AR025310A1 - Sistema catalizador de rodio / yoduro inorganico para el proceso de carbonilacion de metanol con perfeccionado perfil de impureza. - Google Patents
Sistema catalizador de rodio / yoduro inorganico para el proceso de carbonilacion de metanol con perfeccionado perfil de impureza.Info
- Publication number
- AR025310A1 AR025310A1 ARP000104257A ARP000104257A AR025310A1 AR 025310 A1 AR025310 A1 AR 025310A1 AR P000104257 A ARP000104257 A AR P000104257A AR P000104257 A ARP000104257 A AR P000104257A AR 025310 A1 AR025310 A1 AR 025310A1
- Authority
- AR
- Argentina
- Prior art keywords
- methanol
- iodine
- impurity
- carbonilation
- perfected
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
El método proporciona un perfeccionamiento sobre los métodos de carbonilacion de metanol del arte previo, que reduce sustancialmente la produccion deimpurezas de carbonilo. La produccion de impurezas de carbonilo, en particular acetaldehído, crotonaldehido y 2-etil crotonaldehído, en reacciones decarbonilacion de metanol, ha demostrado disminuir, manteniendo una presion parcial de hidrogeno entre aproximadamente 0,1 y 4 psia (0,68 y 27,5 kPa abs.) a unapresion total de reaccion de desde aproximadamente 15 a aproximadamente 40 atmosferas (1,5 a 4,05 MPa) de presion de reaccion total.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/386,708 US6303813B1 (en) | 1999-08-31 | 1999-08-31 | Rhodium/inorganic iodide catalyst system for methanol carbonylation process with improved impurity profile |
Publications (1)
Publication Number | Publication Date |
---|---|
AR025310A1 true AR025310A1 (es) | 2002-11-20 |
Family
ID=23526710
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP000104257A AR025310A1 (es) | 1999-08-31 | 2000-08-17 | Sistema catalizador de rodio / yoduro inorganico para el proceso de carbonilacion de metanol con perfeccionado perfil de impureza. |
Country Status (25)
Country | Link |
---|---|
US (1) | US6303813B1 (es) |
EP (1) | EP1208073B1 (es) |
JP (1) | JP4994549B2 (es) |
KR (1) | KR100651455B1 (es) |
CN (1) | CN1185198C (es) |
AR (1) | AR025310A1 (es) |
AT (1) | ATE295342T1 (es) |
AU (1) | AU775283B2 (es) |
BR (1) | BR0013463A (es) |
CA (1) | CA2381420C (es) |
CZ (1) | CZ2002753A3 (es) |
DE (1) | DE60020128T2 (es) |
ES (1) | ES2240139T3 (es) |
MX (1) | MXPA02002255A (es) |
MY (1) | MY131985A (es) |
NO (1) | NO327989B1 (es) |
NZ (1) | NZ517677A (es) |
PL (1) | PL199388B1 (es) |
RS (1) | RS50170B (es) |
RU (1) | RU2240305C2 (es) |
TR (1) | TR200200545T2 (es) |
TW (1) | TW506964B (es) |
UA (1) | UA70385C2 (es) |
WO (1) | WO2001016070A1 (es) |
ZA (1) | ZA200200935B (es) |
Families Citing this family (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4526381B2 (ja) * | 2004-12-27 | 2010-08-18 | ダイセル化学工業株式会社 | 酢酸の製造方法 |
US7820855B2 (en) | 2008-04-29 | 2010-10-26 | Celanese International Corporation | Method and apparatus for carbonylating methanol with acetic acid enriched flash stream |
US8835681B2 (en) | 2010-06-14 | 2014-09-16 | Celanese International Corporation | Methanol carbonylation process with rhodium catalyst and a lanthanide metal co-catalyst |
