SAFETY DATA SHEET
DAPHNE PUNCH OIL AF-2AS
Version Revision Date: SDS Number: Date of last issue: -
1.0 2017/03/29 100000002769 Date of first issue: 2017/03/29
1. PRODUCT AND COMPANY IDENTIFICATION
Product name : DAPHNE PUNCH OIL AF-2AS
Product code : KS_263
Recommended use of the chemical and restrictions on use
Recommended use : Lubricant
Restrictions on use :
None known.
Manufacturer or supplier's details
Company : S-OIL TOTAL LUBRICANTS CO., LTD.
Address : 3F, Ace Tower,Sunhwa-dong ,3F, 92 Tongil-ro , Jung-gu,
Seoul, 100-712 Korea
Telephone : +82-2-6320-2000
Emergency telephone number : +82 (0)234 798 401
2. HAZARDS IDENTIFICATION
GHS Classification
Flammable liquids : Category 3
Skin corrosion/irritation : Category 2
Aspiration hazard : Category 1
GHS label elements
Hazard pictograms :
Signal word : Danger
Hazard statements : H226 Flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
Precautionary statements :
Prevention:
P210 Keep away from heat/sparks/open flames/hot surfaces.
No smoking.
P233 Keep container tightly closed.
KS_263 - DAPHNE PUNCH OIL AF-2AS Revision Date:
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P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ ventilating/ lighting/
equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P264 Wash the contact area thoroughly after handling.
P280 Wear protective gloves/ eye protection/ face protection.
Response:
P301 + P310 IF SWALLOWED: Immediately call a POISON
CENTER or doctor/ physician.
P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off
immediately all contaminated clothing. Rinse skin with water/
shower.
P331 Do NOT induce vomiting.
P332 + P313 If skin irritation occurs: Get medical advice/
attention.
P362 Take off contaminated clothing and wash before reuse.
P370 + P378 In case of fire: Use dry sand, dry chemical or
alcohol-resistant foam for extinction.
Storage:
P403 + P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
Disposal:
P501 Dispose of contents and container according to wastes
control act.
Other hazards which do not result in classification
No information available.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture : Mixture
Components
Chemical name Common CAS-No. Concentration (%
Name w/w)
alkanes, C10-13-iso- alkanes, C10- 68551-17-7 >= 80 - < 85
13-iso-
dodec-1-ene dodec-1-ene 112-41-4 >= 15 - < 20
nonane nonane 111-84-2 >= 1 - < 5
No hazardous ingredients
Chemical name Common CAS-No. Concentration (%
Name w/w)
Lubricating oil additive - - <1
For explanation of abbreviations see section 16.
4. FIRST AID MEASURES
General advice : Move out of dangerous area.
Show this safety data sheet to the doctor in attendance.
Symptoms of poisoning may appear several hours later.
Do not leave the victim unattended.
In case of eye contact : Flush eyes with water as a precaution.
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Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.
In case of skin contact : If skin irritation persists, call a physician.
If on skin, rinse well with water.
If on clothes, remove clothes.
If inhaled : If unconscious, place in recovery position and seek medical
advice.
If symptoms persist, call a physician.
If swallowed : Keep respiratory tract clear.
Do NOT induce vomiting.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
Take victim immediately to hospital.
Most important symptoms : May be fatal if swallowed and enters airways.
and effects, both acute and Causes skin irritation.
delayed
5. FIREFIGHTING MEASURES
Suitable and unsuitable extinguishing media
Suitable extinguishing media : Alcohol-resistant foam
Carbon dioxide (CO2)
Dry chemical
Unsuitable extinguishing : High volume water jet
media
Specific hazards during : Do not allow run-off from fire fighting to enter drains or water
firefighting courses.
Hazardous combustion : No hazardous combustion products are known
products
Specific extinguishing : Collect contaminated fire extinguishing water separately. This
methods must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
For safety reasons in case of fire, cans should be stored
separately in closed containments.
Use a water spray to cool fully closed containers.
Special protective equipment : Wear self-contained breathing apparatus for firefighting if
for firefighters necessary.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, : Use personal protective equipment.
protective equipment and Ensure adequate ventilation.
emergency procedures Remove all sources of ignition.
Evacuate personnel to safe areas.
