (ja) | 2002-06-20 | 2002-06-20 | 殺虫性フタラミド誘導体 |
Publications (1)
Publication Number | Publication Date |
---|---|
AR039719A1 true AR039719A1 (es) | 2005-03-09 |
Family
ID=29996585
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP030102204A AR039719A1 (es) | 2002-06-20 | 2003-06-20 | Derivados de ftalamida |
Country Status (14)
Country | Link |
---|---|
US (1) | US7132455B2 (es) |
EP (1) | EP1517886B1 (es) |
JP (2) | JP2004018506A (es) |
KR (1) | KR101004070B1 (es) |
CN (3) | CN1955162A (es) |
AR (1) | AR039719A1 (es) |
AT (1) | ATE487694T1 (es) |
AU (1) | AU2003258495B2 (es) |
BR (1) | BR0311955B1 (es) |
DE (1) | DE60334907D1 (es) |
ES (1) | ES2355138T3 (es) |
MX (1) | MXPA04012739A (es) |
TW (1) | TWI329101B (es) |
WO (1) | WO2004000796A1 (es) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2006089469A (ja) * | 2004-08-23 | 2006-04-06 | Nippon Nohyaku Co Ltd | 光学活性フタルアミド誘導体及び農園芸用殺虫剤並びにその使用方法 |
KR100854608B1 (ko) * | 2004-08-23 | 2008-08-27 | 니혼노야쿠가부시키가이샤 | 광학 활성 프탈아미드 유도체, 농원예용 살충제, 및 그의사용 방법 |
JP4977607B2 (ja) * | 2004-08-31 | 2012-07-18 | バイエル・クロップサイエンス・アーゲー | 光学活性フタルアミド |
GB0419420D0 (en) * | 2004-09-01 | 2004-10-06 | Syngenta Participations Ag | Novel insecticides |
TW200626532A (en) * | 2004-09-21 | 2006-08-01 | Syngenta Participations Ag | Novel insecticides |
JP2006347936A (ja) * | 2005-06-15 | 2006-12-28 | Bayer Cropscience Ag | 殺虫性ベンズアニリド類 |
BR102013021210B1 (pt) | 2013-01-25 | 2015-12-01 | Fundação Universidade Fed De São Carlos | processo de obtenção de nanopartículas biopoliméricas contendo óleo e extratos de azadirachta indica a. juss (neem), nanopartículas biopoliméricas e micropartículas em pó |
CN104007231A (zh) * | 2014-05-12 | 2014-08-27 | 青岛农业大学 | 一种用于杀虫剂对玉米螟毒力的测定方法和测定装置 |
CN108601353B (zh) | 2016-02-08 | 2024-04-05 | 高文作物保护公司 | 杀菌性组合物 |
CN118085297B (zh) * | 2024-04-23 | 2024-07-19 | 广东东溢新材料科技有限公司 | 一种用于柔性电路板的交联杂化型聚酰亚胺树脂及其制备方法、柔性电路板 |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB9510459D0 (en) | 1995-05-24 | 1995-07-19 | Zeneca Ltd | Bicyclic amines |
GB9624611D0 (en) | 1996-11-26 | 1997-01-15 | Zeneca Ltd | Bicyclic amine compounds |
ID22349A (id) | 1996-11-26 | 1999-09-30 | Zeneca Ltd | Turunan dari 8-azabisiklo [3.2.1] oktana-, 8-azabisiklo [3.2.1] okt-6-ena-, 9-azabisiklo-[3.3.1] nonana-, 9-aza-3-oksabisiklo [3.3.1] nonana- dan 9-aza-3-tiobisiklo [3.3.1] nonana, pembuatannya dan penggunaannya sebagai insektisida |
TW515786B (en) * | 1997-11-25 | 2003-01-01 | Nihon Nohyaku Co Ltd | Phthalic acid diamide derivatives, agricultural and horticultural insecticides, and a method for application of the insecticides |
US6362369B2 (en) | 1997-11-25 | 2002-03-26 | Nihon Nohyaku Co., Ltd. | Phthalic acid diamide derivatives fluorine-containing aniline compounds as starting material, agricultural and horticultural insecticides, and a method for application of the insecticides |
CZ299375B6 (cs) | 1998-11-30 | 2008-07-09 | Nihon Nohyaku Co., Ltd. | Ftalamidové deriváty nebo jejich soli, zemedelsko-zahradnický insekticid je obsahující a jeho použití |
PL352197A1 (en) | 1999-06-24 | 2003-08-11 | Nihon Nohyaku Co Ltd | Diamide derivatives of heterocyclic dicarboxylic acid, insecticides for agriculture and horticulture and the method of making same |
DE60004853T2 (de) | 1999-06-25 | 2004-05-27 | Nihon Nohyaku Co., Ltd. | Benzamid-derivate, insektizide zur verwendung im agrar- und gartenbereich und ihre verwendung |
AR030154A1 (es) * | 1999-07-05 | 2003-08-13 | Nihon Nohyaku Co Ltd | Derivado de ftalamida, derivado de amina heterociclico util como intermediario para la produccion del mismo, insecticida agrohorticola y metodo para utilizar dicho insecticida |
