Unit 1: States of matter

Everything is made of particles. Particles in solid are not free to move around. Liquids and gases can. As
particles move they collide with each other and bounce off in all directions. This is called random
motion. In 2 substances, when mixed, particles bounce off in all directions when they collide. This mixing
process is called diffusion. It’s also the movement of particles without a force. The smallest particle that
cannot be broken down by chemical means is called an atom. ·In some substances, particles are just
single atoms. For example the gas argon, found in air, is made up of single argon atoms. In many
substances, particles consist of 2 atoms joined together. These are called molecules. In other substances,
particles consist of atoms or groups of atoms that carry a charge. These particles are called ions.
Solids liquids and gases
Solid Properties:
• Definite shape and volume
• Normally hard and rigid
• Large force required to change shape
• High Density
• Incompressible
Model:
• Closely packed
• Occupy minimum space
• Regular pattern
• Vibrate in fixed position
• Not free to move

Liquid Properties:
• Definite volume but no shape.
• High Density
• Not compressible
Model:
• Occur in clusters with molecules slightly further apart compared to solids
• Free to move about within a confined vessel
Gas Properties:
• No Fixed volume and no fixed shape
• Low density
• Compressible
Model:
• Very far apart
• Travel at high speed
• Independent and random motions
• Negligible forces of attraction between them

Diffusion in Gases
Gases diffuse in different rates. Those rates depend on their factors:
1.Mass of the particles -The lower the mass of its particles the faster a gas will diffuse. Why?
Because the lighter the molecules...the faster it will travel (obviously...)

2. The temperature-The higher the temperature, the faster a gas will diffuse. Why?
Because particles gain energy as they are heated
Mixtures, Solutions, and Solvents
Mixture: Contains more the one substance. They are just mixed together and not chemically combined.
Example: Sand and water.
Solution: It is when a solute and a solvent mix. The solute dissolves in the solvent making a solution.
Example: sugar (solute) dissolves in water (solvent) making a solution of sugar and water.
The solubility of every substance is different. To help a solute dissolve you could:
• Stir it OR rise the temperature
If you add excess amount of sugar in a small amount of water...it won’t dissolve as there is no space for
it. The solution becomes saturated.
Solvent: A substance that allows solutes to dissolve in Example: Water, Ethanol
Pure substances and impurities
A pure substance is a substance that has no particles of any other substance mixed with it. An unwanted
substance, mixed with a wanted substance, is called an impurity. To check if a substance is pure, you
have to check its melting and boiling points. A pure substance has a definite, sharp, melting point. When
a substance is impure, the melting point falls and its boiling point rises. So the more impurity present,
the wider and bigger the change in melting and boiling point.

Separation methods
Filter ------------------------- Solid from liquid
Centrifuge ------------------ Solid from liquid
Evaporation ---------------- Solid from its solution
Crystallization -------------- Solid from its solution
Distillation ------------------ Solvent from a solution
Fractional distillation ----- Liquid from each other
Chromatography ---------- Different substances from a solution

1. Filtering- Example: A mixture of chalk and water...

1. A filter paper is placed in a funnel, the funnel placed on a flask.
2. The mixture is poured on the filter paper.
The chalk (the residue) will remain in the filter paper and the water (the filtrate) will fall down in the
flask.

2. Centrifuging-This method is used to separate small amounts of solid and liquid. Inside a centrifuge
(it’s a machine), test tubes are spun very fast so the solid gets flung to the bottom.

3. Evaporation -This method is used to separate a solution in which the solid is dissolved in the liquid.
The solution is heated so that the liquid evaporates and the solid remains in the bottom of the
evaporating dish.

4. Crystallization-This method is similar to evaporation but here the solid forms crystals then the crystals
are left to dry.
Separating a mixture of two solids
1. This can be done by dissolving one in an appropriate solvent.
2. Then filtering one and extracting the other from the solution by evaporation.

5. Simple distillation
1. The impure liquid is heated.
2. It boils, and steam rises into the condenser.
3. The impurities are left behind.
4. The condenser is cold so the steam condenses to the pure liquid and it drops out on the beaker.

6. Fractional distillation
1. The mixture is heated.
2. The wanted substance boils and evaporates (some of the unwanted liquid will evaporate too) and rises
up the column.
3. The substance will condense on the beads in the column causing them to heat.
4. When the beads reach a certain temperature when the wanted liquid won’t condense anymore
(That’s the boiling point) it will rise while the unwanted liquid will condense and drop. The wanted liquid
will make its way through the condenser where it will condense and drop down in the beaker.

7. Chromatography -This method is used to separate a mixture of substances. For example you can use it
to find how many colored substances there are in black ink.
Steps:
1. Drop the black ink on to the center of a filter paper and allow it to dry.
2. Drop water on to the ink spot, one drop at a time.
3. Suppose there are three rings: yellow, red and blue. This shows the ink contains 3 colored substances.
The substances travel across the paper at different rates. That’s why they separate into rings. The filter
paper showing the separate substances is called a chromatogram. This method works because different
substances travel at different speeds because they have different levels of attraction to it.

Uses of chromatography:
• Separate mixtures of substances
• Purify a substance by separating the impurities from it
• Identify a substance

Unit 2: The Atom

Atoms are the smallest particles. Each atom consists of a nucleus and a cloud of particles called electrons
that whizz around the nucleus. An element is a substance that contains only one kind of atom. The
periodic table is the “map/address book” for elements where each element is given a symbol (E.g. K for
potassium). The group of elements that have similar properties are put in a numbered column. For
example, if you know how one element in group 1 behaves, you can easily guess how the others in the
same group will behave. The rows are called periods. The zigzag line separates metals from non-metals,
with the non-metals on the right. So most of the elements are metals.

A compound contains atoms of different elements joined together where the atoms are chemically
combined. For example carbon dioxide is a compound of carbon and oxygen (1 carbon and 2 oxygen
molecules) The symbol for compound is made from the symbols of the elements in it. So the formula
for carbon dioxide is CO2.
Isotopes and Radioactivity
You can identify an atom by the number of protons in it. For example, only sodium atoms
have 11 protons. Isotopes are atoms of the same element, with different numbers of neutrons.
Some isotopes are radioactive. That means its nucleus is unstable, sooner or later the atoms breaks
down or decays, giving out radiation in the form of rays and tiny particles, as well as large amount of
energy. Like carbon-14, a number of other elements have radioisotopes that occur naturally and
eventually decays. But the other two isotopes of carbon (like most natural isotopes) are non-radioactive.
You can know when radioisotopes decay by looking at their half life. Radiation affects humans as it may
cause them radiation sickness but radiation also has some uses.

Uses of radiation:
1. Check for leaks in pipes (industry)-This is done by adding a radioisotope to the oil or gas. At a leak, the
radiation is detected using an instrument. Radioisotopes used in this way are called tracers.

