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Degradation of groundwater quality in coastal aquifer of Sabratah area, NW Libya

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Abstract

Overextraction of groundwater is widely occurring along the coast where good quality groundwater is at risk, due to urbanization, tourist development and intensive agriculture. The Sabratah area at the northern central part of Jifarah Plain, Northwest Libya, is a typical area where the contamination of the aquifer in the form of saltwater intrusion, gypsum/anhydrite dissolution and high nitrate concentrations is very developed. Fifty groundwater samples were collected from the study area and analysed for certain parameters that indicate salinization and pollution of the aquifer. The results demonstrate high values of the parameters electrical conductivity, sodium, potassium, magnesium, chloride and sulphate which can be attributed to seawater intrusion. The intensive extraction of groundwater from the aquifer reduces freshwater outflow to the sea, creates drawdown cones and lowering of the water table to as much as 30 m below mean sea level. Irrigation with nitrogen fertilizers and domestic sewage and movement of contaminants in areas of high hydraulic gradients within the drawdown cones probably are responsible for the high nitrate concentration towards the south of the region. Seawater intrusion and deep salt water upconing result in general high SO4 2− concentrations in groundwater near the shoreline, where localized SO4 2− anomalies are also due to the dissolution of sebkha deposits for few wells in the nearby sebkhas. Upstream, the increase in SO4 2− concentrations in the south is ascribed to the dissolution of gypsum at depth in the upper aquifer.

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References

  • Alfarrah N (2011) Hydrogeological and hydrogeochemical investigation of the coastal area of Jifarah Plain, NW Libya. PhD thesis, Laboratory of Applied Geology and Hydrogeology, Ghent University, Belgium

  • Alfarrah N, Martens K, Walraevens K (2011) Hydrochemistry of the Upper Miocene–Pliocene–Quaternary aquifer complex of Jifarah plain, NW-Libya. Geol Belg 14(3–4):159–174

    Google Scholar 

  • Alfarrah N, Van Camp M, Walraevens K (2013) Deducing transmissivity from specific capacity in the heterogeneous upper aquifer system of Jifarah Plain, NW-Libya. J Afr Earth Sc 85:12–21

    Article  Google Scholar 

  • Andersen MS, Nyvang V, Jakobsen R, Postma D (2005) Geochemical processes and solute transport at the seawater/freshwater interface of a sandy aquifer. Geochim Cosmochim Acta 69(16):3979–3994

    Article  Google Scholar 

  • APHA (American Public Health Association) (1985) In: Greenberg AE, Trussell RR, Clesceri LS (eds) Standard methods for the examination of water and wastewater. APHA, Washington, DC

  • Appelo CAJ (1994) Cation and proton exchange, pH variations, and carbonate reactions in a freshening aquifer. Water Resour Res 30:2793–2805

    Article  Google Scholar 

  • Appelo CAJ, Postma D (1993) Geochemistry, groundwater and pollution. A. A. Balkema, Rotterdam

    Google Scholar 

  • Appelo CAJ, Postma D (2005) Geochemistry, groundwater and pollution, 2nd edn. A.A. Balkema, Leiden, The Netherlands, p 649

    Book  Google Scholar 

  • Ben-Asher J, Beltrao J, Costa M (2000) Modelling the effect of seawater intrusion on ground water salinity in agricultural areas in Israel, Portugal, Spain and Turkey. In: International symposium on techniques to control salination for horticultural productivity, Antalya, Turkey

  • Camur MZ, Yazicigil H (2005) Effects of the planned Ephesus recreational canal on freshwater-seawater interface in the Selcuk sub-basin, Izmir. Environ Geol 48:229–237

    Article  Google Scholar 

  • Chaouni Alia A, Halimi NEL, Walraevens K, Beeuwsaert E, De Breuck W (1997) Investigation de la salinisation de la plaine de Bou-Areg (Maroc nord-oriental). In: Proceedings of reports international association of hydrological sciences. Freshwater Contamination, vol 243, pp 211–220

  • Coetsiers M, Walraevens K (2006) Chemical characterization of the Neogene Aquifer, Belgium. Hydrogeol J 14:1556–1568

    Article  Google Scholar 

  • Coetsiers M, Walraevens K (2009) A new correction model for 14C ages in aquifers with complex geochemistry—application to the Neogene Aquifer, Belgium. Appl Geochem 24:768–776

    Article  Google Scholar 

  • Coetsiers M, Blaser P, Martens K, Walraevens K (2009) Natural background levels and threshold values for groundwater in fluvial Pleistocene and Tertiary marine aquifers in Flanders, Belgium. Environ Geol 57:1155–1168

