DPP – 1 SOME BASIC CONCEPTS OF CHEMISTRY

MEASUREMENTS IN CHEMISTRY , LAWS OF CHEMICAL COMBINATION

SUBJECTIVE CLASS: XI
Q1. Express the following in scientific notation or exponential notation:
(a) 23 (b) 589,000,000 (c) 0.00058
Q2. How many significant figures are there in each of the following numbers?
(a) 1.2 (b) 0.0012 (c) 10.0 (d) 10 (e) 12300 (f) 123.0  103
Q3. Round off the following to three significant figures:
(a) 0.9811 (b) 1.745 (c) 14.29 (d) 21.74 (e) 2.65981  103
Q4. How many significant digits are there in
(a) Avogadro’s number (6.0  1023) (b) Planck’s constant (6.62  10-34 J s)?
Q5. How many significant figures are there in the answer of each of the following calculations:
(a) 58.32  6.3 (b) 6.9 + 31.29 (c) (16.37 / 6.1)  2.9
Q6. Express each of the following in SI units:
(i) 3 million miles (This is the distance between earth and sun).1 mile = 1.60 km
(ii) 5 feet 2 inches (the average height of an Indian female).1 inch = 2.54  102 m
(iii) 0.74 Å (the bond length of hydrogen molecule).
(iv) 46oC (the peak summer temperature in Delhi)
(v) 150 pounds (the average weight of an Indian male).1pound= 454 103 kg
Q7. Fill in the blanks in the following conversions :
(i) 1 km = ….. mm = …… pm (ii) 1 mg = ……. Kg = …….. ng (iii) 1 mL = …. L = …… dm3
Q8. If the speed of light is 3.0  108ms1 , calculate the distance covered by light in 2.00 ns.
Q9. Convert the following into basic units: (i) 28.7 pm (ii) 15.15 s (iii) 25365 mg
Q10. The wavelength of a beam of light is 5894 Å. Express the value in nanometers.
Q11. Convert 6 cubic metres into cubic centimetres.
Q12. The mass of copper metal is 6.342 g and the density of copper is 7.6 g/cm3. What is its volume?
OBJECTIVE
Q1. The correctly reported answers of the addition of 294.406, 280.208 and 24 will be
(a) 598.61 (b) 599 (c) 598.6 (d) 598.614
Q2. On dividing 0.25 by 22.1170, the actual answer is 0.011303. The correctly reported answer will be
(a) 0.011 (b) 0.01 (c) 0.0113 (d) 0.013
Q3. In which of the following numbers all zeros are significant?
(a) 0.0005 (b) 0.0500 (c) 50.000 (d) 0.0050
Q4. Which of the following is correct?
(a) 1 L = 1 m3 (b) 1 L = 1 dm3 (c) 10 L = 1 dm3 (d) 1 L = 10 dm3
Q5. Two oxides of a metal contain 27.6% and 30.0% of oxygen respectively. If the formula of the first oxide is
M3O4, then second one is
(a) MO2 (b) M2O (c) M2O3 (d) M3O2

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 Anjana Chemistry Classes SCO-41, Top floor Sec 20 C, Chandigarh ,Contact: 0172-2925111, 9464010111
Q6. The oxygen – carrying protein known as haemoglobin is 0.335% Fe by mass and contains four Fe atoms
per haemoglobin molecule. Calculate the molecular weight of this protein. ( M.M of Fe = 56.8gm )
(a) 66 g mol-1 (b) 66.6 g mol-1 (c) 6.6683  104 g mol-1 (d) 666 g mol-1
Q7. A 400mg Fe capsule contains 100mg of ferrous fumarate,(CHCOO) 2Fe.The % of Fe present in it, is
(a) 33% (b) 25% (c) 14% (d) 8%
Q8. The mass percentage of nitrogen in urea CO(NH2)2 is about
(a) 46 (b) 85 (c) 18 (d) 28
Q9. The result of the operation 2.5  1.25 should be which of the following on the basis of significant figures?
(a) 3.125 (b) 3.13 (c) 3.1 (d) 31.25
Q10. How many significant figures are present in 0.010100  103?
(a) 7 (b) 5 (c) 3 (d) 10
Q11. Which set of figures will be obtained after rounding up the following up to three significant figures?
34.216, 0.04597, 10.4107
(a) 34.3, 0.0461, 10.4 (b) 34.2, 0.0460, 10.4 (c) 34.20, 0.460, 10.40 (d) 34.21, 4.597, 1.04
Q12. If the density of a solution is 3.12 g mL1, the mass of 1.5 ml, solution in significant figures is _________
(a) 4.7 g (b) 4680  103 g (c) 4.680 g (d) 46.80 g

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 DPP – 2 : SOME BASIC CONCEPTS OF CHEMISTRY

ATOMIC MASS, MOLECULAR MASS AND EMPERICAL FORMULA

Molecular Mass/ Atomic mass

Molecular weight = Vapour density  2
1 Weight of volatile subs tan ce
Vapour density =   22400
2 Volume at NTP

Dulong – Petit law states that Atomic weight  specific heat = 6.4 (Approximate atomic weight)
For Answers
SUBJECTIVE ASSIGNMENT
Q1. Why are atomic masses of most of the elements fractional?
Q2. What is the difference between the mass of a molecule and gram molecular mass?
Q3. Calculate the percentage of the naturally occurring isotopes 35Cl and 37Cl that accounts for the atomic mass
of chlorine taken as 35.45.
Q4. Calculate the molecular mass of:
(i) H2O (ii) CO2 (iii) CH4
Q5. Calculate the mass per cent of different elements present in sodium sulphate (Na 2SO4).
Q6. How much copper can be obtained from 100 g of copper sulphate (CuSO4)?(Atomic mass of Cu=63.5 amu).
Q7. Write the empirical formulae of the following:
(i) N2O4 (ii) C6H6 (iii) C6H12O6 (iv) H2O2 (v) H2O (vi) Na2CO3 (vii) CH3COOH
Q8. A compound contains 4.07% hydrogen,24.7% carbon and 71.65% chlorine. Its molar mass is 98.96g. What
are its empirical formula and molecular formula?
Q9. An organic liquid gave on analysis the following results:
C- 10.06% , H=0.84% , Cl=89.10% . Its vapour density is 60. Find the molecular formula of the substance.
Q10. A compound on analysis gave the following percentage composition: Na = 14.31%, S = 9.97%, H = 6.22%
and O = 69.50%. Calculate the molecular formula of the compound on the assumption that all the
hydrogen in the compound is present in combination with oxygen as water of crystallization. The
molecular mass of the compound is 322.
OBJECTIVE ASSIGNMENT
Q1. One ‘u’ stands for:
(a) An atom of carbon (C – 12) (b) 1/12 of the carbon atom (C – 12)
(c) 1/12th of hydrogen atom (d) One atom of all the elements
Q2. Given that abundances of isotopes 54Fe, 56Fe and 57Fe are 5%, 90% and 5% respectively. Atomic mass of
Fe is:
(a) 55.85 (b) 55.95 (c) 55.75 (d) 56.05
Q3. Which one of the following is not a mixture?
(a) Iodized salt (b) Gasoline
(c) Liquefied Petroleum Gas (LPG) (d) Distilled water
Q4. Which of the following is a characteristic of both mixtures and compounds?
(a) Their properties are same as those of their constituents
(b) energy is absorbed when they are formed

