Atomic Structure & Nuclear Chemistry
Marked questions are recommended for Revision.
This Section is not meant for classroom discussion. It is being given to promote self-
study and self testing amongst the Resonance students.
PART - I : PRACTICE TEST-1 (IIT-JEE (MAIN Pattern))
Max. Marks: 100 Max. Time : 1 Hour
Important Instructions:
A. General %
1. The test paper is of 1 hour duration.
2. The Test Paper consists of 25 questions and each questions carries 4 Marks. Test Paper consists of
Two Sections.
B. Test Paper Format and its Marking Scheme:
1. Section-1 contains 20 multiple choice questions. Each question has four choices (1), (2), (3) and (4) out
of which ONE is correct. For each question in Section-1, you will be awarded 4 marks if you give the
corresponding to the correct answer and zero mark if no given answers. In all other cases, minus one
(–1) mark will be awarded.
2. Section-2 contains 5 questions. The answer to each of the question is a Numerical Value. For each
question in Section-2, you will be awarded 4 marks if you give the corresponding to the correct
answer and zero mark if no given answers. No negative marks will be answered for incorrect
answer in this section. In this section answer to each question is NUMERICAL VALUE with two digit
integer and decimal upto two digit. If the numerical value has more than two decimal places
truncate/round-off the value to TWO decimal placed.
SECTION-1
This section contains 20 multiple choice questions. Each questions has four choices (1), (2), (3) and (4)
out of which Only ONE option is correct.
1. A 5 g orbital has
(1) Zero angular node and zero radial node (2) Zero radial node and two angular nodes
(3) 4 radial nodes and 4 angular nodes (4) Zero radial node and 4 angular nodes
2. Calculate the number of photons emitted by a 100 W yellow lamp in 1.0 s. Take the wavelength of
yellow light as 560 nm and assume 100 percent efficiency.
(1) 6.8 × 1020 (2) 4 × 1012 (3) 4 × 1020 (4) 2.8 × 1020
3. In a photoelectric experiment, kinetic energy of photoelectrons was plotted against the frequency of
incident radiation (), as shown in figure. Which of the following statements is correct?
(1) The threshold frequency is 1.
(2) The slope of this line is equal to Plank’s constant.
(3) As the frequency of incident wavelength increases beyond threshold frequency, kinetic energy of
photoelectrons decreases.
(4) It is impossible to obtain such a graph.
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Atomic Structure & Nuclear Chemistry
4. Which of the following process not lead to formation of isobars ?
(1) 1 particle and 2 particles are emitted (2) Positron emission
(3) particle (–1e ) emission
0
(4) K-electron capture
5. In what region of the electromagnetic spectrum would you look for the spectral line resulting from the
electronic transition from the tenth to the fifth electronic level in the hydrogen atoms? (RH = 1.10 × 105
cm–1)
(1) Microwave (2) Infrared (3) Visible (4) Ultraviolet
6. Consider Xenon (Z = 54). The maximum number of electrons in this atom that can have the values for
1
their quantum numbers as n = 4, = 3 and s = in its ground state is :
2
(1) Zero (2) 7 (3) 9 (4) 14
7. The increasing order for the values of e/m (charge/mass) is :
(1) e, p, n, (2) n, p, e, (3) e, , e (4) n, , p, e
x
8. An electron in an atom jumps in such a way that its kinetic energy changes from x to . The change in
4
potential energy will be :
3 3 3 3
(1) + x (2) x (3) x (4) x
2 8 4 4
1
9. Select the incorrect graph for velocity of e– in an orbit VS. Z, and n :
n
(1) (2) (3) (4)
10. The mass of a proton is 1836 times more than the mass of an electron. If electron in a H atom is
replaced by a sub-atomic particle of mass (m’) 207 times the mass of electron and same charge as that
of electron, then the first ionization potential of H :
(1) decreases (2) increases
(3) remains same (4) may be decrease or increase
11. Which quantum number defines the orientation of orbital in the space around the nucleus ?
(1) Principal quantum number (n) (2) Angular momentum quantum number
(3) Magnetic quantum number (m) (4) Spin quantum number (ms)
12. For similar orbitals having different values of n :
(1) the most probable distance increases with increase in n
(2) the most probable distance decreases with increase in n
(3) the most probable distance remains constant with increase in n
(4) none of these
13. The possible set of quantum no. for the unpaired electron of chlorine is :
n m n m
(1) 2 1 0 (2) 2 1 1
(3) 3 1 1 (4) 3 0 0
14. Which of the following has the maximum number of unpaired electrons ?
(1) Mn (2) Ti (3) V (4) Al
15. The angular velocity of an electron occupying the second Bohr orbit of He+ ion is (in sec–):
(1) 2.067 × 1016 (2) 3.067 × 1016 (3) 1.067 × 1018 (4) 2.067 × 1017
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Atomic Structure & Nuclear Chemistry
16. An excited state of H-atom emits a photon of wavelength and returns in the ground state, the principal
quantum number of excited state is given by :
R ( R 1)
(1) R(R 1) (2) (3) R(R 1) (4)
(R 1) R
17. Light of wavelength strikes a metal surface with intensity X and the metal emits Y electrons per
second of average energy Z. What willl happen to Y and Z if X is havled?
(1) Y will be halved (2) Y will double
(3) Y will be remain same (4) Z will be halved
18. The nucleus of an atom is located at x = y = z = 0. If the probability of finding an electron in dx2 y2
orbital in a tiny volume around x = a, y = 0, z = 0 is 1 × 10–5, what is the probablility of finding the
electron in the same size volume around x = 0, y = a, z = 0 ?
(1) 1 × 10–5 (2) 1 ×10–5 × a (3) –1 × 10–5 × a (4) zero
4E
19. The energy of a I, II and III energy levels of a certain atom are E, and 2E respectively. A photon of
3
wavelength is emitted during a transition from III to I. What will be the wavelength of emission for
transition II to I ?
(1) (2) (3) 2 (4) 3
2
20. Calculate the minimum and maximum number of electrons which may have magnetic quantum number,
1
m = +1 and spin quantum number, s = – in chromium (Cr) :
2
(1) 0, 1 (2) 1, 2 (3) 4, 6 (4) 2, 3
SECTION-2
This section contains 5 questions. Each question, when worked out will result in Numerical Value.
21. The threshold wavelength (0) of sodium metal is 6500Å. If UV light of wavelength 360Å is used. Than
Kinetic energy of the photoelectron in ergs is y × 10–12. Than value of y is :
22. An electron beam can undergo diffraction by crystals. Through what potential should a beam of
electrons be accelerated so that its wavelength becomes equal to 1.54 Å?
23. Radiation corresponding to the transition n = 4 to n = 2 in hydrogen atoms falls on a certain metal (work
function = 2.5 eV). The maximum kinetic energy of the photo-electrons will be :
24. If the value of En = – 78.4 kcal/mole, the order of the orbit in hydrogen atom is :
25. What atomic number of an element “X” would have to become so that the 4th orbit around X would fit
inside the 1st Bohr orbit of Hydrogen ?
Practice Test-1 (IIT-JEE (Main Pattern))
OBJECTIVE RESPONSE SHEET (ORS)
Que. 1 2 3 4 5 6 7 8 9 10
Ans.
Que. 11 12 13 14 15 16 17 18 19 20
Ans.
Que. 21 22 23 24 25
Ans.
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ADVATS - 73
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