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Herman Pines

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Herman Pines
Born(1902-01-17)January 17, 1902
Łódź, Russian Empire
DiedApril 10, 1996(1996-04-10) (aged 94)
San Rafael, California, U.S.
Alma materÉcole Supérieure de Chimie Physique Électronique de Lyon
Known forCatalysis of high-octane fuels
Scientific career
InstitutionsUniversal Oil Products, Northwestern University

Herman Pines (January 17, 1902 – April 10, 1996) was a Russian Empire–born American chemist best known for his work with Vladimir Ipatieff on the catalytic conversion of high-octane aviation fuel (and innovation credited with helping the Royal Air Force win the Battle of Britain).[1][2] Because of his scientific contributions, new processes were developed for the isomerization of paraffins, the alkylation of aromatic compounds, and base-catalyzed organic reactions.[3][4]

Biography

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Herman Pines was born on January 17, 1902, to Isaac and Eugenia (Grynfeld) Pines, a Jewish couple in Łódź[5] (then in the Russian Empire, now Poland). Pines left Łódź as a young man, because Jewish quotas[2][6]: 119–121  and other anti-Jewish practices prevented Jewish students from attending university.[6]: 119–124 [7][8] Instead Pines went to France to study. In 1927, Pines received a degree in chemical engineering at the École Supérieure de Chimie Industrielle de Lyon (now the École Supérieure de Chimie Physique Électronique de Lyon).[9]

In 1928[10][5] Pines emigrated to the United States.[10] After working at routine jobs for a couple of years, he joined Universal Oil Products (now UOP LLC) in McCook, Illinois, in 1930. He began by doing routine analyses, and was later transferred to the research department.[5] By 1930 Pines was a doctoral student at the University of Chicago, and working at UOP.[10] There he met Russian-born Vladimir Ipatieff. Pines became his assistant, beginning a twenty-two-year scientific collaboration.[2][11] Initially, the two expatriates used French and Russian as working languages, since they spoke both of them better than English.[9]

Studying at night, Pines completed a Ph.D in organic chemistry at the University of Chicago in 1935 with the thesis A study of the electronegativities of organic radicals.[12][13] In 1941, Pines received a part-time research professorship at Northwestern University in Evanston, Illinois.[2] He continued to work for UOP,[3] serving as OUP's full-time Coordinator of Exploratory Research from 1945 to 1951.[5][12]

After the death of Ipatieff in 1952, Pines left UOP to focus on his work at Northwestern University. In 1953 he became the Ipatieff Research Professor of Chemistry and director of the Ipatieff High Pressure and Catalytic Laboratory. Pines retired from the position in 1970,[3] but continued to be scientifically active as a professor emeritus[12] until a few months before his death on April 10, 1996.[3]

Pines greatly appreciated the willingness of the United States to welcome refugees.[10]

"The U.S. is the blending place for all people. Here you are valued for who you are and what you can do, not for where you are from. Here outsiders become members of the community very quickly. People don`t understand how difficult that is elsewhere in the world, because here it is so easy. But I know."[10]

Family

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Pines married Dorothy Mlotek in 1927.[5] Together they emigrated to Chicago. She was a scholar and apassionate Zionist. They had a daughter, Judith[5] or Judy (Pines) Suessmeier.[2] Discouraged about faculty opportunities for Jews during the Depression, the three of them left Chicago to settle in Israel[clarification needed] shortly before the outbreak of World War II, but became disillusioned and soon returned to Illinois.

Pines's mother, brothers and uncle, as well as other members of his family were killed during The Holocaust.[2][10]

Work

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Pines and Ipatieff worked closely together for 22 years, until Ipatieff died and Pines succeeded him at Northwestern University.[14] A modest man who tended to emphasize the contributions of others, Pines has nonetheless been described as "one of the towering scientists of this century".[15] Throughout his career, Pines made significant contributions to the understanding of heterogeneous catalysis and the chemistry of petroleum hydrocarbons.[3][4][9]

Ipatieff encouraged each person on his staff to spend 10–15% of their time on a personal project, pleasing to their "chemical soul".[14] Early on, Pines chose to test one of the dominant doctrines of the time:[10][14] the belief that paraffin hydrocarbons or alkanes were inert substances that did not react with other substances at low temperatures.[2][14][16][17] The very name paraffin reflected this belief, coming from the Latin "parum affinis" (limited affinity).[15]

Pines was able to demonstrate that catalysis could occur at low temperatures, counter to previous belief.[14] At low temperatures, in the presence of sulfuric acid (H2SO4), isoparaffins such as isobutane reacted with olefins.[15][17][18] This alkylation process[4] was discovered in 1932 and commercialized in 1938.[19]

Ipatieff and Pines were trying to understand complex chemical reactions that were affected by many factors including temperature, concentration of acid used, and ratio of acid to other compounds.[20][21] Such reactions often resulted in the formation of a complex mixture of products, including intermediate products which could participate in further reactions.[20]

By working with pure hydrocarbons rather than petroleum fractions, Pines was better able to isolate and understand specific chemical reactions.[12] He emphasized that a reaction was not understood until all the products of the reaction were identified and understood. His student Herbert Appel later recalled being taught, "never to be satisfied with a mechanism until it explains all the products".[12]: 84 

Pines was able to understand and describe the isomerization of butanes and pentanes.[4][14] Isomerization is a rearrangement reaction, in which one molecule is transformed into another that contains the same atoms in a different arrangement.[22] Pines developed a method for the catalytic conversion of n-butane into isobutane. The first step was protonation of butene by sulfuric acid, forming a reactive but short-lived carbenium ion intermediate.[15]: 157 [14] The second step was alkylation of isobutane by the carbenium cations.[14] Butane isomerization was discovered in 1935 and commercialized in 1941.[19] Ongoing research into the chemical processes involved showed that it was impossible to achieve isomerization of paraffinic hydrocarbons without a chemical catalyst: heat alone could not be sufficient.[23] Pure n-butane would not react without a source of olefin cations.[12]

The production of isobutane was a necessary step in the production of high-octane gasoline.[14] The catalytic conversion of paraffins into isoparaffins has been described as "one of the cornerstones of the petroleum industry."[15] Combining the processes of alkylation and butane isomerization led to the development of high octane fuels for use in aviation gasoline.[24] Isobutane and C3–C4 olefins are by-products of fluid catalytic cracking and other catalytic and thermal conversion processes. During the alkylation process, light molecular weight iso-paraffins such as isobutane can be combined with C3–C4 olefins to form higher weight iso-paraffins or alkylates that do not contain olefinic or aromatic hydrocarbons.[24][25]

Hawker Hurricane Mk I, July 1940
Groundcrew refuelling a Hawker Hurricane Mk I, August 1940

These methods of preparation were kept secret by the Americans during World War II, but the fuels were made available to the Allies for their Spitfires and Hurricanes, and are said to have given the Royal Air Force an advantage in the Battle of Britain.[1][16] Another war-time accomplishment by Pines and his co-workers was the chemical analysis of the fuel of German aircraft. This enabled the Allies to target mines and other facilities that produced materials critical to the German war effort.[16] Alkylation processes have since been used to produce gasoline for motors, as engines became more powerful. Alkylation can be a preferable process for environmental reasons as well.[24]

Having established that such reactions were possible, Pines and his co-workers explored the mechanisms involved in the catalysis of hydrocarbons. They studied a variety of transformations including "polymerization, alkylation, cyclization, additions, eliminations and hydride transfer reactions."[26] They made basic discoveries that furthered the understanding of mechanisms involving carbonium ions, carbanions, free radicals, intermediates, thermal reactions, and relationships between catalytic behavior and surface chemistry.[15][27] Pines studied both acid and base catalysis; catalytic properties of aluminas; and aromatization, dehydrogenation and metal hydrogenation catalysts.[12]

