Safety Data Sheet

Safety data sheet according to 1907/2006/EC, Article 31

Supersedes Date 2022-12-01 Revision Date: 2023-01-04 Revision Number: 24

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
Product name ZINPLEX 15 (EU)

Material No. 8258

Historic Material No. U415

Unique Formula Identifier (UFI) 3NH1-20UE-500K-YA7Y

Pure substance/mixture Mixture

Relevant identified uses Polymerization aid - crosslinking agent

Uses advised against Consumer use

Manufacturer Munzing - Ultra Additives LLC.

1455 Broad Street
Bloomfield, NJ 07003
United States

Email: info@munzing.com
Phone: 1-973-279-1306

Supplier Münzing Chemie GmbH

Münzingstrasse 2
74232 Abstatt
Germany

Email: info@munzing.com
Phone: +49 (0) 7131/987-0

Emergency Telephone
Emergency telephone CHEMTREC: +1 703 741 5970

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Regulation (EC) No 1272/2008
Skin corrosion/irritation Category 1 - (H314)
Serious eye damage/eye irritation Category 1 - (H318)
Skin sensitization Category 1 - (H317)
Acute aquatic toxicity Category 1 - (H400)
Chronic aquatic toxicity Category 1 - (H410)

2.2. Label elements

Contains Zinc(2+), tetraammine-, (T-4)-, carbonate (1:1)

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Signal word
Danger

Hazard statements
H314 - Causes severe skin burns and eye damage
H317 - May cause an allergic skin reaction
H410 - Very toxic to aquatic life with long lasting effects

Precautionary Statements - EU (§28, 1272/2008)

P260 - Do not breathe dust/fume/gas/mist/vapors/spray
P264 - Wash face, hands and any exposed skin thoroughly after handling
P273 - Avoid release to the environment
P280 - Wear protective gloves and eye/face protection
P280 - Wear protective gloves/protective clothing and eye/face protection
P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing
P310 - Immediately call a POISON CENTER or doctor
P321 - Specific treatment (see First Aid on this label)
P391 - Collect spillage

Additional information
This product requires child resistant fastenings if supplied to the general public. This product requires tactile warnings if supplied to
the general public.

2.3. Other hazards

No information available.

SECTION 3: Composition/information on ingredients

3.1 Substances

Not applicable

3.2 Mixtures

Chemical nature Aqueous solution of inorganic salts. (Zinc ammonium complex).

Chemical name CAS No Weight-% EC No (EU REACH Classificatio Specific M-Factor M-Factor
Index No) registration n according concentrati (long-term)
number to on limit
Regulation (SCL)
(EC) No.
1272/2008
[CLP]
Ammonium 1336-21-6 1 - <3 215-647-6 - Skin Corr. STOT SE 3 - -
hydroxide 1B (H314) :: C>=5%
Aquatic
Acute 1
(H400)
STOT SE 3
:: C>=5%
Note B
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Carbonic acid, 10361-29-2 1 - <3 233-786-0 - Acute Tox. 4 - - -
ammonium salt (H302)
Zinc(2+), 38714-47-5 20 - 50 254-099-2 01-21207606 Skin Irrit. 2 - - -
tetraammine-, 26-49 (H315)
(T-4)-, carbonate Skin Sens. 1
(1:1) (H317)
Eye Irrit. 2
(H319)
Aquatic
Acute 1
(H400)
Aquatic
Chronic 1
(H410)

Full text of H- and EUH-phrases: see section 16

Acute Toxicity Estimate

If LD50/LC50 data is not available or does not correspond to the classification category, then the appropriate conversion
value from CLP Annex I, Table 3.1.2, is used to calculate the acute toxicity estimate (ATEmix) for classifying a mixture
based on its components

Chemical name Oral LD50 mg/kg Dermal LD50 mg/kg Inhalation LC50 - 4 Inhalation LC50 - 4 Inhalation LC50 - 4
hour - dust/mist - hour - vapor - mg/L hour - gas - ppm
mg/L
Ammonium hydroxide 350 No data available No data available No data available No data available
1336-21-6
Carbonic acid, ammonium No data available 2000 No data available No data available No data available
salt
10361-29-2

Additional information
Substance name: Ammonium Hydroxide: Note B : Some substances (acids, bases, etc.) are placed on the market in aqueous
solutions at various concentrations and, therefore, these solutions require different classification and labelling since the hazards
vary at differentconcentrations. 31.12.2008 EN Official Journal of the European Union L 353/333 In Part 3 entries with Note B have
a general designation of the following type: ‘nitric acid … %’. In this case the supplier must state the percentage concentration of
the solution on the label. Unless otherwise stated, it is assumed that the percentage concentration is calculated on a weight/weight
basis.

This product does not contain candidate substances of very high concern at a concentration >=0.1% (Regulation (EC) No.
1907/2006 (REACH), Article 59)

SECTION 4: First aid measures

4.1. Description of first aid measures

General advice Immediate medical attention is required. Show this safety data sheet to the doctor in
attendance.

Inhalation Remove to fresh air. If breathing has stopped, give artificial respiration. Get medical
attention immediately. Do not use mouth-to-mouth method if victim ingested or inhaled the
substance; give artificial respiration with the aid of a pocket mask equipped with a one-way
valve or other proper respiratory medical device. If breathing is difficult, (trained personnel
should) give oxygen. Delayed pulmonary edema may occur. Get immediate medical
attention.

Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep
eye wide open while rinsing. Do not rub affected area. Remove contact lenses, if present
and easy to do. Continue rinsing. Get immediate medical attention.

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Skin contact Wash off immediately with soap and plenty of water while removing all contaminated
clothes and shoes. Get immediate medical attention. May cause an allergic skin reaction.

Ingestion Do NOT induce vomiting. Rinse mouth. Never give anything by mouth to an unconscious
person. Get immediate medical attention.

Self-protection of the first aider Ensure that medical personnel are aware of the material(s) involved, take precautions to
protect themselves and prevent spread of contamination. Avoid contact with skin, eyes or
clothing. Avoid direct contact with skin. Use barrier to give mouth-to-mouth resuscitation.
Wear personal protective clothing (see section 8).

4.2. Most important symptoms and effects, both acute and delayed

Symptoms Burning sensation. Itching. Rashes. Hives.

4.3. Indication of any immediate medical attention and special treatment needed

Note to physicians Product is a corrosive material. Use of gastric lavage or emesis is contraindicated.
Possible perforation of stomach or esophagus should be investigated. Do not give
chemical antidotes. Asphyxia from glottal edema may occur. Marked decrease in blood
pressure may occur with moist rales, frothy sputum, and high pulse pressure. May cause
sensitization in susceptible persons. Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.

Large Fire CAUTION: Use of water spray when fighting fire may be inefficient.

Unsuitable extinguishing media Do not scatter spilled material with high pressure water streams.

5.2. Special hazards arising from the substance or mixture

Specific hazards arising from the The product causes burns of eyes, skin and mucous membranes. Thermal decomposition
chemical can lead to release of irritating gases and vapors. Product is or contains a sensitizer. May
cause sensitization by skin contact.

Hazardous combustion products Oxides of sulfur. Thermal decomposition can lead to release of irritating and toxic gases
and vapors.

5.3. Advice for firefighters

Special protective equipment and Firefighters should wear self-contained breathing apparatus and full firefighting turnout
precautions for fire-fighters gear. Use personal protection equipment.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Attention! Corrosive material. Avoid contact with skin, eyes or clothing. Ensure adequate
ventilation. Use personal protective equipment as required. Evacuate personnel to safe
areas. Keep people away from and upwind of spill/leak.

Other information Refer to protective measures listed in Sections 7 and 8.

For emergency responders Use personal protection recommended in Section 8.

6.2. Environmental precautions

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Environmental precautions Prevent further leakage or spillage if safe to do so. Should not be released into the
environment. Do not allow to enter into soil/subsoil. Prevent product from entering drains.

6.3. Methods and material for containment and cleaning up

Methods for containment Prevent further leakage or spillage if safe to do so.

Methods for cleaning up Take up mechanically, placing in appropriate containers for disposal.

Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.

6.4. Reference to other sections

Reference to other sections See section 8 for more information. See section 13 for more information.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with
skin, eyes or clothing. In case of insufficient ventilation, wear suitable respiratory
equipment. Handle product only in closed system or provide appropriate exhaust
ventilation. Do not eat, drink or smoke when using this product. Take off contaminated
clothing and wash before reuse.

