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ARJUNA JEE 2.0 - 2023: General Organic Chemistry

The document is a question set focused on General Organic Chemistry, specifically addressing the stability of various organic compounds including free radicals, carbanions, and carbocations. It includes multiple-choice questions that require the arrangement of stability orders and identification of the most stable species among given options. An answer key is provided at the end for reference.

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34 views3 pages

ARJUNA JEE 2.0 - 2023: General Organic Chemistry

The document is a question set focused on General Organic Chemistry, specifically addressing the stability of various organic compounds including free radicals, carbanions, and carbocations. It includes multiple-choice questions that require the arrangement of stability orders and identification of the most stable species among given options. An answer key is provided at the end for reference.

Uploaded by

rcicollegebansur
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© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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1

ARJUNA JEE 2.0 - 2023


General Organic Chemistry DPP-06

1. The mesmeric effects of the groups 5. Which free radical is the most stable:

(1) C6 H 5  CH 2

(2) CH 2  CH  CH 2
(1) + M, – M, – M, + M 
(2) + M, –M, + M, – M (3) CH3  CH  CH3
(3) – M, – M, + M, + M 

(4) + M, + M, – M, – M (4) CH3  C CH3


|
CH3
2. Arrange in order of stability

6. C H3 is less stable than

(1) CH3 — C H 2

(2) CH3 — C H — CH3
(1) 1 > II > III > IV

(2) I > II > IV > III (3) C H 2 — NO 2
(3) III > II > I > IV 
(4) IV > III > II > I (4) CH3 — C H — C2 H5

3. Arrange following carbanions in the stability order: 7. Which of the following options is the correct order
Θ Θ of relative stabilities of cations, I, II and III written
CH CH2
(a) (b) below (most stable first)?
+
CH2
Θ (I)
CH2 – CH2
(c) (d) CH2 = CH – CH2Θ 
(II) H 2 C  CH  CH 2  CH  CH 3
(1) d > c > a > b (2) b > a > c > d CH 3
(3) a > b > d > c (4) c > a > b > d | 
(III) H 3C  C  CH 2
4. Which carbon cation is the most stable: |
CH 3
 
CH2 CH2 (1) I > II > III (2) II > III > I
(3) III > I > II (4) I > III > II
(1) (2)
8. The correct order of stability of given carbanions
will be
CH3 OH

  (I) CH3 — C H 2
CH2 CH2 
(II) CH 2  C H
(3) (4) 
(III) HC  C
Cl NO2 (1) I > II > III (2) III > II > I
(3) I > III > II (4) II > I > III
2

9. The most stable carbanion among the following is 12. The carbocation which is most stable is

(1)
(1) (2)

(2)

(3) (3) (4)

13. Which of the following radical is most stable?



(1) C6 H5 — C H 2
(4)

(2) CH 2  CH — C H 2

10. Most stable carbocation is (3) CH3 — C H — CH3

(4) CH3 — C— CH3
|
CH3
(1) (2)
14. Arrange the following cation in increasing order of
stability

(a) (b)
(3) (4)

11. Consider the following carbocations

(a)
(c)
(b)

(c) (1) a < b < c (2) a < c < b


(3) c < a < b (4) c < b < a

(d) CH3 — C H 2
The relative stabilities of these carbocations are such
that
(1) d<b<c<a (2) b < d < c < a
(3) d<b<a<c (4) b < d < a < c
3

Note: Kindly find the Video Solution of DPPs Questions in the DPPs Section.

Answer Key
1. (2)
2. (4)
3. (3)
4. (2)
5. (1)
6. (3)
7. (1)
8. (2)
9. (4)
10. (1)
11. (1)
12. (2)
13. (1)
14. (4)

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