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 Anjana Chemistry Classes SCO-41, Top floor Sec 20 C, Chandigarh ,Contact: 0172-2925111, 9464010111
(c) Their mass equals to the sum of the masses of their compounds
(d) They contain components in fixed proportions
Q5. Elements Y has an atomic number 30, element X has an atomic number 15. The formula of possible
compound containing these elements is
(a) YX (b) YX2 (c) Y2X3 (d) Y3X2
Q6. The specific heat of a metal is 0.16. Its approximate atomic weight would be
(a) 32 (b) 16 (c) 40 (d) 64
Q7. 26.8 g of Na2SO4 . x H2O contains 12.6 g of water. The value of ‘x’ is
(a) 1 (b) 10 (c) 6 (d) 7
Q8. The most abundant elements by mass in the body of a healthy human adult are:
Oxygen (61.4%), Carbon (22.9%), Hydrogen (10.0%) and Nitrogen (2.6%)
The weight which a 75 kg person would gain if all the 1H atoms are replaced by 2H atoms is
(a) 7.5 kg (b) 10 kg (c) 15 kg (d) 37.5 kg
Q9. The arsenic content of an agricultural insecticide was reported as 28% As2O5. What is the percentage of
arsenic in this preparation?
(a) 15% (b) 16% (c) 18% (d) 20%
Q10. The mass percentage of nitrogen in urea CO(NH2)2 is about
(a) 46 (b) 85 (c) 18 (d) 28
Q11. Amount of oxygen (in grams) in 32.2 g of Na2SO4. 10H2O is
(a) 20.8 (b) 22.4 (c) 2.24 (d) 2.08
Q12. Study the following table:
Compound Mass of the compound
(mol. mass) (in gram) taken
I. CO2(44) 4.4
II. NO2(46) 2.3
III. H2O2(34) 6.8
IV. SO2 (64) 1.6
Which two compounds have least mass of oxygen? (Molecular masses of compounds are given in
brackets)
(a) II and IV (b) I and III (c) I and II (d) III and IV
Q13. Example of isosters are
(a) CO2 and SO2 (b) N2O and CO2 (c) NO2 and SO2 (d) All of these
Q14. Crystalline salt Na2SO4. xH2O on heating loses 55.9% of its weight. The formula of the crystalline salt is:
(a) Na2SO4. 5H2O (b) Na2SO4 . 7H2O (c) Na2SO4.2H2O (d) Na2SO4 . 10H2O
Q15. A compound contains two elements ‘X’ and ‘Y’ in the ratio of 50% each. Atomic mass of ‘X’ is 20 and ‘Y’ is
40. What can be its simplest formula?
(a) XY (b) X2Y (c) XY2 (d) X2Y3
Q16. A gas has molecular formula (CH)n. If vapour density of the gas is 39, what should be the formula of the
compound?
(a) C3H3 (b) C4H4 (c) C2H2 (d) C6H6

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 Anjana Chemistry Classes SCO-41, Top floor Sec 20 C, Chandigarh ,Contact: 0172-2925111, 9464010111
Q17. An organic compound on analysis gave C = 54.2%, H = 9.2% by mass. Its empirical formula is
(a) CHO2 (b) CH2O (c) C2H8O (d) C2H4O
Q18. Two elements ‘P’ and ‘Q’ combine to form a compound. Atomic mass of ‘P’ is 12 and ‘Q’ is 16. Percentage
of ‘P’ in the compound is 27.3. What will be the empirical formula of the compound?
(a) P2Q2 (b) PQ (c) P2Q (d) PQ2
Q19. An organic compound containing C, H and N gave the following analysis: C = 40%, H = 13.33% and N =
46.67%. Its empirical formula would be
(a) CHN (b) C2H2N (c) CH4N (d) C2H7N
Q20. The empirical formula of a compound is CH2O and its molecular weight is 120. Its molecular formula is
(a) C2H4O2 (b) C3H6O3 (c) C4H8O4 (d) CH2O
Q21. The empirical formula of an organic compound containing C and H is CH 2. The mass of one litre of this
organic gas is exactly equal to that of one litre of N2.Therefore, the molecular formula of the organic gas is
(a) C2H4 (b) C3H6 (c) C6H12 (d) C4H6
Q22. The percentage of P2O5 in diammonium hydrogen phosphate [(NH4)2HPO4] is , if one mole of P2O5 is
formed by heating 2 moles of [(NH4)2HPO4]
(a) 23.48 (b) 46.96 (c) 53.78 (d) 71.00
Q23. When 2.46 g of hydrated salt (MSO4 . xH2O) is completely dehydrated, 1.20 g of anhydrous salt is
obtained. If the molecular weight of anhydrous salt is 120 g mol1, what is the value of x?
(a) 2 (b) 4 (c) 5 (d) 7
Q24. 0.1 mole of a carbohydrate with empirical formula CH 2O contains 1g of hydrogen. Its molecular formula is
(a) C5H10O5 (b) C6H10O6 (c) C4H8O4 (d) C3H6O3
Q25. All the oxygen in 0.5434 g sample of a pure oxide of iron is removed by reduction in a steam of hydrogen.
The loss in weight is 0.1210 g. Hence, formula of iron oxide is (Fe = 56)
(a) FeO (b) Fe2O3 (c) Fe3O4 (d) FeO2

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 DPP – 3 : SOME BASIC CONCEPTS OF CHEMISTRY

MOLE CONCEPT
CLASS - XII
SUBJECTIVE ASSIGNMENT
Q1. What will be the mass of one 12C atom in g?
Q2. Which one of the following will have largest number of atoms?
(i) 1 g Au (s) (ii) 1 g Na (s) (iii) 1 g Li (s) (iv) 1 g of Cl2 (g) For Answers
Q3. Calculate the mass of (i) an atom of silver (ii) a molecule of carbon dioxide.
Q4. (a) What is the mass of (i) 1 mole of water (ii) 0.5 mole of CO2 (iii) 2.5 moles of Cl2?
(b)How many moles are contained in:(i)9.0 g of Aluminium (ii) 0.8g of Iron (iii)50g CaCO 3 (iv)196g H2SO4.
Q5. What is the mass in grams of : (i) 6.022  1023 atoms of oxygen? (ii) 1.0  1023 molecules of H2S?
Q6. A sample of phosphorus has 0.25 moles of P4 molecules.
(i) How many P4 molecules are there? (ii) How many P atoms are there?
(iii) How many moles of P atoms are there in the sample? (iv) What is the mass of the sample?
7
Q7. The volume of a gas is 1.12  10 cm3 at NTP. Calculate the number of molecules of the gas.
Q8. Calculate number of atoms of each type in 3.42 gm sucrose of formula C12H22O11.
Q9. A flask P contains 0.5 mole of oxygen gas . Another flask Q contains 0.4 mole of ozone gas. Which of the
two flasks contains greater nu of oxygen atoms?
Q10. Calculate volume at NTP occupied by:(a) 28 gm of nitrogen gas(b)1.5gm of CO2 (c)10 21 molecules of O2
Q11. Calculate number of moles in 44.8 lit of SO2 at STP and 8 gm of calcium.
Q12. A sample of gaseous substance weighing 0.5 gm occupies a volume of 1.12. lts under NTP conditions.
Calculate the molar mass of the substance.
Q13. Find nu of atoms in (i) 8g of helium (ii) 22.4 lts of Cl2 (iii) 1 mole of NH3
Q14. What is the volume of the following at STP .Find number of molecules as well : a) 2 moles of methane
gas b) 0.5 moles of SO3
Q15. Calculate the number of atoms of oxygen present in 88g of CO2? What would be the weight of CO having
the same number of oxygen atoms?
Q16. Which of following has max mass (a) 20 g of phosphorus (b)5 moles of water (c)12 1024 atoms of H.
Q17. Calculate the number of molecules in a drop of water weighing 0.05 g.
OBJECTIVE ASSIGNMENT
Q1. Number of molecules in 16 g of methane is:
(a) 3.011  1023 (b) 6.022  1023 (c) 12.46  1023 (d) 1.5  1023
Q2. The number of atoms in 4.25 g of NH3 is approximately
(a) 1  1023 (b) 2  1023 (c) 4  1023 (d) 6  1023
Q3. 4.4 g of an unknown gas occupies 2.24 L of volume under N.T.P. conditions. The gas may be:
(a) CO2 (b) CO (c) O2 (d) SO2
Q4. Which has the maximum number of atoms?
(a) 6.022  1021 molecules of CO2 (b) 22.4 L of CO2 at N.T.P (c) 0.44 g of CO2 (d) None of these
Q5. The weight of one molecule of compound C60H122 is:
(a) 1.2  1020 g (b) 1.4  1021 g (c) 5.025  1023 g (d) 6.023  1023 g
Q6. The litres of CO2 represented by 4.4 g of CO2 at S.T.P. are:
(a) 2.4 litres (b) 2.24 litres (c) 44 litres (d) 22.4 litres

