[go: up one dir, main page]
Skip to main content
Springer Nature Link
Log in

Thermodynamic Characteristics of Silver Perfluorobenzoates C6F5COOAg·0.5C6F5COOH and C6F5COOAg

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

The thermodynamic characteristics of silver perfluorobenzoates C6F5COOAg·0.5C6F5COOH and C6F5COOAg were studied by thermogravimetry, differential scanning calorimetry, and mass spectrometry. It was found that vaporization of these compounds occurs incongruently to give metallic silver and C6F5COOH, C12F10, CO2, and C18F14 molecules. Using the 2nd and 3rd laws of thermodynamics, the standard enthalpy of formation of silver perfluorobenzoate was found to be \({{\Delta }_{{\text{f}}}}H_{{{\text{298}}}}^{^\circ }\)(C6F5COOAg, cr) = –1195.6 ± 15.7 kJ/mol and the standard enthalpy of formation of the pentafluorobenzoic acid radical was estimated to be \({{\Delta }_{{\text{f}}}}H_{{{\text{298}}.{\text{15}}}}^{^\circ }\)(C6F5COO•, cr) = –878.6 ± 25.0 kJ/mol.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Subscribe and save

Springer+ Basic
$34.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or eBook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.

Similar content being viewed by others

REFERENCES

  1. Pierson, H.O., Handbook of Chemical Vapor Deposition (CVD): Principles, Technology and Applications, New York: Noyes, 1992.

    Google Scholar 

  2. Syrkin, V.G., CVD-metod. Khimicheskoe parofaznoe osazhdenie (CVD. Chemical Vapor Deposition), Moscow: Nauka, 2000.

  3. Grodzicki, A., Lakomska, I., Piszcek, P., et al., Coord. Chem. Rev., 2005, vol. 249, p. 2232.

    Article  CAS  Google Scholar 

  4. Kretzschmar, B.S.M., Assim, K., Preub, A., et al., RSC Adv., 2018, vol. 8, p. 15632.

    Article  CAS  Google Scholar 

  5. Mungkalasiri, J., Bedel, L., Emieux, F., et al., Chem. Vap. Deposition, 2010, vol. 16, p. 35.

    Article  CAS  Google Scholar 

  6. Puurunen, R.L., J. Appl. Phys., 2005, vol. 97, p. 121.

    Article  Google Scholar 

  7. Morozova, E.A., Dobrokhotova, Zh.V., and Alikhanyan, A.S., J. Therm. Anal. Calorim., 2017, vol. 130, p. 2211.

    Article  CAS  Google Scholar 

  8. Lukyanova, V.A., Papina, T.S., Didenko, K.V., and Alikhanyan, A.S., J. Therm. Anal. Calorim., 2008, vol. 92, p. 743.

    Article  CAS  Google Scholar 

  9. Lukyanova, V.A., Pimenova, S.M., Ilin, D.Yu., et al., J. Chem. Thermodyn., 2019, vol. 131, pp. 336–339. https://doi.org/10.1016/j.jct.2018.11.016

    Article  CAS  Google Scholar 

  10. Szlyk, E., Lakomska, I., and Grodzicki, A., Thermochim. Acta, 1993, vol. 223, p. 207.

    Article  CAS  Google Scholar 

  11. Logvinenko, V., Polunina, O., Michailov, Yu., et al., J. Therm. Anal. Calorim., 2007, vol. 90, no. 3, p. 813.

    Article  CAS  Google Scholar 

  12. Bazhanova, Z.G., Tarasov, Yu.I., Kovtun, D.M., et al., J. Struct. Chem., 2010, vol. 51, no. 3, p. 433.

    Article  Google Scholar 

  13. Roberts, G.D. and Edward, W.V., Org. Mass Spectrom., 1981, vol. 16, p. 546.

    Article  CAS  Google Scholar 

  14. Kayumova, D.B., Malkerova, I.P., Kiskin, M.A., et al., Russ. J. Inorg. Chem., 2021, vol. 66, p. 868. https://doi.org/10.1134/S0036023621060127

    Article  CAS  Google Scholar 

  15. Database. Thermal Characteristics of Compounds. http://www.chem.msu.ru/cgi-bin/tkv.pl.

  16. NIST Chemistry Webbook. http://webbook.nist.gov/ chemistry/.

Download references

ACKNOWLEGEMENTS

The study was carried out using the equipment of the Center for Collective Use of the Physical Investigation Methods, Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences.

Funding

This study was supported by the Russian Science Foundation (grant no. 21-13-00086).

Author information

Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

    I. P. Malkerova, D. B. Kayumova, E. V. Belova, M. A. Shmelev, A. A. Sidorov, I. L. Eremenko & A. S. Alikhanyan

  2. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia

    I. L. Eremenko

Authors
  1. I. P. Malkerova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. D. B. Kayumova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. V. Belova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. A. Shmelev
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. A. Sidorov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. I. L. Eremenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. A. S. Alikhanyan
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. A. Sidorov.

Ethics declarations

The authors declare that they have no conflicts of interest.

Additional information

Translated by Z. Svitanko

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Malkerova, I.P., Kayumova, D.B., Belova, E.V. et al. Thermodynamic Characteristics of Silver Perfluorobenzoates C6F5COOAg·0.5C6F5COOH and C6F5COOAg. Russ J Coord Chem 48, 84–88 (2022). https://doi.org/10.1134/S107032842202004X

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S107032842202004X

Keywords: