Deuterated DMF

Deuterated DMF
Ball and stick model of deuterated DMF	Spacefill model of deuterated DMF
Names
	IUPAC name 1-Deuterio-N,N-bis(trideuteriomethyl)formamide[citation needed]
	Other names Dimethylformamide-d7[citation needed]; N,N-Dimethylformamide-d7[citation needed]; Heptadeutero-N,N-dimethylformamide[citation needed];
Identifiers
CAS Number	4472-41-7 ;
3D model (JSmol)	Interactive image;
Abbreviations	DMF-d7[citation needed]
Beilstein Reference	1908468
ChemSpider	70601 ;
ECHA InfoCard	100.022.497
EC Number	224-745-8;
PubChem CID	78225;
UN number	2265
CompTox Dashboard (EPA)	DTXSID30196283 ;
	InChI InChI=1S/C3H7NO/c1-4(2)3-5/h3H,1-2H3/i1D3,2D3,3D Key: ZMXDDKWLCZADIW-YYWVXINBSA-N ;
	SMILES [2H]C(=O)N(C([2H])([2H])[2H])C([2H])([2H])[2H];
Properties
Chemical formula	C; 32; H; 7NO or C; 3D; 7NO
Molar mass	80.1369 g mol−1
Appearance	Colourless liquid
Density	1.03 g mL−1
Boiling point	153 °C (307 °F; 426 K)
Refractive index (nD)	1.428
Hazards
	GHS labelling:
Pictograms
Signal word	Danger
Hazard statements	H312, H319, H332, H360
Precautionary statements	P280, P305+P351+P338, P308+P313
Flash point	58 °C (136 °F; 331 K)
Explosive limits	2.2–15.2%
	Lethal dose or concentration (LD, LC):
LD50 (median dose)	2.8 g kg−1 (oral, rat); 1.5–4.72 g kg−1 (dermal, rabbit);
Related compounds
Related alkanamides	N-Methylformamide; Dimethylformamide;
Related compounds	N-Nitroso-N-methylurea; ENU;
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). verify (what is ?) Infobox references

Deuterated dimethylformamide ((CD₃)₂NCOD), also known as deuterated DMF, is an isotopologue of DMF ((CH₃)₂NCOH) in which the hydrogen atom ("H") is replaced with a deuterium isotope ("D"). Deuterated DMF is a relatively uncommon solvent used in NMR spectroscopy.^[1]^[2]

References

^ Walker, Lynn M.; Wagner, Norman J. (1996-01-01). "SANS Analysis of the Molecular Order in Poly(γ-benzyl l -glutamate)/Deuterated Dimethylformamide (PBLG/d-DMF) under Shear and during Relaxation". Macromolecules. 29 (6): 2298–2301. doi:10.1021/ma951127p. ISSN 0024-9297.
^ Kim, Ahran; Kim, Cheal (2019-05-14). "A hydrazono-quinoline-based chemosensor sensing In3+ and Zn2+via fluorescence turn-on and ClO−via color change in aqueous solution". New Journal of Chemistry. 43 (19): 7320–7328. doi:10.1039/C9NJ00899C. ISSN 1369-9261. S2CID 132588760.

This article about an organic compound is a stub. You can help Wikipedia by expanding it.

This nuclear magnetic resonance–related article is a stub. You can help Wikipedia by expanding it.

[1] Walker, Lynn M.; Wagner, Norman J. (1996-01-01). "SANS Analysis of the Molecular Order in Poly(γ-benzyl l -glutamate)/Deuterated Dimethylformamide (PBLG/d-DMF) under Shear and during Relaxation". Macromolecules. 29 (6): 2298–2301. doi:10.1021/ma951127p. ISSN 0024-9297.

[2] Kim, Ahran; Kim, Cheal (2019-05-14). "A hydrazono-quinoline-based chemosensor sensing In3+ and Zn2+via fluorescence turn-on and ClO−via color change in aqueous solution". New Journal of Chemistry. 43 (19): 7320–7328. doi:10.1039/C9NJ00899C. ISSN 1369-9261. S2CID 132588760.

[1]

[2]

v t e Deuterated NMR solvents
Deuterated acetone - (CD₃)₂C=O Deuterated benzene - C₆D₆ Deuterated chloroform - CDCl₃ Deuterated dichloromethane - CD₂Cl₂ Deuterated DMF - (CD₃)₂NCOD Deuterated DMSO - (CD₃)₂S=O Deuterated ethanol - C₂D₅OD Deuterated methanol - CD₃OD Deuterated THF - (C₄D₈)O Deuterated water - D₂O
Reference 1H and 13C chemical shifts