Iodate sulfate
Iodate sulfates are mixed anion compounds that contain both iodate and sulfate anions. Iodate sulfates have been investigated as optical second harmonic generators, and for separation of rare earth elements.[1] Related compounds include the iodate selenates[2] and chromate iodates.[3]
Iodate sulfates can be produced from water solutions of iodic acid and sulfate salts.[4]
List
[edit]| formula | name | formula
weight |
system | space group | cell Å | volume | density | comments | ref |
|---|---|---|---|---|---|---|---|---|---|
| Na7(IO3)(SO4)3 | 624.01 | orthorhombic | P212121 | a=6.839 b=10.851 c=18.519 Z=4 | 1374.2 | 3.016 | at 100K; band gap 4.83; SHQ 0.5×KDP; birefringence 0.075 at 1064 nm | [5] | |
| Na9(IO3)(SO4)4 | Hectorfloresite | monoclinic | P21/a | a = 18.775 b = 6.9356 c = 14.239 β = 108.91° Z = 4 | [5][6] | ||||
| K2SO4·HIO3 | 350.17 | monoclinic | P21/n | a=7.4215 b=7.1578 c=13.802 β=93.330° Z=4 | 731.9 | 3.178 | colourless; birefingence 0.14 at 589.3 nm; UV edge 275 nm | [7] | |
| K3Na5Mg5(IO3)6(SO4)6(H2O)5 | trigonal | P3c1 | |||||||
| K7.2Na8.8Mg10(IO3)12(SO4)12(H2O)12 | Fuenzalidaite | trigonal | P3c1 | a = 9.4643 c = 27.336 | 2,120.52 | colourless; Uniaxial (-) nω = 1.622 nε = 1.615; Birefringence = 0.007 | [5][8][9] | ||
| Nb2O3(IO3)2(SO4) | 679.68 | monoclinic | P21 | a=5.299 b=20.479 c=5.452 β=119.095° Z=2 | 517.0 | 4.366 | band gap 3.25; SHG 6 × KDP; birefringence 0.22 at 1064 nm; stable below 580 °C | [5][10] | |
| Ce(IO3)2(SO4) | CISO | 585.98 | orthorhombic | P212121 | a=7.5366 b=8.9787 c=11.6121 Z=4 | 785.78 | 4.953 | yellow; SHG 3.5 × KDP; birefringence 0.259 at 546 nm | [11] |
| Sm(IO3)(SO4) | monoclinic | P21/c | a=9.3148 b=6.8678 c=8.2852 β=104.701° | [12] | |||||
| Sm2(IO3)3(SO4)OH·3H2O | triclinic | P1 | a 7.3858 b 9.6166 c 11.8629 α=66.482° β=76.884° γ=69.101° | [12] | |||||
| Eu(IO3)(SO4) | monoclinic | P21/c | a=9.3083 b=6.8460 c=8.2575 β=104.696° | [5][1] | |||||
| Eu2(IO3)3(SO4)OH·3H2O | triclinic | P1 | a=7.3666 b=9.5817 c=11.8263 α=66.5365° β=76.8591° γ=69.1131° | [12] | |||||
| Dy(IO3)(SO4)(H2O) | orthorhombic | P212121 | a=7.3088 b=9.4824 c=11.7302 α=66.6573° β=76.8745° γ=69.2970° | [5] | |||||
| Dy(IO3)(SO4)(H2O)3 | orthorhombic | P212121 | a=6.682 b=8.791 c=13.632 | [1] | |||||
| Dy2(IO3)3(SO4)OH·3H2O | triclinic | P1 | [12] | ||||||
| Hg2(IO3)2(SO4) | monoclinic | C2/c | a=12.040 b=4.7133 c=15.533 β=102.43° | [13] | |||||
| Hg2(IO3)2(SO4)(H2O) | monoclinic | C2 | a=11.767 b=4.9190 c=7.8076 β=97.10° | band gap 3.98 eV; SHG 6 × KDP; dehydrate 250 °C | [13] | ||||
| Bi(IO3)(SO4) | 479.94 | monoclinic | P21/c | a=9.4355 b=6.9168 c=8.3374 β=105.168° Z=4 | 525.17 | 6.070 | band gap 3.91 eV; birefringence 0.087 at 1064 nm; colourless | [14] | |
| Bi2O(SO4)(IO3)2 | monoclinic | P21/n | a=7.2391 b=17.907 c=7.7964 β = 109.652° Z =4 | [4] | |||||
| AgBi(SO4)(IO3)2 | 1525.42 | triclinic | P1 | a=5.5189 b=6.9129 c=11.8527 α=90.598° β=92.151° γ=109.895° Z=1 | 424.78 | 5.963 | colourless; SHG 3.0 × KDP | [15] | |
| CdBi(IO3)(SO4)2 | 688.40 | monoclinic | P21/c | a=12.777 b=6.8491 c=9.984 β=103.23° Z=4 | 850.5 | 5.376 | band gap 4.03 eV; birefringence 0.100 at 1064 nm | [14] |
References
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- ^ Chen, Qian-Qian; Hu, Chun-Li; Li, Bing-Xuan; Mao, Jiang-Gao (2023). "[M(OH) 2 ] 3 (IO 3 )(SeO 4 )·H 2 O (M = Ga and In): metal iodate–selenate nonlinear optical materials with a hexagonal tungsten oxide-type topology". Inorganic Chemistry Frontiers. 10 (10): 3121–3130. doi:10.1039/D3QI00415E. ISSN 2052-1553. S2CID 258123310.