2. in cancer treatment (Medical)-Radioisotopes can cause cancer but yet also can cure it. Using
radiotherapy the radioisotope will decay and give out rays that can kill cancer cells. These rays will be
aimed exactly at the cancer cells.

3. To find the age of old remains-A tiny percentage of a living thing contains carbon-14 atoms. When
living thing dies it no longer takes in new carbon atoms. But existing carbon-14 atom decay over time -
we can measure the faint radiation from them.

How electrons are arranged

The electrons in an atom circle fast around the nucleus, at different levels from it. These energy levels
are caller electron shells. The further the shell is from the nucleus, the higher the energy level. Each shell
can hold a limited number of electrons. First shell can hold up to 2 electrons, second shell can hold up to
8 electrons the third shell can also hold up to 8 electrons

Electronic configuration means the arrangement of electrons in an atom.

Example:
• Argon has the electronic configuration: 2,8,8
Magnesium has the electronic configuration: 2,8,2
NB: • The shells fill in order, from lowest energy level to highest energy level
• All the elements in a group have the same number of electrons in their outer shells. These are
called valency electrons.
• The group number is the same number of outer shell electrons
• The period number shows how many shells there are.
• If an element posses a full outer shell, the element become unreactive
 Unit 3: Atoms combining

Most elements form compounds because they want a full outer shell and to achieve that they must react
with other atoms. For example, sodium has just one electron in its outer shell. It can obtain a full outer
shell by losing this electron to anther atoms and by that it becomes a sodium ion. Now because sodium
lost a electron...it now has 10 electrons but 11 protons...so it has a 1 positive charge. An ion is a charged
particle. It is charged because it has an unequal number of protons and electrons.

The ionic bond

Example: Sodium and chlorine react together; sodium gives its electron to chlorine. Now both elements
have a full outer shell, but with a charge. Now they are ions. Sodium now has 10 electrons but 11
protons so it has a positive charge. Chlorine now has 18 electrons but 17 protons so it has a negative
charge. The two ions have opposite charges, so they attract each other. The force of attraction between
them is strong. It is called an ionic bond.

When sodium reacts with chlorine, billions and billions of sodium and chlorine ions form and they attract
each other. But the ions don’t stay in pairs. They cluster together so that each ion is surrounded by 6 ions
of opposite charges. The pattern grows until a giant structure of ions is formed. The overall charge of the
structure is 0 since 1 positive charge and 1 negative charge neutralize each other.

The ionic bonding is only between metals and non-metals.

Important notes:
• Hydrogen and the metals form positive ions
• Non-metals form negative ions, and their names end in -ide
• Group 4 and 5 do not usually form ions because they would have to lose or gain several
electrons and that takes too much energy
• Group 0 elements do not form ions; they already have full outer shells
• Some of the transition metals form more than one ion.
• Some ions can be formed from groups of joined atoms. These are called compound ions.
 Properties of ionic compound
1. Ionic compounds have high melting and boiling points. This is because ionic bonds are very strong, so
it takes a lot of heat energy to break up the lattice.
2. Ionic compounds are usually soluble in water. The water molecules can attract the ions away from the
lattice. The ions can then move freely, surrounded by water molecules.
3. Ionic compounds can conduct electricity when they are melted or dissolved.

When melted the lattice breaks up and the ions are free to move. Since they are charged, this means
they can conduct electricity. The solutions of ionic compounds conduct electricity too because they are
also free to move.

The covalent bond

Giving and losing an electron is not the only way to gain full outer shells since atoms can also share
electrons. Covalent bonding is for non-metals only since only non-metals need to gain electrons. A
molecule is a group of atoms held together by covalent bonds. When a pair of electrons is shared, it is
called a single covalent bond, or just single bond. When 2 pairs of electrons are shared, it is called a
double covalent bond, or just double bond. When 3 pairs of electrons are shared, it is called a triple
covalent bond, or just triple bond.

Covalent compounds -A covalent compound is when atoms of different elements share electrons with
each other. The molecules in a covalent compound isn’t flat because each electron repel each other
and try to get as far apart from each other.

Molecular substances -Most molecular substances are gases or liquids at room temperature. Molecular
solids are held in a lattice but the forces between the molecules are weak. All molecular solids have
similar structure. The molecules are held in regular pattern in a lattice. So the solids are crystalline.

When you cool down a molecular liquid or gas the molecules lose energy so they start moving slowly and
at the freezing point, they form a lattice (a good example would be ice)

Properties of covalent bonding

1. Covalent compounds have low melting and boiling point. This is because the forces between the
molecules are weak.
2. They do not conduct electricity this is because molecules are not charged, so they cannot conduct,
even when melted.
Giant covalent structures -A giant covalent structure, or macromolecules are made of billions of atoms
bonded together in a covalent structure.

Diamond – a giant covalent structure diamond is made of carbon atoms held in a strong lattice. Each
carbon atom forms a covalent bond to four others. Eventually billions of carbon atoms bond together to
form a crystal of diamond.

Diamond properties:
1. It is very hard because each atom is held by four strong bonds.
2. It has a very high melting point because of the strong bonds.
3. It can’t conduct electricity because there are no free electrons to carry the charge.

Silica is similar to diamond.

Graphite – a very different giant structure Like diamond graphite is made only of carbon atoms. So
diamond is and graphite are allotropes of carbon (means they are two forms of the same element)
Graphite, unlike diamond, is one of the softest solids on earth. In graphite, each carbon atom forms a
covalent bond to three others. This gives rings of six atoms.

Graphite properties:
1. Is soft and slippery because the sheets can slide over each other
2. Is a good conductor of electricity because each carbon atom has four outer electrons and graphite
bonds 3 only so the fourth electron is free to move carrying a charge.

Metallic bonding

Metals form giant structures in which electrons in the outer shells of the metal atoms are free to move.
The metallic bond is the force of attraction between these free electrons and metal ions. Metallic bonds
are strong, so metals can maintain a regular structure and usually have high melting and boiling points.

Properties of metals:
1. Metals have high melting points -This is because it takes a lot of heat energy to break up the lattice.
2. Metals are malleable and ductile- They can be bent and pressed into shapes.
Ductile: They can be drawn out into wires. This is because the layers can slide without the metallic bond
breaking, because the electrons are free to move too.
3. Metals are good conductors of heat- That’s because the free electrons take in heat energy, which
makes them move faster and they quickly transfer the heat through the metal structure.
4. Metals are good conductors of electricity -This is because the free electrons can move through the
lattice carrying the charge.

Unit 4: The Periodic Table

The periodic table is a list of all the elements, in order of increasing atomic number. The columns are
called groups. The rows are called periods.

