SAFETY DATA SHEET
Printing Date:31.05.2021 Date:31.05.2021
SECTION I. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name ARALDITE AW 106 IN
Product description Epoxy resin
Product use Epoxy resin base to use with hardener
Manufacturer/supplier PIDILITE ADHESIVES PRIVATE LIMITED
(Formerly known as Huntsman Advanced Materials Solutions Private Limited),
Ramkrishna Mandir Road,
Kondivita, Off: M. Vasanji Road, P.O. Box 17411,
Andheri (East), Mumbai – 400059
Email: pilmsds@pidilite.co.in
Telephone: +91-22-2835 7000 Fax: +91-22-2821 6007
SECTION II- IDENTIFICATION OF HAZARDS
Classification according to GHS
Eye irritation (Cat.2); Skin irritation (Cat.2); Skin sensitization (Cat.1); Chronic aquatic toxicity (Cat. 2)
Hazard Labeling:
Signal word: WARNING
Hazard statement(s):
H315: Causes skin irritation
H317: May cause an allergic skin reaction
H319: Causes serious eye irritation
H411: Toxic to aquatic life with long lasting effects
Precautionary statement(s):
Prevention:
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/ eye protection/ face protection.
(Contd. on page 2)
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Response:
P302 + P352 IF ON SKIN: Wash with plenty of water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention.
P337 + P313 If eye irritation persists: Get medical advice/ attention.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P391 Collect spillage.
Storage:
Not available
Disposal:
P501 Dispose of contents/container to an approved facility in accordance with local, regional, national and
international regulations.
SECTION III – COMPOSITION/ INFORMATION ON INGREDIENTS
Chemical characterization: Mixture
Chemical name CAS-No. Concentration (% w/w)
2,2'-[(1-methylethylidene)bis(4,1- 1675-54-3 >= 70 - < 90
phenyleneoxymethylene)]bisoxirane
bisphenol A - epoxy resins, number average MW 25068-38-6 >= 1 - < 10
>700 - <1100
Phenol, 4,4'-(1-methylethylidene)bis-, polymer 25036-25-3 >= 1 - < 10
with 2,2'-[(1-methylethylidene)bis(4,1-
phenyleneoxymethylene)]bis[oxirane]
Both 25068-38-6 and 1675-54-3 can be used to describe the epoxy resin which is produced through the reaction
of bisphenol A and epichlorohydrin
SECTION IV- FIRST AID MEASURES
Skin contact: Flush skin with soap & water. Remove contaminated cloths. Wash contaminated cloths
before reuse Seek medical help if required
Eye contact: Immediately flush eyes with plenty of water for at least 15 minutes. Consult Physician if
irritation persists.
Inhalation: Move the subject to fresh air. If not breathing, give artificial respiration. If respiration is
difficult, give Oxygen and seek help from Physician.
Ingestion: Immediately give two glasses of water to drink. Do not induce vomiting. Never give
anything by mouth to an unconscious person. Seek medical help.
Note to physician: There is no specific antidote. Treatment should be given symptomatically on the clinical
conditions.
(Contd. on page 3)
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SECTION V - FIRE-FIGHTING MEASURES
Product does not present fire or explosion hazard.
Fire extinguishing media: Use extinguishing media appropriate for surrounding fire.
Special fire fighting procedure: As in any fire, wear self-contained breathing apparatus pressure-
demand, MSHA/NIOSH (approved or equivalent) and full protective
gear.
Unusual fire and explosion hazards: May generate toxic or irritating combustion products
SECTION VI - ACCIDENTAL RELEASE MEASURES
Personal precautions: Avoid contact with the skin and the eyes. See sections VII & VIII for personal
protective equipment & handling.
Environment precautions: Do not allow material to contaminate ground water system. Do not flush into
surface water or sanitary sewer system. Collect the spilled material by sweeping
the floor in a paper and dispose off in accordance with the local regulations.
Cleaning methods: Wash floor with water after collecting the material.
SECTION VII- HANDLING AND STORAGE
Precautions for safe handling: Use only in well ventilated areas. Avoid contact with the skin and the eyes.
Wash hands before breaks and at the end of workday. When using, do not
eat, drink or smoke.
Conditions for safe storage, Store in cool place. Keep containers tightly closed in a dry and well- ventilated
including any incompatibilities: place.
SECTION VIII- EXPOSURE CONTROL/ PERSONAL PROTECTIVE EQUIPMENT
Ventilation: Local exhaust ventilation and/or mechanical (general) exhaust are recommended.
General protective and hygienic measures:
Respiration protection: Maintain good ventilation in the area. Suggested MSHA/NIOSH approved respirator
where vapors concentrations is more
Personal protective equipment:
Skin and body protection :
Impervious clothing
Choose body protection according to the amount and concentration of the dangerous substance at the work
place.
(Contd. on page 4)
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Protection of hands:
Protective gloves
Material : butyl-rubber
Break through time : > 8 h
Material : Solvent-resistant gloves (butyl-rubber)
Material : Nitrile rubber
Material : Neoprene gloves
Material : PVC
Remarks: The suitability for a specific workplace should be discussed with the producers of the protective gloves
Eye Protection
Eye wash bottle with pure water
Tightly fitting safety goggles
Wear face-shield and protective suit for abnormal processing problems.
Hygiene measures :
When using do not eat or drink.
When using do not smoke.
Wash hands before breaks and at the end of workday.
SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES
Appearance: paste Colour: white, opaque
Odour: slight pH: ca. 6 (20 °C), Concentration: 500 g/l
Boiling point: > 200 °C Flash point : > 200 °C, closed cup
Vapour pressure : < 0.0001 hPa (25 °C) Density : 1.2 g/cm3 (25 °C)
Auto-ignition temperature : does not ignite Decomposition temperature : > 200 °C
Viscosity : 30,000 - 50,000 mPa.s ( 25 °C) Water Solubility: Practically insoluble @ 20°C
SECTION X - STABILITY AND REACTIVITY DATA
Reactivity: No dangerous reaction known under conditions of normal use.
Chemical stability: Stable under normal conditions.
Possibility of hazardous reactions: No hazards to be specially mentioned.
Conditions to avoid : None known.
Incompatible materials : None known.
Hazardous decomposition products: No dangerous decomposition products known.
(Contd. on page 5)
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SECTION XI - TOXICOLOGICAL INFORMATION
Acute toxicity
Acute oral toxicity - Product : LD50(Rat): > 5,000 mg/kg
Acute inhalation toxicity : No data available
Potential health effects
On the skin: Toxic by skin absorption. Not expected to be irritating. May cause allergic skin reaction with
symptoms of reddening, itching, swelling, and rash.
On the eye: Causes serious eye irritation
Inhalation: May be harmful if inhaled. Causes respiratory tract irritation
Sensitization: No data available
CMR Effects: The product has not been tested for CMR effects
STOT - single exposure: No data available
STOT - repeated exposure:No data available
Additional toxicological information:
When used and handled according to specifications, the product does not have any harmful effects.
SECTION XII - ECOLOGICAL INFORMATION
Aquatic toxicity: Quantitative data on the ecological effect of this product are not available.
Persistence and degradability:
Biodegradability: According to the results of tests of biodegradability this product is not readily biodegradable.
Behaviour in environmental systems:
Bioaccumulative potential: No further relevant information available.
Mobility in soil: No further relevant information available.
Results of PBT and vPvB assessment: No information is available
Other adverse effects: No further relevant information available.
Suggested not to allow to enter soil, waterways and open bodies of water. Resin used is toxic to aquatic
organisms, may cause long-term adverse effects in the aquatic environment.
(Contd. on page 6)
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SECTION XIII - DISPOSAL INFORMATION
Waste from Residues / Unused Products:
The product should not be allowed to enter drainages or water courses or the soil.
Do not contaminate ponds, waterways or ditches with chemical or used container.
Send to a licensed waste management company.
Dispose of as hazardous waste in compliance with local and national regulations.
Dispose of contents/ container to an approved waste disposal plant.
Contaminated Packaging:
Empty containers should be taken to local recyclers for disposal
SECTION XIV - TRANSPORTATION INFORMATION
IATA
UN/ID No. : UN 3082
Proper shipping name : Environmentally hazardous substance, liquid, n.o.s.UN-Number
(BISPHENOL A EPOXY RESIN)
Class : 9
Packing group : III
Labels : Class 9 - Miscellaneous dangerous substances and articles
Packing instruction (cargo aircraft): 964
Packing instruction (passenger aircraft): 964
Environmentally hazardous : yes
IMDG
UN number : UN 3082
Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(BISPHENOL A EPOXY RESIN)
Class : 9
Packing group : III
Labels : 9
EmS Code : F-A, S-F
Marine pollutant : yes
Transport in bulk according to IMO instruments: Not applicable for product as supplied.
Special precautions for user:
The transport classification(s) provided herein are for informational purposes only, and solely based upon the
properties of the unpackaged material as it is described within this Safety Data Sheet. Transportation
classifications may vary by mode of transportation, package sizes, and variations in regional or country
regulations.
SECTION XV - REGULATORY INFORMATION
Safety, health and environmental regulations/legislation specific for the substance or
mixture
The components of this product are reported in the following inventories:
AICS (Australia), Canada (DSL), New Zealand (NZIoC), Japan (ENCS), Korea (KECI), PICCS (Philippines),
TSCA (US), Switzerland (CH Inv),
Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
(Contd. on page 6)
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SECTION XVI - MISCELLANEOUS INFORMATION
DISCLAIMER:
The data presented here is based on information we believe to be reliable but unknown risks may be present.We
disclaim liability for damage or injury which results from the use of the above data and nothing contained therein
shall constitute a guarantee or a warranty (including warranty of Merchantability or fitness for a particular
purpose) or representation (including freedom from Patentability) by us with respect to the accuracy or
completeness of the data, the product described or their use for any specific purpose as known to us. The final
determination of the suitability of information, the manner of use of information or product and potential
infringement of patents is the sole responsibility of the user.
Hazards, toxicity and behaviour of the products may differ when used with other materials and are dependent
upon the manufacturing circumstances or other processes. Such hazards, toxicity and behaviour should be
determined by the user and made known to handlers, processors and end users.
NO PERSON OR ORGANIZATION EXCEPT A DULY AUTHORIZED PIDILITE EMPLOYEE IS AUTHORIZED
TO PROVIDE OR MAKE AVAILABLE DATA SHEETS FOR PIDILITE PRODUCTS. DATA SHEETS FROM
UNAUTHORIZED SOURCES MAY CONTAIN INFORMATION THAT IS NO LONGER CURRENT OR
ACCURATE.
ABBREVIATIONS USED: NA - NOT APPLICABLE, NH - NON HAZARDOUS,
CI - CONTENT INSIGNIFICANT.
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