Safety Data Sheet

SECTION 1 PRODUCT AND COMPANY IDENTIFICATION

Havoline Xtended Life Antifreeze/Coolant - Premixed 33/67

Product Use: Antifreeze/Coolant
Product Number(s): 510565
Company Identification
Astron Energy (Pty) Ltd
5 Century Boulevard
Century City 7441
South Africa

Health Emergency
South Africa: 0861-555-777 (Red Cross Hospital Poison Information Centre, Cape Town)
Product Information
email : ZALubricantsTechSupp@astronenergy.co.za
Product Information: 0860-300-860
SDS Requests: 0860-300-860

SECTION 2 HAZARDS IDENTIFICATION

CLASSIFICATION: Target organ toxicant (repeated exposure): Category 2. Reproductive toxicant

(developmental): Category 2. Acute oral toxicant: Category 5.

Signal Word: Warning

Health Hazards: Suspected of damaging the unborn child (H361D). May be harmful if swallowed (H303).

Target Organs: May cause damage to organs (Kidney) through prolonged or repeated exposure (H373).

PRECAUTIONARY STATEMENTS:
Prevention: Obtain special instructions before use (P201). Do not handle until all safety precautions have been
read and understood (P202). Do not breathe dust/fume/gas/mist/vapours/spray (P260). Wear protective
gloves/protective clothing/eye protection/face protection (P280).
Response: Call a POISON CENTER or doctor/physician if you feel unwell (P312). Get medical advice/attention
if you feel unwell (P314). IF exposed or concerned: Get medical advice/attention (P308+P313).

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Storage: Store locked up (P405).
Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international
regulations (P501).

SECTION 3 COMPOSITION/ INFORMATION ON INGREDIENTS

COMPONENTS CAS NUMBER AMOUNT

Ethylene Glycol 107-21-1 30 - 40 %weight
Sodium 2-ethylhexanoate 19766-89-3 1 - 5 %weight

SECTION 4 FIRST AID MEASURES

Eye: No specific first aid measures are required. As a precaution, remove contact lenses, if worn, and flush eyes
with water.
Skin: No specific first aid measures are required. As a precaution, remove clothing and shoes if contaminated.
To remove the material from skin, use soap and water. Discard contaminated clothing and shoes or thoroughly
clean before reuse.
Ingestion: If swallowed, get immediate medical attention. Do not induce vomiting. Never give anything by
mouth to an unconscious person.
Inhalation: No specific first aid measures are required. If exposed to excessive levels of material in the air, move
the exposed person to fresh air. Get medical attention if coughing or respiratory discomfort occurs.

IMMEDIATE HEALTH EFFECTS

Eye: Not expected to cause prolonged or significant eye irritation.
Skin: Contact with the skin is not expected to cause prolonged or significant irritation. Contact with the skin is not
expected to cause an allergic skin response. Not expected to be harmful to internal organs if absorbed through the
skin.
Ingestion: Toxic; may be harmful or fatal if swallowed.
Inhalation: Breathing this material at concentrations above the recommended exposure limits may cause central
nervous system effects. Central nervous system effects may include headache, dizziness, nausea, vomiting,
weakness, loss of coordination, blurred vision, drowsiness, confusion, or disorientation. At extreme exposures,
central nervous system effects may include respiratory depression, tremors or convulsions, loss of consciousness,
coma or death.

DELAYED OR OTHER HEALTH EFFECTS:

Reproduction and Birth Defects: Contains material that may cause harm to the unborn child if swallowed based
on animal data.
Target Organs: Contains material that may cause damage to the following organ(s) following repeated
inhalation at concentrations above the recommended exposure limit:Kidney

SECTION 5 FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames.
Dry Chemical, CO2, AFFF Foam or alcohol resistant foam.

PROTECTION OF FIRE FIGHTERS:

Fire Fighting Instructions: This material will burn although it is not easily ignited. See Section 7 for proper
handling and storage. For fires involving this material, do not enter any enclosed or confined fire space without
proper protective equipment, including self-contained breathing apparatus.
Combustion Products: Highly dependent on combustion conditions. A complex mixture of airborne solids,
liquids, and gases including carbon monoxide, carbon dioxide, and unidentified organic compounds will be evolved
when this material undergoes combustion. Combustion may form oxides of: Sodium.
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 SECTION 6 ACCIDENTAL RELEASE MEASURES

Protective Measures: Eliminate all sources of ignition in vicinity of spilled material.

Spill Management: Stop the source of the release if you can do it without risk. Contain release to prevent
further contamination of soil, surface water or groundwater. Clean up spill as soon as possible, observing
precautions in Exposure Controls/Personal Protection. Use appropriate techniques such as applying non-
combustible absorbent materials or pumping. Where feasible and appropriate, remove contaminated soil. Place
contaminated materials in disposable containers and dispose of in a manner consistent with applicable regulations.
Reporting: Report spills to local authorities as appropriate or required.

SECTION 7 HANDLING AND STORAGE

General Handling Information: Do not taste or swallow antifreeze or solution. Keep out of the reach of children
and animals.
Precautionary Measures: Do not get in eyes, on skin, or on clothing. Do not breathe vapor or fumes. Wash
thoroughly after handling. Keep out of the reach of children.
Static Hazard: Electrostatic charge may accumulate and create a hazardous condition when handling this material.
To minimize this hazard, bonding and grounding may be necessary but may not, by themselves, be sufficient.
Review all operations which have the potential of generating and accumulating an electrostatic charge and/or a
flammable atmosphere (including tank and container filling, splash filling, tank cleaning, sampling, gauging, switch
loading, filtering, mixing, agitation, and vacuum truck operations) and use appropriate mitigating procedures.
Container Warnings: Container is not designed to contain pressure. Do not use pressure to empty container or it
may rupture with explosive force. Empty containers retain product residue (solid, liquid, and/or vapor) and can be
dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks,
static electricity, or other sources of ignition. They may explode and cause injury or death. Empty containers
should be completely drained, properly closed, and promptly returned to a drum reconditioner or disposed of
properly.

General Storage Information: Do not store in open or unlabeled containers.

SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION

GENERAL CONSIDERATIONS:
Consider the potential hazards of this material (see Section 2), applicable exposure limits, job activities, and other
substances in the work place when designing engineering controls and selecting personal protective equipment. If
engineering controls or work practices are not adequate to prevent exposure to harmful levels of this material, the
personal protective equipment listed below is recommended. The user should read and understand all instructions
and limitations supplied with the equipment since protection is usually provided for a limited time or under certain
circumstances.

ENGINEERING CONTROLS:
Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below the
recommended exposure limits.

PERSONAL PROTECTIVE EQUIPMENT

Eye/Face Protection: No special eye protection is normally required. Where splashing is possible, wear safety
glasses with side shields as a good safety practice.
Natural rubber, Neoprene, Nitrile Rubber, Polyvinyl Chloride (PVC or Vinyl).
Respiratory Protection: Determine if airborne concentrations are below the recommended occupational exposure
limits for jurisdiction of use. If airborne concentrations are above the acceptable limits, wear an approved
respirator that provides adequate protection from this material, such as:

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Use a positive pressure air-supplying respirator in circumstances where air-purifying respirators may not provide
adequate protection.
Occupational Exposure Limits:

Component Country/ TWA STEL Ceiling Notation

Agency
Ethylene Glycol ACGIH -- -- 100 mg/m3 --

Consult local authorities for appropriate values.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Attention: the data below are typical values and do not constitute a specification.

Color: Orange
Physical State: Liquid
Odor: Faint or Mild
Odor Threshold: No data available
pH: 8.20 - 8.70
Vapor Pressure: <0.01 mmHg @ 20 °C (68 °F)
Vapor Density (Air = 1): 2.10
Initial Boiling Point: 100°C (212°F) (Min)
Solubility: Miscible
Freezing Point: -19°C (-2.2°F) (Max)
Melting Point: No data available
Density: 1.0472 kg/l @ 15°C (59°F) (Typical)
Viscosity: No data available
Decomposition temperature: No data available
Octanol/Water Partition Coefficient: No data available

FLAMMABLE PROPERTIES:
Flammability (solid, gas): No Data Available

Flashpoint: Not Applicable

Autoignition: Not Applicable
Flammability (Explosive) Limits (% by volume in air): Lower: Not Applicable Upper: Not
Applicable

SECTION 10 STABILITY AND REACTIVITY

Reactivity: May react with strong acids or strong oxidizing agents, such as chlorates, nitrates, peroxides, etc.
Chemical Stability: This material is considered stable under normal ambient and anticipated storage and
handling conditions of temperature and pressure.
Incompatibility With Other Materials: Not applicable
Hazardous Decomposition Products: Ketones (Elevated temperatures), Aldehydes (Elevated temperatures)
Hazardous Polymerization: Hazardous polymerization will not occur.

SECTION 11 TOXICOLOGICAL INFORMATION

Information on toxicological effects

Serious Eye Damage/Irritation: The eye irritation hazard is based on evaluation of data for product components.
Skin Corrosion/Irritation: The skin irritation hazard is based on evaluation of data for product components.
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Skin Sensitization: The skin sensitization hazard is based on evaluation of data for similar materials.
Acute Dermal Toxicity: The acute dermal toxicity hazard is based on evaluation of data for product components.
Acute Oral Toxicity: The acute oral toxicity hazard is based on evaluation of data for similar materials or product
components.
Acute Inhalation Toxicity: The acute inhalation toxicity hazard is based on evaluation of data for product
components.
Acute Toxicity Estimate: Not Determined

Germ Cell Mutagenicity: The hazard evaluation is based on data for components or a similar material.

Carcinogenicity: The hazard evaluation is based on data for components or a similar material.

Reproductive Toxicity: The hazard evaluation is based on data for components or a similar material.

Specific Target Organ Toxicity - Single Exposure: The hazard evaluation is based on data for components or a
similar material.

Specific Target Organ Toxicity - Repeated Exposure: The hazard evaluation is based on data for components or a
similar material. Risk depends on duration and level of exposure.
ADDITIONAL TOXICOLOGY INFORMATION:
This product contains ethylene glycol (EG). The toxicity of EG via inhalation or skin contact is expected to be slight
at room temperature. The estimated oral lethal dose is about 100 cc (3.3 oz.) for an adult human. Ethylene
glycol is oxidized to oxalic acid which results in the deposition of calcium oxalate crystals mainly in the brain and
kidneys. Early signs and symptoms of EG poisoning may resemble those of alcohol intoxication. Later, the victim
may experience nausea, vomiting, weakness, abdominal and muscle pain, difficulty in breathing and decreased urine
output. When EG was heated above the boiling point of water, vapors formed which reportedly caused
unconsciousness, increased lymphocyte count, and a rapid, jerky movement of the eyes in persons chronically
exposed. When EG was administered orally to pregnant rats and mice, there was an increase in fetal deaths and
birth defects. Some of these effects occurred at doses that had no toxic effects on the mothers. We are not aware
of any reports that EG causes reproductive toxicity in human beings.

2-Ethylhexanoic acid (2-EXA) caused an increase in liver size and enzyme levels when repeatedly administered
to rats via the diet. When administered to pregnant rats by gavage or in drinking water, 2-EXA caused teratogenicity
(birth defects) and delayed postnatal development of the pups. Additionally, 2-EXA impaired female fertility in rats.
Birth defects were seen in the offspring of mice who were administered sodium 2-ethylhexanoate via intraperitoneal
injection during pregnancy.