He has contributed to understanding the mechanism of dehydration of alcohols on alumina as a catalyst and supporter.[4][15]: 89, 211 [28] He has also examined mechanisms of aromatization of alkanes over chromia.[4][15]: 89 [29] He has analyzed hydrogen transfer reactions involving aromatic hydrocarbons.[4][15]: 89  [30][31] His work influenced Nobel winner George Andrew Olah, who was able to chemically stabilize carbocations and further investigate their structure and activity.[15]: 157 

Pines and Ipatieff's discoveries about the catalysis of hydrocarbon reactions laid fundamental groundwork for the oil refining and chemical industries.[15]: 89  These industries use various types of catalysts to unlock the saturated hydrocarbons in natural gas and raw oil. Processes involving noble-metal, liquid- and solid-acid catalysts are essential to the production of energy and of widely-used industrial chemicals in the twentieth century.[19][32] The work of Pines, Ipatieff, Louis Schmerling, Herman S. Bloch, Vladimir Haensel and others at Universal Oil Products (UOP)'s Riverside Laboratory has been recognized by the presentation of a National Historic Chemical Landmark at the laboratory building in McCook, Illinois, on November 15, 1995.[12][33]

Pines was a founder of the Catalysis Club of Chicago.[34] Since 1999, the Catalysis Club of Chicago and Honeywell-Universal Oil Products (UOP) have given an annual award, the Herman Pines Award, to recognize exceptional research in catalysis.[34][35]

Awards

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Publications

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Pines published at least 265 scientific publications. He held 145 U.S. patents. He co-edited Advances in Catalysis for more than twenty years.[30] He wrote three books:[9]

  • Pines, Herman; Stalick, Wayne M. (1977). Base-catalyzed reactions of hydrocarbons and related compounds. New York: Academic Press. ISBN 978-0-12-557150-0.
  • Pines, H. (1981). The Chemistry of Catalytic Hydrocarbon Conversions. New York: Academic Press. ISBN 9780323155922.
  • Pines, Herman (1992). Genesis and evolution of the Ipatieff Catalytic Laboratory at Northwestern University, 1930-1970. Department of Chemistry, Northwestern University.

Papers

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Pines's papers are in the archives of Northwestern University.[30][41]

