Molecular Dynamics in Two-Dimensional Supramolecular Systems Observed by STM
<p>Thermodynamic equilibriums between a homogeneous solution, an air–liquid interface and a solid–liquid interface.</p> "> Figure 2
<p>Four isothermal adsorption states against adsorption strength.</p> "> Figure 3
<p>Molecular motion of fullerene C<sub>60</sub> on various substrates. Adapted with permission from reference [<a href="#B18-materials-03-04252" class="html-bibr">18</a>]. Copyright 2004 American Chemical Society.</p> "> Figure 4
<p><span class="html-italic">In situ</span> STM images and corresponding models of the self-ordering process of TMPyP on I/Au(111) captured at each step of adsorption and ordering. Adapted with permission from reference [<a href="#B12-materials-03-04252" class="html-bibr">12</a>]. Copyright 1995 American Chemical Society.</p> "> Figure 5
<p>Sequential STM images (A-C) of a phenylene ethynylene derivative (D) at the solution–HOPG interface. Reproduced with permission from reference [<a href="#B25-materials-03-04252" class="html-bibr">25</a>]. Copyright Wiley-VCH Verlag GmbH & Co. KGaA.</p> "> Figure 6
<p><span class="html-italic">In-situ</span> STM images and a schematic illustration of CyDs at the aqueous solution–Au(111) interface controlled by electrochemical potential. Reprinted with permission from reference [<a href="#B32-materials-03-04252" class="html-bibr">32</a>]. Copyright 2003 American Chemical Society.</p> "> Figure 7
<p>Chemical structure (A), STM images (B and D) and schematic illustrations (C and E) of TMA order-order transitions at the aqueous solution–Au(111) interface under the electrochemical control. Reproduced from reference [<a href="#B33-materials-03-04252" class="html-bibr">33</a>] by permission of The Royal Society of Chemistry.</p> "> Figure 8
<p>STM image and tentative model of coronene and iodine co-adsorption at the aqueous solution–Au(111) interface under the electrochemical potential control. Reproduced from reference [<a href="#B40-materials-03-04252" class="html-bibr">40</a>] by permission ECS―The Electrochemical Society.</p> "> Figure 9
<p>Dynamic processes during co-adsorption of perfluorinated and non-fluorinated isophthalic acid derivatives on HOPG. Reproduced with permission from reference [<a href="#B41-materials-03-04252" class="html-bibr">41</a>]. Copyright Wiley-VCH Verlag GmbH & Co. KGaA.</p> "> Figure 10
<p>Dynamic processes of a hexapod molecule at the solution–HOPG interface. Reprinted with permission from reference [<a href="#B43-materials-03-04252" class="html-bibr">43</a>]. Copyright 2009 American Chemical Society.</p> "> Figure 11
<p>STM images (A and B) and tentative models (C and D) of self-assembled structures of guanines. Without (A and C) and with (B and D) potassium. Reproduced with permission from reference [<a href="#B45-materials-03-04252" class="html-bibr">45</a>]. Copyright Wiley-VCH Verlag GmbH & Co. KGaA.</p> "> Figure 12
<p>STM images of fullerene C<sub>60</sub> adlayers on Au(111). (A) The adlayers were prepared by the transfer of L films. STM observation was in aqueous electrolyte solution at room temperature. (B) The adlayers were prepared by the sublimation. STM was conducted in UHV at 4.5 K. The observation at room temperature is shown as the inset. Reprinted with permission from reference [<a href="#B58-materials-03-04252" class="html-bibr">58</a>]. Copyright Springer.</p> "> Figure 13
<p>UHV-STM images (A-D) and tentative models (E and F) of propeller-shaped hexa-<span class="html-italic">tert</span>-butyl decacyclene on Cu(100) at room temperature. Reproduced from reference [<a href="#B63-materials-03-04252" class="html-bibr">63</a>] by permission of the American Association for the Advancement of Science.</p> "> Figure 14
<p>Sequential STM images (A, C-I) and the schematic illustration (B) of a porphyrin derivative on Cu(111) at different temperatures. Reproduced with permission from reference [<a href="#B64-materials-03-04252" class="html-bibr">64</a>]. Copyright Wiley-VCH Verlag GmbH & Co. KGaA.</p> "> Figure 15
<p>STM images of double-decker complexes at the solution–HOPG interface. Reprinted with permission from reference [<a href="#B74-materials-03-04252" class="html-bibr">74</a>]. Copyright 2009 American Chemical Society.</p> ">
Abstract
:1. Introduction
2. Thermodynamic Equilibrium for Molecules on a Substrate
3. Relation between Molecular Motion and Adsorption Strength
4. Dynamics of 2D Supramolecular Structures
4.1. Self-ordering Processes Induced by Adsorption from Solution [12,23]
4.2. Ostwald Ripening
4.3. Two-Dimensional Phase Transition
4.3.1. Single-molecular species
4.3.2. Competitive physisorption dynamics
4.4. Conformational Changes
5. Molecular Rotations in Arrays
5. Conclusions
References and Notes
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Uemura, S.; Tanoue, R.; Yilmaz, N.; Ohira, A.; Kunitake, M. Molecular Dynamics in Two-Dimensional Supramolecular Systems Observed by STM. Materials 2010, 3, 4252-4276. https://doi.org/10.3390/ma3084252
Uemura S, Tanoue R, Yilmaz N, Ohira A, Kunitake M. Molecular Dynamics in Two-Dimensional Supramolecular Systems Observed by STM. Materials. 2010; 3(8):4252-4276. https://doi.org/10.3390/ma3084252
Chicago/Turabian StyleUemura, Shinobu, Ryota Tanoue, Neval Yilmaz, Akihiro Ohira, and Masashi Kunitake. 2010. "Molecular Dynamics in Two-Dimensional Supramolecular Systems Observed by STM" Materials 3, no. 8: 4252-4276. https://doi.org/10.3390/ma3084252