NEB CRASHCOURSE
Clamphook
CSL Sir
organic chemistry Santosh Lamichhane
halide
Alyl
X
RH
Akane
H
Ring I havde Haloalkane
y F, C1, Br, I
EN F Cl Br I F
EN
Br
electronegative
most
I element
I
Most Reactive non metal
& Super haugen is
a. Fluorine b. chlorine C. Bromine d. Iodine
9. Write method ofpreparation of halide. How would
any,
two
convert
any into and rice
you
chloropropane chloropropane e
verya.
the term ambidentnucleophile.
Define
2211
preparation ofany/havide zuce
RO4 Mc
1 From alcohol Acty as dehydrating agent
RC1
anny.
Ince
RC1 Groove's Reaction
HCIg new
·
Groove's Reagent..any zncle Mag
Note
Lucas Reagent: equimolar mixture ofany. Incle & conceal
RON
PC15
Aconol RCI POC HC
PC13 the
Best method
·
RC HyPog for prepa
ofRC.
SOCI2 RC1 SO2 HCI Dazzen's Reaction
pyridine e
Cageous platest can be
easilyescaped out
11 From alkene
CH2 CH2 HBr
CHICHeBr
Markonica's Rule
Chy CH CH2 MBr
CHICH CH3
Br
2-bromopropane
Anto Marmonicar's Rule
peroxide
Cy CH
CH2 MB
Cy CH2CH2
Br
I
bromopropane
conversion
into
I
chosopropane 2
chloropropane
[Link] *
CH3 CH2 CH2CI Cy CH
CH2 E on
cy
RCI
Cl
I
chloropropane 20
2
chloropropane
into
2
chloropropane a
chloropropane
oxide
almon
CHE C4
cy cy
CH CHe Me MeBr
XCI
Cl
H20 ->
kB
ag. KOH
2
chloropropane SOCI2
CHICHI CHCH2H
pyridineSO2
1.
chloropropane HC
Ambidentnucleophile.
[Link] RNC Nucleophiles which can attack through
R Y Ally/iso cyanide two
differen sites are called ambident
alc. KCN
RCN
nucleophiles.
Alnylcyanide
Methyl alcohol one investigemozide
P45 [Link] dilc
CHOM CAC CCN cngcoon
LYAIK
PC15
Cycl CHICHEN
which
B: 1 chloroform is sweet smeling colourless liquid can be used as
anaesthetic how
reagent. Starting from chloroform
would
prepare
you
a.
ethy ne 5
b. tea
gas
C. Chlozetone
9.
Salicyaldehyde
e. methane and
methylene chloride
9.2 which ofthe following
gives positive iodogram test?
OH
CHON
O
[Link]
a. C
NH2
0
CHIC CHI CH
b. HCHO b.
CHg C Cl
C.
CHECHO [Link]
that
c OH
cHy
a.
CIGCHZON d.
All of
above
methy, retire
0 0 O
H
Cy Cly
C
C H CH
O
3
N
Note
CIECHON I2 NaOH ICOONG NaI 20
CHIg
9.1
Ans a
Cl Cl
↑C
sAg
Cl Cl C HC-CH
H
C Cl
onge Ethyne
Chlorogozm
Cl
Ans b
Cl C H NO NO2 CCNOz
Cl
CONC.
10 Chloropicsin tear
gap
was
gas
Ans C
Cy NaOH C On
0
CHC
C
C
Cy Cng CC
cetone chlozetone sleep inducing dang
A
Mypnotic
Ans d
OH OH
CHO
60 70
CHC [Link] Nach H20
Savingalowly
de
phenol
Anse zu H20
complete Reduction
CHK
[H]
CHCG Methane
zu Hal
Checle partial Reduction
Methylene chiazide
conversion
into and
chlorogorm saving
, dic
so on 07
- cool
CCI [Link]
samyclic acid
CHI COOH
CHEO4
alcohol
2
Metly into
puccinic acid CH2 COOH
SO14:
Little in
[Link]
dilal
cICN Ccoo
LAINK
or Na
32 O2
Cetzon CHICHON
170° conc.120K
Bre
CH2 CN [Link] CH2 Br
CH2 CHe
Br
CH2
ea Cry
dil. HCI
CH2 coon
CH2 COO4
succinic and