References

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  1. ^ a b "Then: Lab Discovery Powered Allied Fighters in Battle of Britain". Northwestern University. Retrieved September 12, 2018.
  2. ^ a b c d e f g Saxon, Wolfgang (April 21, 1996). "Herman Pines, 94, Chemist Who Enhanced Fuels". The New York Times. Retrieved September 12, 2018.
  3. ^ a b c d e Sachtler, Wolfgang (January 19, 2012). "Herman Pines – He revolutionized the general understanding of catalysis". North American Catalysis Society. Retrieved September 13, 2018.
  4. ^ a b c d e f g h "ACS 1983 national award winners announced: E. V. Murphree Award in Industrial & Engineering Chemistry". Chemical and Engineering News. 60 (37): 57. September 13, 1982. doi:10.1021/cen-v060n037.p044.
  5. ^ a b c d e f Seymour, Raymond B.; Fisher, Charles H. (1988). Profiles of eminent American chemists. Sydney: Litarvan Enterprises Pty. Ltd. pp. 373–374. ISBN 978-0937557051.
  6. ^ a b Heller, Celia S. (January 1, 1994). On the edge of destruction : Jews of Poland between the two World Wars. Wayne State University Press. pp. 107–124. ISBN 978-0814324943. Retrieved October 21, 2018.
  7. ^ Auerbach, Karen. "Polish Jewry Between the Wars". My Jewish Learning. Retrieved September 13, 2018.
  8. ^ Bodo, Béla. "The Role of Antisemitism in the Expulsion of non-Aryan Students, 1933-1945" (PDF). Shoah Resource Center. The International School for Holocaust Studies. Retrieved September 13, 2018.
  9. ^ a b c d Davis, Burt (2013). "The Founders and Innovators of Catalysis Science, Part 2: Herman Pines (1902–1996)" (PDF). Energeia. 24 (3): 3. Archived from the original (PDF) on September 9, 2015. Retrieved September 12, 2018.
  10. ^ a b c d e f g Mullen, William (July 15, 1990). "Unlikely hero: A Polish immigrant's high-octane role in winning the Battle of Britain". Chicago Tribune. Chicago, Ill. pp. 23–27. Retrieved September 12, 2018.
  11. ^ Pines, Herman (June 3, 1983). "Chapter 3: V. N. Ipatieff: As I Knew Him". Heterogeneous Catalysis. ACS Symposium Series. Vol. 222. American Chemical Society. pp. 23–32. doi:10.1021/bk-1983-0222.ch003. ISBN 978-0-8412-0778-3.
  12. ^ a b c d e f g h Hoffman, Norman E. (June 3, 1983). "Chapter 7 Herman Pines and Organic Heterogeneous Catalysis". Heterogeneous catalysis : selected American histories : based on a symposium sponsored by the Division of History of Chemistry, at the 183rd Meeting of the American Chemical Society, Las Vegas, Nevada, March 28 – April 2, 1982. ACS Symposium Series. Vol. 222. American Chemical Society. pp. 77–87. doi:10.1021/bk-1983-0222.ch007. ISBN 9780841210479. Among the areas he has researched are acid catalysis, base catalysis, aluminas, aromatization and dehydrogenation catalysts and metal hydrogenation catalysts.
  13. ^ Pines, Herman (1937). A Study of the Electronegativities of Organic Radicals. Chicago, Illinois: University of Chicago.
  14. ^ a b c d e f g h i Schmerling, Lewis (1975). Vladimir Nikolaevich Ipatieff 1867–1952 A Biographical Memoir (PDF). Washington, D.C.: National Academy of Sciences. Retrieved September 13, 2018.
  15. ^ a b c d e f g h i j k Zecchina, Adriano; Califano, Salvatore (February 28, 2017). The Development of Catalysis: A History of Key Processes and Personas in Catalytic Science and Technology. Hoboken, New Jersey: Wiley. pp. 83–91, 156–157, 211. ISBN 9781119181286.
  16. ^ a b c Heise, Kenan (April 13, 1996). "Herman Pines, 94, Inventor Who Gave The World High-octane Fuel". Chicago Tribune. Retrieved September 20, 2018.
  17. ^ a b Linn, Carl B.; Grosse, Aristid V. (October 1945). "Alkylation of Isoparaffins by Olefins in Presence of Hydrogen Fluoride". Industrial & Engineering Chemistry. 37 (10): 924–929. doi:10.1021/ie50430a012.
  18. ^ Ipatieff, V. N.; Grosse, Aristid V.; Pines, Herman; Komarewsky, V. I. (June 1936). "Alkylation of Paraffins with Olefins in the Presence of Aluminum Chloride". Journal of the American Chemical Society. 58 (6): 913–915. doi:10.1021/ja01297a018.