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 Anjana Chemistry Classes SCO-41, Top floor Sec 20 C, Chandigarh ,Contact: 0172-2925111, 9464010111
Q7. Maximum number of molecules are present in
(a) 15 L of H2 gas at S.T.P. (b) 5 L of N2 gas at S.T.P. (c) 0.5 g of H2 gas (d) 10 g of O2 gas
Q8. Which has maximum number of molecules among the following?
(a) 44 g of CO2 (b) 48 g of O3 (c) 8 g of H2 (d) 64 g of SO2
Q9. The number of water molecules is maximum in:
(a) 1.8 g of water (b) 18 g of water (c) 18 moles of water (d) 18 molecules of water
Q10. The numbers of molecules in 100 mL each of O2, NH3 and CO2 at STP are
(a) in the order CO2 < O2 < NH3 (b) in the order NH3 < O2 < CO2
(c) the same (d) in the order NH3 < CO2 < O2
Q11. Which of the following has greatest number of atoms?
(a) 1 g of butane (C4H10) (b) 1 g of nitrogen (N2) (c) 1 g of silver (Ag) (d) 1 g of water (H2O)
Q12. Which of the following is/are correct?
(a)1mole of H-atom=6.0231023 molecules of hydrogen (b)1 mole of NaCl=6.0231023 formula units of NaCl
(c) 1 mole of CO2=2  6.023  1023 atoms of oxygen (d) 1 mole of N2 gas = 6.023  1023 molecules of nitrogen
Q13. Which of the following have equal number of molecules?
(a) 0.5 mole of CO2 gas (b) 11.2 L of CO2 gas (c) 22 g of CO2 gas (d) 6.02  1023 molecules of CO2
Q14. Which of the following is not correct regarding 14 gram of carbon monoxide?
(a) it corresponds to 0.5 mole of CO (b) it occupies 2.24 litres at S.T.P.
(c) It corresponds to 3.01  1023 molecules of CO
(d) It corresponds to same number of moles of CO 2 and nitrogen (I) oxide gases
Q15. Which of the following has the highest mass?
(a)20 g of sulphur (b)4 mol of carbon dioxide (c)121024 atoms of hydrogen (d)11.2 L of helium at N.T.P.
Q16. One atom of an element weighs 1.8  1022 g, its atomic mass is
(a) 29.9 (b) 18 (c) 108.36 (d) 154
Q17. Total number of atoms in 44 g of CO2 is
(a) 6.02  1023 (b) 6.02  1024 (c) 1.806  1024 (d) 18.06  1022
Q18. The flask A and B of equal size contain 2 g of H2 and 2 g of N2 respectively at the same temperature. The
number of molecules in flask A is
(a) same as those in flask B (b) less than those in flask B
(c) greater than those in flask B (d) exactly half than those in flask B
Q19. Which of the following will not have a mass of 10 g?
(a) 0.1 mol CaCO3 (b) 1.51  1023 Ca2+ ions (c) 0.16 mol of CO32 ions (d) 7.525  1022 Br atom
Q20. How many moles of magnesium phosphate, Mg3(PO4)2 will contain 0.25 mole of oxygen atoms?
(a) 0.02 (b) 3.125  102 (c) 1.25  102 (d) 2.5  10-2
Q21. Mass of CO2 is 88 g. The number of atoms of oxygen present is:
(a) 2.41  1024 (b) 1.2  1023 (c) 1.4  1023 (d) 2.41  1023
Q22. Formula of cane sugar is C12H22O11. No. of molecules present in 34.2 g of cane sugar is
(a) 6.022  1021 (b) 6.022  1020 (c) 6.022  1022 (d) 6.022  1018
Q23. The correct sequence of decreasing mass of the following is:
(i) 6.022  1023 atoms of oxygen (ii) 1.0  1023 molecules of H2S (ii) 6.022  1023 molecules of oxygen

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 Anjana Chemistry Classes SCO-41, Top floor Sec 20 C, Chandigarh ,Contact: 0172-2925111, 9464010111
(a) (i) > (ii) > (iii) (b) (i) > (iii) > (ii) (c) (iii) > (i) > (ii) (d) (ii) > (i) > (iii)
Q24. Which amount of dioxygen (in grams) contains 1.8  1022 molecules?
(a) 0.960 (b) 96.0 (c) 0.0960 (d) 9.60
Q25. Which weighs the maximum?
(a) 2.24 litres of CO2 at N.T.P. (b) 6.022  1023 molecules of CO2
(c) 6.022  1023 atoms of carbon (d) 10 g of CO2
Q26. Number of moles of oxygen in 1 L of air which contains 21% oxygen by vol under standard conditions is:
(a) 0.186 mol (b) 0.21 mol (c) 2.10 mol (d) 0.0093 mol
Q27. The number of atoms in 0.1 mole of a triatomic gas is:
(a) 6.026  1022 (b) 1.806  1023 (c) 3.6  1023 (d) 1.8  1022
Q28. What is the number of atoms in 560 g of Fe (atomic mass = 56 g mol-1)?
(a) Twice that of 70 g of nitrogen gas (b) Half that of 20 g of hydrogen gas
(c) Both (a) and (b) are correct (d) Neither is correct
Q29. Which has maximum number of atoms?
(a) 24 g of C (12) (b) 56 g of Fe (56) (c) 27 g of Al (27) (d) 108 g of Ag (108)
Q30. A sample of Na2CO3 contains 6.02  1023 Na+ ions. Mass of the sample is (at. Mass Na = 23, C = 12, O = 16)
(a) 53 g (b) 106 g (c) 165 g (d) 212 g
Q31. 4.48 litre of CH4 at S.T.P. corresponds to
(a) 1.2  1022 molecules of CH4 (b) 0.5 mole of CH4 (c) 3.2 g of CH4 (d) 0.1 mole of CH4
3
Q32. If the density of water is 1 g cm , then the volume occupied by one molecule of water is approximately
(a) 18 cm3 (b) 22400 cm3 (c) 6.02  1023 cm3 (d) 3.0  1023 cm3
Q33. The number of oxygen atoms present in 14.6 g of magnesium bicarbonate is
(a) 6N0 (b) 0.6 N0 (c) N0 (d) N0/2
Q34. Out of 1.0 g O2 1.0 g (atomic) oxygen and 1.0 g ozone, maximum number of oxygen atoms are contained in
(a) 1.0 g of atomic oxygen (b) 1.0 g of ozone
(c) 1.0 g of oxygen gas (d) All contains same number of atoms
Q35. Which of the following contains maximum number of atoms?
(a) 2.0 mol of S8 (b) 6.0 and of S (c) 5.5 mol of SO2 (d) 44.8 L of CO2 at S.T.P.
Q36. A sample of AlF3 contains 3.0  1024 F ions. The number of formula units of this sample are
(a) 9.0  1024 (b) 3.0  1024 (c) 0.75  1024 (d) 1.0  1024
Q37. The number of atoms present in 0.1 mole of P4 (at. Mass = 31) are
(a) 2.4  1024 atoms (b) same as in 0.05 mol of S8 (c) 6.02  1022 atoms (d) same as in 3.1 g of phosphorus
Q38. Out of the following the largest number of atoms are contained in
(a) 11 g of CO2 (b) 4 g of H2 (c) 5 g of NH3 (d) 8 g of SO2
Q39. The number of neutrons in 1.8 g of water will approximately be
(a) 4.216  1021 (b) 8.432  1023 (c) 4.816  1023 (d) 4.216  1024
Q40. x L of N2 at STP contains 3  1022 molecules. The number of molecules in x/2 L of ozone at STP will be
(a) 3  1022 (b) 1.5  1022 (c) 1.5  1021 (d)1.5101