Beware of vapours accumulating to form explosive
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concentrations. Vapours can accumulate in low areas.
Environmental precautions : Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.
Methods and materials for : Contain spillage, and then collect with non-combustible
containment and cleaning up absorbent material, (e.g. sand, earth, diatomaceous earth,
vermiculite) and place in container for disposal according to
local / national regulations (see section 13).
7. HANDLING AND STORAGE
Advice on protection against : Do not spray on a naked flame or any incandescent material.
fire and explosion Take necessary action to avoid static electricity discharge
(which might cause ignition of organic vapours). Keep away
from open flames, hot surfaces and sources of ignition.
Advice on safe handling : Avoid formation of aerosol.
Do not breathe vapours/dust.
Avoid contact with skin and eyes.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the
application area.
Take precautionary measures against static discharges.
Provide sufficient air exchange and/or exhaust in work rooms.
Open drum carefully as content may be under pressure.
Dispose of rinse water in accordance with local and national
regulations.
Conditions for safe storage : No smoking.
Keep container tightly closed in a dry and well-ventilated
place.
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.
Observe label precautions.
Electrical installations / working materials must comply with
the technological safety standards.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
Components CAS-No. Value type Control Basis
(Form of parameters /
exposure) Permissible
concentration
nonane 111-84-2 TWA 200 ppm KR OEL
1,050 mg/m3
TWA 200 ppm ACGIH
Personal protective equipment
Eye protection : Eye wash bottle with pure water
Tightly fitting safety goggles
Hand protection
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Remarks : The suitability for a specific workplace should be discussed
with the producers of the protective gloves.
Skin and body protection : Impervious clothing
Choose body protection according to the amount and
concentration of the dangerous substance at the work place.
Hygiene measures : When using do not eat or drink.
When using do not smoke.
Wash hands before breaks and at the end of workday.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : transparent
Physical state : liquid
Colour : colourless
Odour : characteristic
Odour Threshold : No data available
pH : No data available
Pour point : < -50.0 °C
Melting point/range No data available
Drop point No data available
Initial boiling point and boiling : No data available
range
Flash point : 58 °C
Method: Pensky-Martens closed cup
Upper/Lower explosion limit
Upper explosion limit : No data available
Lower explosion limit : No data available
Solubility(ies)
Water solubility : insoluble
Relative vapour density : No data available
Density : 0.7590 g/cm3 (15 °C)
Viscosity
Viscosity, kinematic : 1.371 mm2/s (40 °C)
10. STABILITY AND REACTIVITY
Chemical stability and : No decomposition if stored and applied as directed.
possibility of hazardous No decomposition if stored and applied as directed.
reactions No decomposition if stored and applied as directed.
Vapours may form explosive mixture with air.
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Conditions to avoid : Heat, flames and sparks.
Incompatible materials : Strong acids and strong bases
Hazardous decomposition : No hazardous decomposition products are known.
products
11. TOXICOLOGICAL INFORMATION
Health hazard information
Acute toxicity
Not classified based on available information.
Skin corrosion/irritation
Causes skin irritation.
Product:
Remarks: May cause skin irritation in susceptible persons.
Serious eye damage/eye irritation
Not classified based on available information.
Product:
Remarks: Vapours may cause irritation to the eyes, respiratory system and the skin.
Respiratory or skin sensitisation
Skin sensitisation
Not classified based on available information.
Respiratory sensitisation
Not classified based on available information.
Carcinogenicity
Not classified based on available information.
Germ cell mutagenicity
Not classified based on available information.
Reproductive toxicity
Not classified based on available information.
STOT - single exposure
Not classified based on available information.
STOT - repeated exposure
Not classified based on available information.
Aspiration toxicity
May be fatal if swallowed and enters airways.
Further information
Product:
Remarks: Solvents may degrease the skin.
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12. ECOLOGICAL INFORMATION
Ecotoxicity
No data available
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Other adverse effects
Product:
Additional ecological : No data available
information
13. DISPOSAL CONSIDERATIONS
Disposal methods
Waste from residues : Do not dispose of waste into sewer.
Do not contaminate ponds, waterways or ditches with
chemical or used container.
Send to a licensed waste management company.
Contaminated packaging : Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.
Do not burn, or use a cutting torch on, the empty drum.
