SYNTHESIS AND
CHARACTERIZATION OF
         Ce65al25co10 METALLIC GLASS
                                 Presentation
                               Session: 2015-16
UNDER THE SUPERVISION OF:                                   BY:
Dr. R. S. TIWARI                                       MOHD ALAM
Professor and Head,                                         M.Sc.(final)
    Department Of Physics,                        Enrolment No.-331085
    Banaras Hindu University                      Roll No.-14481SC069
                   Contents
1.INTRODUCTION TO METALLIC GLASS
2 .PRESENT WORK
    a. Synthesis of Ce65Al25Co10 Metallic Glass.
    b. Characterizations (XRD, TEM, DSC,HARDNESS)
3.RESULTS AND DISCUSSIONS
4.CONCLUSIONS
                      INTRODUCTION
• With the advent of material science and so many new engineering
 material are discovered having major application in industries.
• This are classified as metals and alloys, ceramics, glasses, glass
 ceramics, composites and semiconductor.
• Our presentation is on one of such material which is METALLIC GLASS.
                     METALLIC GLASSES
• The material which has the properties of both metals and glasses is
 known as metallic glass or metglass.
                METALLIC GLASS = AMORPHOUS METAL
• Metallic glasses are metal alloy and are a special case of amorphous
 which shows the glass transition.
• They have high strength, good magnetic properties and better
 corrosion resistance.
                     PREPARATION
Principle:
      Extreme rapid cooling of molten metal alloy called ‘quenching’ .
            Cooling so rapidly that there is no formation of crystalline
structure     forming      solid     frozen      in     liquid     structure.
      During the process of solidification, atoms do not have enough
time or energy to rearrange for crystal nucleation. Thus, reaching the
glass transition temperature Tg solidifies as metallic glass. Again, upon
heating metallic glasses shows a reversible glass-liquid transition at Tg .
                       Conventional solidification:
Volume
                                                      Cooling a melt slowly
                                                       Crystallization
                           Tm Temperature
         Solid state           Liquid state
                                                                              6
                               Production of a metallic glass:
         Metallic glass                                Cooling a melt slowly
                                                        Crystallization
                                                       To avoid crystallization
Volume
                                                        Rapid cooling
                                                             Metallic Glass!
                          Tg          Tm Temperature
         Glassy state      Super cooled Liquid state
                             Liquid
                              Region
                              (SLR)
                                                                                  7
              GLASS TRANSITION TEMPERATURE(TG):
• Metallic glass is prepared by cooling a metallic liquid having
 disordered structure.
 [ RATE OF COOLING IS 2 X 106 K/S]
• The temperature at which the transition from liquid to solid occurs
 is known as glass transition temperature(Tg).
         TECNIQUES OF PREPARATION
Various rapid cooling techniques such as spraying,
  spinning and laser deposition are used for the
         production of metallic glasses.
                      Interesting, right?
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