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Anjana Chemistry Classes
DPP – 4 (SOME BASIC CONCEPTS OF CHEMISTRY)
MOLARITY AND MOLALITY, MOLE FRACTION
CLASS : XI
Q1. A solution is prepared by dissolving 3.65g of HCl in 500mL of water. Calculate molarity of the solution.
Q2. What is the molality of a solution which contains 18 g of glucose (C6H12O6) in 250 g of water?
Q3. How many moles and how many grams of NaCl are present in 500 cm3 of a 0.500 M NaCl solution?
Q4. A student needs 0.250 mol. of NaCl. What volume of 0.400 M solution he should use?

Q5. What is the concentration of sugar (C12H22O11) in mol L1 if its 20 g are dissolved in enough water to make
a ‘final volume up to 2L’?
Q6. Calculate the Molarity of water if its density is 1000 kg/m 3.
Q7. Hydrochloric acid is sold commercially as 12.0 M solution. How many mole and how many grams of HCl
are in 300.0 mL of 12.0 M solution?
Q8. What mass of MgCl2 should be dissolved in 750 gm of water in order to prepare a solution of 1.05 molal?
Q9. A solution consists of 250 gm of C2H5OH & 750 gm of H2O . Calculate mole fraction of each component.
Q10. Calculate molarity of CaCO3 (aq.) solution which has concentration of CaCO 3 = 200 ppm.

 CH 2 OH 
Q11. Ethylene glycol  |  C 2 H 6 O 2  is an antifreeze. A solution contains 20% of ethylene glycol by mass.
 CH OH 
 2 
Calculate the mole fraction of ethylene glycol.
Q12. A solution contains 25% water, 25% ethanol & 50% acetic acid by mass. Calculate mole fraction of water.
Q13. A sugar syrup of weight 214.2 g contains 34.2 g of sugar (C12H22O11). Calculate (i) molal concentration (ii)
mole fraction of sugar in the syrup.
Q14. A certain sample of concentrated HCl is 37.0% by mass of HCl. Calculate the molality of this solution.
Q15. Determine molarity of 3% w/v urea solution.
Q16. Calculate molarity of 12% w/w solution of glucose, if density of solution is 1.15 g/mL.
Q17. Calculate the molality of a solution of 20.7 g of K2CO3 dissolved in 500mL of solution ( density = 1 g mL1).
Q18. Concentrated nitric acid used in the laboratory is 68% nitric acid by mass in aqueous solution. What
should be the molarity of such a sample of the acid if the density of solution is 1.504 g mL1.
Q19. Calculate molality of 1.2 M H2SO4 solution? If its  = 1.4 g/mL
Q20. How much solvent is needed to make a 14.0% solution by mass using 25.0 g of solute?
OBJECTIVE
Q1. Calculate the molality of a solution that contains 51.2 g of naphthalene (C10H8) in 500 mL of carbon
tetrachloride. Density of CCl4 is 1.60 g/mL
(a) 0.250 m (b) 0.500 m (c) 0.750 m (d) 0.840 m (e) 1.69 m
Q2. Which of the following is dependent on temperature?
(a) Molality (b) Molarity (c) Mole fraction (d) Mass percent
Q3. 6.022  1020 molecules of urea are present in 100 mL of its solution. The concentration of urea solution is:
(a) 0.001 M (b) 0.01 M (c) 0.02 M (d) 0.1 M
Q4. The density of 2.0 M solution of a solute is 1.2 g mL . If the molecular mass of the solute is 100 g mol1,
1

then the molality of the solution is:

(a) 2.0 m (b) 1.2 m (c) 0.6 m (d) 2.4 m
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 Anjana Chemistry Classes SCO-41, Top floor Sec 20 C, Chandigarh ,Contact: 0172-2925111, 946401011

Q5. A solution of HCl is prepared by dissolving 5.5 g HCl in 200 g ethanol. The density of the solution is 0.79 g
mL1. Molarity of solution is:
(a) 0.58 M (b) 0.16 M (c) 0.92 M (d) 1.2 M
Q6. Density of a 2.05 M solution of acetic acid in water is 1.02 g/mL. The molality of solution will be:
(a) 1.14 m (b) 3.28 m (c) 2.28 m (d) 0.44 m
1
Q7. The density(in g mL ) of 3.60 M sulphuric acid solution that is 29% (molar mass=98g) by mass will be:
(a) 1.45 (b) 1.64 (c) 1.88 (d) 1.22
Q8. Assuming that sea water is an aqueous solution of NaCl, its density is 1.025 g/mL at 20oC and NaCl
concentration is 3.5% (by mass). The molarity of sea water is:
(a) 0.65 M (b) 0.68 M (c) 0.66 M (d) 0.61 M
Q9. Concentrated aqueous sulphuric acid is 98% by mass and has a density of 1.80 g mL 1. Volume of acid
required to make one litre of 0.1 M H2SO4 solution is:
(a) 16.65 mL (b) 22.20 mL (c) 11.10 mL (d) 5.55 mL

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 Anjana Chemistry Classes SCO-41, Top floor Sec 20 C, Chandigarh ,Contact: 0172-2925111, 946401011

DDP – 4 MOLE CONCEPT ; ANSWER AND SOLUTION

Q1. 0.2
Q2. 0.4m
Q3. (i) 0.250 (ii) 14.62g
Q4. 0.625

Q5. 0.029 mol L1

Q6. 55.56 moles
Q7. 131.4 g HCl

nB x1000 gB
Q8. Molality = ; nB = moles of MgCl2 ; nB =
gA 95
(gB / 95)x1000
 1.05 =  gB = 75.0 g
750

Q9.

