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Lab: Thermal Energy Transfer
Pre-Lab Information
Purpose          Explore the process of thermal energy transfer using a laboratory procedure.
Time               Approximately 45 minutes
Question         How do mass and type of material affect thermal energy transfer?
Hypothesis #1 Different masses will change temperature at different rates when exposed to the same
                    amount of thermal energy. This is because the amount of mass affects an object’s ability
                    to absorb thermal energy.
Variables          Independent Variable: mass of the substance
                   Dependent Variable: amount of heat absorbed
                   Controlled Factors: type of substance, initial temperature
Hypothesis #2 Different materials will change temperature at different rates when exposed to the same
                    amount of thermal energy. This is because each substance has its own specific heat.
Variables          Independent Variable: type of substance
                   Dependent Variable: amount of heat absorbed
                   Controlled Factors: mass, initial temperature
Summary         
                    In Part I of the experiment, students will determine how changing the mass of a given material affects
                    thermal energy transfer by observing the amount of heat absorbed, as indicated by a temperature
                    change. Students will also compare how different materials transfer and absorb thermal energy, and
                    provide qualitative observations on their experimental results.
                    In Part II, students will explore how different materials of the same mass, such as aluminum, steel, and
                    lead, transfer different amounts of thermal energy. Then, the specific heat capacities of these three
                    substances will be calculated and compared, using the equation below.
Safety
   ● Always wear a lab coat, gloves, and safety goggles when performing an experiment. Wearing gloves is very
       important when handling metal samples, especially lead if used.
   ● Behavior in the lab needs to be purposeful. Use caution when heating and cooling substances.
   ● Use the right gear, such as tongs and thermal mitts, to handle hot objects.
   ● Check glassware, such as beakers and flasks, for cracks and chips prior to use.
   ● Report all accidents—no matter how big or small—to your teacher.
Lab Procedure
Step 1: Gather Materials
    ● 300 g of dry sand                              ● Pencils
    ● 300 g of wet sand, drained                     ● Stir sticks
    ● Tap water (room temperature)                   ● 500 mL beaker
    ● Utility knife                                  ● 1 L beaker
    ● 9 foam coffee cups (16 oz.)                    ●   50 g of aluminum wire
    ● Mass balance                                   ●   50 g of steel wire
    ●   3 thermometers                               ●   50 g of lead pellets
    ●   1 or 2 120W heat lamps                       ●   Wire cutters
    ●   Timer (or clock)                             ●   Tongs
    ●   Hot plate                                    ●   Long-handled strainer or spoon
PART I: Examining the Effect of Material and Mass on Thermal Energy Transfer
Step 2: Set up samples to examine thermal energy transfer with varying material and mass.
            a) Trim off the bottom half of three foam cups. Place an empty trimmed cup on the mass balance and tare
            for zero. Add water to the cup until the total mass reads 200 g. Repeat for the other two cups, filling one with
            200 g of wet sand and one with 200 g of dry sand.
            b) Trim three more foam cups to half size. Place an empty trimmed cup on the mass balance and tare for
            zero. Add water to the cup until the total mass reads 100 g. Repeat for the other two cups, filling one with
            100 g of wet sand and one with 100 g of dry sand.
            c) The three material types should be room temperature, but place a thermometer in each cup, allow the
            reading to stabilize. Record an initial temperature for each type of material in Table A.
            d) Place the cups under the heat lamp(s). If using one heat lamp, put the six cups in a tight circle, each
            equidistant from the lamp. The lamp bulb should be positioned over the cups at a height of 10 cm from the
            materials. If using two lamps, place three cups under each.
            e) Turn on your heat lamp(s). Start a timer or note the time on a clock. From this point, let the samples set
            for approximately 25 minutes. Time can vary slightly as needed to complete other steps of the lab.
            f) Make a hypothesis about which set of sample mass, the 200 g or 100 g, will heat up the fastest. Also
            make a hypothesis about which type of material will heat up the fastest. Record these guesses in Table A.
            You may continue with Part II until it is time to check these samples.
 Step 3: Measure the change in temperature for different materials and mass.
            a) After the time has elapsed, record the actual elapsed time in the Tfinal column in Table A. Remove the
            three cups that have samples of 100 g. Stir each sample gently to mix them, then place a thermometer in
            each cup and observe the readings until they do not climb any higher. Record the final temperature value for
            each cup in Table A.
            b) Repeat Step 3a for the 200 g samples. Record all data in Table A, and calculate the temperature change,
            ΔT, for each sample. In your observations, include qualitative descriptions of the heat gained by water, wet
            sand, and dry sand that you have made by touching the materials to assess their thermal energy.
PART II: Examining the Effect of Material Type on Thermal Energy Transfer and Specific Heat
         Be sure to wear protective gloves when handling all metal samples!
Step 4: Establish an initial temperature of the metal samples.
            a) Measure out 500 mL of tap water in the 1 L beaker and bring it to a boil using a hot plate or other heating
            source.
            b) Measure out approximately 50 g of aluminum wire using a mass balance. Coil the wire slightly to facilitate
            measurement, if needed, and carefully trim the sample down to 50 g. Record the exact mass in Table B.
            c) Coil the wire around a pencil or other object, or fold the wire tightly to create a more compact mass. Use
            tongs to carefully place the sample in the hot water bath.
            d) Repeat Steps 4b–c for 50 g of the steel wire.
            e) Measure out approximately 50 g of lead pellets, record the exact mass in Table B, and place the pellets in
            the strainer. Place the strainer and lead in the hot water bath.
            f) Allow the metal samples to reach thermal equilibrium with the boiling water over the next 5 minutes, while
            you prepare the calorimeter in the next steps.