US9024061B2 (en) | 2010-06-14 | 2015-05-05 | Celanese International Corporation | Methanol carbonylation process with rhodium catalyst and a metallic co-catalyst selected from transition metals, zinc, beryllium, indium, tin, strontium and barium |
US8785684B2 (en) | 2010-06-14 | 2014-07-22 | Celanese International Corporation | Methanol carbonylation process with rhodium catalyst, an iodide salt and a metallic co-catalyst selected from transition metals, indium, strontium, barium, zinc, tin and heteropoly acids |
KR101879006B1 (ko) | 2010-12-15 | 2018-07-16 | 주식회사 다이셀 | 아세트산의 제조 방법 |
CN103370300B (zh) | 2010-12-15 | 2016-07-06 | 株式会社大赛璐 | 乙酸的制备方法 |
EP2791099B1 (en) | 2011-12-16 | 2017-02-01 | Celanese International Corporation | Production of acetic acid with enhanced catalyst stability |
TWI547477B (zh) | 2012-03-14 | 2016-09-01 | 大賽璐股份有限公司 | 醋酸之製造方法 |
US9409846B2 (en) | 2013-03-15 | 2016-08-09 | Celanese International Corporation | Process for separating product gas using carbonylation processes |
CN107108434A (zh) * | 2014-11-14 | 2017-08-29 | 国际人造丝公司 | 通过去除铁改进乙酸产率的方法 |
US9260369B1 (en) * | 2014-11-14 | 2016-02-16 | Celanese International Corporation | Processes for producing acetic acid product having low butyl acetate content |
US9540304B2 (en) * | 2014-11-14 | 2017-01-10 | Celanese International Corporation | Processes for producing an acetic acid product having low butyl acetate content |
KR102467611B1 (ko) | 2014-11-14 | 2022-11-16 | 셀라니즈 인터내셔날 코포레이션 | 낮은 요오드화에틸 함량을 갖는 반응 매질로부터 아세트산을 제조하기 위한 방법 |
US9340481B1 (en) | 2014-11-14 | 2016-05-17 | Celanese International Corporation | Process for flashing a reaction medium comprising lithium acetate |
US9302969B1 (en) | 2014-11-14 | 2016-04-05 | Celanese International Corporation | Processes for producing acetic acid by introducing a lithium compound |
US9540303B2 (en) | 2015-04-01 | 2017-01-10 | Celanese International Corporation | Processes for producing acetic acid |
US9416088B1 (en) | 2015-10-02 | 2016-08-16 | Celanese International Corporation | Process to produce acetic acid with recycle of water |
US9957216B2 (en) | 2015-11-13 | 2018-05-01 | Celanese International Corporation | Processes for producing acetic acid |
KR102257566B1 (ko) * | 2017-03-08 | 2021-05-31 | 주식회사 다이셀 | 아세트산의 제조 방법 |
US10550058B2 (en) | 2017-03-08 | 2020-02-04 | Daicel Corporation | Method for producing acetic acid |
MX2019011249A (es) | 2017-03-22 | 2019-11-01 | Daicel Corp | Metodo para producir acido acetico. |
CN107141213A (zh) * | 2017-05-24 | 2017-09-08 | 北京三聚环保新材料股份有限公司 | 一种甲醇羰基化合成醋酸的方法 |
US10737996B2 (en) * | 2018-05-29 | 2020-08-11 | Daicel Corporation | Method for producing acetic acid |
CN116217369A (zh) * | 2022-12-30 | 2023-06-06 | 江苏索普化工股份有限公司 | 一种提高甲醇低压羰基合成醋酸中三碘化铑溶解度的方法 |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3769329A (en) | 1970-03-12 | 1973-10-30 | Monsanto Co | Production of carboxylic acids and esters |
US5144068A (en) | 1984-05-03 | 1992-09-01 | Hoechst Celanese Corporation | Methanol carbonylation process |