250 750
Moles of C2H5OH = = 5.43Moles of H2O = = 41.67
46 18
Now let XA = mole fraction of H2O and XB = mole fraction of C2H5OH

41.67 5.43
XA = = 0.885 XB = = 0.115 Note: XA + XB = 1
41.67  5.43 47.10
Q10. 200 g of CaCO3 in 108 g of water.
200 2
= 2 moles of CaCO3 in 103litres of water. (density = 1g/mL) So molarity = = 2  10-3 M.
100 10 3
Q11. 0.9323
Q12. H2O = 0.502, C2H5OH = 0.1965, CH3COOH = 0.3014
Q13. Molar mass of sugar (C12H22O11) = 12  12 + 12 + 11  16 = 342 g mol1
Mass of water = Mass of sugar syrup – Mass of sugar = 214.2  34.2 = 180 g
Mass of sugar (in gms) 1000
(i) Molal concentration = 
Molar mass of sugar Mass of water (in gms)

34.2 1000
 Molal concentration =  = 0.1  5.555 = 0.5555
342 180
Mass of sugar 34.2
(ii) Moles of sugar (n1) =  = 0.1
Molar mass of sugar 342

Mass of water 180

Molar mass (n2) = = = 10
Molar mass of water 18

n1 0.1 0.1
 Mole fraction of sugar in the syrup =   = 0.0099
n 1  n 2 0.1  10 10.1

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 Anjana Chemistry Classes SCO-41, Top floor Sec 20 C, Chandigarh ,Contact: 0172-2925111, 946401011

Q14. 16.1 molal

Q15. [Hint: Molarity is volume dependent concentration , So 3% urea solution should be considered as 3%

(w/V) solution ] M= ==
Q16. [ Hint: Take 12% concentaration as 12% (w/w) because density is given and molarity has to be calculated.

M= == ]
1
Q17. Molar mass of K2CO3 = 2  39 + 12 + 3  16 = 138 g mol
Mass of solution = 500 mL  1 g mL1 = 500 g
Mass of K2CO3 = 20.7 g ; Mass of H2O = 500 – 20.7 = 479.3 g
Mass of K 2 CO 3 (in gms) 1000 20.7 1000
Molality of K2CO3 =  =  = 0.3129 mol kg1 = 0.313 m
Molar mass of K 2 CO 3 Mass of water 138 479.3

Q18. Mol. mass of HNO3 = 1 + 14 + 3  16 = 63 Weight of HNO3 per 100 g of solution = 68 g

68 Mass 100
Gram moles of HNO3 = , volume of solution = = = 66.49 mL
63 Density 1.504

Moles of HNO 3 68 1000

Molarity of HNO3 =  1000 ;  = 16.23 M
Volume of solution (mL ) 63 66.49

1.2  1000
Q19. Molality = = 0.936
1000  1.4  1.2  98
Q20. 1.54 g of solvent.
OBJECTIVE
Q1. (b) Mass of CCl4 (WA) = Volume  density ; 4= (500 mL)  (1.60 g mL1) = 800 g = 0.8 kg

No. of moles of naphthalen e ( 51.2g ) / 1.28 g mol 1 )

Molality of CCl4 (m) = = = 0.5 mol kg1 = 0.5
Mass of CCl 4 in kg (0.8 kg )

Q2. (b) Molarity (M) of a solution is temperature dependent since it takes into consideration the volume of
the solution.

6.022  10 20
Q3. (b) No. of moles of urea = = 0.001 mol
6.022  10 23

(10 5 mol )
Concentration of solution =  102 mol L1 = 0.01 M
(0.01L )

Q4. (a) Volume of solution containing 2 moles of solute = 1 L = 1000 mL

Mass of solution = V  d = 1000 mL  1.2 g mL1 = 1200 g
Mass of solvent = 1000 g = 1.0 kg
No. of moles of solute ( 2 moles )
Molality of solution (m) = = = 2 mol kg1 = 2.0 m
Mass of solvent in kg 1 kg

Mass of HCl / Molar mass

Q5. Molarity (M) = ; Mass of HCl solution = 200 + 5.5 = 205.5 g
Volume of solution in litre

( 205.5g )
Density of solution = 0.79 g mL1 ; Volume of solution = = 260.13 mL
(0.79 g mL1 )

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 Anjana Chemistry Classes SCO-41, Top floor Sec 20 C, Chandigarh ,Contact: 0172-2925111, 946401011

( 5.5g ) /( 36.5 g mol 1 )

Molarity = = 0.58 mL1 = 0.58 M
0.260 L

Q6. (c)2.05 M solution of acetic acid means that (2.05  60 = 129 g) of acid is present in 1000 mL of solution.
Mass of solution =Vd = (1000 mL)  (1.02 g mL1) = 1020 g
Mass of solvent = 1020 – 129 = 897 g
( 2.05 mol )
Molality (m) = = 2.28 mol kg1 = 2.28 m
(0.897 kg )

Q7. (d) By definition, 3.6 M (3  98 = 352.8 g) of H2SO4 are present in 1000 mL of solution.
29.0 of acid are present in solution = 100 g
(100g )
352.8 g of acid are present in solution =  (352.8 g) = 1216 g
( 29.0g )

Mass of solution ( 1216 g )

Density of solution = = = 1.22 g mL1
Volume of solution (1000mL )

Q8. (d) Mass of NaCl = 3.5 g ; Mass of solution = 100 g

Mass (100g )
Volume of solution = m= = 97.56 m
Density (1.025 g m L1 )

Equivalent mass of NaCl = 58.5 g equiv1

No. of g equiv 1 of solute ( 3.5 g ) /( 58.5 g equiv 1 )

Normality of solution (N) = =
Volume of solutoin in litres 97.56 / 1000L

= 0.61 equiv L1 = 0.61 N

Q9. (d) Volume of 98% (W/W) solution of H2SO4
Mass (100g )
=  = 55.55 mL = 0.055 L
density (1.80g mL1 )

(98g )
Molarity (M) =
(98 g mol 1 )  (0.055 L )

= 18.02 mol1 L = 18.02 M

(1L )  (0.1M )
V  (18.02 M) = 1 L  (0.1 M) ;V= = 0.0055 L = 5.5 mL
(18.02 M )