General hygiene considerations Avoid contact with skin, eyes or clothing. Wear suitable gloves and eye/face protection. Do
not eat, drink or smoke when using this product. Remove and wash contaminated clothing
and gloves, including the inside, before re-use. Contaminated work clothing should not be
allowed out of the workplace. Regular cleaning of equipment, work area and clothing is
recommended. Wash hands before breaks and immediately after handling the product.

7.2. Conditions for safe storage, including any incompatibilities

Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Protect from
moisture. Store locked up. Keep out of the reach of children. Store away from other
materials.

7.3. Specific end use(s)

Risk Management Methods (RMM) The information required is contained in this Safety Data Sheet.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Exposure Limits

Chemical name Cyprus Czech Republic Denmark Estonia Finland

Ammonium hydroxide - - - - TWA: 20 ppm
1336-21-6 TWA: 14 mg/m3
STEL: 50 ppm
STEL: 36 mg/m3
Chemical name France Germany TRGS Germany DFG Greece Hungary
Zinc(2+), tetraammine-, - - TWA: 0.1 mg/m3 - -
(T-4)-, carbonate (1:1) TWA: 2 mg/m3
38714-47-5 Peak: 0.4 mg/m3
Peak: 4 mg/m3

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Biological occupational exposure This product, as supplied, does not contain any hazardous materials with biological limits
limits established by the region specific regulatory bodies.

Derived No Effect Level (DNEL) No information available.

Predicted No Effect Concentration No information available.
(PNEC)

8.2. Exposure controls

Personal protective equipment

Eye/face protection Tight sealing safety goggles. Face protection shield.

Hand protection Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls,
as appropriate, to prevent skin contact. Glove thickness. > 0.4 mm. Ensure that the
breakthrough time of the glove material is not exceeded. Refer to glove supplier for
information on breakthrough time for specific gloves. Wear suitable gloves. Impervious
gloves.

Skin and body protection Wear suitable protective clothing. Long sleeved clothing. Chemical resistant apron.

Respiratory protection In case of mist, spray or aerosol exposure wear suitable personal respiratory protection and
protective suit.

General hygiene considerations Avoid contact with skin, eyes or clothing. Wear suitable gloves and eye/face protection. Do
not eat, drink or smoke when using this product. Remove and wash contaminated clothing
and gloves, including the inside, before re-use. Contaminated work clothing should not be
allowed out of the workplace. Regular cleaning of equipment, work area and clothing is
recommended. Wash hands before breaks and immediately after handling the product.

Environmental exposure controls No information available.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state Liquid
Appearance Colorless
Odor ammoniacal.

Property Values Remarks • Method

Melting point No data available Not determined, technically not possible
Boiling point 100 °C ASTM D 86
Flammability (solid, gas) not ignitable
Flammability Limit in Air
Upper flammability limit Not applicable
Lower flammability limit Not applicable
Flash Point > 100 °C (DIN EN ISO 2719)
Autoignition temperature No data available Not available for the mixture or its components
Decomposition temperature Not applicable
pH 10.5 ASTM D 1293
pH (as aqueous solution) No data available
Kinematic viscosity ~ 49 mm2/s Newtonian calculated 25°C
Dynamic viscosity 60 cPs (100 rpm) ISO 2555
Water solubility Soluble
Solubility in other solvents Completely soluble
Partition coefficient: n-octanol/waterNot applicable Mixture
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Vapor Pressure No data available Not determined, technically not possible
Relative density 1.22 ASTM D 1475
Vapor density Not applicable not measurable
Particle characteristics
Particle Size Not applicable
Particle Size Distribution Not applicable

9.2. Other information

9.2.1. Information with regard to physical hazard classes

Not applicable

9.2.2. Other safety characteristics

No information available

SECTION 10: Stability and reactivity

10.1. Reactivity

Reactivity No information available.

10.2. Chemical stability

Stability Stable under normal conditions.

Explosion Data
Sensitivity to mechanical impact None.
Sensitivity to static discharge None.

10.3. Possibility of hazardous reactions

Possibility of hazardous reactions None under normal processing.

10.4. Conditions to avoid

Conditions to avoid Exposure to air or moisture over prolonged periods.

10.5. Incompatible materials

Incompatible materials Acids. Bases. Oxidizing agent.

10.6. Hazardous decomposition products

Hazardous decomposition products Thermal decomposition can lead to release of irritating and toxic gases and vapors.
Nitrogen oxides (NOx).