Groups
• The group number tells you how many electrons there are in the outer shell of the atoms.
• The outer-shell electrons are also called valency electrons and their number shows how the elements
behave.
• All elements in a group have similar properties.
• Group 0 elements have a full outer shell. This makes them unreactive.
• Some of the groups have special names:
Group 1 – The alkali metals
Group 2 – The alkaline earth metals
Group 7 – The halogens
Group 0 – The noble gases

Periods
The period number gives information about the number of electron shells that are available in that
period. Hydrogen sits alone in the table because it’s the only element with one electron shell.Trends in
the periodic table. The elements in each numbered group shows trends in their properties. For example
as you go down group 1, the elements become more reactive or as you go down group 7 the elements
become less reactive and so on.

Group 1: The alkali metals

Their physical properties:
1. Like all metals, they are good conductors of heat and electricity.
2. They are softer than most other metals and they have low density.
3. They have low melting and boiling points, compared to most metals.

Their chemical properties:

1. All alkali metals react vigorously with water, releasing hydrogen gas and forming hydroxides. The
hydroxides give alkaline solutions.
2. They react with non-metals. With chlorine they react to make chlorides and with oxygen they make
oxides.
They form ionic compounds in which the metal ion has a charge of 1+. The compounds are white solids,
which dissolve in water to give a colorless solution
Why they have similar properties? Because atoms with the same number of valency electrons react in a
similar way. As you go down the group reactivity increase. Why? Because the atoms get larger down the
group because they add electron shells.

Group 7: The halogens

A non-metal group
• Form colored gases.
• Are poisonous
• Are brittle and crumbly in their solid form, and do not conduct electricity.
•
Form diatomic molecules (means they exist as 2 atoms)

Trends in their chemical properties

Reactivity increases as you go up group 7. Why? Because the smaller the atom, the easier it is to attract
the electron – so the more reactive the element will be.
Why are they so reactive? Because their atoms are only one electron short of a full shell.

Group 0: The noble gases

A non-metal group
• Contains colorless gases, which occur naturally in air
• Monatomic – they exist as single atoms
• Unreactive because they have a full outer shell.
 The transition elements

The transition elements are the block of 30 elements in the middle of the periodic table. They are all
metals.

Their physical properties

• Hard, tough and strong
• High melting points (mercury is an exception)
• Malleable and ductile
• Good conductors of heat and electricity
• High density

Their chemical properties

1. They are much less reactive than the metals of group 1.
2. They show no clear trend in reactivity, unlike the metals of group 1.
3. Most transition metals form colored compounds
4. Most can form ions with different charges (they have variable valency)
5. They can form more than one compound with another element
6. Most transition metals can form complex ions

Uses of transition metals

• The hard strong transition metals are used in structure such as bridges,
buildings, cars etc.
• Many transition metals are used in making alloys.
• Transition metals are used as conductors of heat and electricity.
• Many transition metals and their compounds act as catalysts
 Unit 6: Chemical equations

Physical and chemical change

A substance can be changed by heating it, adding water to it, mixing another substance with it, and so
on. The change that takes place will be either chemical change or a physical change.

Chemical change
In a chemical change, a new chemical substance is produced.
The difference between a mixture and a compound
Mixture: 2 substances are mixed together but not chemically bonded.
Compound: 2 substances are chemically bonded together

The signs of a chemical change- A chemical change is usually called a chemical reaction. You can tell
when a chemical reaction has taken place by these signs:

1. Once or more new chemical substances are formed- The new substance usually looks different from
the starting substances.
2. Energy is taken in or given out during the reaction- A change that gives out heat energy is called
exothermic- A change that takes in heat energy is called endothermic
3. The change is usually difficult to reverse- This means it will be hard to get back the raw materials of
the reaction.

Physical change

If no new chemical substance is formed, a change is a physical change.

Equations for chemical reactions
The
reaction between carbon and oxygen. When they react together, they form carbon
dioxide. Carbon and oxygen are the reactants. Carbon dioxide is the product of the
reaction.
Or in a shorter way, using symbols and numbers like this: C + O 2 CO2 This short way to describe the
reaction is called a chemical equation.

The reaction between hydrogen and oxygen:

Adding state symbols

- (s) for solid

- (l) for liquid
- (g) for gas
- (aq) for aqueous solution (solution in water)

Unit 8: Acids and alkalis

Acids-You can tell if something is acid, by its effect on litmus. Litmus is a purple dye. It can be used as a
solution, or on paper. Acids turn litmus red. Alkali turn litmus blue Litmus is called an indicator, because
it indicates whether something is an acid or an alkali. Neutral substances- Many substances are not acids
or alkalis. They are neutral. Example is pure water.

You can say how acidic or alkaline a solution is using a scale of numbers called pH scale. The numbers go
from 0 to 14:
On this scale:

An acidic solution has a pH number less than 7

An alkaline solution has a pH number greater than 7

A neutral solution has a pH number of exactly 7

Acids produce hydrogen ions Acidic solutions contain hydrogen ions, this what makes them ‘acidic’

The difference between strong and weak acids

In solution of strong acids, all molecules become ions (complete ionization). In solution of weak acids,
only some do (partial ionization).

The higher the concentration of hydrogen ions, the lower the pH, the stronger the acid.

Alkalis produce hydroxide ions. Alkaline solutions contain hydroxide ions, this is what makes them
alkaline.

The difference between a strong alkali and weak alkali

In solution of strong alkali, it contains more hydroxide ions. In solution of weak alkali, it contains less
hydroxide ions.

The higher the concentration of hydroxide ions, the higher the pH.
To tell if the solution is a weak or strong acid. You can also measure there conductivity. A strong acid will
show high conductivity and low pH. A weak acid does not conduct well, and has a higher pH. For alkali’s,
a strong alkali will show high conductivity and high pH. A weak acid will show low conductivity and low
pH.

Reaction of acids with metals

When an acid reacts with a metal, hydrogen is displaced, leaving a salt in solution. It’s a redox reaction.

Reaction of acids with bases

Bases are a group of compound that reacts with acids, and neutralize them, giving a salt and water. Bases
include alkalis, and insoluble metal oxides, hydroxides and carbonates.

1. With alkalis acid + alkali salt + water

2. With metal oxides Acid + metal oxide salt + water
3. With carbonates Acid + metal carbonatesalt + water + carbon dioxide

Reactions of bases

1. Neutralizing acids, giving salt and water. With carbonates carbon dioxide is produce too.
2. All the alkalis (except ammonia) will react with ammonium compounds, giving ammonia out.

The ionic equation

An ionic equation shows only the ions that actually take part in a reaction. It leaves out
the rest.

1. First write down all the ions present in the equation(except for gases and solids)
2. Now cross out any ions that appear, unchanged, on both sides of the equation
3. What’s left is the ionic equation for the reaction
Proton donors and acceptors

Acids donate its protons to bases and bases accept them.