5
 DPP – 5 (SOME BASIC CONCEPTS OF CHEMISTRY)

WHEN SOLUTIONS ARE MIXED

CLASS : XI
SUBJECTIVE
Q1. A 35 ml 2.40 M HCl solution is diluted by adding water till the molarity of solution decreases to 0.30 M.
Determine the volume of water added.
Q2. What volume of a 3.0 M HCl solution be mixed with 500-mL of a 7.0 MHCl solution to prepare a HCl
solution where molarity will be 4.0?
Q3. Determine molarity of a solution obtained by mixing 50 ml of a 0.26 M H2SO4 solution with another 150 ml
0.48 M H2SO4 solution.
Q4. A 150 ml 0.15 M NaCl solution is added to another 200 ml 0.20 MNaCl solution and resulting solution was
mixed with a 150 ml NaCl solution of unknown molarity. Molarity of the final solution was found to be
0.25 M. Determine the unknown molarity of solution.
Q5. What volume of a 5.00 M H2SO4 solution should be added to a 150 ml 1.0 M H2SO4 solution in to obtain a
solution of sulphuric acid to molarity 2.5?
Q6. What volume of 6 M H2SO4 (aq) is needed to prepare 250 mL of 0.4 M H2SO4 (aq)?
Q7. If the density of methanol is 0.793 kg L1, what is its volume needed for making 2.5 L of its 0.25 M solution.
Q8. A sample of drinking water found to be severely contaminated with chloroform (CHCl3), supposed to be
carcinogenic in nature. The level of contamination was 15 ppm (by mass).
(i) Express this in per cent by mass.
(ii) Determine the molality of chloroform in the water sample.(Given : Molar mass of CHCl3 = 119.5 g)
OBJECTIVE
Q1. The volume of water to be added to 100 cm3 of 0.25 M H2SO4 to get 0.05 M concentration is
(a) 150 cm3 (b) 450 cm3 (c) 500 cm3 (d) 400 cm3
Q2. 250 mL of a sodium carbonate solution contains 2.65 grams of Na2CO3. If 10 ml of this solution is diluted to
one litre, what is the concentration of the resultant solution? (mol. wt. of Na2CO3 = 106)
(a) 0.1 M (b) 0.001 M (c) 0.01 M (d) 10-4 M
Q3. 1M and 2.5L NaOH solution is mixed with 0.5 M & 3L NaOH solution. Find the molarity of solution.
(a) 0.80 M (b) 1.0 M (c) 0.73 M (d) 0.5 M
Q4. Equal volume of 0.1M AgNO3 and 0.2M NaCl solution are mixed.Concentration of NO3- in mixture will be
(a) 0.1 M (b) 0.2 M (c) 0.05 M (d) 0.15 M
Q5. The volume of water to be added to half M HCl (0.5 M) to prepare 500 cc of decimolar (0.1M) solution is
(a) 400 cc (b) 45 cc (c) 100 cc (d) 450 cc
Q6. The final molarity of a solution made by mixing 50 mL of 0.5 M HCl, 150 mL of 0.25 M HCl and water to
make the volume 250 mL is
(a) 0.5 M (b) 1 M (c) 0.75 M (d) 0.25 M
Q7. 5 mL of 1 NHCl; 20 mL of N/2 H2SO4 and 30 mL of N/3 HNO3 solutions are mixed to make the volume to
one litre. The normality of the resulting solution will be:
(a) N/5 (b) N/10 (c) N/20 (d) N/40

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 Anjana Chemistry Classes SCO-41, Top floor Sec 20 C, Chandigarh ,Contact: 0172-2925111, 9464010111
Q8. To neutralize complete 20 mL of 0.1 M aqueous solution of phosphorus acid (H3PO3), the volume of 0.1 M
aqueous KOH solution required is:
(a) 40 mL (b) 20 mL (c) 10 mL (d) 60 mL
Q9. You are supplied with 500 mL each of 2N HCl and 5 N HCl. What is the maximum volume of 3 M HCl
that you can prepare using only these two solutions?
(a) 250 mL (b) 500 mL (c) 750 mL (d) 1000 mL
Q10. The maximum amount of BaSO4 precipitated on mixing equal volumes of BaCl 2(0.5 M) with H2SO4(1M)
will correspond to
(a) 0.25 M (b) 0.50 M (c) 1.0 M (d) 1.5 M
Q11. 25.3 g of sodium carbonate, Na2CO3 is dissolved in enough water to make 250 mL of solution. If sodium
carbonate dissociates completely, molar concentrations of sodium ions, Na+ and carbonate ions, CO32 are
respectively. (Molar mass of Na2CO3 = 106 g mol1)
(a) 0.477 M and 0.477 M (b) 0.955 M and 1.910 M
(c) 1.910 M and 0.955 M (d) 1.90 M and 1.910 M
Q12. You have two different HCl solution having concentration 3 M and 1 M respectively. How many mL of
both solution should be mixed to form 1 L of 1.2 M?
(a) 900 mL of 1 M and 100 mL of 3 M (b) 100 mL of 1 M and 900 mL of 3 M
(c) 500 mL of each (d) 333.33 mL of 3 M and 666.66 mL of 1 M
Q13. You are given two samples of HCl with molarity 0.341 and 0.143, volume of each sample being 1 litre. If
water is added for dilution, then the maximum volume of 0.243 M HCl that can be obtained by mixing the
given samples is
(a) 2 (b) 2.5 (c) 3 (d) 4

FOR ANSWERS & SOLUTIONS

2
ANJANA CHEMISTRY CLASSES
DPP – 6 STOICHIOMETRY-I AND LIMITING REAGENTS
CLASS : XI
Q1. What mass of slaked lime would be required to decompose completely 4 grams of ammonium chloride
and what would be the mass of each product? Ca (OH)2 + 2NH4Cl  CaCl2 + 2NH3 + 2H2O
Q2. In the commercial manufacture of nitric acid, how many moles of NO2 produce 7.33 mol of HNO3 in the
reaction: 3NO2(g) + H2O(l)  2HNO3(aq) + NO(g)?
Q3. Calculate the mass of graphite that must be burnt to produce 13.2 g of CO2.
Q4. Calculate the mass of 60% of H2SO4 required to decompose 50 g of chalk (calcium carbonate).
CaCO3 + H2SO4  CaSO4 + H2O + CO2
Q5. 5.6 litres of methane (CH4) gas are ignited in oxygen gas. Calculate the number of moles of CO2 formed
Q6. Calculate the weight of Fe which will be converted into its oxide(Fe3O4) by the action of 18 g of steam on it.
Q7. Hydrogen gas is prepared in the laboratory by reacting dilute HCl with granulated zinc. Following
reaction takes place: Zn + 2 HCl  ZnCl2 + H2
Calculate the volume of hydrogen gas liberated at STP when 32.65 g of zinc reacts with HCl .
Q8. 4 g carbon were heated with enough mass of sulphur. How much carbon disulphide (CS 2) will be formed
when the reaction is complete? C+ 2S  CS2
Q9. If 20.0 g of CaCO3 is treated with 20.0 g of HCl, how many grams of CO2 will be produced?
Q10. Dinitrogen and dihydrogen react with each other to produce ammonia according to the following chemical
equation: N2(g) + 3H2(g)  2NH3(g)
(i) Calculate the mass of ammonia produced if 2.00  103 g dinitrogen reacts with 1.00  103 g H2
(ii) Will any of the two reactants remain unreacted? (iii) If yes, which one & what would be its mass?
Q11. In a reaction, A + B2  AB2, identify the limiting reagent when 2 mole of A are mixed with 3 mol of B 2.
Q12. 50.0 kg of N2(g) and 10.0 kg of H2(g) are mixed to produced NH3(g). Calculate the NH3(g) formed. Identify the
limiting reagent in the production of NH3 in this situation.
Q13. 1.0 g of magnesium is burnt in a closed container which contains 0.6 g of oxygen.
(a) Which reactant is left in excess? (b) Find the mass of the excess reactant.
Q14. 3.0 g of H2 reacts with 29.0 g of O2 to yield H2O. (i) Which is the limiting reactant?
(ii) Calculate the maximum amount of H2O that can be formed.
(iii) Calculate the amount of one of the reactants which remains unreacted.
Q15. 20 g of CaCO3 and 20 g of H2SO4 react to give CaSO4 along with water and CO3.
(i) Determine the limiting reagent for the above reaction. (ii) How much CaCO4 will be formed?
(iii) Calculate the volume of CO2 evolved in the above reaction.
Q16. Calcium carbonate reacts with aqueous HCl to give CaCl2 and CO2 according to the reaction:

CaCO3(s) + 2HCl(aq) 
 CaCl2(aq) + CO2(g) + H2O(l)
What mass of CaCO3 is required to react completely with 25 mL of 0.75 M HCl?