Disposal precautions
Dispose of in accordance with local regulations.
14. TRANSPORT INFORMATION
International Regulations
UNRTDG
UN number : UN 1993
Proper shipping name : FLAMMABLE LIQUID, N.O.S.
(, )
Class : 3
Packing group : III
Labels : 3
IATA-DGR
UN/ID No. : UN 1993
Proper shipping name : FLAMMABLE LIQUID, N.O.S.
(, )
Class : 3
Packing group : III
Labels : Flammable Liquids
Packing instruction (cargo : 366
aircraft)
Packing instruction : 355
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(passenger aircraft)
IMDG-Code
UN number : UN 1993
Proper shipping name : FLAMMABLE LIQUID, N.O.S.
(, )
Class : 3
Packing group : III
Labels : 3
EmS Code : F-E, S-E
Marine pollutant : no
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
National Regulations
Refer to section 15 for specific national regulation.
Special precautions for user
Not applicable
15. REGULATORY INFORMATION
National regulatory information
Regulation under the Occupational Safety and Health Act
Harmful Substances Prohibited from Manufacturing
Not applicable
Harmful Substances Required Permission for Manufacture
Not applicable
Hazardous substances requiring management
Not applicable
Controlled Substances Subject to Environment Monitoring
Not applicable
Controlled Substances Subject to Health Examination
Not applicable
Act on the Registration and Evaluation, etc. of Chemical Substances, Chemicals Control
Act
Toxic Chemicals
Not applicable
Restricted Chemicals
Not applicable
Prohibited Chemicals
Not applicable
Toxic Release Inventory
Not applicable
Accident Precaution Chemicals
Not applicable
Dangerous Substances Safety Management Act
Classification : Group 4, Flammable liquids, Type 2 petroleums, Water
insoluble liquid
Hazard rank : Hazardous rank III
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Designated Quantity : 1000 litre
Safety Warning : Keep away from fire
Wastes Control Act
Industrial waste
Follow article 13 of the act to dispose the product waste
Other requirements in domestic and other countries
The components of this product are reported in the following inventories:
ENCS : Listed
TSCA : Listed
EINECS : Listed
REACH : For further information, please contact
DSL : Listed
AICS : Listed
KECI : Listed
PICCS : Listed
IECSC : Listed
TCSI : Listed
16. OTHER INFORMATION
Full text of other abbreviations
AICS - Australian Inventory of Chemical Substances; ANTT - National Agency for Transport by
Land of Brazil; ASTM - American Society for the Testing of Materials; bw - Body weight; CMR -
Carcinogen, Mutagen or Reproductive Toxicant; CPR - Controlled Products Regulations; DIN -
Standard of the German Institute for Standardisation; DSL - Domestic Substances List (Canada);
ECx - Concentration associated with x% response; ELx - Loading rate associated with x%
response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan);
ErCx - Concentration associated with x% growth rate response; ERG - Emergency Response
Guide; GHS - Globally Harmonized System; GLP - Good Laboratory Practice; IARC -
International Agency for Research on Cancer; IATA - International Air Transport Association; IBC
- International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals
in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation
Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International
Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety
and Health Law (Japan); ISO - International Organisation for Standardization; KECI - Korea
Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 -
Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International
Convention for the Prevention of Pollution from Ships; n.o.s. - Not Otherwise Specified; Nch -
Chilean Norm; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed
(Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NOM - Official Mexican
Norm; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD
- Organization for Economic Co-operation and Development; OPPTS - Office of Chemical Safety
and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS -
Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure
Activity Relationship; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of
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the Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals;
SADT - Self-Accelerating Decomposition Temperature; SDS - Safety Data Sheet; TCSI - Taiwan
Chemical Substance Inventory; TDG - Transportation of Dangerous Goods; TSCA - Toxic
Substances Control Act (United States); UN - United Nations; UNRTDG - United Nations
Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very
Bioaccumulative; WHMIS - Workplace Hazardous Materials Information System
Issuing date : 2017/03/29
Revision number and date
Number of Revision : 0.1
Revision Date : 2017/03/29
Date format : yyyy/mm/dd
The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the
specific material designated and may not be valid for such material used in combination with any
other materials or in any process, unless specified in the text.
KR / EN
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