For example: Magnesium oxide is a insoluble base. The acid donates its H+ protons and the oxygen
from magnesium oxide react with it to make water molecules.

Acidity in soil- Most crops grow best when the pH of the soil is near 7. If soil is too acidic or too alkaline,
crops grow badly or not at all. Usually acidity is the problem. Why? Because of a lot of vegetation rotting
in it or because too much fertilizer was used in the past. To reduce the acidity, the soil is treated with a
base like limestone or quicklime or slaked lime.

Acid rain is caused by factories, power stations, homes who burn fossil fuels to make electricity. The
waste gases from all these reactions include sulphur dioxide, and oxides of nitrogen. They go into the air
and react with air and water to produce sulphuric acid and nitric acid which are strong acids.

Making salts

You can make salts by reacting metals, insoluble bases, or soluble bases with acids.

With metals:
Example:
1. Add the zinc to the sulphuric acid in a beaker, It will start to dissolve and hydrogen bubbles are given
off. Stops when all the acid is used up.
2. Excess zinc is removed by filtering. This leaves a aqueous solution of zinc sulphate.
3. The solution is heated to evaporate some water. Then it is left to cool and crystals of zinc sulphate
start to form.
With insoluble base:

It’s the same method as the one above but, the metal won’t react with the acid. So you must start with a
metal oxide.

With an alkali (soluble base):

1. Put the alkali into a flask and add some drops of indicator
2. Add the acid from a burette, just a little at a time. Swirl the flask to help the acid and alkali mix.
3. When the indicator turns green stop adding acid.
4. Calculate how much acid was used.
5. Carry out the experiment again without the indicator and add same amount of acid that was used
before. This is because the indicator will make the salt impure.
6. Heat the solution from the flask and crystals will start to form.

Making insoluble salts by precipitation

Not all salts are soluble

Insoluble salts can be made by precipitation

Preparing barium sulphate

Barium sulphate is an insoluble salt. You can make it by mixing solutions of barium chloride and
magnesium sulphate.

1. Make up solutions of barium chloride and magnesium sulphate.

2. Mix them. A white precipitate of barium sulphate forms at once.
3. Filter the mixture. The precipitate is trapped in the filter paper.
4. Rinse the precipitate by running distilled water through it.
5. Then place it in a warm oven to dry

To precipitate an insoluble salt, you must mix a solution that contains its positive ions with one that
contains its negative ions.

Rates of reaction

Some reactions are fast and some are slow.

What is rate?
Rate is a measure of how fast or slow something is.
Rate is a measure of the change that happens in a single unit of time.
To find rate of a reaction, you should measure:
• The amount of a reactant used up per unit of time

Or
• The amount of a product produced per unit of time

A reaction that produces a gas

When you react magnesium and hydrochloric acid, it produces hydrogen gas. To measure the rate of this
reaction this method is set up:

Stop clock
Using this you can measure the amount of hydrogen produced in a period of time.

Collisions

For a chemical reaction to occur, the reactant particles must collide. But collisions with too little energy
do not produce a reaction.
The particles must have enough energy for the collision to be successful in producing a reaction.
The rate of reaction depends on the rate of successful collisions between reactant particles. The more
successful collisions there are, the faster the rate of reaction.

Changing the temperature

If the temperature is increased:
• the reactant particles move more quickly
• they have more energy
• the particles collide more often, and more of the collisions result in a reaction
• the rate of reaction increases

Changing the concentration or pressure

If the concentration of a dissolved reactant is increased, or the pressure of a reacting gas is increased:
• the reactant particles become more crowded
• there is a greater chance of the particles colliding
• the rate of reaction increases

Changing the surface area

If a solid reactant is broken into small pieces or ground into a powder:
• its surface area increases
• more particles are exposed to the other reactant
• there are more collisions
• the rate of reaction increases

The effect of light

Some chemical reactions obtain the energy from light. They are called photochemical reactions. For
example:
1. Silver bromide is pale yellow, but darkens on exposure to light because the light causes it to
decompose to silver:

Light
2AgBr  2Ag + Br²
2. Plants use carbon dioxide from the air to make sugar called glucose, in a reaction called
photosynthesis. This uses the energy in sunlight. The green substance – chlorophyll – in leaves speeds
up the reaction:

Light
6CO² + 6H²O  C6 H12 O6 + 6O²
chlorophyll
Carbon dioxide + water  glucose + oxygen
In both these reaction, the stronger the light, the more energy it provides so the faster the reaction goes.
Effect of catalysts
A catalyst is a substance that can increase the rate of a reaction. The catalyst itself remains unchanged at
the end of the reaction it catalyses. Only a very small amount of catalyst is needed to increase the rate of
reaction between large amounts of reactants.
A catalyst works by lowering the activation energy for the reaction.
Enzymes: biological catalysts
Enzymes are proteins that act as catalysts. So they are often called biological catalysts.
How enzymes work
First the enzyme and the reactant molecule fit together like jigsaw pieces. The reactant molecule has to
be the right shape. The enzyme breaks down the molecule to smaller pieces and so on.
Important notes:
• An enzyme works best in conditions that match those in the living cells it came from.
• This means most enzymes work best in the temperature range 25-45ºC
• If the temperature is too high, an enzyme loses its shape and it becomes denatured.
• An enzyme also works best in a particular pH range.

Uses of enzymes
1. In making ethanol
2. In making bread
3. In biological detergents

Redox reactions

This page looks at the various definitions of oxidation and reduction (redox) in terms of the transfer of
oxygen, hydrogen and electrons. It also explains the terms oxidising agent and reducing agent.

Oxidation and reduction in terms of oxygen transfer

Definitions
• Oxidation is gain of oxygen.
• Reduction is loss of oxygen.
For example, in the extraction of iron from its ore:

Because both reduction and oxidation are going on side-by-side, this is known as a redox reaction.
Oxidising and reducing agents
An oxidising agent is substance which oxidises something else. In the above example, the iron(III) oxide is
the oxidising agent.
A reducing agent reduces something else. In the equation, the carbon monoxide is the reducing agent.
• Oxidising agents give oxygen to another substance.
• Reducing agents remove oxygen from another substance.

Oxidation and reduction in terms of hydrogen transfer

These are old definitions which aren't used very much nowadays. The most likely place you will come
across them is in organic chemistry.
Definitions
• Oxidation is loss of hydrogen.
• Reduction is gain of hydrogen.
Notice that these are exactly the opposite of the oxygen definitions.
For example, ethanol can be oxidised to ethanal:

You would need to use an oxidising agent to remove the hydrogen from the ethanol. A commonly used
oxidising agent is potassium dichromate(VI) solution acidified with dilute sulphuric acid.
Ethanal can also be reduced back to ethanol again by adding hydrogen to it. A possible reducing agent is
sodium tetrahydridoborate, NaBH4. Again the equation is too complicated to be worth bothering about
at this point.