Q17. Bromine is prepared commercially by the reaction: 2Br (aq) + Cl2 (aq) 
 2 Cl (aq) + Br2(aq)
Suppose we have 50.0 mL of 0.060 M solution of NaBr. What volume of 0.050 M solution of Cl2 is needed
to react completely with the Br?

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 Anjana Chemistry Classes SCO-41, Top floor Sec 20 C, Chandigarh ,Contact: 0172-2925111, 9464010111

OBJECTIVE
Q1. The mass of CaO that shall be obtained by heating 20 kg of 90% pure lime – stone (CaCO 3) is
(a) 11.2 kg (b) 8.4 kg (c) 10.08 kg (d) 16.8 g
Q2. 20.0 g of magnesium carbonate sample decomposes on heating to give carbon dioxide and 8.0 g
magnesium oxide. What will be the percentage purity of magnesium carbonate in the sample.
(a) 60 (b) 84 (c) 75 (d) 96 (Atomic wt. of Mg = 24)
Q3. Chlorine is prepared in the laboratory by treating manganese dioxide (MnO2) with aqueous hydrochloric
acid. How many grams of HCl react with 5.0 g of manganese dioxide. (Atomic mass of Mn = 55 u)
(a) 4.20 g (b) 6.40 g (c) 8.40 g (d) 20.0 g
Q4. What quantity of ammonium sulphate in necessary for the production of NH3 gas sufficient to neutralize a

solution containing 292 g of HCl? [HCl = 36.5; (NH4)2SO4 = 132; NH3 = 17] (NH4)2 SO4  NH3 + H2SO4
(a) 272 g (b) 408 g (c) 528 g (d) 1056 g
Q5. What mass of calcium chloride in grams would be enough to produce 14.35 g of AgCl (At. mass Ca = 40;
Ag = 108) CaCl 2  AgNO 3  AgCl + Ca(NO3)2

(a) 5.55 g (b) 8.295 g (c) 16.59 g (d) 11.19 g

Q6. The weight of slaked lime necessary to decompose completely 1.07 g of ammonium chloride is
NH 4 Cl + Ca( OH) 2  CaCl2 + NH3 + H2O

(a) 0.74 g (b) 1.48 g (c) 7.4 g (d) 0.37 g

Q7. The molar mass of CaCO3 is 100 g. The maximum amount of carbon dioxide that can be liberated on
heating 25 g of CaCO3= is
(a) 11 g (b) 55 g (c) 22 g (d) 2.2 g
Q8. For the formation of 3.65 g of hydrogen chloride gas, what volumes of hydrogen gas and chlorine gas are
required at N.T.P condition?
(a) 1.12 lit. 1.12 lit (b) 1.12 lit, 2.24 lit (c) 3.65 lit, 1.83 lit (d) 1 lit, 1 lit
Q9. The amount of zinc required to produce 224 ml of H2 at STP on treatment with dil. H2SO4 will be
(a) 0.65 g (b) 6.5 g (c) 65 g (d) 0.065 g
Q10. The volume of Cl2 at STP obtained on reacting 4.35 g MnO2 with conc. HCl (at. wt. of Mn = 55) is
MnO 2 + HCl  MnCl2 + H2O + Cl 2

(a) 4.48 litre (b) 2.24 litre (c) 1.12 litre (d) 0.56 litre
Q11. 12 g of Mg with excess of HCl at NTP gives
(a) 11.2 dm3 of H2 (b) 22.4 dm3 of H2 (c) 5.6 dm3 of H2 (d) 15.6 dm3 of H2
Q12. 100 ml of PH3 on heating form P and H2. The volume change in the reaction is:
(a) an increase of 50 ml (b) an increase of 100 ml (c) an increase of 150 ml (d) a decrease of 50 ml
Q13. 20 cc of CO2 are passed over red hot coke. The volume of CO evolved is CO2 + C  CO
(a) 10 cc (b) 20 cc (c) 30 cc (d) 40 cc
Q14. One mole of magnesium nitride on reaction with an excess of water gives Mg3N2 + H2O  Mg(OH)2 +
NH3
(a) 1 mole of ammonia (b) 1 mole of nitric acid (c) 2 moles of nitric acid (d) 2 moles of ammonia

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 Anjana Chemistry Classes SCO-41, Top floor Sec 20 C, Chandigarh ,Contact: 0172-2925111, 9464010111

Q15. How many mole of KI are required to produce 0.4 moles of K2HgI4? KI  HgI 2  K 2 HgI 4

(a) 0.4 (b) 0.8 (c) 3.2 (d) 1.6

Q16. One mole of calcium phosphide on reaction with excess of water gives Ca3P2 + H2O  Ca(OH)2 + PH3
(a) one mole of phosphine (b) two moles of phosphoric acid
(c) two moles of phosphine (d) one mole of phosphorus pentoxide
Q17. In the reaction, 2Al(s) + 6HCl(aq)  2 Al3+ (aq) + 6 Cl (aq) + 3 H2(g)
(a) 11.2 L H2 (g) at STP is produced for every mole HCl (aq) consumed
(b) 6 L HCl (aq) is consumed for every 3 L H2 (g) produced
(c) 33.6 L H2 (g) is produced regardless of temperature and pressure for every mole of Al that reacts
(d) 67.2 L H2(g) is at STP is produced for every mole of Al that reacts
Q18. If 30 mL of H2 and 20 mL of O2 react to form water, what is left at the end of the experiment?
(a) 10 mL of H2 (b) 5 mL of H2 (c) 10 mL of O2 (d) 5 mL of O2
Q19. How many moles of lead (II) chloride are formed from a reaction between 6.5 g of PbO and 3.2 g of HCl?
(a) 0.011 (b) 0.029 (c) 0.044 (d) 0.333
Q20. 10 g of hydrogen and 64 g of oxygen were filled in a steel vessel and exploded. Amount of water produced
in the reaction will be:
(a) 3 mol (b) 4 mol (c) 1 mol (d) 2 mol
Q21. When 22.4 litres of H2(g) is mixed with 11.2 litres of Cl2 (g), each of S.T.P., the moles of HCl (g) formed in
equal to:
(a) 0.5 mol of HCl (b) 1.5 mol of HCl(g) (c) 1.0 mol of HCl (d) 2.0 mol of HCl (g)
Q22. 1 g of Mg is burnt in a closed vessel containing 0.5 g of O2. Which of the following statements is correct?
(a) O2 is the limiting reagent and Mg is in excess by 0.25 g
(b) Mg is the limiting reagent and is in excess by 0.5 g
(c) O2 is the limiting reagent and is in excess by 0.25 g
(d) O2 is the limiting reagent and Mg is in excess by 0.75 g
Q23. 10 lit of O2 gas is reacted with 10 litres of CO at STP.The volume of each gas present at the end reaction are
(a) O2 = 5 litres, CO2 = 10 litres (b) O2 = 10 litres, CO = 30 litres
(c) CO = 20 litres, CO2 = 10 litres (d) O2 = 10 litres, CO2 = 20 litres
Q24. In Haber’s process, 30 litre of dihydrogen and 30 litres of dinitrogen were taken for reaction which yielded
only 50% of the expected product. What will be the composition of the gaseous mixture under the
aforesaid conditions in the end?
(a) 20 litres, ammonia, 20 litres nitrogen, 20 litres hydrogen
(b) 10 litres ammonia, 25 litres nitrogen, 15 litres hydrogen
(c) 20 litres ammonia, 10 litres nitrogen, 30 litres hydrogen
(d) 20 litres ammonia, 25 litres nitrogen, 15 litres hydrogen
Q25. 12 L of H2 and 11.2 L of Cl2 are mixed and exploded. The composition by volume of mixture is
(a) 24 L of HCl (b) 0.8 L Cl2 and 20.8 L HCl
(c) 0.8 L H2, 22.4 L, HCl (d) 22.4 L HCl

