Abstract
Dye wastewater is one of the most harmful wastewater types generated during industrial processes. Effectively treating dye wastewater is essential. This study used TiO2 and cornstalk biochar to prepare biochar-TiO2 composites in order to treat methyl orange (MO) in the water. It is found that composites prepared using biochar generated at 700 ℃ and TiO2/biochar mass ratio values of 0.75/1 showed the best performance on decolorization efficiency and mineralization efficiency of MO while low pH, low initial MO concentration, and 1 g/L of composite amount added can enhance MO degradation efficiency. Additionally, it is also noted that biochar-TiO2 composites were easier to separate from water compared to pure TiO2. This benefits the recycling of biochar-TiO2 composites after application. Furthermore, the study indicated that the biochar-TiO2 composites degrade MO by a combination of adsorption and photocatalysis while photoelectron (e−) and ·O2− are the key species participating in photocatalytic degradation of MO. These research outcomes suggest that cornstalk biochar and TiO2 can be used to prepare composites, which can be seen as an alternative photocatalyst for dye wastewater treatment. However, further investigations related to their long-term applications and in real scale projects are recommended.
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References
Abdelhay A, Jum’h I, Albsoul A, Arideh DA, Qatanani B (2021) Performance of electrochemical oxidation over BDD anode for the treatment of different industrial dye-containing wastewater effluents. Water Reuse 11(1):110–121
Afzal MZ, Zu P, Zhang CM, Guan J, Song C, Sun XF, Wang SG (2022) Sonocatalytic degradation of ciprofloxacin using hydrogel beads of TiO2 incorporated biochar and chitosan. J Hazard Mater 434:128879
Al-Tohamy R, Ali SS, Li FH, Okasha KM, Mahmoud YAG, Elsamahy T, Jiao HX, Fu YY, Sun JZ (2022) A critical review on the treatment of dye-containing wastewater: ecotoxicological and health concerns of textile dyes and possible remediation approaches for environmental safety. Ecotoxicol Environ Saf 231:113160
Chairungsri W, Subkomkaew A, Kijjanapanich P, Chimupala Y (2022) Direct dye wastewater photocatalysis using immobilized titanium dioxide on fixed substrate. Chemophere 286:131762
Chaturvedi A, Rai BN, Singh RS, Jaiswal RP (2021) Comparative toxicity assessment using plant and luminescent bacterial assays after anaerobic treatments of dyeing wastewater in a recirculating fixed bed bioreactor. J Environ Chem Eng 9(4):105466
Chiu YH, Chang TFM, Chen CY, Sone M, Hsu YJ (2019). Mechanistic insights into photodegradation of organic dyes using heterostructure photocatalysts. Catalysts 9(5). https://doi.org/10.3390/catal9050430
Dihom HR, Al-Shaibani MM, Mohamed RMSR, Al-Gheethi AA, Sharma A, Khamidun MHB (2022) Photocatalytic degradation of disperse azo dyes in textile wastewater using green zinc oxide nanoparticles synthesized in plant extract: a critical review. J Water Process Eng 47:102705
Farimah I, Nurillahi R, Sahroni I, Muraza O (2019) TiO2-pillared saponite and photosensitization using a ruthenium complex for photocatalytic enhancement of the photodegradation of bromophenol blue. Appl Clay Sci 183:105302
Guo DW, Feng DD, Zhang YL, Zhang ZJ, Wu JB, Zhao YJ, Sun SZ (2022) Synergistic mechanism of biochar-nano TiO2 adsorption-photocatalytic oxidation of toluene. Fuel Process Technol 229:107200
Guo SS, Liu XM, Zhao H, Wang L, Tang JC (2021) High pyrolysis temperature biochar reduced the transport of petroleum degradation bacteria Corynebacterium variabile HRJ4 in porous media. J Environ Sci 100:228–239