An update on oxidising and reducing agents

• Oxidising agents give oxygen to another substance or remove hydrogen from it.
• Reducing agents remove oxygen from another substance or give hydrogen to it.

Oxidation and reduction in terms of electron transfer

This is easily the most important use of the terms oxidation and reduction.
Definitions
• Oxidation is loss of electrons.
• Reduction is gain of electrons.
It is essential that you remember these definitions. There is a very easy way to do this. As long as you
remember that you are talking about electron transfer:
OIL RIG
Oxidation Is Loss Reduction Is Gain
A simple example
The equation shows a simple redox reaction which can obviously be described in terms of oxygen
transfer.
CuO + Mg → Cu + MgO
Copper(II) oxide and magnesium oxide are both ionic. The metals obviously aren't. If you rewrite this as
an ionic equation, it turns out that the oxide ions are spectator ions and you are left with:

A last comment on oxidising and reducing agents

If you look at the equation above, the magnesium is reducing the copper(II) ions by giving them
electrons to neutralise the charge. Magnesium is a reducing agent.
Looking at it the other way round, the copper(II) ions are removing electrons from the magnesium to
create the magnesium ions. The copper(II) ions are acting as an oxidising agent.
Warning!
This is potentially very confusing if you try to learn both what oxidation and reduction mean in terms of
electron transfer, and also learn definitions of oxidising and reducing agents in the same terms.
It is recommend that you work it out if you need it. The argument (going on inside your head) would go
like this if you wanted to know, for example, what an oxidising agent did in terms of electrons:
• An oxidising agent oxidises something else.
• Oxidation is loss of electrons (OIL RIG).
• That means that an oxidising agent takes electrons from that other substance.
• So an oxidising agent must gain electrons.
Or you could think it out like this:
• An oxidising agent oxidises something else.
• That means that the oxidising agent must be being reduced.
• Reduction is gain of electrons (OIL RIG).
• So an oxidising agent must gain electrons.
Understanding is a lot safer than thoughtless learning!

ELECTROLYSIS

The decomposition of a substance using electrical energy. Electric current is passed through the
substance to be decomposed.

DEFINITION OF TERMS

Electrodes – these are conducting plates through which current enters and leaves electrolyte. The
electrodes have the positive (anode) and the negative (Cathode) ends.
Anodes – this is the positive electrode through which current enters the electrolyte. Negative ions
migrate to the anode and lose electrons to it. Oxidation takes place at the anode.

Cathode - this is the negative electrode through which current leaves the electrolyte. Electrons
flow from cathode to the anode. Reduction takes place at the cathode.

Active electrodes - electrodes which react with products of electrolysis/electrolytes hence affect the
course of the electrolysis. e.g using copper electrodes in electrolysis of CuSO4.

Inert electrodes – electrodes which do not react with the products of electrolyte during
electrolysis. Eg Platinum and carbon (graphite) are normally used as inert electrodes.

Electrolyte - a substance which conducts electricity when molten or in solution. This is a liquid which
allows electric current to pass through e.g NaCl, solution of acid in water, molten salts e.t.c.

Non-electrolyte- a compound in molten state which does not allow electric current to pass
through. E.g ethanol, pure water, sugar solution.

AN ELECTRIC CELL

NB: +ve ions (cations) are attracted towards the cathode- (negative electrodes).
-ve ions (anions) are attracted towards the anode+ (positive electrodes).
ELECTROLYSIS OF MOLTEN COMPOUNDS (Pure Science)

Electrolysis of molten lead ( ) bromide (PbBr2). The melting point of lead ( ) bromide is 370˚C. ions
present, Pb+2, Br-.

At the anode ………….........................

Bromide ions are attracted. They give up their electrons and turn into bromine molecules.
2Br-(l) →Br2(g) + 2e-

At the cathode………………………………….
Lead ions are attracted. Lead ions take in the electrons and change to atoms.
Pb+2 + 2e- →Pb(…)

NB: the metal of the compound will be formed at the cathode. Non-metals will be formed at the
Anode.

ELECTROLYSIS OF AQUEOUS SOLUTIONS (All sciences)

The products form electrolysis of a solution of a salt may differ from those obtained by electrolysis of
molten salt. This is because water itself produces ions, but only a few molecules split into ions.
These ions migrate to the respective electrodes and compet3e with the ions of the electrolyte for
discharge.

FACTORS AFFECTING DISCHARGE OF IONS AT ELECTRODES

When two or more ions of similar charge are present under similar conditions in a solution e.g H+ and
Na+ or OH- and Cl-. One is selected for a discharge over the other. The preferential discharge depends on
the following factors:
• Position of the ion or group in the electrochemical series.
• Concentration of the solution.
• Nature electrode.

• POSITION OF THE ION OR GROUP IN THE ELECTROCHEMICAL SERIES

At the cathode a more reactive metal will tend to say as ions e.g Na+ can not discharge while the ions of a
less reactive metal like Cu+2 are present (electrons readily to form atoms). Any ion will be discharged
from solution in preference to those above it in the electrochemical series.

ELECTROCHEMICAL SERIES

CATIONS NOT EASY TO DISCHARGE ANIONS

K+ Ease of discharge increase SO4-2
Na+ Most reactive NO3-
Ca+2 Cl-
Mg+2 Br-
Zn+2 I-
Fe+2 OH-
Pb+2
H+
Cu+2
Ag+

Less reactive

Easily discharge

NB: the more the reactive an element is, its ion remains in solution but the least reaction the more
easily it becomes discharged.

2. CONCENTRATION
If a solution is concentrated the anions which are greater in concentration compared to the hydroxide
ions will be discharged. If a solution is dilute the hydroxide ion will be discharged on preference to the
halogens.

3 NATURE OF ELECTRODES
This factor depends on whether the electrodes are active or inert. Active electrodes usually affect the
products of electrolysis.

ELECTROLYSIS OF CONCENTRATED AQUEOUS HYDROCHLORIDE ACID

The anode must be carbon to resist attack by chloride. Cathode could be carbon or platinum.

Ions present: H+ and Cl- from acid

H+ and OH- from water

REACTION AT THE CATHODE

2H+ (aq) + 2e- →H2(g) Reduction

REACTION AT THE ANODE

The chloride ions and hydroxide ions are attracted to the anode. Chloride ion is discharged in preference
to the hydroxide because of its high concentration. Hydroxide ion is expected to be discharged because
of its position in the electrochemical series, but its concentration is very low and therefore chloride ion is
discharged.

2Cl- (aq)→ Cl2 + 2e- oxidation

Electrolysis of concentrated aqueous sodium chloride (NaCl) using inert electrodes.