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 Anjana Chemistry Classes SCO-41, Top floor Sec 20 C, Chandigarh ,Contact: 0172-2925111, 9464010111

Q26. When 22.4 L of C4H8 at STP is burnt completely, 89.6 L of CO2 gas at STP and 72 g of water are produced.
The volume of oxygen gas at STP consumed in the reaction is closest to
(a) 89.6 L (b) 112 L (c) 134.4 L (d) 22.4 L
Q27. In the reaction 4A + 2B + 3C  A4B2C3, what will be the number of moles of product formed, starting from
one mole of A, 0.6 mole of B and 0.72 mole of C?
(a) 0.25 (b) 0.30 (c) 0.24 (d) 2.32
Q28. 30 g of Magnesium and 30 g of oxygen are reacted, then the residual mixture contains
(a) 60 g of Magnesium oxide only (b) 40 g of Magnesium oxide and 20 g of oxygen
(c) 45 g of Magnesium oxide and 15 g of oxygen (d) 50 g of Magnesium oxide and 10 g of oxygen
Q29. 20 mL of acetic acid reacts with 20 mL of ethyl alcohol to form ethyl acetate. The density of acid and
alcohol are 1 g/mL and 0.7 g/mL respectively. The limiting reagent in this reaction is
(a) Acetic acid (b) Ethyl alcohol
(c) Acetic acid and ethyl alcohol (d) Ester
Q30. How much of Fe can be theoretically obtained by the reduction of 1kg of Fe2O3 ? (Fe = 55.8)
(a) 697.5 gm (b) 600 gm (c) 69.75 gm (d) 6975 gm
Q31. How many moles of methane are required to produce 22 g CO2 (g) after combustion?
(a) 1 mole (b) 0.5 moles (c) 1.5 moles (d) 0.05 moles
Q32. 100 mL of M/5 HCl was added to 1 g of pure CaCO3. What would remain after the reaction?
(a) 0.5 g of CaCO3 (b) neither CaCO3 nor HCl (c) 50 mL of HCl (d) 25 mL of HCl
Q33. 1.0 g of pure calcium carbonate was found to require 50 mL of dilute HCl for complete reaction. The
strength of HCl solution is given by
(a) 4 M (b) 2 M (c) 0.4 M (d) 0.2 M

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 DPP – 7 SOME BASIC CONCEPTS OF CHEMISTRY

SUBJECTIVE CLASS: XI

Q1. Express What mass of silver nitrate will react with 5.85 g of sodium chloride to produce 14.35 g of silver
chloride and 8.5 g of sodium nitrate. If the law of conservation of mass is true?

Q2. 6.488 g lead combines directly with 1.002 g of oxygen to form lead dioxide (PbO2). Lead dioxide is also
produced by heating lead nitrate and it was found that the percentage of oxygen present in lead dioxide is
13.38 percent. Use these data to illustrate the law of constant composition.
Q3. Two oxides of nitrogen contain the following percentage composition:
(i) Oxide A contain 63.64% nitrogen and 36.36% oxygen.
(ii) Oxide B contains 46.67%nitrogen and 53.33% oxygen. Establish the law of multiple proportions.
Q4. A welding fuel gas contains carbon and hydrogen only. Burning a small sample of it in oxygen gives 3.38
g carbon dioxide, 0.690 g of water and no other products. A volume of 10.0 L (measured at STP) of this
welding gas is found to weigh 11.6 g.Calculate (i) empirical formula, (ii) molar mass of the gas and (iii)
molecular formula.
OBJECTIVE
Q1. 6 g of carbon combines with 32 g of sulphur to form CS2. 12 g of C also combine with 32 g of oxygen to
form carbon dioxide. 10 g of sulphur combines with 10 g of oxygen to form sulphur dioxide. Which law is
illustrated by them?
(a) Law of multiple proportion (b) Law of constant composition
(c) Law of reciprocal proportions (d) Gay Lussac’s law
Q2. Which of the following data illustrates the law of conservation of mass?
(a) 56 g of CO reacts with 32 g of oxygen to produce 44 g of CO2
(b) 1.70 g of AgNO3 reacts with 100 mL of 0.1 MHCl to produce 1.435 g of AgCl and 0.63 g of HNO3
(c) 12 g of C is heated in vacuum and on cooling there is no change in mass
(d) None of the above
Q3. If law of conservation of mass was to hold true, then 20.8 g of BaCl2 on reaction with 9.8 g of H2SO4 will
produce 7.3 g of HCl and BaSO4 equal to
(a) 11.65 g (b) 23.3 g (c) 25.5 g (d) 30.6 g
Q4. 1.5g of hydrocarbon on combustion in excess of oxygen produces 4.4g CO2 & 2.7g H2O,the data illustrates
(a) Law of conservation of mass (b) Law of multiple proportion
(c) Law of constant composition (d) Law of reciprocal proportions
Q5. The law of multiple proportions is illustrated by
(a) carbon monoxide and carbon dioxide (b) potassium bromide and potassium chloride
(c) water and heavy water (d) calcium hydroxide and barium hydroxide
Q6. Hydrogen and oxygen combine to form H2O2 and H2O containing 5.93% & 11.2% hydrogen respectively.
The data illustrates
(a) Law of conservation of mass (b) Law of constant proportions
(c) Law of reciprocal proportions (d) Law of multiple proportions

1
 Anjana Chemistry Classes SCO-41, Top floor Sec 20 C, Chandigarh ,Contact: 0172-2925111, 9464010111
Q7. Two elements X (at. Mass 16) and Y (at. Mass 14) combine to form compounds A, B and C. The ratio of
different masses of Y which combine with a fixed mass of X in A, B and C is 1 : 3 : 5. If 32 parts by mass of
X combines with 84 parts by mass of Y in B, then in C 16 parts by mass of X will combine with
(a) 14 parts by mass of Y (b) 42 parts of mass of Y (c) 70 parts by mass of Y (d) 84 parts by mass of Y
Q8. Which one of the following pair of substances illustrates law of multiple proportions?
(a) CO, CO2 (b) NaCl, NaBr (c) H2O, D2O (d) MgO,Mg(OH)2
Q9. One of the following combinations which illustrates the law of reciprocal proportions?
(a) N2O3, N2O4, N2O3 (b) NaCl, NaBr, NaI (c) CS2, CO2, SO2 (d) PH3, P2O3, P2O5
Q10. Law of multiple proportions is illustrated by one of the following pairs.
(a) H2S and SO2 (b) NH3 and NO2 (c) Na2S and Na2O (d) N2O and NO
Q11. How much mass of silver nitrate will react with 5.85 g of sodium chloride to produce 14.35 g of silver
chloride and 8.5 g of sodium nitrate if law of conservation of mass is followed?
(a) 22.85 g (b) 108 g (c) 17.0 g (d) 28.70 g
Q12. In an experiment, 2.4 g of iron oxide on reduction with hydrogen gave 1.68 g of iron. In another
experiment, 2.9 g of iron oxide gave 2.09 g of iron on reduction. Which law is illustrated from above data?
(a) Law of constant proportions (b) Law of multiple proportions
(c) Law of reciprocal proportions (d) Law of conservation of mass