    Article  Google Scholar 

  • Custodio E (2010) Coastal aquifers of Europe: an overview. Hydrogeol J 18:269–280

    Article  Google Scholar 

  • Custodio E, Bruggeman GA (1987) Groundwater problems in coastal areas. UNESCO-IHP, Studies and Reports in Hydrology, vol 45. París, pp 1–576

  • Da’as A, Walraevens K (2010) Groundwater salinity in Jericho Area, West Bank, Palestine. In: Proceedings of SWIM-21 salt water intrusion meeting, Ponta Delgada, San Miguel, Azores, Portugal, pp 28–31

  • Da’as A, Walraevens K (2013) Hydrogeochemical investigation of groundwater in Jericho area in the Jordan Valley, West Bank, Palestine. J Afr Earth Sc 82:15–32

    Article  Google Scholar 

  • De Montety V, Radakovitch O, Vallet-Coulomb C, Blavoux B, Hermitte D, Valles V (2008) Origin of groundwater salinity and hydrochemical processes in a confined coastal aquifer: case of the Rhône delta (Southern France). Appl Geochem 23:2337–2349

    Article  Google Scholar 

  • Demirel Z (2004) The history and evaluation of saltwater intrusion into a coastal aquifer in Mersin, Turkey. J Environ Manag 70(3):275–282

    Article  Google Scholar 

  • Edmunds WM, Milne CJ (eds) (2001) Palaeowaters in coastal Europe: evolution of groundwater since the late Pleistocene. Geological Society of London, Special publication

  • GiméNez E, Morell I (1997) Hydrogeochemical analysis of salinization processes in the coastal aquifer of Oropesa (Castellon, Spain). Environ Geol 29:118–131

    Article  Google Scholar 

  • Gordu F, Yurtal R, Motz LH (2001) Optimization of groundwater use in the Goksu delta at Silifke. In: First international conference on saltwater intrusion and coastal aquifers monitoring, modeling, and management (SWICA-M3), Essaouira, Morocco, Turkey, pp 1–10

  • Grimaldi S, Angeluccetti I, Coviello V, Vezza P (2015) Cost-effectiveness of soil and water conservation measures on the catchment sediment budget—the Laaba watershed case study, Burkina Faso. Land Degrad Dev 26(7):737–747

    Article  Google Scholar 

  • Jones BF, Vengosh A, Rosenthal E, Yechieli Y (1999) Geochemical investigation of groundwater quality. In: Seawater intrusion in coastal aquifers-concepts, methods and practices. Kluwer, The Netherlands, pp 51–71

    Chapter  Google Scholar 

  • Karahanoglu N, Doyuran V (2003) Finite element simulation of seawater intrusion into a quarry-site coastal aquifer, Kocaeli-Darica, Turkey. Environ Geol 44(4):456–466

    Article  Google Scholar 

  • Kassa Teka B, Van Rompaey A, Poesen J, Van Bruyssel S, Deckers J, Amare Kassa (2015) Spatial analysis of land cover changes in Eastern Tigray (Ethiopia) from 1965 to 2007: are there signs of a forest transition. Land Degrad Dev 26(7):680–689

    Article  Google Scholar 

  • LIRC (Libyan Industrial Research Centre) (1995) Geological map of Jifarah Plain, 2nd edn. LIRC, Tajura

    Google Scholar 

  • Lyles JR (2000) Is seawater intrusion affecting ground water on Lopez Island, Washington. USGS Numbered Series, U.S. Geological Survey. Fact sheet FS-057-00

  • Masciopinto C (2006) Simulation of coastal groundwater remediation: the case of Nardò fractured aquifer in Southern Italy. Environ Model Softw 21:85–97

    Article  Google Scholar 

  • Mjemah IC, Van Camp M, Walraevens K (2009) Groundwater exploitation and hydraulic parameter estimation for a Quaternary aquifer in Dar-es-Salaam, Tanzania. J Afr Earth Sci 55(3–4):134–146

    Article  Google Scholar 

  • Mjemah IC, Van Camp M, Martens K, Walraevens K (2011) Groundwater exploitation and recharge rate estimation of quaternary sand aquifer in Dar-es-Salaam area, Tanzania. Environ Earth Sci 63:559–569

