Fabrication and Characterization of Polysaccharide Ion Gels with Ionic Liquids and Their Further Conversion into Value-Added Sustainable Materials
"> Figure 1
<p>Structures of cellulose, chitin, and starch.</p> "> Figure 2
<p>Structures of hydrocolloid polysaccharides, which are used in the fabrication of ion gels.</p> "> Figure 3
<p>Schematic diagram for procedures of fabrication of polysaccharide ion gels with IL and conversion into value-added sustainable materials.</p> "> Figure 4
<p>Procedure for fabrication of cellulose ion gel with 1-butyl-3-methylimidazolium chloride (BMIMCl).</p> "> Figure 5
<p>Plausible mechanism for formation of cellulose ion gel.</p> "> Figure 6
<p>Stress-strain curves of regenerated cellulose materials obtained from cellulose ion gels by Soxhlet extraction with ethanol for 0.5 h (<b>a</b>); 1 h (<b>b</b>); and 4 h (<b>c</b>) (tensile mode).</p> "> Figure 7
<p>Dissolution (<b>a</b>) and gelation (<b>b</b>) of chitin with 1-allyl-3-methylimidazolium bromide (AMIMBr).</p> "> Figure 8
<p>Procedures for fabrication of self-assembled chitin nanofiber dispersion and film, and their SEM images.</p> "> Figure 9
<p>Physical and chemical approaches for fabrication of composite materials of chitin with another polymeric component.</p> "> Figure 10
<p>Procedure for fabrication of anionic polysaccharide ion gels with BMIMCl.</p> "> Figure 11
<p>Plausible associate structure of xanthan gum and BMIMCl in ion gel.</p> "> Figure 12
<p>Procedure for fabrication of galactomannan ion gels with BMIMCl.</p> "> Figure 13
<p>Viscoelastic measurement results on BMIMCl solution of a standard pullulan (MW = 4.04 × 10<sup>5</sup>, MWD =1.13). <span class="html-italic">G</span>', <span class="html-italic">G</span>", and ω are storage modulus, loss modulus and angular frequency, respectively. <span class="html-italic">C</span> = 4.0 × 10<sup>−2</sup> (g/cm<sup>3</sup>), <span class="html-italic">T</span> = 25 °C. The broken lines show fitting curves by the revised Rouse model.</p> "> Figure 14
<p>Procedure for fabrication of binary ion gels with BMIMCl.</p> "> Figure 15
<p>Procedure for fabrication of cellulose/chitin binary ion gel with ILs, BMIMCl and AMIMBr.</p> ">
Abstract
:1. Introduction
2. Cellulose Ion Gels
3. Chitin Ion Gels
4. Hydrocolloid Polysaccharide Ion Gels
5. Binary Polysaccharide Ion Gels Containing Cellulose
6. Conclusions
Acknowledgments
Author Contributions
Conflicts of Interest
References
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Takada, A.; Kadokawa, J.-i. Fabrication and Characterization of Polysaccharide Ion Gels with Ionic Liquids and Their Further Conversion into Value-Added Sustainable Materials. Biomolecules 2015, 5, 244-262. https://doi.org/10.3390/biom5010244
Takada A, Kadokawa J-i. Fabrication and Characterization of Polysaccharide Ion Gels with Ionic Liquids and Their Further Conversion into Value-Added Sustainable Materials. Biomolecules. 2015; 5(1):244-262. https://doi.org/10.3390/biom5010244
Chicago/Turabian StyleTakada, Akihiko, and Jun-ichi Kadokawa. 2015. "Fabrication and Characterization of Polysaccharide Ion Gels with Ionic Liquids and Their Further Conversion into Value-Added Sustainable Materials" Biomolecules 5, no. 1: 244-262. https://doi.org/10.3390/biom5010244