US5026908A (en) | 1984-05-03 | 1991-06-25 | Hoechst Celanese Corporation | Methanol carbonylation process |
US5001259A (en) | 1984-05-03 | 1991-03-19 | Hoechst Celanese Corporation | Methanol carbonylation process |
CA1299195C (en) | 1986-06-16 | 1992-04-21 | G. Paull Torrence | Addition of hydrogen to carbon monoxide feed gas in producing acetic acid by carbonylation of methanol |
DE69414361T3 (de) * | 1993-08-18 | 2006-06-29 | Daicel Chemical Industries, Ltd., Sakai | Verfahren zur herstellung von acetanhydrid oder einer mischung von acetanhydrid und essigsäure |
US5625095A (en) | 1994-06-15 | 1997-04-29 | Daicel Chemical Industries, Ltd. | Process for producing high purity acetic acid |
GB9503382D0 (en) * | 1995-02-21 | 1995-04-12 | Bp Chem Int Ltd | Process |
IN192600B (es) | 1996-10-18 | 2004-05-08 | Hoechst Celanese Corp | |
JPH10231267A (ja) * | 1997-02-19 | 1998-09-02 | Chiyoda Corp | 有機カルボン酸の製造方法 |
GB9712601D0 (en) * | 1997-06-16 | 1997-08-20 | Bp Chem Int Ltd | Chemical process |
GB9816564D0 (en) * | 1998-07-31 | 1998-09-30 | Bp Chem Int Ltd | Process |
-
1999
- 1999-08-31 US US09/386,708 patent/US6303813B1/en not_active Expired - Lifetime
-
2000
- 2000-07-08 UA UA2002021703A patent/UA70385C2/uk unknown
- 2000-08-07 CA CA002381420A patent/CA2381420C/en not_active Expired - Fee Related
- 2000-08-07 CN CNB008122628A patent/CN1185198C/zh not_active Expired - Fee Related
- 2000-08-07 TR TR2002/00545T patent/TR200200545T2/xx unknown
- 2000-08-07 ES ES00952611T patent/ES2240139T3/es not_active Expired - Lifetime
- 2000-08-07 CZ CZ2002753A patent/CZ2002753A3/cs unknown
- 2000-08-07 WO PCT/US2000/021562 patent/WO2001016070A1/en active IP Right Grant
- 2000-08-07 EP EP00952611A patent/EP1208073B1/en not_active Expired - Lifetime
- 2000-08-07 NZ NZ517677A patent/NZ517677A/en not_active IP Right Cessation
- 2000-08-07 RU RU2002107997/04A patent/RU2240305C2/ru not_active IP Right Cessation
- 2000-08-07 BR BR0013463-5A patent/BR0013463A/pt not_active Application Discontinuation
- 2000-08-07 MX MXPA02002255A patent/MXPA02002255A/es active IP Right Grant
- 2000-08-07 KR KR1020027002419A patent/KR100651455B1/ko not_active IP Right Cessation
- 2000-08-07 PL PL353356A patent/PL199388B1/pl not_active IP Right Cessation
- 2000-08-07 AU AU65277/00A patent/AU775283B2/en not_active Ceased
- 2000-08-07 AT AT00952611T patent/ATE295342T1/de active
- 2000-08-07 JP JP2001519640A patent/JP4994549B2/ja not_active Expired - Lifetime
- 2000-08-07 DE DE60020128T patent/DE60020128T2/de not_active Expired - Lifetime
- 2000-08-07 RS YUP-115/02A patent/RS50170B/sr unknown
- 2000-08-17 AR ARP000104257A patent/AR025310A1/es active IP Right Grant
- 2000-08-29 MY MYPI20003980A patent/MY131985A/en unknown
- 2000-08-29 TW TW089117495A patent/TW506964B/zh not_active IP Right Cessation
-
2002
- 2002-02-01 ZA ZA200200935A patent/ZA200200935B/en unknown
- 2002-02-27 NO NO20020961A patent/NO327989B1/no not_active IP Right Cessation
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Legal Events
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