SECTION 11: Toxicological information

11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008

Information on likely routes of exposure

Product Information Information given is based on data on the components and the toxicology of similar
products.
Eyes Causes severe skin burns and eye damage. Avoid contact with eyes.
Skin Causes severe skin burns and eye damage. May cause sensitization by skin contact. Avoid
contact with skin.
Inhalation Health injuries are not known or expected under normal use.
Ingestion Health injuries are not known or expected under normal use.

Symptoms related to the physical, chemical and toxicological characteristics

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Symptoms Redness. Burning. May cause blindness. Coughing and/ or wheezing. Itching. Rashes.
Hives.

Numerical measures of toxicity

The following values are calculated based on chapter 3.1 of the GHS document
ATEmix (oral) 10,338.50 mg/kg
ATEmix (dermal) 46,945.40 mg/kg

Component Information

Chemical name Oral LD50 Dermal LD50 Inhalation LC50

Ammonium hydroxide = 350 mg/kg ( Rat ) - -
Carbonic acid, ammonium salt > 1800 mg/kg ( Rat ) > 2000 mg/kg ( Rat ) -

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Skin corrosion/irritation Classification based on data available for ingredients. Causes severe skin burns and eye
damage.

Serious eye damage/eye irritation Classification based on data available for ingredients. Causes serious eye damage. Causes
burns.

Respiratory or skin sensitization May cause an allergic skin reaction.

Germ cell mutagenicity No information available.

Carcinogenicity No information available.

Reproductive toxicity No information available.

STOT - single exposure No information available.

STOT - repeated exposure No information available.

Aspiration hazard No information available.

11.2. Information on other hazards

11.2.1. Endocrine disrupting properties

Endocrine disrupting properties No information available.

11.2.2. Other information

Other adverse effects No information available.

SECTION 12: Ecological information

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12.1. Toxicity

Ecotoxicity Very toxic to aquatic life with long lasting effects.

Unknown aquatic toxicity Contains 0 % of components with unknown hazards to the aquatic environment.

Chemical name Algae/aquatic plants Fish Toxicity to Crustacea

microorganisms
Ammonium hydroxide - LC50: =8.2mg/L (96h, - EC50: =0.66mg/L (48h,
Pimephales promelas) Daphnia pulex)
EC50: =0.66mg/L (48h,
water flea)
Carbonic acid, - - EC20 (0.5 h): 1,000 mg/l -
ammonium salt

12.2. Persistence and degradability

Persistence and degradability No information available.

12.3. Bioaccumulative potential

Bioaccumulation No information available.

12.4. Mobility in soil

Mobility in soil No information available.

12.5. Results of PBT and vPvB assessment

PBT and vPvB assessment

Chemical name PBT and vPvB assessment

Carbonic acid, ammonium salt The substance is not PBT / vPvB

12.6. Endocrine disrupting properties

Endocrine disrupting properties No information available.

12.7. Other adverse effects

No information available.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Waste from residues/unused Dispose of in accordance with local regulations. Dispose of waste in accordance with
products environmental legislation.

Contaminated packaging Do not reuse empty containers.

Waste codes / waste designations 160303 - inorganic wastes containing dangerous substances.
according to EWC / AVV

Other information According to the European Waste Catalogue, Waste Codes are not product specific, but
application specific. Waste codes should be assigned by the user based on the application
for which the product was used.

SECTION 14: Transport information

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RID
UN number or ID number UN1719 ,
14.2 Proper Shipping Name Caustic alkali liquid, n.o.s
Technical Description (Ammonia Complex Solution)
14.3 Transport hazard class(es) 8
14.4 Packing Group II
14.5 Environmental hazard yes
Marine Pollutant Yes
14.6
Classification Code (Kemler) 80
Tunnel restriction code 2 (E)
EmS No. F-A, S-B
14.7 Transport in bulk according to No information available
Annex II of MARPOL 73/78 and the
IBC Code

IMDG
UN number or ID number UN1719
14.2 Proper Shipping Name Caustic alkali liquid, n.o.s.
14.3 Transport hazard class(es) 8
14.4 Packing Group II
14.5 Environmental hazard yes Marine Pollutant Yes
14.6 Special Provisions Not sensitive
EmS No. F-A, S-B

IATA
UN number or ID number UN1719
14.2 Proper Shipping Name Caustic alkali liquid, n.o.s.
14.3 Transport hazard class(es) 8
14.4 Packing group II
14.5 Environmental hazard yes Marine Pollutant Yes
14.6