    Article  Google Scholar 

  • Mollema PN (2016) Water and chemical budgets of gravel pit lakes: Case studies of fluvial gravel pit lakes along the Meuse River (the Netherlands) and coastal gravel pit lakes along the Adriatric Sea (Ravenna, Italy). PhD thesis, Technische Universiteit Delft

  • Mollema PN, Antonellini M, Dinelli E, Gabbianelli G, Greggio N, Stuyfzand PJ (2013) Hydrochemical and physical processes influencing salinization and freshening in Mediterranean low-lying coastal environments. Appl Geochem 34:207–221

    Article  Google Scholar 

  • Mollema PN, Antonellini M, Stuyfzand PJ, Juhasz-Holterman MHA, Van Diepenbeek PMJA (2015) Metal accumulation in an artificially recharged gravel pit lake used for drinking water supply. J Geochem Explor 150:35–51

    Article  Google Scholar 

  • Morell I, Gimenez E, Esteller MV (1996) Application of principal components analysis to the study of salinization on the Castellon plain, Spain. Sci Total Environ 177:161–171

    Article  Google Scholar 

  • Mtoni YE, Mjemah IC, Msindai K, Van Camp M, Walraevens K (2012) Saltwater intrusion in the Quaternary aquifer of the Dar es Salaam region, Tanzania. Geol Belg 15(1–2):16–25

    Google Scholar 

  • Mtoni YE, Mjemah IC, Bakundukize C, Van Camp M, Walraevens K (2013) Saltwater intrusion and nitrate pollution in the coastal aquifer of Dar es Salaam, Tanzania. Environ Earth Sci 70(3):1091–1111

    Article  Google Scholar 

  • Parkhurst DL, Appelo CAJ (1999) User’s guide to PHREEQC (version 2)—a computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations. U.S. Geological Survey water-resources investigations report 99-4259

  • Pulido-Leboeuf P (2004) Seawater intrusion and associated processes in a small coastal complex aquifer (Castell de Ferro, Spain). Appl Geochem 19:1517–1527

    Article  Google Scholar 

  • Radfar M, Van Camp M, Walraevens K (2013) Drought impacts on long-term hydrodynamic behavior of groundwater in the Tertiary-Quaternary aquifer system of Shahrekord Plain, Iran. Environ Earth Sci 70(2):927–942

    Article  Google Scholar 

  • Stuyfzand PJ (1986) A new hydrogeochemical classification of water types: principles and application to the coastal dunes aquifer system of the Netherlands. In: Proceedings 9th SWIM, Delft (The Netherlands), pp 641–656

  • Stuyfzand PJ (1993) Hydrochemistry and hydrology of the coastal dune area of the Western Netherlands. PhD dissertation, Free University (VU), Amsterdam 90-74741-01-0

  • Stuyfzand PJ (1999) Patterns in groundwater chemistry resulting from groundwater flow. Hydrogeol J 7:15–27

    Article  Google Scholar 

  • Sukhija BS, Varma VN, Nagabhushanam P, Reddy DV (1996) Differentiation of paleomarine and modern intruded salinities in coastal groundwaters (of Karaikal and Tanjavur, India) based on inorganic chemistry, organic biomarker fingerprints and radiocarbon dating. J Hydrol 174:173–201

    Article  Google Scholar 

  • Trabelsi R, Zairi M, Dhia HB (2007) Groundwater salinization of the Sfax superficial aquifer, Tunisia. Hydrogeol J 15:1341–1355

    Article  Google Scholar 

  • Van Camp M, Walraevens K (2009) Recovery scenarios for deep over-exploited aquifers with limited recharge: methodology and application to an aquifer in Belgium. Environ Geol 56(8):1505–1516

    Article  Google Scholar 

  • Van Camp M, Radfar M, Walraevens K (2010) Assessment of groundwater storage depletion by overexploitation using simple indicators in an irrigated closed aquifer basin in Iran. Agric Water Manag 97(11):1876–1886

    Article  Google Scholar 

  • Van Camp M, Radfar M, Martens K, Walraevens K (2012) Analysis of the groundwater resource decline in an intramountain aquifer system in Central Iran. Geol Belg 15(3):176–180

    Google Scholar 

  • Van Camp M, Mjemah IC, Alfarrah N, Walraevens K (2013) Modeling approaches and strategies for data-scarce aquifers: example of the Dar es Salaam aquifer in Tanzania. Hydrogeol J 21:341–356

    Article  Google Scholar 

  • Van Camp M, Mtoni YE, Mjemah IC, Bakundukize C, Walraevens K (2014) Investigating seawater intrusion due to groundwater pumping with schematic model simulations: the example of the Dar Es Salaam coastal aquifer in Tanzania. J Afr Earth Sc 96:71–78