Ions present: Na+, Cl- from NaCl

H+, OH- from water

At the cathode
2H+ (aq) + 2 e- →H2(g) Reduction

At the anode
2Cl- (aq) → Cl2(g) + 2e-

NB: Concentrated aqueous NaCl is known as BRINE. The sodium ions will combine
with the hydroxide ions forming sodium hydroxide (NaOH) which is also an important
product. The electrolyte will then change from being neutral to alkaline.

ELECTROLYSIS OF DILUTE SULPHURIC ACID USING INERT ELECTRODES/THE

SO CALLED ELECTROLYSIS OF ACIDIFIED WATER
THE HOOFMANN VOLTAMETER

CATHODE REACTION

4H+(aq) + 4e- →2H2(g)

ANODE REACTION

4OH- (aq) →2H2O(l) + O2(g) + 4e-

NB: Ions of water are discharged leaving behind ions of H2SO4. The electrolyte
therefore become more concentrated with sulphuric acid.

The same number of electrons are evolve at each chloride. From the equation, one
molecule of oxygen is produced for every two molecules of hydrogen. 2 volumes of
hydrogen at the cathode and 1 volume of O2 at the anode is equivalent to the
electrolysis of water.

The volume of O2 obtained is half of H2 because O2 is more soluble in H2O.

ELECTROLYSIS OF AQUEUOS COPPER(II) SULPHATE USING CARBON

ELECTRODES(Inert electrode)

Ions present : Cu+2, ……… from CuSO4

H+, OH- from H2O

Cathode reaction
Cu+2(aq) + 2e- →Cu(s)
(Brown copper deposit is observed at the cathode)
OBSERVATION MADE
The solution changes from blue to light blue to colourless ie the intensity of the blue
colour reduces with time.

Copper (II) ions (Cu+2) in solution are blue, so the solution loses its colour, they are being discharged.

Bubble of oxygen gas at the anode.

Brown copper deposit at the cathode.

ELECTROLYSIS OF AQUEOUS COPPER (II) SULPHATE USING COPPER

ELECTRODES (ACTIVE ELECTRODES)

Ions present : Cu+2, …….

H+, OH-

At the cathode
Cu+2 (aq) + 2e- →Cu(s)
At the anode
Both ……………… and OH- ions migrate here but neither of them is discharged, instead
the copper anode dissolves in the solution by giving away its electrons. This is called
electrode ionisations.

Cu(s) →Cu+2(aq) + 2e-

Observations
=the CuSo solution remains the same colour. Why?
*the anode is reduced in mass and the cathode increases.

Mass of copper gained = mass of copper lost

at the cathode at the anode

PURIFICATON OF COPPER

Copper is a very good conduct of electricity. It must be pure to be used for electrical
wiring and cables. To ensure the level of purity, copper has to be purified by electrolysis.

NOTE:
• the electrolyte is a solution of copper (II) sulphate or copper (II) salt solution
• the impure copper is used as the anodes
• the cathode is made from pure copper
at the anode
The impure copper is used as the anode. The anode loses mass because the copper
atoms lose eletrons and become copper ions.
Therefore the impurities fall to the bottom of the cell.

Cu (s) → Cu+2(aq) + 2e-

At the cathode
The copper ions are discharged and pure copper is deposited on the cathode.

ELECTROPLATING
It is defined as the process of coating one metal with another metal using electricity or by
electrolysis.

IMPORTANT POINTS:
• The substance electroplated is made the cathode
• The metal used for electroplating is made the anode
• The electrolyte is a salt solution of the metal used for electroplating.
Example
Electroplating an ion nail with copper

Remember:
the ion nail is made the cathode
copper is made the anode
a copper salt solution e.g CuCl2, CuSO4 is used as the electrolyte

At the cathode
Cu+2(aq) + 2e-→Cu(s)
At the anode
Cu(s) → Cu+2(aq) + 2e-

USES OF ELECTROPLATING
• To protect against corrosion
• To improve appearance or for decoration

USES OF ELECTROLYSIS
• Extraction of metal(s)
• Electroplating
• Purification of metals e.g copper
• Manufacture of chemicals e.g NaOH
•
ELECTROLYSIS CALCUTIONS

The quantity of electricity or charge (Q) flowing through an electrolysis all is measured in
Coulombus (C)
*one coulomb (1C) is equivalent to a current of 1 ampere (1A) following for 1 second.

FARADAY’S FIRST LAW OF ELECTROLYSIS (Pure Science)

The mass of a substance deposited or liberated at an electrode during electrolysis is

proportioned to the quantity of electricity passing through one electrolyte.

Quantity of = current (I) x time (t)

Charge (Q)
Q = It

Current is measured in ampere (A). Change is measured in Coulombus (C) and time in
seconds (s).

The quantity of electricity (charge) transferred by 1 mole of electrons is equal to 96 500

coulombs per mole. This is called the Faraday’s constant.

Faranday’s constant = 96 500 c/mol

1 Faraday = 96 500C
2 Faraday = 96 500 C x 2
1 mole of e- = 96 500 C

Number of moles of = charge (Q)

e- Faraday constant

Mol of e- = Q
F

Number of moles = moles of e-

Of an element charge of 1 ion of element

Mol of E = Mole of e-
Charge of ion
 Metals

The Reactivity Series of Metals:

The reactivity series is metal is an arrangement of the metals (and carbon and
hydrogen) in order of their reactivity starting with the most reactive metal at the
top and ending with the least reactive metal at the bottom.
The reactivity of a metal is determined by its ability to form a positive ion. For
example, potassium is extremely reactive because it has only one valence electron,
so it is very easy to lose it forming a positive ion.
One the other hand, copper is a weakly reactive metal because it has more valence
electrons so it is harder for it to become a positive ion.
Reactions of Metals:
The reactivity series of metals was deduced by performing several experiments in
the lab which enabled scientists to arrange metals according to their reactivity with
dilute acid, oxygen (air), and water.
Reactions with Dilute Hydrochloric Acid:
In the previous chapter, you studied those reactions involving a metal and an acid are used to prepare
soluble salts and that this method is only suitable for preparing salts of moderately reactive metals
(MAZIT). This is because any metal more reactive that magnesium will react very violently with acids
which is dangerous.
Metal + HCl → Metal Chloride + Hydrogen
The photo on the right shows magnesium reacting with dilute hydrochloric acid. Those
effervescences are caused by the evolution of hydrogen gas, which is a product in this
reaction. This reaction was repeated using the other metals of the reactivity series. The
rate of evolution of hydrogen gas in each experiment was measured. The metals were
arranged in order of reactivity starting with the most reactive metal which had the highest
rate of effervescence of hydrogen gas. The rate of effervescence is also the rate of this
reaction is measured by measuring the volume of hydrogen produced per unit time.
Metals Reactivity with Dilute HCl
React extremely violently with rapid effervescence and
Potassium, Sodium & Calcium
splashing
Magnesium & Aluminum React violently with rapid effervescence
Zinc, Iron & Lead React slowly with bubbles
Copper, Silver, Gold &
Do not react
Platinum

Reactions with Oxygen in Air:

Most metals react with oxygen from air forming a metal oxide. You have previously studied that metal
oxides are basic oxides and that some of them are insoluble in water and some of them are soluble in
water forming an alkaline solution. The most reactive metals like potassium, sodium, calcium and
magnesium react with oxygen with a very bright flame and producing white ashes and their oxides are
soluble. Moderately reactive metals like aluminum and zinc react with oxygen forming white powdered
ashes but their oxides are insoluble. Iron and copper react very slowly with oxygen. The result of iron
oxygen reactions is rust which is reddish brown iron oxide. When a copper lump reacts with oxygen, a
white layer of black copper oxide forms on it. When the lump gets covered by this layer; the reaction
stops. Oxides of iron and copper are insoluble. Metals that are less reactive than copper like silver, gold
and platinum do not react with oxygen.