  19. ^ a b c Gembicki, Stanley A. (2000). "New solid acid based breakthrough technologies". In Corma, A.; Melo, F.V.; Mendioroz, S.; Fierro, J.L.G. (eds.). 12th International Congress on Catalysis : proceedings of the 12th ICC, Granada, Spain, July 9-14, 2000 (1st ed.). Elsevier. p. 148. ISBN 9780080528632. Retrieved September 22, 2018.
  20. ^ a b Ipatieff, V. N.; Pines, Herman (1936). "Conjunct polymerization - the influence of temperature, concentration, and quantity of sulfuric acid on polymerization of olefins". The Journal of Organic Chemistry. 1 (5): 464–489. doi:10.1021/jo01234a003.
  21. ^ Lafferty, W. L. Jr.; Stokeld, R. W. (1971). "Alkylation and Isomerization". Origin and Refining of Petroleum. Advances in Chemistry. Vol. 103. pp. 130–149. doi:10.1021/ba-1971-0103.ch007. ISBN 978-0-8412-0120-0.
  22. ^ Speight, James G. (August 31, 2018). Reaction mechanisms in environmental engineering : analysis and prediction. Butterworth-Heinemann. p. 357. ISBN 978-0128044223. Retrieved September 23, 2018.
  23. ^ Asinger, F.; Steiner, H. M. E. (March 5, 2016). Paraffins : Chemistry and Technology. Elsevier Science. pp. 695–696. ISBN 9781483146621. Retrieved September 23, 2018.
  24. ^ a b c Dutton, John A. "Alkylation". FSC 432 Petroleum Processing. Penn State. Retrieved September 22, 2018.
  25. ^ "Alkylation is an important source for octane in gasoline". U.S. Energy Information Administration. February 13, 2013. Retrieved September 22, 2018.
  26. ^ Elomari, Saleh A.; Timken, Hye-Kyung C. "US Patent Application US20100147740A1 Recovery and use of conjunct polymers from ionic liquid catalysts". Google Patents. Retrieved September 13, 2018.
  27. ^ Pines, H. (1981). The Chemistry of Catalytic Hydrocarbon Conversions. New York: Academic Press. ISBN 9780323155922.
  28. ^ Pines, Herman; Manassen, Joost (1966). The Mechanism of Dehydration of Alcohols over Alumina Catalysts. Vol. 16. pp. 49–93. doi:10.1016/S0360-0564(08)60351-X. ISBN 9780120078165. {{cite book}}: |journal= ignored (help)
  29. ^ Pines, Herman; Goetschel, Charles T. (October 1965). "Alumina: Catalyst and Support. XXIV. Discussion of the Mechanism of the Aromatization of Alkanes in the Presence of Chromia—Alumina Catalysts". The Journal of Organic Chemistry. 30 (10): 3530–3536. doi:10.1021/jo01021a058.
  30. ^ a b c d e f "Guide to the Herman Pines (1902-1996) Papers 1935/1996". UNCAP. Northwestern University Library. Retrieved September 13, 2018.
  31. ^ Pines, Herman; Stalick, Wayne M. (1977). Base-catalyzed reactions of hydrocarbons and related compounds. New York: Academic Press. ISBN 978-0-12-557150-0.
  32. ^ Sommer, J.; Jost, R. (2000). "Carbenium and carbonium ions in liquid- and solid-superacid-catalyzed activation of small alkanes" (PDF). Pure Appl. Chem. 72 (12): 2309–2318. doi:10.1351/pac200072122309. S2CID 46627813. Archived from the original (PDF) on October 22, 2018. Retrieved September 20, 2018.
  33. ^ a b "Universal Oil Products (UOP) Riverside Laboratory". Chemical Landmarks. American Chemical Society. Retrieved September 20, 2018.
  34. ^ a b "CCSS Awards". Center for Catalysis and Surface Science (CCSS). Northwestern University. Retrieved September 12, 2018.
  35. ^ McMahon, Mike M. (April 2017). "Northwestern Chemist Wins Herman Pines Award for Catalysis". Northwestern Campus News. Retrieved September 12, 2018.
  36. ^ "Ernest Guenther Award in the Chemistry of Natural Products". American Chemical Society. Retrieved September 12, 2018.
  37. ^ "Eugene J. Houdry Award in Applied Catalysis". North American Catalysis Society. Retrieved September 13, 2018.
  38. ^ "George A. Olah Award in Hydrocarbon or Petroleum Chemistry". American Chemical Society. Retrieved September 12, 2018.
  39. ^ "Chemical Pioneer Award Winners". American Institute of Chemists. Retrieved September 12, 2018.
  40. ^ "E. V. Murphree Award in Industrial and Engineering Chemistry". American Chemical Society. Retrieved September 12, 2018.
  41. ^ a b "Herman Pines (1902–1996) Papers". Archival and Manuscript Collections. Northwestern University. Retrieved September 13, 2018.
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