    Article  Google Scholar 

  • Walraevens K, Van Camp M (2005) Advances in understanding natural groundwater quality controls in coastal aquifers, 18 SWIM. Cartagena 2004, Spain, pp 451–460

  • Walraevens K, Boughriba M, De Breuck W (1993a) Groundwater quality evolution in the Black-Sluice Polder area around Assenede (Belgium). In: Custodio E, Galofre A (eds) Study and modelling of saltwater intrusion into aquifers. Centro Internacional de Métodos Numéricos en Ingenieria, Barcelona, pp 121–142

    Google Scholar 

  • Walraevens K, Lebbe L, Van Camp M, Angius G, Serra M, Vacca A, Massidda R, De Breuck W (1993b) Study and modelling of saltwater intrusion into aquifers. In: Proceedings 12th saltwater intrusion meeting, Barcelona, November 1992, pp 407–420

  • Walraevens K, Lebbe L, De Ceukelaire M, Van Houtte E, De Breuck W, Marras F (1994) Influence on groundwater quality of the Paleozoic Brabant Massif in Belgium due to overexploitation. IAHS Publ Groundw Qual Manag 220:461–470

    Google Scholar 

  • Walraevens K, Cardenal-Escarcena J, Van Camp M (2007) Reaction transport modelling of a freshening aquifer (Tertiary Ledo-Paniselian Aquifer, Flanders Belgium). Appl Geochem 22:289–305

    Article  Google Scholar 

  • Walraevens K, Mjemah IC, Mtoni Y, Van Camp M (2013) Sources of salinity and urban pollution in the Quaternary sand aquifers of Dar es Salaam, Tanzania. J Afr Earth Sci 102:149–165

    Article  Google Scholar 

  • Walraevens K, Gebreyohannes T, Amare K, Hussein A, Berhane G, Baert R, Ronsse S, Kebede S, Van Hulle L, Deckers J, Martens K, Van Camp M (2015) Water balance components for sustainability assessment of groundwater dependent agriculture: example of the Mendae Plain (Tigray, Ethiopia). Land Degrad Dev 26(7):725–736

    Article  Google Scholar 

  • Wang C et al (2014) Assessment of river water quality based on theory of variable fuzzy sets and fuzzy binary comparison method. Water Resour Manag 28(12):4183–4200

    Article  Google Scholar 

  • Wang C, Yang Y, Zhang Y (2016) Cost-effective targeting soil and water conservation: a case study of Changting County in Southeast China. Land Degrad Dev 27(2):387–394

    Article  Google Scholar 

  • Werner AD, Ward JD, Morgan LK, Simmons CT, Robinson NI, Teubner MD (2012) Vulnerability indicators of sea water intrusion. Ground Water 50:48–58

    Article  Google Scholar 

  • WHO (2008) Guidelines for drinking-water quality (electronic resource): incorporating 1st and 2nd addenda, vol 1, recommendations, 3rd edn. WHO Library Cataloguing-in-Publication Data, p 668

  • Wildemeersch JCJ, Garba M, Sabiou M, Sleutel S, Cornelis W (2015) The effect of water and soil conservation (WSC) on the soil chemical, biological, and physical quality of a Plinthosol in Niger. Land Degrad Dev 26(7):773–783

    Article  Google Scholar 

  • Wu WY, Dandy GC, Maier HR (2013) Protocol for developing ANN models and its application to the assessment of the quality of the ANN model development process in drinking water quality modeling. Environ Modell Softw 54:108–127. doi:10.1016/j.envsoft.2013.12.016

    Article  Google Scholar 

  • Yazicigil H, Ekmekci M (2003) Perspectives on Turkish ground water resources. Ground Water 41(3):290–291

    Article  Google Scholar 

  • Zouhri L, Carlier E, Ben Kabbour B, Toto EA, Gorini C (2008) Groundwater interaction in the coastal environment: hydrochemical, electrical and seismic approaches. Bull Eng Geol Environ 67:123–128

    Article  Google Scholar 

Download references

Acknowledgements

This study was supported by the Libyan government through the Libyan Embassy in Brussels. Thanks to all who supported in the field campaigns.

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Alfarrah, N., Berhane, G., Bakundukize, C. et al. Degradation of groundwater quality in coastal aquifer of Sabratah area, NW Libya. Environ Earth Sci 76, 664 (2017). https://doi.org/10.1007/s12665-017-6999-5

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