Note: When aluminum reacts with oxygen, a layer of aluminum oxide adheres and covers the aluminum.
At this point no further reaction can take place.

Reactions of Metals with Water and Steam:

Some metals are so reactive that they will just react with water immediately if they come in contact.
Other metals will react slowly will cold water, but with steam they react much faster. And other metals
can only react slowly with steam. Unreactive metals such as silver and gold do not react with water.
Potassium, sodium and calcium react vigorously with cold water and may catch on fire. The products of
these reactions are metal hydroxide and hydrogen gas. If hydrogen gas being produced accumulates it
may ignite and cause an explosion.
Metal + Water → Metal hydroxide + Hydrogen
E.g.: 2Na + 2H2O → 2NaOH + H2
Magnesium, aluminum, zinc and iron are less reactive. They react with steam forming metal oxide and
hydrogen. Magnesium and aluminum will react vigorously with steam while zinc and iron react slowly.
Metal + Steam → Metal Oxide + Hydrogen
E.g.: Magnesium + Steam → Magnesium oxide + Hydrogen

Competition Reactions in Solid State:

Previously you’ve studied displacement reactions which are pre-formed in aqueous states. A very similar
reaction takes place in the solid state, it is called thermite reaction. This reaction is used to repair
damaged railway lines. In this reaction, aluminum and iron (III) oxide are the reactants. In the reaction,
aluminum removes the oxygen ion from iron and bonds with it. This happens because aluminum is more
reactive than iron. The products are aluminum oxide and iron in molten form. In the fixing procedure,
the reactants are put in the cut in the railway line and the reaction is triggered by heating using a
magnesium fuse. The reaction leaves aluminum oxide and molten iron with then condenses in the cut
welding it. Like displacement reactions, this reaction is exothermic.
2Al + Fe2O3 → Al2O3 +2Fe

Competition Reactions in Aqueous State:

These are ordinary displacement reactions in which the two positive ions compete for the negative ion.
The ion of the more reactive metal wins. Zinc is higher than copper in the reactivity series. If zinc is
added to a solution of copper nitrate, a displacement reaction will take place in which the zinc will
displace the copper ion from the solution in its salt. The products of this reaction are zinc nitrate and
copper. Copper salt solutions have a blue color which fades away as the reaction proceeds because the
concentration of the copper salt decreases. This type of reaction also helped in confirming reactivity of
metals since the more reactive metal displaces the less reactive one.
Zn + Cu(NO3)2 → Zn(NO3)2 + Cu

Action of Heat on Metal Compounds:

Applying heat to a metal compound such as potassium nitrate will cause it to decompose into potassium
nitrite and oxygen. This is a thermal decomposition reaction.

Anion:
Metal:
Nitrate (NO3) Carbonate (CO3) Hydroxide (OH)
Potassium Metal Nitrate → Metal nitrite +
NO DECOMPOSITION
Sodium Oxygen
Calcium Metal Nitrate → Metal oxide + Metal Carbonate → Metal Metal hydroxide →Metal
Magnesium Nitrogen dioxide + Oxygen oxide + Carbon dioxide oxide + Hydrogen
Aluminum
Zinc
Iron
Lead
 Copper

Metal Nitrate → Metal + Metal Carbonate → Metal +

-
Silver
Gold Nitrogen dioxide + Oxygen Carbon dioxide + Oxygen

Silver and gold hydroxides do not exist.

Ions of more reactive metals tend to hold on tightly to their anions and do not decompose easily this is
why lots of heat is needed.

Extracting Metals From Their Ores:

Most metals do not exist in nature as pure elements. Instead, they are found as naturally occurring
compounds called ores. Ores are naturally occurring minerals from which a metal can be extracted. Most
ores are metals oxide, carbonate or sulfide mixed with other impurities. The extraction of metal from
ores begun long ago when people started purifying iron from its iron oxide ore by reducing it using
charcoal. This was possible because carbon is more reactive than iron so it can reduce it take the oxygen
ion from it. But then other metals were discovered which were higher than carbon in the reactivity
series. Those metals were not possibly extracted from their ores until in the 19th century when a
method of extracting them by electrolysis was invented. The method extracting a metal depends on its
reactivity.

Metals - in decreasing order of reactivity Reactivity

 potassium
 sodium
 calcium Extract by electrolysis
 magnesium
 aluminium
  carbon
 zinc
 iron
Extract by reaction with carbon or carbon monoxide
 tin
 lead
 hydrogen
 copper
 silver
Extracted by various chemical reactions
 gold
 platinum

Extraction of Aluminum: (Pure Science)

Aluminum exists naturally as aluminum oxide (alumina) in its ore, which is called bauxite. Because
aluminum is a very reactive metal, it holds on very tightly to the anion it bonds with, which is oxide in
this case. This is why the best way to extract and purify aluminum is by electrolysis in a cell like the one
below.

In this cell, the electrodes are made of graphite (Carbon). The cathode is a layer at the bottom of the cell
and the anodes are bars dipped in the electrolyte. The electrolyte in this process is a molten mixture of
aluminum oxide and cryolite. Aluminum oxide by its self has a very high melting point of 2050oC which is
higher than the melting point of the steel container in which this process is done. That means the steel
container will melt before the aluminum oxide. This is why aluminum oxide is mixed with cryolite which
decreases the melting point of it to under 1000oC, thus saving a lot of money because heating is
expensive and preventing the steel container from melting. Heat must be continuously supplied to the
mixture to keep it molten. Aluminum oxide does not conduct electricity when solid because it does not
have free mobile ions to carry the charge.