Hong N, Cheng Q, Goonetilleke A, Bandala ER, Liu A (2020) Assessing the effect of surface hydrophobicity/hydrophilicity on pollutant leaching potential of biochar in water treatment. Journal of Industry and Engineering Chemistry 89:222–232
Hou RJ, Gao Y, Zhu HJ, Yang GX, Liu WH, Huo YN, Xie ZL, Li HX (2017) Coupling system of Ag/BiOBr photocatalysis and direct contact membrane distillation for complete purification of N-containing dye wastewater. Chem Eng J 317:386–393
Kormann C, Bahnemann DW, Hoffmann MR (1991) Photolysis of chloroform and other organic molecules in aqueous TiO2 suspensions. Environ Sci Technol 25(3):494–500
Kumar MS, Sonawane SH, Bhanvase BA, Bethi B (2018) Treatment of ternary dye wastewater by hydrodynamic cavitation combined with other advanced oxidation processes (AOP’s). J Water Process Eng 23:250–256
Liu H, Deng L, Sun C, Li J, Zhu Z (2015) Titanium dioxide encapsulation of supported Ag nanoparticles on the porous silica bead for increased photocatalytic activity. Appl Surf Sci 326:82–90
Liu LM, Chen Z, Zhang JW, Shan D, Wu Y, Bai LM, Wang BQ (2021) Treatment of industrial dye wastewater and pharmaceutical residue wastewater by advanced oxidation processes and its combination with nanocatalysts: a review. J Water Process Eng 42:102122
Lu LL, Shan R, Shi YY, Wang SX, Yuan HR (2019) A novel TiO2/biochar composite catalysts for photocatalytic degradation of methyl orange. Chemosphere 222:391–398
Luo LM, Yang M, Chen GW (2022) Continuous synthesis of TiO2-supported noble metal nanoparticles and their application in ammonia borane hydrolysis. Chem Eng J 251:117479
Mahmoodi M, Rafiee E, Eavani S (2022) Photocatalytic removal of toxic dyes, liquorice and tetracycline wastewaters by a mesoporous photocatalyst under irradiation of different lamps and sunlight. J Environ Manag 313:115023
Mortazavian S, Jones-Lepp T, Bae JH, Chun D, Bandala ER, Moon J (2019) Heat-treated biochar impregnated with zero-valent iron nanoparticles for organic contaminants removal from aqueous phase: material characterizations and kinetic studies. J Ind Eng Chem 76:197–214
Mu RH, Liu B, Chen X, Wang N, Yang J (2020) Hydrogel adsorbent in industrial wastewater treatment and ecological environment protection. Envrion Technol Innov 20:101107
Premarathna KSD, Rajapaksha AU, Sarkar B, Kwon EE, Bhatnagar A, Ok YS, Vithanage M (2019) Biochar-based engineered composites for sorptive decontamination of water: a review. Chem Eng J 372:536–550
Priyanka U, Lens PNL (2022) Light driven Aspergillus niger-ZnS nanobiohybrids for degradation of methyl orange. Chemosphere 298:134162
Qambrani NA, Rahman MM, Won S, Shim S, Ra C (2017) Biochar properties and eco-friendly applications for climate change mitigation, waste management, and wastewater treatment: A review. Renew Sustain Energy Rev 79:255–273
Radha E, Sayanna DKR, Sivakumar J (2022) Photoluminescence and photocatalytic activity of rare earth ions doped anatase TiO2 thin films. J Lumin 244:118727
Rodriguez-Narvaez OM, Peralta-Hernandez JM, Goonetilleke A, Bandala ER (2019) Biochar-supported nanomaterials for environmental applications. J Ind Eng Chem 78:21–33
Rong X, Xia M, Kong LS, Natarajan V, Ma L, Zhan JH (2019) The magnetic biochar derived from banana peels as a persulfate activator for organic contaminants degradation. Chem Eng J 372:294–303
Schnabel T, Jautzus N, Mehling S, Springer C, Londong J (2021) Photocatalytic degradation of hydrocarbons and methylene blue using floatable titanium dioxide catalysts in contaminated water. Water Reuse 11(2):224–235