SECTION 12 ECOLOGICAL INFORMATION

ECOTOXICITY
This material is not expected to be harmful to aquatic organisms.
The product has not been tested. The statement has been derived from the properties of the individual components.

MOBILITY
No data available.

PERSISTENCE AND DEGRADABILITY

This material is expected to be readily biodegradable. The biodegradability of this material is based on an evaluation

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of data for the components or a similar material.
The product has not been tested. The statement has been derived from the properties of the individual components.

POTENTIAL TO BIOACCUMULATE
Bioconcentration Factor: No data available.
Octanol/Water Partition Coefficient: No data available

SECTION 13 DISPOSAL CONSIDERATIONS

Use material for its intended purpose or recycle if possible. This material, if it must be discarded, may meet the
criteria of a hazardous waste as defined by international, country, or local laws and regulations.

SECTION 14 TRANSPORT INFORMATION

The description shown may not apply to all shipping situations. Consult 49CFR, or appropriate Dangerous Goods
Regulations, for additional description requirements (e.g., technical name) and mode-specific or quantity-specific
shipping requirements.

DOT Shipping Description: PROPRIETARY ANTIFREEZE PREPARATION IN NON-BULK PACKAGING;

NOT REGULATED FOR TRANSPORT UNDER 49 CFR
Additional Information: Bulk shipments containing a reportable quantity (RQ, 5000 pounds or more) of ethylene
glycol in a single packaging are transported as hazardous material. The shipping description is: UN3082,
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (ETHYLENE GLYCOL CONTAINS
BITTERANT), 9, III, RQ (ETHYLENE GLYCOL)

IMO/IMDG Shipping Description: NOT REGULATED AS DANGEROUS GOODS FOR TRANSPORTATION

UNDER THE IMDG CODE

ICAO/IATA Shipping Description: Anti-freeze Preparations, Proprietary; NOT REGULATED AS

DANGEROUS GOODS FOR TRANSPORT UNDER ICAO

SECTION 15 REGULATORY INFORMATION

REGULATORY LISTS SEARCHED:

01-1=IARC Group 1
01-2A=IARC Group 2A
01-2B=IARC Group 2B

No components of this material were found on the regulatory lists above.

CHEMICAL INVENTORIES:
All components comply with the following chemical inventory requirements: AICS (Australia), DSL (Canada),
EINECS (European Union), ENCS (Japan), IECSC (China), PICCS (Philippines), TSCA (United States).

SECTION 16 OTHER INFORMATION

REVISION STATEMENT: This revision updates the following sections of this Material Safety Data Sheet: 1-
16

Revision Date: November 07, 2016

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ABBREVIATIONS THAT MAY HAVE BEEN USED IN THIS DOCUMENT:
TLV - Threshold Limit Value TWA - Time Weighted Average
STEL - Short-term Exposure Limit PEL - Permissible Exposure Limit
CAS - Chemical Abstract Service Number
ACGIH - American Conference of Governmental IMO/IMDG - International Maritime Dangerous
Industrial Hygienists Goods Code

API - American Petroleum Institute SDS - Safety Data Sheet

CVX - Chevron NTP - National Toxicology Program (USA)
DOT - Department of Transportation (USA)
IARC - International Agency for Research on Cancer
NCEL - New Chemical Exposure Limit
SCBA - Self-Contained Breathing Apparatus

Prepared according to the SANS 2014 by Chevron Energy Technology Company, 6001 Bollinger Canyon Road,
San Ramon, CA 94583.

The above information is based on the data of which we are aware and is believed to be correct as of the date
hereof. Since this information may be applied under conditions beyond our control and with which we may
be unfamiliar and since data made available subsequent to the date hereof may suggest modifications of the
information, we do not assume any responsibility for the results of its use. This information is furnished
upon condition that the person receiving it shall make his own determination of the suitability of the
material for his particular purpose.

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