• Aluminum oxide is purified from impurities of oxide by adding sodium hydroxide

• Aluminum oxide is mixed with cryolite and put in the electrolysis cell
• Heat is given in until the mixture becomes molten
• Electrolysis start
• Oxide ions get attracted to the anode and discharged (oxidation); 2O2-, 4e → O2
• Aluminum ions get attracted to the cathode and discharged and settle at the bottom
 of the container (reduction); Al3+ + 3e → Al
• Oxygen gas evolves and is collected with waste gases
• Aluminum is sucked out of the container at regular intervals
Oxygen gas which evolves reacts with carbon from the cathode forming CO2. The cathode gets worn
away. To solve this, the cathode is replaced at regular intervals. Heat supply is very expensive; this is why
cryolite is used to decrease the melting point of aluminum oxide and this process is done in plants which
use hydroelectric energy because it is cheap.

Uses of aluminum:
• Construction of air-craft bodies because aluminum is very strong and very light and it is resistant
to corrosion
• Food containers because it is resistant to corrosion
• Overhead power cables because it conducts electricity, is very light, malleable and ductile.
Although it is strengthened with steel core

Extraction of Iron: (All Sciences)

The ore of iron is called hematite. It consists of 60% iron in form of Iron oxide (Fe2O3) with other
impurities such as silicon
oxide (SiO2). This process takes place in a tower called a Blast furnace.
Substances Products and Waste Materials
 Iron ore (Hematite)  Pure Iron
 Coke (heated coal)  Carbon dioxide
 Lime stone (Calcium carbonate)  Air
 Hot Air  Slag (Calcium silicate)
• Substances are put in the blast furnace
• The process starts by blowing in hot air at the bottom of the furnace
• Coke burns in oxygen from the hot air producing carbon dioxide; C + O2 → CO2
• Heat makes lime stone decompose into calcium oxide and carbon dioxide; CaCO3 → CaO + CO2

carbon monoxide; CO2 + C → 2CO

• Carbon dioxide produced goes up the furnace and reacts with more coke up there producing

and starts reducing it producing iron and carbon dioxide; Fe2O3 + 3CO → 2Fe + 3CO2
• Carbon monoxide is a reducing agent. It rises further up the furnace where it meets iron oxide

• Calcium oxide which was produced from the thermal decomposition of lime stone is a base. It

which is called slag; CaO + SiO2 → CaSiO3

reacts with impurities of hematite such as silicon oxide which is acidic forming calcium silicate
• Molten Iron and slag produced trickles down and settles at the bottom of the furnace. Iron is
denser than slag so it settles beneath it.
Iron and slag are tapped off separately at regular intervals and pure iron is collected alone
• Waste gases such as carbon dioxide formed in the process and nitrogen and other gases from air
blown in escape at the top of the furnace.

Conversion of Iron into Steel:

Iron produced in the blast furnace is called pig iron. It contains 4% carbon as well as other impurities
such as sulfur, silicon and phosphorus which make it hard and brittle. It got that name from the fact that
it has to be poured into mould called pigs before it is converted into steel. Most of produced iron is
converted into steel because steel has better properties.
Making steel out of pig iron is a process done in a basic oxygen furnace:
• Molten pig iron is poured into the oxygen furnace
• A water cooled lance is introduced which blows oxygen onto the surface of the molten iron
• Impurities start to react
• Carbon is oxidized into carbon monoxide and carbon dioxide and escape
• Sulfur is oxidized into sulfur dioxide and escapes
• Silicon and phosphorus are oxidized into silicon oxide and phosphorus pentoxide which are
solids.
• Calcium oxide (lime) is added to remove the solid impurities as slag which is skimmed off the
surface
• Throughout the process, sample of the iron are being taken and analyzed for the percentage of
carbon present in it. When the percentage of carbon desired is reached, the furnace is switched
off and the steel is collected.

There are many different forms of steel. Each has different components and properties and is used for
different purposes.
Steel Composition Properties Uses
Car bodies
99.5% Iron
Mild Steel Easily worked lost brittleness large structures
0.5% Carbon
Machinery
99% Iron
Hard Steel Tough and brittle Cutting tools and chisels
1% Carbon
87% Iron Drill bits and springs and chemical
Stainless Steel Tough and springy
13% Manganese plants
Manganese 74% Iron Tough and resistant to corrosion Cutlery and surgical tools, kitchen
Steel 18% Chromium
 8% Nickel sinks
95% Iron Tough and hard even at high
Tungsten Steel Edges of high speed cutting tools
5% Tungsten temperatures

Extraction of Zinc:
The ore of zinc is called zinc blende and it is made of zinc sulfide. Zinc is obtained from zinc sulfide by
converting it into zinc oxide then reducing it using coke, but first zinc sulfide must be concentrated.
Zinc sulfide from zinc blende is concentrated by a process called froth floatation. In this process, the ore
is crushed and put into tanks of water containing a frothing agent which makes the mixture froth up. Hot
air is blown in and froth starts to form. Rock impurities in the ore get soaked and sink to the bottom of
the tank. Zinc sulfide particles cannot be soaked by water; they are lifted by the bubbles of air up with
the froth and are then skimmed off. This is now concentrated zinc sulfide.
Then, zinc sulfide gets heated very strongly with hot air in a furnace. Zinc sulfide reacts with oxygen from
the air to produce zinc oxide and sulfur dioxide gas which escapes as waste gas.
2ZnS + 3O2 → 2ZnO + 2SO2
Sulfur dioxide is used in the manufacture of sulfuric acid.
Zinc oxide produced is put into a furnace with powdered coke. The mixture is heated till 1400oC. Carbon
from the coke reduces the zinc oxide into zinc producing carbon monoxide which escapes as waste gas.
ZnO + C → Zn + CO
Carbon monoxide produced is hot and is used to heat the furnace to reduce heating costs. The pure zinc
produced is collected and left to cool down. Zinc is used in many ways like the production of the alloy
brass, galvanization and making car batteries.

Extraction of Copper:
Copper is one of the most popular metals. Native copper occurs in some regions in the world. Otherwise,
copper exists in its ore, copper pyrites (2CuFeS2). You have studied before that copper can be purified by
electrolysis. It can also be extracted from it ore by converting pyrites into copper sulfide by reacting it
with oxygen:
2CuFeS2 + 4O2 → Cu2S + 3SO2 + 2FeO
Sulfur oxide produced escapes as waste gas and iron oxide impurities are removed by heating the
mixture with silicon converting it in to iron silicate which is run off. The remaining copper sulfide is then
heated strongly with air. Copper sulfide reacts with oxygen from air producing sulfur oxide which escapes
as waste gas and pure copper.
Cu2S + O2 → 2Cu + SO2
Thus copper is extracted.

Uses of Copper:
• In electrical wires because it is a perfect electrical conductor and very ductile, malleable and
cheap
• Making alloys such as bronze and brass
• Cooking utensils because it conducts heat and it is has high melting and boiling points and also
resists corrosion
• Electrodes because it is a good conductor of electricity
• Water pipes because it is resistant to corrosion