Shang Y, Li X, Yang YL, Wang N, Zhuang XX, Zhou ZW (2020) Optimized photocatalytic regeneration of adsorption-photocatalysis bifunctional composite saturated with Methyl Orange. J Environ Sci 94:40–51
Silva CP, Pereira D, Calisto V, Martins MA, Otero M, Esteves VI, Lima DLD (2021) Biochar-TiO2 magnetic nanocomposites for photocatalytic solar-driven removal of antibiotics from aquaculture effluents. J Environ Manage 294:112937
Singh A, Srivastava A, Saidulu D, Gupta AK (2022) Advancements of sequencing batch reactor for industrial wastewater treatment: major focus on modifications, critical operational parameters, and future perspectives. J Environ Manag 317:115305
Sorayyaei S, Raji F, Rahbar-Kelishami A, Ashrafizadeh SN (2021) Combination of electrocoagulation and adsorption processes to remove methyl orange from aqueous solution. Environ Technol Innov 24:102018
Trandafilović LV, Jovanović DJ, Zhang X, Ptasinska S, Dramicanin MD (2017) Enhanced photocatalytic degradation of methylene blue and methyl orange by ZnO: Eu nanoparticles. Appl Catal B 203:740–752
Waheed A, Baig N, Ullah N, Falath W (2021) Removal of hazardous dyes, toxic metal ions and organic pollutants from wastewater by using porous hyper-cross-linked polymeric materials: a review of recent advances. J Environ Manag 287:112360
Wang W, Zhang J, Chen TY, Sun J, Ma XL, Wang YJ, Wang JH, Xie ZL (2020) Preparation of TiO2-modified biochar and its characteristics of photo-catalysis degradation for enrofloxacin. Sci Rep 10:6588
Wei MB, Zhang P, Zhang B, Zhao L (2022) Synthesis of Fe/C composites derived from cornstalk by one-step hydrothermal method as a reusable adsorbent for dyes. Inorgan Chem Commun 7:109762
Xie YF, Liu A, Bandala ER, Goonetilleke A (2022) TiO2-biochar composites as alternative photocatalyst for stormwater disinfection. J Water Process Eng 48:102913
Yang Z, Wang ZW, Liang GW, Zhang XL, Xie XY (2021) Catalyst bridging-mediated electron transfer for nonradical degradation of bisphenol A via natural manganese ore-cornstalk biochar composite activated peroxymonosulfate. Chem Eng J 426:131777
Zheng L, Yu XJ, Long MC, Li QL (2017) Humic acid-mediated visible-light degradation of phenol on phosphate-modified and Nafion-modified TiO2 surfaces. Chin J Catal 38:2076–2084
Zhou SZ, Wen X, Cao Z, Cheng R, Qian YL, Mi JD, Wang Y, Liao XD, Ma BH, Zou YD, Wu YB (2021) Modified cornstalk biochar can reduce ammonia emissions from compost by increasing the number of ammonia-oxidizing bacteria and decreasing urease activity. Bioresource Technol 319:124120
Znad H, Abbas K, Hena S, Awual MR (2018) Synthesis a novel multilamellar mesoporous TiO2/ZSM-5 for photo-catalytic degradation of methyl orange dye in aqueous media. J Environ Chem Eng 6(1):218–227
Acknowledgements
We thank National Natural Science Foundation of China (52170100, U21A2036), and Shenzhen Science and Innovation Commission (20200813094050001 and JCYJ20200109113006046) for supporting this study.
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Ying Jiang: methodology; investigation; formal analysis; writing—original draft;
An Liu: conceptualization; writing—reviewing and editing.
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Jiang, Y., Liu, A. Cornstalk biochar-TiO2 composites as alternative photocatalyst for degrading methyl orange. Environ Sci Pollut Res 30, 31923–31934 (2023). https://doi.org/10.1007/s11356-022-24490-8
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DOI: https://doi.org/10.1007/s11356-022-24490-8