EXERCISE # O-I
Single correct :
1. The boiling point of C6H6, CH3OH, C6H5NH2 and C6H5NO2 are 800C, 650C, 1840C and 2120C
respectively which will show highest vapour pressure at room temperature :
(A) C6H6 (B) CH3OH (C) C6H5NH2 (D) C6H5NO2
2. Mole fraction of A vapours above the solution in mixture of A and B (XA = 0.4) will be
[Given : PAq = 100 mm Hg and PBq = 200 mm Hg]
(A) 0.4 (B) 0.8 (C) 0.25 (D) none of these
3. At a given temperature, total vapour pressure in Torr of a mixture of volatile components A and B
is given by
PTotal = 120 – 75 XB
hence, vapour pressure of pure A and B respectively (in Torr) are
(A) 120, 75 (B) 120, 195 (C) 120, 45 (D) 75, 45
4. Two liquids A & B form an ideal solution. What is the vapour pressure of solution containing 2 moles
of A and 3 moles of B at 300 K? [Given : At 300 K, Vapour pr. of pure liquid A ( PAo ) = 100 torr,
Vapour pr. of pure liquid B ( PBo ) = 300 torr ]
(A) 200 torr (B) 140 torr (C) 180 torr (D) None of these
5. If Raoult's law is obeyed, the vapour pressure of the solvent in a solution is directly proportional to
(A) Mole fraction of the solvent (B) Mole fraction of the solute
(C) Mole fraction of the solvent and solute (D) The volume of the solution
6. 1 mole of heptane (V. P. = 92 mm of Hg) was mixed with 4 moles of octane (V. P. = 31mm of Hg).
The vapour pressure of resulting ideal solution is :
(A) 46.2 mm of Hg (B) 40.0 mm of Hg (C) 43.2 mm of Hg (D) 38.4 mm of Hg
7. Mole fraction of A vapours above solution in mixture of A and B (XA = 0.4) will be :-
(PA° = 100mm, PB° = 200mm)
(A) 0.4 (B) 0.8 (C) 0.25 (D) None
8. The vapour pressure of a pure liquid 'A' is 70 torr at 270C. It forms an ideal solution with another
liquid B. The mole fraction of B is 0.2 and total vapour pressure of the solution is 84 torr at 270C.
The vapour pressure of pure liquid B at 270C is
(A) 14 (B) 56 (C) 140 (D) 70
9. At 88 °C benzene has a vapour pressure of 900 torr and toluene has a vapour pressure of 360 torr.
What is the mole fraction of benzene in the mixture with toluene that will boil at 88 °C at 1 atm. pressure,
benzene - toluence form an ideal solution:
(A) 0.416 (B) 0.588 (C) 0.688 (D) 0.740
10. The exact mathematical expression of Raoult’s law is (n = moles of solute ; N=
moles of solvent)
P 0 Ps n P 0 Ps N P 0 Ps n P 0 Ps
(A) (B) (C) (D) =n×N
P0 N P0 n Ps N P0
11. The vapour pressure of a solvent decreased by 10 mm of Hg when a non-volatile solute was added
to the solvent. The mole fraction of solute in solution is 0.2, what would be mole fraction of the solvent
if decrease in vapour pressure is 20 mm of Hg
(A) 0.2 (B) 0.4 (C) 0.6 (D) 0.8
12. The vapour pressure of a solution having solid as solute and liquid as solvent is :
(A) Directly proportional to mole fraction of the solvent
(B) Inversely proportional to mole fraction of the solvent
(C) Directly proportional to mole fraction of the solute
(D) Inversely propartional to mole fraction of the solute
13. One mole of non volatile solute is dissolved in two moles of water. The vapour pressure of the solution
relative to that of water is
2 1 1 3
(A) (B) (C) (D)
3 3 2 2
14. The vapour pressure of pure A is 10 torr and at the same temperature when 1 g of B is dissolved in
20 gm of A, its vapour pressure is reduced to 9.0 torr. If the molecular mass of A is 200 amu, then
the molecular mass of B is :
(A) 100 amu (B) 90 amu (C) 75 amu (D) 120 amu
15. The vapour pressure of a pure liquid solvent (X) is decreased to 0.60 atm. from 0.80 atm on addition
of a non volatile substance (Y). The mole fraction of (Y) in the solution is:-
(A) 0.20 (B) 0.25 (C) 0.5 (D) 0.75
16. Among the following, that does not form an ideal solution is :
(A) C6H6 and C6H5CH3 (B) C2H5Cl and C6H5OH
(C) C6H5Cl and C6H5Br (D) C2H5Br and C2H5I
17. Colligative properties of the solution depend upon
(A) Nature of the solution (B) Nature of the solvent
(C) Number of solute particles (D) Number of moles of solvent
18. Elevation of boiling point of 1 molar aqueous glucose solution (density = 1.2 g/ml) is
(A) Kb (B) 1.20 Kb (C) 1.02 Kb (D) 0.98 Kb
19. When common salt is dissolved in water
(A) Melting point of the solution increases (B) Boiling point of the solution increases
(C) Boiling point of the solution decreases (D) Both Melting point and Boiling point is decreases
20. What should be the freezing point of aqueous solution containing 17 gm of C2H5OH in 1000 gm of
water (water Kƒ = 1.86 deg – kg mol–1)
(A) – 0.69°C (B) – 0.34°C (C) 0.0°C (D) 0.34°C
21. If mole fraction of the solvent in solution decreases then :
(A) Vapour pressure of solution increases (B) B. P. decreases
(C) Osmotic pressure increases (D) All are correct
22. 5% (w/v) solution of sucrose is isotonic with 1% (w/v) solution of a compound 'A' then the molecular
weight of compound 'A' is -
(A) 32.4 (B) 68.4 (C) 121.6 (D) 34.2
23. Osmotic pressure of a sugar solution at 240C is 2.5 atmosphere. The concentration of the solution
in mole per litre is :
(A) 10.25 (B) 1.025 (C) 1025 (D) 0.1025
24. A solution containing 4 g of a non volatile organic solute per 100 ml was found to have an osmotic
pressure equal to 500 cm of mercury at 270C. The molecular weight of solute is :
(A) 14.97 (B) 149.7 (C) 1697 (D) 1.497
25. If a 6.84% (wt. / vol.) solution of cane-sugar (mol. wt. 342) is isotonic with 1.52% (wt./vol.) solution
of thiocarbamide, then the molecular wight of thiocarbamide is :
(A) 152 (B) 76 (C) 60 (D) 180
26. Which of the following aqueous solution will show maximum vapour pressure at 300 K?
(A) 1 M NaCl (B) 1 M CaCl2 (C) 1 M AlCl3 (D) 1 M C12H22O11
27. The correct relationship between the boiling points of very dilute solution of AlCl3 (T1K) and
CaCl2 (T2K) having the same molar concentration is
(A) T1 = T2 (B) T1 > T2 (C) T2 > T1 (D) T2 d T1
28. 1.0 molal aqueous solution of an electrolyte A2B3 is 60% ionised. The boiling point of the solution
at 1 atm is ( K b( H 2O) 0.52 K kg mol 1 )
(A) 274.76 K (B) 377 K (C) 376.4 K (D) 374.76 K
29. The freezing point depression of a 0.1 M a solution of weak acid (HX) is –0.20°C.
What is the value of equilibrium constant for the reaction?
HX (aq) P H +(aq) + X¯ (aq)
[Given : Kf for water = 1.8 kg mol–1 K. & Molality = Molarity]
(A) 1.46×10–4 (B) 1.35 × 10–3 (C) 1.21 × 10–2 (D) 1.35 × 10–4
30. The Vant Hoff factor (i) for a dilute solution of K3[Fe(CN)6] is (Asuming 100% ionsation) :
(A) 10 (B) 4 (C) 5 (D) 0.25
31. The substance A when dissolved in solvent B shows the molecular mass corresponding to A3. The
vant Hoff's factor will be -
(A) 1 (B) 2 (C) 3 (D) 1/3
32. The value of observed and calcutated molecular wieght of silver nitrate are 92.64 and 170 respectively.
The degree of dissociation of silver nitrate is :
(A) 60% (B) 83.5 % (C) 46.7% (D) 60.23%
33. The freezing point of 1 molal NaCl solution assuming NaCl to be 100% dissociated in water is :
(Kf = 1.86 K Molality–1)
(A) –1.86 °C (B) –3.72 °C (C) +1.86 °C (D) + 3.72 °C
34. What is the freezing point of a solution containing 8.1 gm. of HBr in 100gm. water assuming the
acid to be 90% ionised (Kf for water=1.86 K molality–1) :-
(A) 0.85°C (B) –3.53°C (C) 0°C (D) –0.35°C
35. If a ground water contains H2S at concentration of 2 mg/l, determine the pressure of H2S in head
space of a closed tank containing the ground water at 20ºC. Given that for H2S, Henry's constant is
equal to 6.8 × 103 bar at 20ºC.
(A) 720 Pa (B) 77 × 102 Pa (C) 553 Pa (D) 55 × 102 Pa
36. A pressure cooker reduces cooking time for food because -
(A) The higher pressure inside the cooker crushes the food material
(B) Cooking involves chemical changes helped by a rise in temperature
(C) Heat is more evenly distributed in the cooking space
(D) Boiling point of water involved in cooking is increased
EXERCISE # O-II
Single correct :
1. An ideal solution was obtained by mixing (MeOH) methanol and (EtOH) ethanol. If the partial
vapour pressure of methanol and ethanol are 2.619 K Pa and 4.556 K Pa respectively, the
composition of vapour (in terms of mole fraction) will be -
(A) 0.635 MeOH, 0.365 EtOH (B) 0.365 MeOH, 0.635 EtOH
(C) 0.574 MeOH, 0.326 EtOH (D) 0.173 MeOH, 0.827 EtOH
2. Molar volume of liquid A(d = 0.8gm/ml) increase by factor of 2000 when it vapourises at 200K.
Vapour pressure of liquid A at 200K is [R = 0.08 L-atm/mol-K]
(Molar mass of A = 80g/mol)
(A) 0.4 atm (B) 8 atm (C) 0.8 atm (D) 0.08 atm
3. Assuming each salt to be 90 % dissociated, which of the following will have highest boiling point?
(A) Decimolar Al2(SO4)3
(B) Decimolar BaCl2
(C) Decimolar Na2SO4
(D) A solution obtained by mixing equal volumes of (B) and (C)
4. The vapour pressure of a saturated solution of sparingly soluble salt (XCl3) was 17.20 mm Hg at 27°C.
If the vapour pressure of pure H2O is 17.25 mm Hg at 300 K, what is the solubility of sparingly soluble
salt XCl3 in mole/Litre.
(A) 4.04 × 10–2 (B) 8.08 ×10–2 (C) 2.02 × 10–2 (D) 4.04 × 10–3
5. A solution has a 1 : 4 mole ratio of pentane to hexane. The vapour pressures of the pure hydrocarbons
at 20°C are 440 mmHg for pentane and 120 mmHg for hexane. The mole fraction of pentane in the
vapour phase would be :-
(A) 0.200 (B) 0.478 (C) 0.549 (D) 0.786
6. For which of the following vant' Hoff's factor is not correctly matched -
Salt D)
Degree of dissociation (D i
(A) Na2SO4 50 % 2
(B) K3[Fe(CN)6] 75% 3.25
(C) [Ag(NH3)2]Cl 80 % 1.8
(D) [Cr(NH3)5Cl]SO4 90 % 2.8
7. In the depression of freezing point experiment, it is found that
(I) The vapour pressure of the solution is less than that of pure solvent.
(II) The vapour pressure of the solution is more than that of pure solvent.
(III) Only solute molecules solidify at the freezing point.
(IV) Only solvent molecules solidify at the freezing point.
(A) I, II (B) II, III (C) I, IV (D) I, II, III
8. Statement-1 :Additon of ethylene glycol (non-volatile) to water lowers the freezing point of water
hence used as antifreeze.
Statement-2 : Addition of any substance to water lowers its freezings point of water.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.
More than one may be correct
9. For an ideal solution having two liquid A( PA0 and liquid B( PB0 ) boiling point versus composition
graph is given below, then select incorrect statement (s) :
Vapour 400K
TB p
Va
q
Li
350K
300K
Liquid
0.1 0.5 0.6
0.4
xB
yB
(A) B is less volatile than A
(B) If mole percent of A in liquid phase is 40% then mole percent of A in vapour phase is 50%
(C) If mole percent of B in liquid phase is 10% then mole percent of B in vapour phase is 40%
(D) If the mole percent of A in solution is 50% then its boiling point is 350K
10 A liquid mixture having composition corresponding to point z in the figure shown is subjected to
distillation at constant pressure.
Which of the following statement is correct about the process
(A) The composition of distillate differs from the mixture
(B) The boiling point goes on changing
(C) The mixture has lowest vapour pressure than for any other composition.
(D) Composition of an azeotrope alters on changing the external pressure.
11. Which of the following is correct for a non-ideal solution of liquids A and B, showing negative
deviation?
(A) 'Hmix = –ve (B) 'Vmix = –ve
(C) 'Smix = +ve (D) 'Gmix = –ve
12. Two solutions S1 and S2 containing 0.1M NaCl(aq.) and 0.08M BaCl2(aq.) are separated by
semipermeable membrane. Which among the following statement(s) is/are correct -
(A) S1 and S2 are isotonic
(B) S1 is hypertonic and S2 is hypotonic S1 S2
(C) S1 is hypotonic and S2 is hypertonic 0.1M NaCl 0.08M BaCl2
(D) Osmosis will take place to from S1 to S2
SPM
13. For an ideal binary liquid solution with PAq > PBq , which relation between XA (mole fraction of A in
liquid phase) and YA(mole fraction of A in vapour phase) is correct?
YA X A YA X A
(A) YA < YB (B) XA > XB (C) Y ! X (D) Y X
B B B B
14. Which of the following plots represents an ideal binary mixture?
(A) Plot of Ptotal v/s 1/XB is linear (XB = mole fraction of 'B' in liquid phase).
(B) Plot of Ptotal v/s YA is linear (YB = mole fraction of 'A' in vapour phase)
1
(C) Plot of P v/s YA is linear
total
1
(D) Plot of P v/s YB is non linear
total
Paragraph for Q.15 to Q.17
An ideal solution is obtained by mixing a non-volatile solute B with a volatile solvent A (molar mass
= 60). If the mass ratio of A : B in solution is 10 : 1 and vapour pressure of pure A is 400 mm and
vapour pressure decreases by 4% on forming the above solution at 300K.
15. The mole fraction of solute in the solution is -
(A) 0.96 (B) 0.04 (C) 0.16 (D) 0.84
16. The molality the solution is -
36 25 36
(A) 1 (B) (C) (D)
25 36 25
17. The molar mass of B in the solution is -
(A) 1440 (B) 14400 (C) 4 (D) 144
Table type question :
Column-I Column-II Column-III
(1) C6H6 + C6H5–CH3 (a) DH = 0 (P) DG = –ve
(2) CHCl3 + CH3COCH3 (b) DH = +ve (Q) Form minimum boiling
azerotrope
(3) CCl4 + CH3COCH3 (c) DH = –ve (R) Form maximum boiling
azerotrope
(4) C2H5OH + H2O (d) DS = +ve (S) No azeotrope
18. Select the correct match -
(A) 1 , a, R (B) 2, b, P (C) 3, b, Q (D) 4, d, R
19. Select the correct match -
(A) 1 , d, S (B) 3, b, S (C) 2, b, S (D) 4, c, P
20. Select the incorrect match -
(A) 1 , d, P (B) 2, c, R (C) 3, d, S (D) 3, b, P
Match the column :
21. Column–I Column–II
(Colligative properties) (Aqueous solution)
(Assume m = M)
(A) 'Tf = 0.3 × Kf (P) 0.1 m – Ca(NO3)2
(B) 'Tb = 0.28 × Kb (Q) 0.14 m – NaBr
(C) S = 0.19 × RT (R) 0.1 m – MgCl2(D = 0.9)
§ 'Tf ·
P P
0 ¨K ¸
(D)
© f ¹ (S) 0.28 m – Urea
P0 § 1000 · § 'Tf ·
¨ ¸
© 18 ¹ ¨© K f ¸¹
(T) 0.1 m – HA (monobasic acid, Ka = 0.81)