Step 5: Assemble a “coffee cup” calorimeter.
            a) Place one foam coffee cup inside the other.
            b) With a third cup, trim off the upper ¼ of the cup and discard it. Invert the trimmed cup to make a lid, and
            check for a snug fit within the other two cups. Punch a small hole in the center of the lid to hold the
            thermometer. Place the thermometer in the hole, and then remove the lid with the thermometer.
Step 6: Measure the mass of the water in the calorimeter.
            a) Place the calorimeter (no lid) on the balance and tare the balance. Using a 500 mL beaker with 300 mL of
            room temperature, add water to the calorimeter until you read 300 g of mass. Record the exact mass in
            Table B in the row for aluminum, as this will be the first sample.
Step 7: Reassemble the calorimeter and position the thermometer.
            a) Place the lid on the calorimeter, and insert the thermometer. If needed, place the calorimeter into a beaker
            or other secondary container to prevent wobbling.
            b) Swirl the thermometer slightly, and confirm that the thermometer is well within the water. Allow the
            temperature to stabilize, and record this initial temperature to the nearest 0.1°C in Table B.
 Step 8: Transfer metal samples to the calorimeter and measure the temperature change.
            a) Use a thermometer to check the hot water bath temperature, which should be near 100°C if the water
            bath is boiling. The temperature of the metals should have reached the same temperature. Record this initial
            temperature for the three metal samples in Table B.
            b) Raise the thermometer and lid off the calorimeter, and carefully transfer the bundle of heated aluminum
            wire from the hot water to the calorimeter using the tongs. Try to let any excess water drip off the wire
            sample, but make the transfer quickly so the metal does not begin to cool. Close the lid snugly and make
            sure the thermometer is immersed in the water.
            c) Observe the increase in temperature every 20 seconds for 3 minutes, or until the bundle of wire and water
            reach an equilibrium temperature (the water temperature stops increasing). Record the equilibrium
            temperature in Table B.
            d) Remove the aluminum wire sample and empty the calorimeter. Repeat Steps 6–8d for the bundle of steel
            wire.
            e) Remove the steel wire sample and empty the calorimeter. Repeat Steps 6–8d for the lead pellets, and
            briefly allow the excess water to drain from the pellets and strainer before dumping the sample into the
            calorimeter.
Step 9: Compute the specific heat of each type of metal.
            a) Using your data in Table B, calculate ∆Twater and ∆Tmetal, using Teq and Ti for each metal and the
            calorimeter water.
            b) Use your data, the equation below, and the specific heat of water (4.184 J/g°C) to compute the specific
            heat values of each type of metal sample. Use a calculator, and round to the nearest hundredth place.
            When solving for the specific heat of each metal (), is the specific heat of water, is the mass
            of the water in the cup, and is the increase in temperature of the water; whereas refers to
             the mass of the metal and is the decrease in temperature of the metal.
            c) Table C lists some known reference values for the specific heat of various materials. How do your
            determined values compare? What factors could cause them to differ? Keep these questions in mind when
            you start to write your lab report.
 Step 10: Check for errors.
            a) Now that you have calculated specific heat values for the metals, see how far off the values are from
            known values. Use data from Tables B and C to calculate the error, as a percent, for each metal sample. Use
            the formula:
            where is your value from Table B, and is the value from Table C. Report the error for each metal as a
            percent, next to the known value in Table C.
 Step 11: Dispose of all materials according to your teacher’s directions.
 Data
Record your data in your lab notebook or in the space below.
Table A: The Effect of Mass or Material Type on Thermal Energy Transfer
        Material                      Mass                      Tinitial                        Tfinal                        ΔT
                                       (g)                       0 min                        _____ min
           Water                      200               5                        10                              8
           Water                      100               5                        10                              8
        Wet sand                      200               5                        10                              8
        Wet sand                      100               5                        10                              8
        Dry sand                      200               5                        10                              8
        Dry sand                      100               5                        10                              8
 Which samples will heat up faster? choose one
            100 g (least massive)          200 g (most massive)              No Difference
 Explain your reasoning:
 Less mass in object.
 Which samples will heat up faster? choose one
                    Water            Wet Sand                 Dry Sand                     No Difference
 Explain your reasoning:
 Liquids heat up reasonably faster than the solids.
Table B: Calculation of Specific Heat
 Material         Mass    Mass of      Ti(Metal)    Ti(Water)            Teq     ∆Twater             ∆Tmetal         Cwater        Cmetal
                    of    Water (g)
                                                                                 (Teq–Ti             (Teq–Ti
                  Metal
                   (g)                  (oC)            (oC)             (oC)     (water))            (metal))
                                                                                                                     J/g°C         J/g°C
                                                                                      (oC)               (oC)
 Aluminum     50          300         100          17.8           20.4          2.6                -79.6         4.18          0.82
    wire
   Steel      50          300         100          18.5           20            1.5                -80           4.18          0.46
   wire
   Lead       50          300         100          18             18.8          0.8                -81.2         4.18          0.25
Formula for the last column of Table B.
Table C: Known Specific Heat Values for Common Materials
                Material                   Specific Heat (J/g*C)           % Error
                                                                   (deviation from known)
                 Water                             4.18                    0.446
               Concrete                            0.88                     0.21
                 Wood                              1.80                    0.573
              Aluminum                             0.90                    0.214
                 Glass                             0.84                     0.16
                 Sand                              0.83                    0.198
                 Steel                             0.49                    0.117
                  Iron                             0.44                    0.107
                Copper                             0.38                    0.092
                 Lead                              0.16                    0.124
                 Gold                              0.13                    0.134
Percent Error Formula