DE60018769T2 (de) | 1999-09-24 | 2005-08-04 | Nihon Nohyaku Co., Ltd. | Aromatische diamid-derivate oder ihre salze, chemikalien für die landwirtschaft/den gartenbau und verfahren zu ihrer anwendung |
AU7446900A (en) | 1999-09-28 | 2001-04-30 | Nihon Nohyaku Co., Ltd. | Thioalkylamine derivatives and process for the preparation thereof |
BR0016573A (pt) * | 1999-12-22 | 2002-09-03 | Nihon Nohyaku Co Ltd | Derivado de diamida aromática, produto quìmico agrìcola e de horticultura, e, método para aplicar um produto quìmico agrìcola e de horticultura |
DE10115406A1 (de) * | 2001-02-06 | 2002-08-08 | Bayer Ag | Phthalsäurediamide |
US20040116299A1 (en) * | 2001-04-26 | 2004-06-17 | Hiroto Harayama | Phthalamide derivates, insecticides for agricultural and horticultural use and method for application thereof |
AR035884A1 (es) * | 2001-05-18 | 2004-07-21 | Nihon Nohyaku Co Ltd | Derivado de amida aromatico sustituido, derivado de amina aromatico sustituido con un grupo fluoroalquilo util como intermediario para obtener el mismo, insecticida para agrohorticultura que lo contiene y metodo para usar este ultimo |
JP2004277333A (ja) * | 2003-03-14 | 2004-10-07 | Bayer Cropscience Ag | 殺虫性フタラミド誘導体 |
-
2002
- 2002-06-20 JP JP2002180028A patent/JP2004018506A/ja active Pending
-
2003
- 2003-06-11 AT AT03760601T patent/ATE487694T1/de not_active IP Right Cessation
- 2003-06-11 WO PCT/EP2003/006105 patent/WO2004000796A1/en active Application Filing
- 2003-06-11 CN CNA2006101464691A patent/CN1955162A/zh active Pending
- 2003-06-11 DE DE60334907T patent/DE60334907D1/de not_active Expired - Lifetime
- 2003-06-11 BR BRPI0311955-6A patent/BR0311955B1/pt not_active IP Right Cessation
- 2003-06-11 US US10/517,859 patent/US7132455B2/en not_active Expired - Lifetime
- 2003-06-11 AU AU2003258495A patent/AU2003258495B2/en not_active Ceased
- 2003-06-11 KR KR1020047020417A patent/KR101004070B1/ko not_active IP Right Cessation
- 2003-06-11 CN CNB2006101464672A patent/CN100556903C/zh not_active Expired - Fee Related
- 2003-06-11 EP EP03760601A patent/EP1517886B1/en not_active Expired - Lifetime
- 2003-06-11 ES ES03760601T patent/ES2355138T3/es not_active Expired - Lifetime
- 2003-06-11 JP JP2004514688A patent/JP4330531B2/ja not_active Expired - Fee Related
- 2003-06-11 CN CNB038185393A patent/CN100516033C/zh not_active Expired - Fee Related
- 2003-06-11 MX MXPA04012739A patent/MXPA04012739A/es active IP Right Grant
- 2003-06-19 TW TW092116606A patent/TWI329101B/zh not_active IP Right Cessation
- 2003-06-20 AR ARP030102204A patent/AR039719A1/es unknown
Also Published As
Publication number | Publication date |
---|---|
TW200407286A (en) | 2004-05-16 |
US7132455B2 (en) | 2006-11-07 |
AU2003258495A1 (en) | 2004-01-06 |
AU2003258495B2 (en) | 2009-03-12 |
CN100516033C (zh) | 2009-07-22 |
JP4330531B2 (ja) | 2009-09-16 |
ATE487694T1 (de) | 2010-11-15 |
US20060035967A1 (en) | 2006-02-16 |
BR0311955A (pt) | 2005-04-26 |
KR20050010057A (ko) | 2005-01-26 |
ES2355138T3 (es) | 2011-03-23 |
CN1955162A (zh) | 2007-05-02 |
DE60334907D1 (de) | 2010-12-23 |
TWI329101B (en) | 2010-08-21 |
KR101004070B1 (ko) | 2010-12-27 |
CN1955172A (zh) | 2007-05-02 |
JP2005529963A (ja) | 2005-10-06 |
MXPA04012739A (es) | 2005-03-23 |
CN100556903C (zh) | 2009-11-04 |
CN1671655A (zh) | 2005-09-21 |
WO2004000796A1 (en) | 2003-12-31 |
BR0311955B1 (pt) | 2014-07-29 |
EP1517886A1 (en) | 2005-03-30 |
EP1517886B1 (en) | 2010-11-10 |
JP2004018506A (ja) | 2004-01-22 |
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