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

International Inventories
US TSCA Active Complies
Australia (AIIC) Complies
Canada (DSL) Complies
China (IECSC) Complies
Europe (EINECS/ELINCS/NLP) Complies
Japan (ENCS) Not listed
South Korea (KECL) Complies
New Zealand (NZIoC) Complies
Philippines (PICCS) Complies
Taiwan (TSCI) Complies

Legend
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
AIIC - Australian Inventory of Industrial Chemicals (AIIC)
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
IECSC - China Inventory of Existing Chemical Substances
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
NZIoC - New Zealand Inventory of Chemicals
TSCI - Inventory - Taiwan - Taiwan Chemical Substance Inventory (TCSI)

National regulations

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Germany Water endangering class = 3 (self classification)

European Union
Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents
at work.

Authorizations and/or restrictions on use:

This product contains one or more substance(s) subject to restriction (Regulation (EC) No. 1907/2006 (REACH), Annex XVII)
Chemical name Restricted substance per REACH Substance subject to authorization per
Annex XVII REACH Annex XIV
Ammonium hydroxide - 1336-21-6 75. -

Persistent Organic Pollutants

Not applicable

Dangerous substance category per Seveso Directive (2012/18/EU)

E1 - Hazardous to the Aquatic Environment in Category Acute 1 or Chronic 1
Named dangerous substances per Seveso Directive (2012/18/EU)

Ozone-depleting substances (ODS) regulation (EC) 1005/2009

Not applicable

15.2. Chemical safety assessment

Chemical Safety Report No information available

SECTION 16: Other information

Key or legend to abbreviations and acronyms used in the safety data sheet

Full text of H-Statements referred to under section 3

H221 - Flammable gas
H302 - Harmful if swallowed
H314 - Causes severe skin burns and eye damage
H315 - Causes skin irritation
H317 - May cause an allergic skin reaction
H319 - Causes serious eye irritation
H331 - Toxic if inhaled
H400 - Very toxic to aquatic life
H410 - Very toxic to aquatic life with long lasting effects

Legend
SVHC: Substances of Very High Concern for Authorization:

Legend Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

TWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit)
Ceiling Maximum limit value * Skin designation

Classification procedure
Classification according to Regulation (EC) No. 1272/2008 [CLP] Method Used
Acute oral toxicity Calculation method
Acute dermal toxicity Calculation method
Acute inhalation toxicity - gas Calculation method
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Acute inhalation toxicity - vapor Calculation method
Acute inhalation toxicity - dust/mist Calculation method
Skin corrosion/irritation Calculation method
Serious eye damage/eye irritation Calculation method
Respiratory sensitization Calculation method
Skin sensitization Calculation method
Mutagenicity Calculation method
Carcinogenicity Calculation method
Reproductive toxicity Calculation method
STOT - single exposure Calculation method
STOT - repeated exposure Calculation method
Acute aquatic toxicity Calculation method
Chronic aquatic toxicity Calculation method
Aspiration hazard Calculation method
Ozone Calculation method

Key literature references and sources for data used to compile the SDS
Agency for Toxic Substances and Disease Registry (ATSDR)
U.S. Environmental Protection Agency ChemView Database
European Food Safety Authority (EFSA)
EPA (Environmental Protection Agency)
Acute Exposure Guideline Level(s) (AEGL(s))
U.S. Environmental Protection Agency Federal Insecticide, Fungicide, and Rodenticide Act
U.S. Environmental Protection Agency High Production Volume Chemicals
Food Research Journal
Hazardous Substance Database
International Uniform Chemical Information Database (IUCLID)
Japan GHS Classification
Australia National Industrial Chemicals Notification and Assessment Scheme (NICNAS)
NIOSH (National Institute for Occupational Safety and Health)
National Library of Medicine's ChemID Plus (NLM CIP)
National Library of Medicine’s PubMed database (NLM PUBMED)
National Toxicology Program (NTP)
New Zealand's Chemical Classification and Information Database (CCID)
Organization for Economic Co-operation and Development Environment, Health, and Safety Publications
Organization for Economic Co-operation and Development High Production Volume Chemicals Program
Organization for Economic Co-operation and Development Screening Information Data Set
World Health Organization

Issue Date: 2009-01-09

Revision Date: 2023-01-04
Reason for revision Update to Format.

Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered as a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
material or in any process, unless specified in the text.

End of Safety Data Sheet

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