- ^ Sullens, Tyler A.; Almond, Philip M.; Byrd, Jessica A.; Beitz, James V.; Bray, Travis H.; Albrecht-Schmitt, Thomas E. (April 2006). "Extended networks, porous sheets, and chiral frameworks. Thorium materials containing mixed geometry anions: Structures and properties of Th(SeO3)(SeO4), Th(IO3)2(SeO4)(H2O)3·H2O, and Th(CrO4)(IO3)2". Journal of Solid State Chemistry. 179 (4): 1192–1201. Bibcode:2006JSSCh.179.1192S. doi:10.1016/j.jssc.2006.01.017.
- ^ a b Shi, Long; Mei, Dajiang; Xu, Jingli; Wu, Yuandong (January 2017). "Bi 2 O(XO 4 )(IO 3 ) 2 (X = S, Se, Cr): Three-dimensional frameworks containing [Bi 4 O 2 ] 8+ clusters". Solid State Sciences. 63: 54–61. Bibcode:2017SSSci..63...54S. doi:10.1016/j.solidstatesciences.2016.11.010.
- ^ a b c d e f Ding, Mengmeng; Yu, Hongwei; Hu, Zhanggui; Wang, Jiyang; Wu, Yicheng (2021). "Na 7 (IO 3 )(SO 4 ) 3 : the first noncentrosymmetric alkaline-metal iodate-sulfate with isolated [IO 3 ] and [SO 4 ] units". Chemical Communications. 57 (75): 9598–9601. doi:10.1039/D1CC03483A. ISSN 1359-7345. PMID 34546233. S2CID 237584872.
- ^ George E. Ericksen; Howard T. Evans; Mary E. Mrose; James J. Mcgee; John W. Marinenko; Judith A. Konnert (1 October 1989). "Mineralogical studies of the nitrate deposits of Chile; VI, Hectorfloresite, Na9(IO3(SO4)4, a new saline mineral". pubs.geoscienceworld.org. Retrieved 2023-09-11.
{{cite web}}: CS1 maint: multiple names: authors list (link) - ^ Bai, Zhiyong; Ok, Kang Min (2023). "Dramatically improved optical anisotropy by realizing stereochemically active lone pairs in a sulfate system, K 2 SO 4 ·HIO 3". Inorganic Chemistry Frontiers. 10 (6): 1919–1925. doi:10.1039/D3QI00192J. ISSN 2052-1553. S2CID 257071174.
- ^ "Fuenzalidaite". Mindat.org.
- ^ "Mineralogical studies of the nitrate deposits of Chile: VII. Two new saline minerals with the composition K6(Na,K)4Na6Mg10(XO4)12(IO3)12·12H2O: Fuenzalidaite (X = S) and carlosruizite (X = Se)". pubs.geoscienceworld.org. Retrieved 2023-09-11.
- ^ Tang, Hong-Xin; Zhang, Yu-Xiao; Zhuo, Chao; Fu, Rui-Biao; Lin, Hua; Ma, Zu-Ju; Wu, Xin-Tao (2019-03-18). "A Niobium Oxyiodate Sulfate with a Strong Second-Harmonic-Generation Response Built by Rational Multi-Component Design". Angewandte Chemie. 131 (12): 3864–3868. Bibcode:2019AngCh.131.3864T. doi:10.1002/ange.201813122. ISSN 0044-8249. S2CID 243005250.
- ^ Wu, Tianhui; Jiang, Xingxing; Zhang, Yiran; Wang, Zujian; Sha, Hongyuan; Wu, Chao; Lin, Zheshuai; Huang, Zhipeng; Long, Xifa; Humphrey, Mark G.; Zhang, Chi (2021-12-14). "From CeF 2 (SO 4 )·H 2 O to Ce(IO 3 ) 2 (SO 4 ): Defluorinated Homovalent Substitution for Strong Second-Harmonic-Generation Effect and Sufficient Birefringence". Chemistry of Materials. 33 (23): 9317–9325. doi:10.1021/acs.chemmater.1c03053. ISSN 0897-4756. S2CID 244494818.
- ^ a b c d Aslani, Ceren Kutahyali; Klepov, Vladislav V.; zur Loye, Hans-Conrad (July 2022). "Hydrothermal synthesis of new mixed-oxoanion materials: Rare earth iodate sulfates Sm(IO3)(SO4) and Ln2(IO3)3(SO4)OH·3H2O (Ln = Sm, Eu, Dy)". Solid State Sciences. 129: 106918. Bibcode:2022SSSci.12906918A. doi:10.1016/j.solidstatesciences.2022.106918.
- ^ a b Li, Yi-Lin; Ji, Meng-Ya; Hu, Chun-Li; Chen, Jin; Li, Bing-Xuan; Lin, Yuan; Mao, Jiang-Gao (April 2022). "Explorations of New SHG Materials in Mercury Iodate Sulfate System**". Chemistry – A European Journal. 28 (19): e202200001. doi:10.1002/chem.202200001. ISSN 0947-6539. PMID 35156759. S2CID 246813632.
- ^ a b Li, Yilin; Hu, Chunli; Chen, Jin; Mao, Jianggao (2021). "Two bismuth iodate sulfates with enhanced optical anisotropy". Dalton Transactions. 50 (44): 16139–16146. doi:10.1039/D1DT02514G. ISSN 1477-9226. PMID 34677566. S2CID 239456548.
- ^ Liu, Hongming; Wu, Qingchen; Liu, Lili; Lin, Zheshuai; Halasyamani, P. Shiv; Chen, Xingguo; Qin, Jingui (2021). "AgBi(SO 4 )(IO 3 ) 2 : aliovalent substitution induces structure dimensional upgrade and second harmonic generation enhancement". Chemical Communications. 57 (30): 3712–3715. doi:10.1039/D0CC07862J. ISSN 1359-7345. PMID 33729224. S2CID 232262974.