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Study on Formation Mechanism of Fayalite (Fe2SiO4) by Solid State Reaction in Sintering Process

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Abstract

The sintering behaviors among SiO2, FeS and Fe3O4 were detected to reveal the formation mechanism of Fe2SiO4. The results indicated that the formation mechanism is divided into five steps: (1) migration of O2− induced by S2− under a reducing atmosphere; (2) formation of Fe3O4−β ; (3) migration of Fe(II) into a ferrite cluster structure to gain oxygen and form Fe3−x O4; (4) Fe(II) invaded the silicon atomic position and released Si(IV); and (5) formation of the stable structure of Fe2SiO4 through chemical diffusion between cations of Fe(II) and Si(IV). These findings can provide theoretical support for controlling the process of the recovery of valuable metals in copper slag through the combined roasting modification–magnetic separation process.

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References

  1. Z. Zhao, L. Chai, B. Peng, Y. Liang, Y. He, and Z. Yan, J. Non-Cryst. Solids 466, 21 (2017).

    Article  Google Scholar 

  2. Z. Fu, F. Wu, L. Chen, B. Xu, C. Feng, Y. Bai, H. Liao, S. Sun, J.P. Giesy, and W. Guo, Environ. Pollut. 219, 1069 (2016).

    Article  Google Scholar 

  3. Z. Guo, D. Zhu, J. Pan, and F. Zhang, JOM 68, 9 (2016).

    Article  Google Scholar 

  4. C. Shi, C. Meyer, and A. Behnood, Resour. Conserv. Recy. 52, 1115 (2008).

    Article  Google Scholar 

  5. M. Díaz and F. Mijangos, JOM 39, 42 (1987).

    Article  Google Scholar 

  6. A. Chen, Z. Peng, J.H. Wang, Y. Ma, X. Liu, and X. Chen, JOM 67, 493 (2015).

    Article  Google Scholar 

  7. Z. Guo, D. Zhu, J. Pan, and F. Zhang, JOM 68, 2341 (2016).

    Article  Google Scholar 

  8. S.A.T. Redfern, G. Artioli, R. Rinaldi, C.M.B. Henderson, and K.S. Knight, Phys. Chem. Miner. 27, 630 (2000).

    Article  Google Scholar 

  9. V.E. Hamilton, Chem. Erde-Geochem. 70, 7 (2010).

    Article  Google Scholar 

  10. D. Daval, D. Testemale, N. Recham, J.M. Tarascon, J. Siebert, I. Martinez, and F. Guyot, Chem. Geol. 275, 161 (2010).

    Article  Google Scholar 

  11. X. Min, B. Zhou, Y. Ke, and L. Chai, Appl. Surf. Sci. 371, 67 (2016).

    Article  Google Scholar 

  12. S.J. Groves, J. Williamson, and A. Sanyal, Fuel 66, 461 (1987).

    Article  Google Scholar 

  13. S.M. Taimoory and J.F. John, Surf. Sci. 15, 31 (2017).

    Google Scholar 

  14. S. Bera, A.A.M. Prince, S. Velmurugan, and P.S. Raghavan, J. Mater. Sci. 36, 5379 (2001).

    Article  Google Scholar 

  15. L. Liang, Y. Cao, H. Liu, and A.C.S. Appl, Mater. Inter. 4, 5673 (2012).

    Article  Google Scholar 

  16. K. Wandelt, Surf. Sci. Rep. 2, 1 (1982).

    Article  Google Scholar 

  17. Y. Liang, X. Min, L. Chai, M. Wang, W. Liyang, and Q. Pan, Chemosphere 168, 1142 (2017).

    Article  Google Scholar 

  18. B. Peng, N. Peng, X. Min, and H. Liu, JOM 67, 1988 (2015).

    Article  Google Scholar 

  19. Z. Zhao, Y. Song, X. Min, Y. Liang, L. Chai, and M. Shi, J. Non-Cryst. Solids 452, 238 (2016).

    Article  Google Scholar 

  20. Afshin Ghanbari-Siahkali and Susanta Mitra, Polym. Degrad. Stabil. 90, 471 (2005).

    Article  Google Scholar 

Download references

Acknowledgements

The authors gratefully acknowledge financial support from the key project of National Natural Science Foundation of China (51634010 and 51574295), Special Program on Environmental Protection for Public Welfare (201509050). Grants from the Project of Innovation-driven Plan in Central South University (No. 2015CX001).

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Authors and Affiliations

  1. School of Metallurgy and Environment, Central South University, Changsha, 410083, Hunan, China

    Zhongbing Wang, Bing Peng, Lifeng Zhang, Zongwen Zhao, Degang Liu, Ning Peng, Dawei Wang, Yanjie Liang & Hui Liu

  2. Chinese National Engineering Research Center for Control and Treatment of Heavy Metal Pollution, Changsha, 410083, Hunan, China

    Bing Peng, Yanjie Liang & Hui Liu

  3. School of Engineering, James Cook University, Townsville, QLD, 4811, Australia

    Yinghe He

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  1. Zhongbing Wang
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Correspondence to Yanjie Liang or Hui Liu.

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Wang, Z., Peng, B., Zhang, L. et al. Study on Formation Mechanism of Fayalite (Fe2SiO4) by Solid State Reaction in Sintering Process. JOM 70, 539–546 (2018). https://doi.org/10.1007/s11837-017-2699-6

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  • DOI: https://doi.org/10.1007/s11837-017-2699-6

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